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bamboo(Phyllostachys edulis) residue was subjected to steam explosion treatment to produce superior fibers for binderless boards.Then,lignin was isolated from extract-free bamboo meal,steam exploded pulp,and binderless boards with characteristics being determined by thermo-gravimetry (TG),differential scanning calorimetry (DSC),and fourier transform infrared spectroscopy (FTIR).Results showed that:1) the yield of lignin directly extracted with dioxane-water from steam exploded bamboo pulp(SEBPL) and binderless board (SEBBL) was higher than that of milled bamboo lignin (MBL).Also,the yield of SEBBL was lower than that of SEBPL.2) FTIR results showed cleavage of ester and ether bonds between lignin and p-coumaric acid during steam explosion treatment.3) SEBBL showed two glass transitions at 115℃and 200℃, while MBL gave one glass transitions at 155℃.And 4) the modulus of rupture(MOR) and modulus of elasticity(MOE) decreased with an increase in steaming time;whereas internal bonding(IB) increased.In all cases the dimensional stability of boards did not exceed the maximum requirements for type GB/T 11718- 1999. 相似文献
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Bamboo (Phyllostachys pubescens) internode was subjected to steam explosion treatment to produce an excellent fiber for binderless boards. Lignin was isolated from extract-free bamboo meal with Björkman’s procedure and steam-exploded pulp. The self binding-mechanism was discussed by scanning electron microscopy (SEM), thermo-gravimetry (TG), differential scanning calorimetry (DSC) and analytical ozonation. It is well-known that steam explosion treatment liberates lignin from the cell wall to the fiber surface, which is the most important component relevant to binderless board production. Results of TG and DSC analyses showed that steam-exploded bamboo pulp started mass loss at lower temperature compared to bamboo internode meal. The thermal softening temperature of lignin prepared from steam-exploded pulp was much lower than that of lignin prepared from extract-free bamboo meal. This suggests that intermonomer linkages of lignin, especially β-aryl-ether linkage which is the major intermonomer linkage of lignin, were cleaved during steam explosion treatment resulting in low molecular weight phenolic compounds. The cleavage of β-aryl-ether intermonomer linkage of lignin was also confirmed by ozonation analysis. 相似文献
4.
Abstract Binderless boards were prepared from kenaf core under various manufacturing conditions and their water resistance
properties were evaluated. The board properties evaluated were retention ratios of modulus of rupture (MOR) and modulus of
elasticity (MOE), internal bonding strength after water treatment (IB), thickness swelling (TS), water absorption (WA), and
linear expansion (LE). These values were then compared with those of boards bonded with urea-formaldehyde (UF), urea melamine
formaldehyde (UMF), and phenol-formaldehyde (PF) resins, and their water resistance properties were assessed. We found that
pressing temperature was one of the most important conditions for the improvement of water resistance properties. The retention
ratios of MOR, MOE, and IB of kenaf core chip binderless boards (pressing temperature 200°C, target density 0.8g/cm3, and the three-step pressing of 6MPa for 10min, then 4MPa for 3min, and 2MPa for 3min) were 37.1%, 49.9%, and 55.7%, respectively,
compared with values for UMF-bonded boards of 22.5%, 27.1%, and 40.7%, and values for PF-bonded boards of 42.8%, 41.8%, and
54.1%, respectively. The results showed that the water resistance properties of binderless boards were higher than those of
UMF-bonded boards and almost as high as those of PF-bonded boards.
Part of this article was presented at the 53rd Annual Meeting of the Japan Wood Research Society, Fukuoka, March 2003 相似文献
5.
Binderless particleboards were manufactured from sugi (Cryptomeria japonica D. Don) heartwood and sapwood by hot-pressing (pressure: 5 MPa; temperatures: 180°, 200°, and 220°C; times: 10, 20, and 30
min), and the board properties [internal bonding (IB), thickness swelling (TS), water absorption (WA)] were investigated to
evaluate the self-bonding ability. The IB, TS, and WA of the boards from sugi heartwood were better than those of the boards
from sugi sapwood at any hot-pressing condition. Therefore, it was suggested that the self-bonding ability of sugi heartwood
was superior to that of sugi sapwood. Then, sugi heartwood and sapwood powder with grain size 10 βm were used as a binder
for plywoods. Four kinds of plywood were manufactured from the combination of powder and veneer, both of which were prepared
from sugi heartwood and sapwood under the same hot-pressing conditions as the binderless particleboard, and the adhesive shear
strength and wood failure of the plywood were investigated. As a result, the plywood composed of sugi heartwood veneer met
the second grade of JAS for plywood, when either powder was used as a binder, when they were pressed at 200°C for 20–30 min
and 220°C for 10 min. 相似文献
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This study investigated the effects of mild steam treatment (0.1 MPa for 2 h) of natural bio-based fibers and orientation
(0° and 90°) of those fibers in various fiberboards. Ramie bast, pineapple leaf, and sansevieria fiber bundles were used as
materials. The composite fiberboards were prepared using phenol-formaldehyde (PF) resin. To investigate the effect of mild
steam treatment on wettability, contact angles of PF resin to the fiber were measured. The mechanical properties of the boards
were examined as well as their dimensional stability. The contact angle data showed that mild steam treatment was effective
in improving the wettability of fibers. Unioriented steam-treated boards showed better performance of internal bond (IB),
moduli of rupture (MOR) and elasticity (MOE), thickness swelling (TS), and water absorption (WA) than other boards. Unioriented
steam-treated sansevieria board with longitudinal fiber direction showed higher average values of MOR (403 MPa), MOE (39.2
GPa), and IB (1.33 MPa) and lower values of TS (5.15%) and WA (8.68%) than other boards. The differences in the mechanical
properties and dimensional stability of boards were found mainly due to the differences in the ratios of fiber fraction of
the boards to the density of the fiber bundles. 相似文献
7.
Self-bonding is the main factor of the performance expression of binderless boards, and therefore its clarification is considered
to be an important issue. For this purpose, a series of chemical analyses were conducted on kenaf core binderless boards and
their chemical changes during the hot-pressing process are discussed in this article. First of all, binderless boards were
prepared from kenaf core powder at different pressing temperatures (without steam-explosion process) and were used for chemical
analyses after they were reduced into powders and extracted with methanol. To investigate their chemical changes, lignin,
holocellulose, and neutral sugar contents were determined, Fourier transform infrared (FTIR) spectra were recorded, and the
nitrobenzene oxidation procedure was applied. As a result, it was found that parts of lignin and hemicelullose were decomposed
during the hot-pressing process; however, the contribution of the resulting fractions to selfbonding was not observed. In
addition, progress of condensation reactions in lignin and the formation of chemical bonds by low molecular weight conjugated
carbonyl compounds in methanol extractives were observed. Thermal softening of lignin is also suggested to play an important
role in the expression of board performance. 相似文献
8.
不同热压方法对无胶竹碎料板力学性能影响 总被引:1,自引:0,他引:1
分别采用普通热压和喷蒸热压两种热压方法制备了无胶竹碎料板,对它们的物理力学性能进行了对比研究与分析.结果表明,与普通热压法相比,喷蒸热压法制备的无胶竹碎料板的静曲强度、弹性模量与内结合强度明显提高,吸水厚度膨胀率显著减小,这可能是因为两种热压法热压过程中竹碎料发生的化学变化不同所致. 相似文献
9.
This paper describes the features of binderless particleboard manufactured from sugarcane bagasse, under a high pressing temperature of 200–280 °C. Mechanical properties [i.e., modulus of rupture (MOR) and elasticity (MOE) in dry and wet conditions, internal bonding strength (IB)] and dimensional stability [i.e., thickness swelling (TS)] of the board were evaluated to investigate the effect of high pressing temperature. Recycled chip binderless particleboards were manufactured under the same conditions for comparison, and particleboards bonded with polymeric methylene diphenyl diisocyanate (PMDI) resin were manufactured as reference material. The target density was 0.8 g/cm3 for all of the boards. The results showed that the mechanical properties and dimensional stability of both types of binderless boards were improved by increasing the pressing temperature. Bagasse showed better performance than that of recycled chip as a raw material in all evaluations. Bagasse binderless particleboard manufactured at 260 °C had an MOE value of 3.5 GPa, which was equivalent to the PMDI particleboard, and a lower TS value of 3.7 % than that of PMDI particleboard. The MOR retention ratio under the dry and wet conditions was 87.0 %, while the ratio for the PMDI particleboard was only 54.6 %. The obtained results showed the possibility of manufacturing high-durability binderless particleboard, with good dimensional stability and water resistance, which previously were points of weakness for binderless boards. Manufacturing binderless boards under high temperature was effective even when using particles with poor contact area, and it was possible to express acceptable properties to allow the manufacture of particleboards. Further chemical analysis indicated a contribution of a saccharide in the bagasse to the improvement of the board properties. 相似文献
10.
Jianying Xu Ragil Widyorini Hidefumi Yamauchi Shuichi Kawai 《Journal of Wood Science》2006,52(3):236-243
Binderless fiberboards with densities of 0.3 and 0.5 g/cm3 were developed from kenaf core material using the conventional dry-manufacturing process. The effects of steam pressure (0.4–0.8
MPa) and cooking time (10–30 min) in the refining process, fiber moisture content (MC) (10%, 30%), and hot-pressing time (3–10
min) on the board properties were investigated. The results showed that kenaf core binderless fiberboards manufactured with
high steam pressure and long cooking time during the refining process had high internal bond (IB) strength, low thickness
swelling (TS), but low bending strength values. The binderless fiberboards made from 30% MC fibers showed better mechanical
and dimensional properties than those from air-dried fibers. Hot-pressing time was found to have little effect on the IB value
of the binderless board at the refining conditions of 0.8 MPa/20 min, but longer pressing time resulted in lower TS. At a
density of 0.5 g/cm3, binderless fiberboard with the refining conditions of 0.8 MPa/20 min recorded a modulus of rupture (MOR) of 12 MPa, modulus
of elasticity (MOE) of 1.7 GPa, IB of 0.43 MPa, and 12% TS under the optimum board manufacturing conditions.
Part of this article was presented at the 54th Annual Meeting of the Japan Wood Research Society, Hokkaido, August 3–5, 2004 相似文献
11.
To provide basic information on self-bonding in kenaf core binderless boards, a series of chemical analyses was conducted
on binderless boards and their chemical changes during hot pressing were examined in our previous study. In this study, binderless
boards were manufactured under conditions that may accelerate the supposed chemical changes to investigate their effect on
the board properties. First, to investigate the influence of the chemical bonds formed by carbonyl compounds on self-bonding,
the influence of acetic acid addition prior to board manufacturing was studied and the effect of methanol extractives (containing
the carbonyl compounds) was also examined. Second, the influence of the condensation reaction in lignin was discussed from
the viewpoint of board density. Last, to examine the influence of thermal softening of lignin, the influences of temperature
condition and moisture content, as well as those of microwave pretreatment, were investigated. As a result, the estimated
chemical changes were suggested to influence the binderless board properties. 相似文献
12.
The objective of this study was to investigate the physical and mechanical performance of flakeboard reinforced with bamboo strips. The study investigated three different bamboo strip alignment patterns and an experimental control. All panels were tested in static bending both along parallel and perpendicular to the lengths of the bamboo strips. Internal bond strength (IB), thickness swelling (TS), linear expansion (LE), and water absorption (WA) were also examined. As expected, modulus of rupture (MOR) and modulus of elasticity (MOE) were substantially greater for all three experimental panel types as compared to the control group. LE was also improved for all three experimental panel groups. The bamboo strip alignment patterns had no significant effect on TS, WA and IB. The sample means for MOR, MOE and LE tested perpendicular to the bamboo strip lengths yielded slightly lower mean values than corresponding samples tested parallel to the bamboo strips lengths. This difference in mechanical properties is largely attributed to low panel density in the failure zones. 相似文献
13.
There is a growing desire to improve the properties and use of nonwood plant materials as supplements to wood materials for wood cement-bonded boards (WCBs). This study was conducted to determine the comparative properties of WCBs containing various amounts of discontinuous inorganic fiber materials, such as alkali-resistant glass fiber, normal glass fiber, mineral wool, and nonwood plant materials such as retted flax straw and wheat straw particles. Tested cement-bonded boards were made at wood/additive compositions of 100/0, 90/10, 80/20, 70/30, 60/40, and 50/50 (weight percentages). Seventy-eight laboratory-scale WCBs were produced. Various board properties, such as the modulus of rupture (MOR), internal bonding strength (IB), water absorption (WA), thickness swelling (TS), and linear expansion (LE), were studied. The test results showed that three types of discontinuous inorganic fiber used as reinforcing materials in composites significantly enhanced and modified the performance of WCBs. The mechanical properties and dimensional stability of cement-bonded board were significantly improved with increasing amounts of the additives. MOR and IB were increased; and WA, TS, and LE of boards were reduced by combination with the inorganic fiber materials. The results also indicated that combination with retted flax straw particles only slightly increased the MOR of boards, and wheat straw particles led to marked decreases in all the mechanical properties and the dimensional stability of WCBs.Part of this report was presented at the 50th Annual Meeting of the Japan Wood Research Society, Kyoto, April 2000 相似文献
14.
Ajaye Babatunde 《林业研究》2011,21(1):111-115
Cement-bonded particleboards of 6 mm in thickness were manufactured using maize stalk (Zea mays) particles of uniform sizes at three levels of board density and additive concentrations respectively. The bending strength and dimensional properties were assessed. Increase in board density and additive concentration caused increase in Modulus of rupture (MOR), Modulus of elasticity (MOE), and decrease in Thickness swelling (TS) and Water absorption (WA). The MOR, MOE and TS of the boards were significantly affected by board density except for WA, but additive concentration affected all the boards’ properties examined at p ≥ 0.05. Strong and dimensional stable cement-bonded boards could be manufactured from maize stalk particles with Portland cement as the binder after hot water treatment. Although the dimensional stability and mechanical strength properties of the boards were affected by the board density and additive concentration, the study revealed that cement-bonded particleboards could be manufactured from maize stalk (Zea mays) particles. However, the increase in board density and additive concentration could cause the increase in MOR and MOE, and cause the decrease in TS and WA of boards. 相似文献
15.
An outdoor exposure test was conducted on kenaf core binderless boards (pressing temperatures 200°, 180°, and 160°C; pressing
pressure 3.0 MPa, time 10 min, target board thickness 5 mm, target board density 0.8 g/cm3) to estimate their bond durability. Modulus of rupture (MOR), modulus of elasticity (MOE), internal bonding strength (IB),
thickness change, weight loss, Fourier transform infrared (FTIR) spectra, and color difference (ΔE*) by the CIE L*a*b* system were measured at various outdoor exposure periods up to 19 months. These values were then compared with those of a
commercial medium-density fiberboard (MDF; melamine-urea-formaldehyde resin; thickness 9.0 mm, density 0.75 g/cm3). Generally, dimensional stability and the retention ratios of MOR, MOE, and IB after the outdoor exposure test increased
with increased pressing temperature of binderless boards. The MOR retention ratio of the kenaf core binderless boards with
a pressing temperature of 200°C was 59.5% after 12 months of outdoor exposure, which was slightly lower than that of the MDF
(75.6% after 11 months of outdoor exposure). Despite this, the bond durability of the kenaf core binderless boards should
be viewed as favorable, especially when considering the fact that the retention ratio of 59.5% was achieved without binder
and without obvious element loss.
Part of this report was presented at the International Symposium on Wood Science and Technology, IAWPS2005, November 27-30,
2005, Yokohama, Japan 相似文献
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17.
Development of binderless particleboard from kenaf core using steam-injection pressing 总被引:3,自引:4,他引:3
Binderless particleboards were successfully developed from kenaf core using the steam-injection press. The effects of board density, steam pressure, and treatment time on the properties of the board were evaluated. The target board densities were relatively low, ranging from 0.40 to 0.70g/cm3. The properties [i.e., moduli of rupture (MOR) and elasticity (MOE) in both dry and wet conditions, internal bonding strength (IB), and water absorption (WA)] of the boards increased linearly with increasing board density. Steam pressure and treatment time also affected the board properties. The bending strength and IB were improved with increased steam pressure. A long steam treatment time contributed to low thickness swelling (TS) values and thus better dimensional stability. The appropriate steam pressure was 1.0MPa, and the treatment time was 10–15min. The properties for 0.55g/cm3 density boards under optimum conditions were MOR 12.6MPa, MOE 2.5GPa, IB 0.49MPa, TS 7.5%, and wet MOR 2.4MPa. Compared with the requirement of JIS 5908, 1994 for particleboard, kenaf binderless boards showed excellent IB strength but relatively poor durability.Part of this report was presented at the 19th Annual Meeting of the Japan Wood Technological Association, Tokyo, October 2001 相似文献
18.
Effects of silane coupling agent level and extraction treatment on the properties of UF-bonded reed and wheat straw particleboards 总被引:2,自引:0,他引:2
Guangping Han Kenji Umemura Ee Ding Wong Min Zhang Shuichi Kawai 《Journal of Wood Science》2001,47(1):18-23
Urea formaldehyde resin bonded reed and wheat particleboards with a density of 0.7g/cm3 were manufactured from two types of particle: fine and coarse particles. The effects of the silane coupling agent (SCA) level and ethanol-benzene (EB) treatment on the board properties were examined. For SCA, epoxide silane (SiEP) and amino silane (SiNH) were used for reed and wheat particles, respectively. The results are summarized as follows. (1) For both reed and wheat boards, the internal bond (IB) strength and thickness swelling (TS) were significantly improved at up to 5% SCA content, but the effectiveness of treatment kept constant at above 5%. (2) The level of SCA had little effect on the bending strength, especially for the boards composed of coarse particles. (3) EB treatment upgraded both the IB and TS of wheat board significantly. (4) SiEP incorporation improved the IB and TS of reed board significantly, whereas EB treatment was more effective for wheat board. (5) The dimensional stability of both reed and wheat boards under varying humidity could be improved by increasing the level of SCA and by EB treatment. EB treatment was more effective than SCA addition. 相似文献
19.
In this study, different properties of experimental particleboard produced using a sealed press were determined and were compared
with those for particleboard produced using a conventional press. Three types of binder, namely urea formaldehyde (UF), melamine
formaldehyde (MUF), and polymethylene diphenyl diisocyanate (PMDI), were used for board production. For the UF-bonded boards
produced using the sealed press, the modulus of rupture and the internal bond strength (IB) decreased due to the high temperature
and steam pressure used in comparison to the conditions in a conventional press. However, MUF- and PMDI-bonded boards had
improved IB and thickness swelling (TS). For the PMDI-bonded boards, especially, the TS was further improved and IB was increased
by using a sealed press. PMDI is known to possess superior properties and was confirmed to achieve good properties when used
as a binder for particleboards produced using a sealed press. 相似文献
20.
XU Jinmei ZHAO Rongjun FEI Benhua Research Institute of Wood Industry Chinese Academy of Forestry Beijing P.R.China 《中国林业科技(英文版)》2007,6(3):45-50
The objective of this study is to determine the properties of G. amplexifolia. In this paper; the chemical composition, including holocellulose, acid-insoluble lignin, 1% NaOH solubility, benzene-ethanol extractives and ash content, was considered for the variability with respect to positions along bamboo culm height (bottom, middle and top), parts along radial direction (inner part and outer part)and ages (1-year and 2- year). The test results were also compared to those of moso that is commonly planted and used in China. This study indicated that both the holocellulosecontent and the lignin content in inner part were lower than ; in outer part, but for extractives and ash content, the reverse was true. Bamboo age also had effect on chemical composition; both the holocellulose content and the ash content in the culm of 1- year were higher than those of 2-year; while the lignin content and the extractive content m the culm of 1- year were higher than those of 2-year. High holocellulose content, low lignin contentand extractive content were advantages of G. amplexifolia. 相似文献