Biological performance of wood-based composites treated with a formulation of 3-iodo-2-propynyl butylcarbamate and silafluofen using supercritical carbon dioxide

Wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard, and oriented strand board) treated with a mixture formulation of 3-iodo-2-propynyl butylcarbamate (IPBC) and silafluofen using supercritical carbon dioxide as a carrier solvent were evaluated for their resistance to biological attack in a laboratory study. The formulation was pre-pared by mixing 10g of IPBC and 1g of silafluofen in ethanol solution (20ml). Treatments were conducted at 35°C/7.85MPa, 35°C/9.81MPa, and 55°C/11.77MPa with the direct introduction of 20ml of the formulation into the treatment vessel with a capacity of ca. 2000ml at a rate of 2ml/min. Laboratory tests indicated that the treatment conditions used significantly enhanced the resistance of the treated wood-based composites against fungal and termite attacks. Because no significant difference in efficacy against both biodegrading agents was noticed regardless of the treatment conditions, the treatment at 35°C/7.85MPa was thought to be the most economical in terms of energy consumption and performance of treated materials. However, the amount of biocides in a formulation must be carefully selected in accordance with the required treatment condition to ensure satisfactory performance of the treated wood-based composites against any biological agent.     

Feasibility of supercritical carbon dioxide as a carrier solvent for preservative treatment of wood-based composites

 Supercritical carbon dioxide (SC-CO₂) was tested for its potential as a carrier solvent for preservative treatment of solid wood and wood-based composites. A preliminary trial showed that the treatability of solid wood varied with its original permeability and that the SC-CO₂ treatment was not promising for refractory timber species such a Larix leptolepis Gordon. In contrast, 3-iodo-2-propynyl butylcarbamate (IPBC)/SC-CO₂ treatment resulted in enhanced decay resistance without any detrimental physical or cosmetic damage in all structural-use wood-based composites tested: medium density fiberboard, hardwood plywood, softwood plywood, particleboard, and oriented strand board (OSB). Further trials under various treatment conditions [25°C/7.85 MPa (80 kgf/cm²), 35°C/7.85 MPa, 45°C/7.85 MPa, 35°C/11.77 MPa (120 kgf/cm²), and 45°C/11.77 MPa] indicated that although small changes in the weight and thickness of the treated materials were noted the strength properties were not adversely affected, except for a few cases of softwood plywood and oriented strand board. The results of this study clearly indicated that the treatment condition allowed SC-CO₂ to transport IPBC into wood-based composites, and the optimum treatment condition seemed to vary with the type of wood-based composite. Received: October 24, 2001 / Accepted: February 15, 2002 Part of this work was presented at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 2001; and the 32nd Annual Meeting of the International Research Group on Wood Preservation, Nara, May 2001 Correspondence to:M. Muin     

Rapid production of high-strength cement-bonded particleboard using gaseous or supercritical carbon dioxide

This study deals with the effects of curing treatment with gaseous and supercritical carbon dioxide on the properties of cement-bonded particleboard (CBP) manufactured by the conventional cold-pressing method. The hydration of cement and the mechanism of improvement were examined using X-ray diffractometry (XRD), thermal gravimetry (TG-DTG), and scanning electron microscopy (SEM) observations. The results are as follows: (1) The curing of cement was accelerated concomitantly with the improvement in mechanical and dimensional properties of CBP significantly by curing with gaseous or supercritical carbon dioxide. (2) Supercritical carbon dioxide curing imparted boards optimal properties at a faster rate than did gaseous curing. (3) Accelerated formation of calcium silicate hydrate and calcium carbonate and the interlocking of those hydration products on the wood surface are potentially the main reasons for the superior strength of carbon dioxide-cured boards.     

Photocatalytic activity of TiO<Subscript>2</Subscript> crystallite-activated carbon composites prepared in supercritical isopropanol for the decomposition of formaldehyde

 An effort was made to develop photocatalytic TiO₂ crystallite–activated carbon (TiO₂-AC) composites from tetraisopropyl titanate (TPT)-soaked activated carbon in supercritical isopropanol. It was subsequently found that TPT in supercritical isopropanol could be effectively converted to the anatase form of the TiO₂ crystallites. The prepared composites, composed of activated carbon as an adsorbent and the anatase form of TiO₂ as a photocatalyst, were evaluated for their adsorption capacity and subsequent photocatalytic activity against formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO₂–AC composites, particularly at 300°C and 350°C, had much higher formaldehyde-decomposing ability compared to a noncomposite comprising a simple mixture of activated carbon and TiO₂ granules. This indicates that the supercritical treatment can be effective for preparing the photocatalytic composites that have a high synergetic effect of adsorption and photocatalytic decomposition of formaldehyde for environmental cleaning. Received: May 18, 2001 / Accepted: March 8, 2002 On leave from Fujian Forestry College, Fujian 353001, P.R. China Acknowledgments The authors express their sincere thanks to Miss H. Tokoro and Mr. D. Kusdiana for their kind, valuable help and cooperation and to Dr. H. Miyafuji for SEM observations of samples, all at the Graduate School of Energy Science, Kyoto University. Correspondence to:S. Saka     

Cost, energy and carbon dioxide (CO2) effectiveness of a harvesting and transporting system for residual forest biomass

The purpose of this study is to examine the feasibility of a system to harvest logging residues (or slashes) as a new resource for energy in Japan. A harvesting and transporting system for residual forest biomass was constructed with reference to some European countries where the utilization of bioenergy is making steady progress and examined on the basis of field experiments in Japanese forestry. The feasibility of the system is discussed from the standpoints of cost and energy, and the system is compared with those of the European countries. With respect to the system proposed in this study, it is desirable that the process of chipper comminuting is incorporated into the system as early as possible, considering the trends of harvesting cost and fuel consumption per unit weight of residual forest biomass. Such a system is not particularly feasible in Japan from the standpoint of the harvesting cost per MWh of bioenergy. However, no specific problems are found from the point of view of the energy input rate, and it is clarified that it is possible for Japan to reduce domestic carbon dioxide emissions by utilizing biomass as an energy resource. A comparison with the European countries and a preliminary sensitivity analysis of the system demonstrate that the technical development to reduce the harvesting cost,e.g., improving the forwarding and transporting efficiency, and support from the government are essential for realizing bioenergy utilization in Japan. A part of this paper was orally presented at the 111th Annual Meeting of the Japanese Forestry Society (2000). JSPS Research Fellow. This study was supported in part by a Grant-in-Aid for Scientific Research from the Japan Ministry of Education, Science and Culture (No. 10460061).