Developing UV-protective textiles based on electrospun zinc oxide nanocomposite fibers

This research investigates applying zinc oxide nanoparticles to polypropylene nonwoven fabrics via electrospinning for the development of UV-protective materials. Layered fabric systems with electrospun zinc oxide nanocomposite fiber webs were developed at various concentrations of zinc oxide in a range of web area densities. The effects of zinc oxide concentration and web area density on the UV-protective properties of layered fabric systems were examined. Air and moisture vapor transport properties of layered fabric systems were assessed to examine the effect of electrospun web layers on thermal comfort properties of the material. A very thin layer of electrospun zinc oxide nanocomposite fibers significantly increased the UV blocking for both UV-A and UV-B ranges, and exhibited an ultraviolet protection factor (UPF) of greater than 40, indicating excellent UV protection. UV-protective properties of layered fabric systems increased with increasing zinc oxide concentrations of the nanocomposite fiber web. Increasing the electrospun web area density of the zinc oxide nanocomposite fiber web also enhanced UV-protective properties of layered fabric systems. Air and moisture vapor transport properties of layered fabric systems decreased as the electrospun web area density increased for the range of web area densities examined.     

Sound absorption and viscoelastic property of acoustical automotive nonwovens and their plasma treatment

Sound absorption property, viscoelastic property and the effect of plasma treatment of four automotive nonwoven fabrics on these properties are discussed in this research paper. Needle-punched fabrics used for vehicle headliner include 2 polyester fabrics made of hollow polyester fibers or solid polyester fibers, and 2 polypropylene-composite cellulose fabrics made of jute fibers or kenaf fibers, manufactured with the same web structure of apparent fabric density and fabric thickness. Hollow polyester fiber fabric has the highest sound absorption and the highest loss factor, the second highest is jute fiber fabric. The viscoelastic property is found to be related to the sound absorption property of fabric. The plasma treatment on nonwoven fabrics changes their sound absorption and viscoelastic property as well as their fabric weight and pore size. Hollow polyester fabric shows the increased sound absorption and viscoelastic property after the treatment with the increased pore sizes, while regular polyester fabric displays insignificant changes. The cellulose fabrics are more affected by plasma treatment compared to the polyester fabrics in terms of fabric weight loss and pore size, and jute fabric is more affected than kenaf fabric due to fiber weakness. The jute fabric demonstrates the decreased sound absorption and viscoelastic property, while kenaf fabric shows the increased sound absorption with the unchanged viscoelastic property after the treatment.     

Transport properties of layered fabric systems based on electrospun nanofibers

Layered fabric systems with electrospun polyurethane fiber web layered on spunbonded nonwoven were developed to examine the feasibility of developing protective textile materials as barriers to liquid penetration using electrospinning. Barrier performance was evaluated for layered fabric systems, using pesticide mixtures that represent a range of surface tension and viscosity. Air permeability and water vapor transmission were assessed as indications of thermal comfort performance. Protection performance and air/moisture vapor transport properties were compared for layered fabric systems and existing materials for personal protective equipment (PPE). Layered fabric systems with electrospun nanofiber web showed barrier performance in the range between microporous materials and nonwovens used for protective clothing. Layered fabric structures with the web area density of 1.0 and 2.0 g/m² exhibited air permeability higher than most PPE materials currently in use; moisture vapor transport was in a range comparable to nonwovens and typical woven work clothing fabrics. Comparisons of layered fabric systems and currently available PPE materials indicate that barrier/transport properties that may not be attainable with existing PPE materials could be achieved from layered fabric systems with electrospun nanofibrous web.     

Functional modification of sanitary nonwoven fabric by chitosan/nanosilver colloid solution and evaluation of applicability

For their functional enhancement, sanitary nonwoven fabrics with a relatively smooth surface were treated using chitosan, a natural polymer with excellent biocompatibility, and nanosilver colloid solution, which has strong antibacterial effects even when used in small amounts. The treatment effect was examined at various mixing ratios. When the mixing ratio of the nanosilver solution was higher, antibacterial and deodorization activity was increased. For CH3/NS1 treated fabric, when the mixing ratio of chitosan and nanosilver solution was 3:1, the air permeability was most excellent, and worked as a positive in improving the pleasantness of the sanitary nonwoven fabric. In all samples, the electrostatic propensity was reduced, regardless of the mixing ratio. In terms of the moisture characteristics of chitosan/nanosilver treated nonwoven fabrics, the moisture uptake was found to be superior in the CH3/NS1 treated fabric. When the mixing ratio of the nanosilver solution was higher, moisture permeability decreased, showing a similar tendency to that of air permeability. The vertical water permeability coefficient increased in all treated fabrics. The dynamic water absorption rate was good in CH4 and CH3/NS1 treated fabrics. This means that the absorption of water in the liquid state became easier, thus improving applicability as sanitary nonwoven fabrics.     

Fiber spiral motion in a swirl die melt-blowing process

Melt blowing is a major process for producing nanofibrous nonwovens. Compared to another technology for producing nanofibrous nonwovens, electrospinning, melt blowing applies high-speed air flow field to attenuate the extruded polymer jet. It is known that the essential electrospinning mechanism is a rapidly whipping jet in an electric field. While there are few studies on the fiber whipping in the melt-blowing process. In this study, a high-speed camera was used to capture the fiber path below a single-orifice melt-blowing swirl die. The spiral path of the fiber was revealed. The characteristics of the whipping amplitude, whipping frequency, and the fiber velocity were obtained. Fiber diameter reduction ratio contributed by the spiral path was calculated by establishing a mathematical model. The study indicates that spiral path of the whipping plays an important role in fiber attenuation near the die.     

Study on heat and moisture vapour transmission characteristics through multilayered fabric ensembles

A detailed study on the heat and moisture vapour transmission characteristics of different types of single and multi-layered fabric ensemble by using sweating guarded hot plate (SGHP) has been reported in the present paper. A comparison has been made on thermal and moisture vapour transmission properties of five different insulative fabrics, namely, knitted-raised fabric, needle punched nonwoven, through air bonded nonwoven, spunbonded-through air bonded sandwich nonwoven and warp knitted spacer fabric and three different coated fabrics, namely, plain woven rubber coated, plain woven polyester polymer coated and plain woven polytetrafluoroethylene (PTFE) coated fabric, used for thermal insulation purpose. ANOVA has been conducted to analyse the significance of type of insulative and coated fabrics used. Sandwich nonwoven fabric which has higher thickness and porosity shows higher thermal resistance followed by through air bonded fabric, raised fabric, needle punched fabric and spacer fabric. Spacer fabric shows lesser evaporative resistance due to its lesser thickness and larger aperture size, which increases the diffusion of moisture vapour. Needle punched fabric shows slightly higher evaporative resistance than spacer fabric, followed by raised fabric, through air bonded fabric and sandwich nonwoven fabric. Permeability index of different multilayered fabric ensembles are also compared.     

Process technology and performance evaluation of functional knee pad

In this study, Polylactic Acid (PLA) nonwoven fabric and thermoplastic polyurethane (TPU) honeycomb air cushion (TPU-HAC) were employed to form an impact resistant layer for functional knee pads. PLA nonwoven fabric has low manufacture cost and flexibility of the honeycomb air cushion improved the quality of functional knee pad sold in the market. This study focused on the strength of PLA nonwovens and the impact resistance of TPU honeycomb air pads. The PLA fibers and low-melting-point (low-Tm) PLA fibers are used as raw materials to fabricate PLA nonwoven fabric. The PLA fibers and low-melting-point PLA fibers were mixed at weight ratios of 10, 20, 30, 40, and 50 %. PLA nonwoven fabric and TPU-HAC materials were combined in a sandwich structure to protect against impact. Impact resistance was evaluated using a falling-weight impact-resistance machine. Experimental findings indicate that changing various layers can improve the impact resistance of the sandwich structure of the TPU-HAC materials. A TPU-HAC layer with a thickness of 2/8/10 mm optimized the impact resistance. In 25 J falling-weight impact test, the TPU-HAC layer 2/8/10 mm provides an impact resistance of 2932 N; the PLA/TPU-HAC composite had the best impact resistance; 2516 N. PLA nonwoven fabric had the best mechanical properties with low-Tm PLA fibers at 30 % weight. The impact resistance achieved using above combination of materials met the level 2, range 3 impact values mentioned in EN 14120 standards.     

Studies on compression behaviour of polypropylene needle punched nonwoven fabrics under wet condition

The present study deals with the effect of parallel-laid and cross-laid web of polypropylene needle punched nonwoven fabrics on compression properties (initial thickness, percentage compression, percentage thickness loss and percentage compression resilience) under wet condition. These compression properties of polypropylene needle-punched nonwoven under wet condition have also been compared with its dry condition. With the increase in needling density the initial thickness, percentage compression and percentage thickness loss of the fabrics under wet condition decrease to higher extent compared to its dry condition both in case of parallel-laid and cross-laid fabrics. Cross-laid nonwoven fabric presents lower value of initial thickness percentage compression and thickness loss compared to parallel-laid fabric which is very prominent at high needling density (350 punches/cm²). The percentage compression resilience shows increasing trend with the increase in needling density both under dry and wet conditions of parallel-laid web. It also follows similar trend in case of cross-laid nonwoven under wet condition. The optimum needling density for compression resilience of cross-laid nonwoven fabric under dry condition is 250 punches/cm².     

An investigation in structural parameters of needle-punched nonwoven fabrics on their thermal insulation property

The thermal characteristics of hollow polyester fibers were compared with solid polyester fibers in order to study their processing behavior and performance characteristics. The effects of different processing and structural properties including fiber diameter, bulk density of layer, and surface pressure on layers of needle-punched nonwoven fabrics with hollow fibers on thermal resistance properties were also investigated. The results show that hollow fibers have a higher thermal resistance in comparison with solid ones. This is a consequence of air trapping inside the fibers, higher bulkiness, and higher surface area of hollow fibers. Furthermore, thermal resistance of microfibers is better than those of macrofibers in both hollow and solid fibers. The thermal resistance of nonwoven subjected to this study, have an inverted-U-shaped pattern versus the bulk density of the fabric. The results also showed that thermal resistance of needle-punched nonwoven fabrics can be affected by the range of heater temperature during the test, however considerably can be affected by fabric thickness as a main structural property of nonwoven fabrics.     

Study on anisotropic creep behavior of nonwoven geotextiles

The anisotropy in creep behavior of two types of nonwoven fabrics (needle-punched and thermobonded spun laid) has been studied. It has been observed that the amount of time dependent extension depends on the direction, amount of loading and the structure of nonwoven the fabrics. The time dependent extension (creep) for the nonwoven fabric increases with the increase in amount of load. The higher initial extension and creep are observed for needle-punched nonwoven fabric as compared to thermobonded spun-laid nonwoven fabric. The creep behavior of needle-punched nonwoven shows a logarithmic relationship with time, but the thermobonded spun-laid nonwoven fabric does not show such logarithmic relationship. For a particular fabric, the creep is dependent on the fiber arrangement and is minimum in the direction in which the proportion of fiber is maximum and visa versa.     

Porosity and nonwoven fabric vertical wicking rate

Fabric porosity is the result of fabric constructional parameters combination and used technology of nonwoven production. The effects of fabric porosity structure, as well as the content of hydrophilic viscose and hydrophobic polyester fibres in the web mixture, on the vertical wicking rate by nonwoven fabrics have been explored in this research. Fibrous webs with a different content of viscose and polyester fibres, with the web volume mass range of 0.019-0.035 g/cm³ were utilized during this study. The samples were produced using a dry-laid method of web forming and two methods of web bonding, e.g. needle punching and calendar bonding. Results show that higher volume porosity gives higher vertical wicking rate by all groups of tested samples regarding the content of used hydrophilic/hydrophobic fibres and that fluid flow is faster in samples with larger pores. The higher content of viscose fibres improve the vertical wicking rate, but better rising height can be achieved at samples made from 100 % of coarser polyester fibres. A prediction model of vertical wicking rate of viscose/ polyester nonwovens was developed on the basis of the fundamental constructional parameters of nonwoven fabrics (fibre fineness, type of raw material, and web density) and a non-deterministic modelling method, e.g. genetic algorithms, which can serve as a useful tool for fabric engineers by developing a nonwoven fabric in order to fit desired wicking rate.     

Hemp-fiber based nonwoven composites: Effects of alkalization on sound absorption performance

The effects of the material and treatment parameters on airflow resistivity and normal-incidence sound absorption coefficient of alkalized three layered nonwoven composites have been studied. The material parameters included fiber size and porosity. The treatment factors included the temperature, duration and concentration. The alkalized composite was a three-layered nonwoven sandwich structure consisting layers of Polypropylene/Hemp/Polypropylene. Alkalization treatment has been found to result in a loss of basis weight and a decrease in air flow resistivity. Among treatment factors, only temperature was found to be a statistically-significant factor on air flow resistivity. Higher-temperature alkalization leads to higher air flow resistivity compared to the lower-temperature treatment. Alkalization at higher temperature and higher concentrations gives better results in normalized sound absorption performance compared to lower-temperature and lower-concentration treatments, respectively.     

The study on the air volume fraction of electrospun nanofiber nonwoven mats

Electrospinning is an efficient method to produce polymer fibers with a diameter range from nanometers to a few microns using an electrically driven jet. Electrospun nanofiber nonwoven fabrics can be applied into different areas with higher air volume fraction, especially applied into textile materials with good warmth retention property. In this article, the air volume fraction in nonwoven mats made of electrospun nanofibers was verified by studying fiber volume fraction in the mats. Then the relationship between fiber volume fraction and fiber diameter was derived, and the fiber volume fraction is in direct ratio to the square of fiber radius. By experimental verification, to get electrospun PAN nanofiber nonwoven mats with high air volume fraction about 99 %, it can fix the polymer concentration on 8 %. The voltage fixed on 20 kV, the tip-to-collector distance on 15 cm. The experiment is in accordance with the theory excellently.     

Meltblown nanofiber media for enhanced quality factor

Nanofibers definitely hold great advantage and promise in filtration as they have very high specific surface area, which ensures greater probability of capturing the particles and hence, the filtration efficiency of the nanofiber filter media is high. Electrospun nanofibers are prohibitively expensive due to extremely low production rate. With recent advances in melt blowing technology, nanofibers could be produced at production rate few orders of magnitude higher than that of conventional single syringe electrospinning and hence, quite cost effective. Influence of air pressure and die to collector distance (DCD) were studied on the number average fiber diameter for the nanofibers as well as the performance properties of the nonwoven webs, each factor at three discrete levels. The nanofibers were as fine as 260 nm. A very encouraging observation of the study is very high values of quality factor observed for nanofiber nonwoven filter media. In order to compare the filtration efficiency of different nanofiber nonwoven media samples with different basis weight, a novel term of specific filtration efficiency is proposed and was found that the specific filtration efficiency with the increase in DCD or air pressure.     

Study on melt-blown processing,web structure of polypropylene nonwovens and its BTX adsorption

Petroleum hydrocarbons can have adverse impacts on the environment and human health especially when they exist in the form of emulsion and aqueous solution. Nonwovens prepared by melt-blown method are a potential candidate for the removal of petroleum hydrocarbons. In this study, the processing-structure-oil sorption relationships of the PP (polypropylene) melt-blown nonwovens were investigated. Besides, the kinetics and mechanism of toluene sorption in simulated fire-fighting wastewater on the optimized prepared PP melt-blown nonwovens were studied at the static and dynamic conditions. The results showed that the web structure can be effectively controlled by adjusting the hot air temperature, metering pump speed and distance of collector to die to obtain an average fiber diameter of 3.0-10.5 μm, surface area of 0.5-1.5 m²/g and porosity of 71.0-99.0 %. The sorption capacity for pure BTX medium increased with the decreasing fiber diameter and increasing porosity. The pseudo-second-order kinetic model better fitted the experimental data to describe the sorption of emulsified and dissolved form of toluene at static and dynamic conditions. The toluene sorption can be a combination of adsorption and capillarity, the contribution of which was about 1:14.     

A study of abrasion and frictional behaviour of nonwoven interlining produced with different coating methods

Interlinings are produced recently not only natural and synthetics fibers but also fiber sheet form in nonwoven production methods. During usage, the fabric wears out and because of this problem fabric surface structure deteriorates. As a result of, investigation of fabrics surface and frictional properties has been important before usage of garments. For this reason, a patented laboratory instrument was designed which is based on horizontal working principle of accessing friction coefficient of fibrous textile surfaces. The tested materials were nonwoven interlining materials produced by spunbond methods. Abrasion resistance of paste dot-CoPES nonwoven interlining material is lower than others because of softness handle. On the contrary, friction coefficients have been obtained higher values.     

Application of electrospun polyurethane web to breathable water-proof fabrics

Electrospun web may possibly be widely applied to protective garments or specialty textiles due to its high level of protection as well as comfort. Of particular interest in this study is to develop waterproof-breathable fabric by applying electrospun web of polyurethane directly onto the substrate fabric. The optimal electrospinning condition was examined with regards to the concentration, applied voltage and tip-to-collector distance. Solvent-electospinning of polyurethane was performed at the optimum condition, using N,N-dimethylacetamide as solvent. The thickness of 0.02 mm of electrospun web was applied onto the polyester/nylon blended fabric. For comparison, the polyester/nylon fabrics were coated with 0.02 mm thickness of polyurethane resin membranes adopting four different conditions. The electrospun PU web/fabric was compared to resin coated fabrics in terms of water-proof and breathable properties. The electrospun web applied fabric showed higher air permeability, vapor transmission, and thermal insulation properties than resin coated fabrics, which can be translated as greater comfort sensation of electrospun applied fabrics. However, water resistance value of electrospun web applied fabric did not reach that of resin coated fabrics.     

The efficacy of coconut fibers on the sound-absorbing and thermal-insulating nonwoven composite board

The aim of this study is to examine the efficacy of the coconut fiber on the sound absorption and thermal insulation performance towards the composite nonwoven fabrics. The 2D polyester fiber and 12D fire retardant three-dimensional hollow crimp polyester fiber are individually mixed with 4D low-melting point polyester fiber (4DLMf) to produce 2D polyester nonwoven fabric (2D-PETF) and 12D polyester nonwoven fabric (12D-PETF) respectively. Subsequently, the coconut fiber (CF) is then laminated with the 2D-PETF and 12D-PETF to fabricate two types of PET/CF composite boards through the multiple needle-punching techniques. Accordingly, the sound absorption, thermal insulation, Limiting Oxygen Index and relative mechanical properties of the PET/CF composite boards are evaluated properly. The experimental results reveal that both types of PET/CF composite boards possess excellent thermal insulation performance and fire resistance property. Also, for both types of PET/CF composite boards, the average sound absorption coefficient increases with the increased amount of CF.     

Manufacturing technique and acoustic evaluation of sandwich laminates reinforced high-resilience inter/intra-ply hybrid composites

This study focused on the fabrication and acoustic property evaluation of sandwich cover-ply-reinforced highresilience thermal-bonding nonwoven hybrid composites. P-phenyleneterephthalamides and bicomponent high-resilience bonding polyester intra-ply hybrid nonwoven fabrics were compounded with glass plain fabric to produce the high strength sandwich structural cover ply by means of needle punching and thermal bonding to reinforce the whole composites and dissipate energy when being impacted. Then, the acoustic absorption properties of the homogenous intra-ply hybrid meshwork layer were investigated before and after being reinforced with the aforementioned cover ply. The influencing factors, including areal density, fiber blending ratio, needle punching depth, and air cavity thickness between back plate of the impedance tube and composites, were comparatively investigated. Results revealed that hybrid composites exhibited exceedingly high acoustic absorption properties. Acoustic absorption coefficients were promoted with increases in areal densities and fiber blending ratio of 3D crimped hollow polyester, particularly at low-mid frequency range. In addition, needle punching depths and back air cavity thicknesses considerably affected the average absorption coefficients. The meshwork center layer reinforced with sandwich structural cover-ply perform high resilience properties.     

Preparation and properties of fibers produced from a cellulose/complex PA solvent system precipitating in diverse coagulants

Ethanol, as the first coagulation bath, and several common organic solvents, as well as aqueous solutions of NH₄Cl, NaHCO₃ and NaOH were explored and demonstrated to be adopted as the second coagulation bath for cellulose/phosphoric acid/tetraphosphoric acid (cellulose/complex PA solvent) solution to produce novel cellulose fibers by two-stage dry-wet spinning in a laboratory scale, and effect of coagulants, cellulose concentration, solvent concentration (P₂O₅ concentration) and coagulation temperature on crystal structure and properties of corresponding fibers were investigated. Surface morphology of regenerated fibers as-spun from different coagulants was observed by scanning electronic microscope (SEM), indicating that methanol and 8 wt% NaOH aqueous solution all rendered cellulose fibers relatively dense and smooth surface. X-ray diffraction (XRD) analysis showed that cellulose fiber precipitated from 8 wt% NaOH aqueous solution had pronounced characteristic peak of cellulose II than those of fibers precipitated from other coagulants, and highest crystallinity and orientation. Meanwhile, those two coagulants referred above also gave cellulose fibers relatively higher tensile strength under the same prerequisite. TGA curves exhibited that fibers were thermally stable produced from two salt aqueous solutions (8 wt% NH₄Cl and NaHCO₃) since they had the relatively higher onset decomposition temperatures. By evaluating the effect of cellulose concentration, P₂O₅ concentration and coagulation temperature on the structure and properties of asprepared fibers, it was preferable to produce cellulose fiber from a solution at 20 wt% cellulose concentration, 73 % P₂O₅ concentration, and coagulating in methanol at coagulation temperature of 60 °C at the second-stage.