Pretreatment of Coke Oven Waste Water with Blast Furnace Sludge Method and Blast Furnace Sludge Plus Scrap Iron Method

Coke oven waste water is respectively pretreated by blast furnace sludge method and blast furnace sludge plus iron scrap method, the effects of pH and the quantity of materials and treatment time on the removal efficiency of COD are analyzed. The results indicate that blast furnace sludge plus iron scrap method is superior to blast furnace sludge method .The treatment time and pH can greatly affect on the removal efficiency of COD using blast furnace sludge plus iron scrap method. The treatment time after 30 minutes and pH have no remarkable effects the removal efficiency of COD using blast furnace sludge method. The removal efficiency of COD increases with the increase of blast furnace sludge and iron scrap, but the increase rate decreases gradually.     

Optimization and Realization for Sinter and Ore Blending for Blast Furnace

In the ironmaking process, it is essential that sinter and feed of blast furnace are established economically and reasonably. Taking some steel company for example, the best economical condition for feed of blast furnace is comprehensively considered from technologic demand and economic efficiency. According to LP and based on practice and trial, aimed function and confined condition is confirmed, computation programs are made by Matlab while realizing optimization feed. The blast furnace material balance and heat balance are calculated by program with visual interface. Thus, we can directly judge rationality of optimization. The results show that LP is effective method to realize feed of blast furnace.     

An artificial immunity based predictive method for neural networks and its applications

A radial basis function (RBF) neural network learning algorithm based on immune recognition was proposed to improve the low forecast precision and the slow convergence speed of such networks. In the algorithm, artificial immunity was used to determine the center and width parameters of the Gauss basis function. The recognized data were regarded as antigens and the compression mapping of antigens were taken as antibodies, i.e., the centers of the hidden layer. The recursion least square algorithm (RLS) was employed to determine the output layer weights. The algorithm improved the convergence speed and precision of the RBF neural networks. The model was applied to the blast furnace of a large iron and steel company. The results show that the model has forecast precision far superior to existing models and requires less training time than they do.     

A Primary Investigation on Concrete Made from Iron and Steel Slags for Building Ecological Artifical Reefs

A method of orthogonal test was used to optimize the strength of the cementitious material for preparing the concrete of high-strength artifical reefs.The results show that with the ratio of iron slag:steel slag=7:1,and when 10% cement clinker and 10% gypsum of Flue Gas Desulfurization Waste (FGDW) was mixed with 80% iron and steel slags powder,the mixed cementitious material had an optimized strength.The optimized specific surface area are 480 m 2/kg and 550 m 2/kg for iron slag and steel slag powder respectively.The ordinary portland cement can be totally substituted by such a mixed cementitious material with iron and steel slags as its major components in preparing the concrete for building high-strength artificial reefs.A concrete with a compressive strengh over 65MPa can be prepared by using such a mixture as a cementitious material and steel slag grains as its fine and coarse aggregats which have been stubilized by a hot-simmering method. Hydration processes of net slurry were analysized by XRD and SEM methods. The results show that the hydration products in the system are mainly AFt and C-S-H gel. The results also show that the pozzolanic reaction of iron slags could be largely promoted by the coordinations of steel slags,clinker and FGDW.     

Fractographic Analysis of Grey Cast Iron Weld Cracking

In this paper,the fracture of grey cast iron weld has been observed by SEM,and the mechanisms of the cracking initation and progression have been discussed.The results show that the fracture of grey cast iron weld is quasi cleavage.     

Reduction of Titanium Oxide and Thickening of Blast Furnace Slag Bearing Higher Titania

The slag samples that have some titanium oxide reduction grade are reduced with blast furnace slag taken from Pan Zhi Hua Iron & Steel (Group) Co. in site. Then the viscosity and free running temperature of slag samples were measured in laboratory. With the increasing of reduction grade the viscosity and free running temperature of slags would have rising tendency. The mineral structure of the samples is observed in optical microscope, and quantitative analysis of TiC, TiN in the slag samples is made with image analysiser. The results show that the thickening of titanium slag has relationship with the amount of TiC, TiN, which was reduced from titania. So the usage of titanium oxide reduction grade as the index of thickening in blast furnace process is reasonable, and which could represent characteristic of the blast furnace smelting iron ore bearing titanium and vanadium.     

Modeling and realizing of integrated batch planning for steelmaking-continuous casting and hot strip rolling

An integrated batch planning mathematical model based on multi-object optimization is proposed to solve the orderly and efficient flow of material between different working stations in iron and steel enterprises, where production technology constraints, material variations and coupling between steelmaking-continuous casting and hot rolling are analyzed first. According to the requirements of the hot rolling steel strip contracts, the integrated batch planning is divided into sub-plans of rolling plan, casting plan and furnace plan which are independent and coupling to each other, forming rolling plan and furnace plan simultaneously to influence casting plan. Heuristic method based on modified co-evolutionary algorithm is advanced to resolve this problem. The results of simulation and analysis in an iron and steel plant for strip steel production shows that it is feasible to provide effective guidance for integrated batch plan making.     

SEPARATION OF THE SECOND PHASE IN STEEL AND DETERMINATION OF SOLIDIFIED VANDIUM

In this paper, the dissolving condition of iron and vandium solidified in iron and the collecting method of the second phase vandium compounds in alloy steel are studied, the existing possibility of spreading phase vandium compounds in steel is discussed, which provide the possible conditions for concentration and electrochemical separation of the second phase vandium compounds. Using this method, quite reliable results in measuring vandium solidified in iron can be obtained.     

Fabrication and Formation Mechanism of FoamedIron Slag-Steel Slag Concrete

In order to achieve the comprehensive utilization of iron slag and steel slag, foamed concrete were prepared by adding small amount of gypsum, lime and clinker in steel slag-iron slag system and using aluminum powder as foaming agent,. The three-day, seven-day and twenty-eight-day bulk density and compressive strength of foamed concrete with the different ratio of the main raw materials were researched. Furthermore, in order to research the hydration mechanism and microstructure of foamed concrete, the XRD and SEM images of the three productions of foamed concrete were analyzed. The results showed that the coordination of the dosage of steel slag and iron slag was better when the former was 30% and the latter was 45%, Meanwhile, the compressive strength was 5.1 MPa, the bulk density was 625 kg/m 3; Ettringite and C-S-H gel synergies generated in steel slag-iron slag system. Besides, hydration activity of steel slag was obviously lower than that of iron slag.     

A simulated experiment on the high titanium slag rheological behavior

The rheological property of high titanium slag is a main factor to influence the vanadium titanomagnetite smelting in blast furnace. It plays a great role in discharging slag, separating iron and slag and even the life of blast furnace hearth. The acrylonitrile-butadiene-styrene multipolymer(ABS) dense suspension is taken to simulate the system of high titanium slag. Apparent viscosity is measured by a NXS-11A rotating cylinder viscometer. The impact of temperature, volume fraction and particle sizes on the suspension apparent viscosity is studied. The results show that temperature and volume fraction have a strong influence on the suspension apparent viscosity, while the particle size has a weak effect. The suspension shows Bingham behavior within a wide concentration range. The dependence of the appear viscosity on temperature and amount of solid addition can be described by a binary function equation.     

Alumina-based Composite Materials for Prefabricated Iron Runner

The relationship between the properties of the composite and the addition of the preventing crack additives, dispersion agent, SiC, graphite, stainless steel fiber have been researched. Finally, alumina-based composite materials used for prefabricated iron runner with better ratio of properties and price has been developed by the studying of the properties and microstructure of alumina based composite materials. The best composition for the iron line is Al 2O 3-14%SiC-5%G-4%SiO 2-2%micropoeder-1%white clay-6%cement;the best composition for the slag line is Al 2O 3-16%SiC-5%G-4%SiO 2-2%micropoeder-1%white clay-6%cement;addition of both is 0.15%Na 5P 3O 10-3B aluminum powder-2%stinless steel fiber. The mechanism on the composite materials eroded by molten iron has also been discussed.     

An Analysis of the Scaling Failure of the Nodular Iron Composite Polls

It is recognized that the scaling failure of nodular iron composite rolls in hot rolling is a problem of fatigue brittle fracture. The temperature field,stress,critical crack size as well as the interior quality of the rolls are presented. The theory of fracture mechanics is used to explain the cause of the scaling failure. At the same time, the way to extend the durability of the rolls is also studied.     

Electro-circuit Design About the Data Acquisition and Wireless Transmission System Based on High-speed SCM

Considering the difficult of acquiring and transmission the signal from the moving equipment, a new fault diagnosis monitoring system is presented. The system acquires the state signal from the moving equipment by data acquisition module that based in W77E58 high-speed SCM, and transmits the data fast by wireless mode. The signal data can be use for fault diagnosis and precise analysis. The system has the ability for acquiring abundance of data with a high speed, the ability for high accuracy data conversion, and has a function of programme controlling gain and programme controlling low-pass filtering. The successful application of this system on the vibration monitor about the material-transporting bogie in an iron works of a domestic steel enterprise proves the stability and credibility about the design project, also testifies its practical value and versatility.     

Distribution Models of the Fracture Resistance of Steel Strands Corroded by Chloride

Mises strain from plastic theory was put forward to be the fracture criterion of corroded steel strands. By tension tests of 14 corroded steel strands with chloride, 46 breaking wires were obtained with the mean tension stress and the geometric configuration of the pit. Based on the above, the fracture resistance of each breaking wire was simulated by the finite element software ANSYS. And the simulation results were addressed to analyse the characteristics of fracture resistance with SPSS software. It was found that at the significance level of 0.05, both normal distribution and logarithmic normal distribution were not refused for the fracture resistance distribution. Hence, the distribution models (percentage distribution function) were obtained under the two distribution modes.     

EFFECT OF MICRO-GALLIUM ON THE INTERGRANULAR SEGREGATINN OF PHOSPHORUS IN CARBON STEELS

The effect of small amounts of gallium on the intergranular segregation of phosphorus in carbon steels is discussed, with the help of the impact test, fracture morphology and micro-structure analyses, combined with composition analysis on the fracture surfaces by Auger electronspectrometer. The results show that gallium in the steel with a content of gallium more than ten thou-sandth can suppress, to some extent, the intergranular segregation of phosphorus and retard the tempering process. As a result, the temper embrittlement of the steel disappears and the embrittlement transition temperature declines.     

MgO对高铝高炉渣脱硫的影响及其动力学分析

随着廉价高铝铁矿石的不断使用,高炉炉渣内Al₂O₃含量也随之升高,这势必会影响高炉炉渣的各项冶金性能。为深入研究高铝高炉渣脱硫性能,明确MgO含量对高铝渣脱硫性能的影响,笔者通过改变高铝渣中MgO的含量,分别设定渣中MgO含量为5%、9%、13% MgO,研究不同MgO含量高炉高铝渣的脱硫性能及其脱硫动力学。结果表明：MgO含量不仅对高铝渣的黏度、脱硫能力有不同的影响,还使炉渣的脱硫速率发生了很大的改变。MgO含量越高对应的黏度越低,脱硫能力越大;但脱硫速率却表现出了不同规律,9% MgO的脱硫速率表现为最大;经过综合比较,当碱度固定为1.1、Al₂O₃含量固定为17%时,MgO含量为9%的炉渣同时具有较好的粘度和脱硫性能。     

Phase Transformation Diffusion Bonding of Titanium Alloy to Stainless Steel

Jointing of titanium alloy and stainless steel is very often in the fields like aviation, chemical plants etc. The combination of materials has the advantages of both titanium alloy and stainless steel and will reduce the consumption of titanium resource. The phase transformation diffusion bonding of TA17 titanium alloy to 0CriSNigTi stainless steel are carried out on Gleeble - 1500D. The effcet of maximum thermal cycle temperature, the tensile strength, the fracture surface and microstruture of the joints are investigated. The results show that TiFe and TiFe2 intermetallics and some solid solutions are formed along the interface, when maximum thermal cycle temperature increase, the area proportion of intermetallics in the fracture surface increase, which are detrimental to the mechanical properties of the transition joints.     

利用共转化方法创制携带Pi9抗稻瘟病基因的无选择标记转基因水稻

水稻稻瘟病是由子囊菌(Magnaporthe oryzae)引起的水稻灾害性病害。培育抗病品种是防治稻瘟病最经济有效的措施之一。水稻Pi9抗稻瘟病基因来源于小粒野生稻并已被克隆和应用于转基因育种。为了提高无选择标记转基因植株的选择效率,将绿色荧光蛋白(GFP)用作可视遗传标记,对双菌株共转化系统进行改良:目的基因载体携带Pi9抗稻瘟病基因;标记基因载体用潮霉素磷酸转移酶(HPT)作为植物转化选择标记,用GFP作为负选择标记,筛除标记基因分离植株。两种载体的农杆菌转化株混合,分别与水稻品种‘浙恢414’、‘浙粳22’、‘浙11B’、‘日本晴’、‘空育131’和‘粤泰B’的愈伤组织共培养,然后从5%~38.3%的起始愈伤组织筛选获得了转化愈伤组织(HPT+GFP+)。对T0植株进行Pi9基因PCR检测,11.8%~77.8%的T0植株为共转化植株(HPT+GFP+Pi9+)。对共转化植株T1代进行绿色荧光检测,筛选阴性植株(GFP-),再通过PCR筛选Pi9+植株。根据13个T1群体的研究结果,61%的共转化植株在T1代分离出无选择标记转基因植株(HPT-GFP-Pi9+)。转Pi9的无选择标记植株和后代株系对水稻稻瘟病呈抗病反应。因此,本研究通过GFP标记提高了双菌株共转化系统的选择效率,转Pi9的无选择标记水稻株系为水稻抗稻瘟病育种提供了有用的遗传资源。     

Effect of nitrogen on microstructure and properties of SWRH82B wire rod

The microstructure, mechanical properties, tensile fractures and the precipitation of the second phase of vanadium microalloyed wire rods with different nitrogen contents are studied by hydraulic universal testing machine, scanning electron microscopy(SEM) and transmission electron microscopy(TEM) . The results show that the interlamellar spacing of pearlite is smaller in high nitrogen steel; the high nitrogen steel has higher yield strength, tensile strength and lower elongation and reduction of area; there are more inclusions on the tensile fracture surfaces of the high nitrogen steel; and in high nitrogen steel, the size of precipitation, mainly precipitating at dislocation or the boundary of austenite, is finer than that of low nitrogen steel, what is more, fine V(C,N) particles are concluded in the precipitations.     

THE EFFECTS OF RESTRAINT STRESS ON PHASE TRANSFORMATION AND FRACTURE TOUGHNESS IN WELD HAZ OF 15MnMoVNRE STEEL

The effects of restraint stress on phase transformation and fracture toughness COD in weld HAZ of 15MnMoVNRE steel were studied by means of weld thermal simulation and COD testing. The results show that restraint stress accelerates phase transformation and makes the fracture toughness COD higher.