Reservoirs' siltation measurments and sediment transport assessment in the Czech Republic,the Vrchlice catchment study

Sediment transport from agricultural land into rivers and reservoirs is a problem within the Czech Republic. This problem was highly accelerated almost 50 years ago during the communist period. At that time strong collectivization was undertaken leading to destruction of traditional landscape patterns, surface outflow, erosion processes intensification and surface water quality deterioration. Thirteen years after political changes erosion problems remain.At the Department of Irrigation, Drainage and Landscape Engineering at the CTU Prague there has been continuous research undertaken in the field of erosion and sediment transport assessment. There are several modelling tools available for this purpose. One of them—USLE (Universal Soil Loss Equation) is commonly used in the Czech Republic for many years at a plot-scale but modern GIS (geographical information systems) tools in computer science allow using it at larger scales. Very important is the validation of this model for two-dimensional topography and GIS routines. Moreover USLE produces only local erosion amount values and has to be completed by another tool to get sediment amounts. For this purpose SDR (sediment delivery ratio) is usually used, applying a lumped approach—total erosion of every watershed is reduced by SDR and by pond’s trapping efficiency. Another available approach is using the Watem/SEDEM model that puts together RUSLE (Revised USLE) and a distributive approach to sediment transport modelling. This has already been used for estimating sediment amount in several catchments of the Czech Republic, but has to be validated as well.At the Dept. of Drainage, Irrigation and Landscape Engineering there are datasets of sediment amount from different reservoirs available and other reservoirs are to be measured soon. As the dataset of various watersheds is expanded, a methodology for sediment amount measurements is needed. The main objective of this paper is to propose a simple methodology to measure the sediment amount within reservoirs as well as to present a review of available methods. The application of the methodology at Vrchlice Catchments (97 km²) case study is presented. Total sediment amounts between 125 000∼140 000 m³ were measured in Vrchlice reservoir and values of 110 976 m³ (using USLE), resp. 105833 m³ (using Watem/SEDEM) were predicted by the erosion models. For catchments of this scale it is a sufficient validation.     

Multi-parameter fingerprinting of sediment deposition in a small gullied catchment in SE Australia

The determination of relative contributions of potential sediment sources is an important step in the development of management strategies to combat soil erosion. In a 1.2 km² gullied catchment in southeastern New South Wales, multi-parameter fingerprinting of sediment deposited in successive downstream pools has identified gully walls as the dominant sediment source when the grazed pasture surface was the only other potential source. The median fractional contributions remained relatively steady in the successive downstream pools, with the gully walls responsible for between 90% and 98% of the pool sediment. This result was achieved despite the ratio of the source areas varying considerably between successive nested subareas. Reliability bounds on the predictions, accounting for limited sampling of sources, were well constrained and varied between 5.4% and 13.8%. Downstream of an unsealed road crossing, sediment from the road source dominated the pool sediments such that contributions from the pasture surface and gully sources could not be determined.     

Prolegomena to sediment and flow connectivity in the landscape: A GIS and field numerical assessment

This paper presents two new definitions of sediment and water flux connectivity (from source through slopes to channels/sinks) with examples of applications to sediment fluxes. The two indices of connectivity are operatively defined, one (IC) that can be calculated in a GIS environment and represents a connectivity assessment based on landscape's information, and another that can be evaluated in the field (FIC) through direct assessment. While IC represent a potential connectivity characteristic of the local landscape, since nothing is used to represent the characteristics of causative events, FIC depend on the intensities of the events that have occurred locally and that have left visible signs in the fields, slopes, etc.IC and FIC are based on recognized major components of hydrological connectivity, such as land use and topographic characteristics. The definitions are based on the fact that the material present at a certain location A reaches another location B with a probability that depends on two components: the amount of material present in A and the route from A to B. The distance to B is weighted by the local gradient and the type of land use that the flow encounters on its route to B, while the amount of material present in A depends on the catchment surface, slope gradient and type of land use of said catchment.Although IC and FIC are independent from each other, and are calculated using different equations and different inputs, they complement each other. In fact, their combined use improves IC's accuracy. Hence, connectivity classes can afterward be rated using IC alone.This procedure has been applied in a medium-size watershed in Tuscany (Italy) with the aim of evaluating connectivity, identifying connected sediment sources and verifying the effects of mitigation measures.The proposed indices can be used for monitoring changes in connectivity in areas with high geomorphological or human induced evolution rates.     

Fingerprinting sediment sources in a typical karst catchment of southwest China

Due to the complex hydrogeological conditions in karst regions, it is difficult to measure sediment source contributions at a catchment scale directly. The objective of this study was to quantify the relative contributions of sediment sources and their temporal variability in a karst catchment in southwest China. Karst depressions can trap eroded sediment similar to a dam or reservoir and, thus, are representative and typical test beds for identifying sediment sources in karst regions. Three sediment cores were taken from a karst depression, 58 soil samples from three potential sediment sources were collected, and 18 soil properties were analyzed. The relative contributions of cropland, forestland, and fissure or crack soils were calculated using a multivariate mixing model. The fingerprinting results demonstrated that the cropland was the main sediment source in karst catchment. Specifically, according to the mean sediment contributions of the three deposited sediment cores, the sediment contribution from cropland topsoil was 69.3%, varying from 46.9% to 92.3%, and forestland soil and crack soil accounted for 8.6% and 22.1% of the sediment yield, and varying from 2.8% to 16.5% and 4.8%–36.6%, respectively. This result indicated that great attention should be paid when using only a single core to quantify sediment provenance. Due to the deposited sediment was generally disturbed as cropland in the karst depression, the area that has not been disturbed in recent decades in depression was more appropriate to trace sediment sources in karst catchment. To the best of our knowledge, this study was the first to quantify the contributions of sediment sources in the karst catchment of southwest China. This study provides valuable information and a preliminary reference for applying a composite fingerprinting technique to quantify sediment sources in karst catchments.     

Land degradation,soil conservation and the sediment load of the Yellow River,China: Review and assessment

Ninety per cent of the sediment load of the Yellow River, the world's muddiest river, comes from the loess plateau region in the middle course of the river. Control of this sediment supply is essential to avoid the danger of flooding in the lower reaches on the South China Plain. Since 1971, sediment loads entering the lower reaches have decreased, by 20 per cent as a result of lower precipitation, and by 27 per cent through soil conservation works and reservoir construction. Reductions in erosion can be obtained by restraining the formation of overland flow through promotion of an effective vegetation cover and elimination of the soil surface cover to encourage infiltration. Reservoir operation is a key to control of sediment movement through tributaries and along the main river. Water demands often conflict with sediment control, and, as a consequence, reservoir operation systems have changed several times in the past decade. The possibility of a further reduction in the sediment load of the Yellow River exists, but much depends on how rapidly control of grazing and deforestation leads to the establishment of plant cover on the loess plateau.     

Improving precision in sediment source and erosion process distinction in an upland catchment,south-eastern Australia

Analysis of sediment sources is an important component in the development of catchment sediment budgets and in determining links between erosion from sources and sediment delivery to catchment outlets. In this study ¹³⁷Cs and ²¹⁰Pb_ex were used to determine surface and sub-surface source contributions of fine sediment in a small upland headwater catchment (1.6 km²) in south-eastern Australia. The findings from this analysis are employed in an adjustment procedure to better differentiate sediment source erosion processes by utilising channel survey and erosion pin data. This improved the precision of estimates of sediment-source erosion-process contributions from hillslopes and channel/gully walls. A mean of 74% of in-channel deposits and suspended sediment exiting the study catchment was derived from sub-surface sources and when adjusted for erosion process this increased to 81%, which may be attributed to channel and gully wall erosion alone. Net erosion of the channel floor was low and constitutes only a small part of the total channel source input to sediment flux. Variability in sediment source contributions within the catchment was high, with rapid transition from hillslope to channel source dominance of sediment flux with distance downstream in the study catchment.     

Quantifying the contributions of sediment, sediment-P and fertiliser-P from forested, cultivated and pasture areas at the landuse and catchment scale using fallout radionuclides and geochemistry

In this paper we use a combination of fallout nuclides and geochemistry to determine the contributions of sediment and sediment bound phosphorus (sed-P) from the major diffuse sources in the Bundella Creek catchment (8700 ha), NSW, Australia. Sources include surface erosion from cultivated, pasture and steep forested land as well as subsoil erosion from channels and gullies. We determine these contributions to the <10 μm fraction of deposited sediments. Concentrations of P were higher in the surface soils of each landuse than the underlying subsoils, and erosion from these contributed more to offsite sediment-P (60%) than did subsoil erosion at the individual landuse scale. At the catchment outlet, the amount of surface sediment eroded from cultivated lands was a factor of 84 higher than from pastures; the steep forested lands contributed 9 times more than pastures. Sed-P eroded from cultivated land was 42 times higher than from pasturelands; the forests were 8 times greater than from pastures. At the catchment outlet the largest contribution of sediment (70%) and sed-P (62%) was from subsoil erosion of gullies and channels within and between the different landuse areas. There was little contribution of sediment or sed-P at the catchment scale from surface erosion of pastures. Concentrations of P were highest in ‘storm event’ suspended sediment samples taken from the pasture and cultivated areas without gullies. In a suite of samples selected for their high P contents, fertiliser P was detected in two storm event suspended sediment samples and one deposited sediment sample, using the ratio of Nd/P. This suggests fertiliser P may be transported-off landsurfaces with sediments and contribute to offsite sediment-P concentrations in some situations. However, the fertiliser contributions were episodic and variable; and probably influenced by particle size selectivity as well as timing of fertiliser application with respect to size and occurrence of subsequent rainfall.     

Modelling soil erosion and sediment yield at a catchment scale: the case of Masinga catchment,Kenya

Development of improved soil erosion and sediment yield prediction technology is required to provide catchment stakeholders with the tools they need to evaluate the impact of various management strategies on soil loss and sediment yield in order to plan for the optimal use of the land. In this paper, a newly developed approach is presented to predict the sources of sediment reaching the stream network within Masinga, a large‐scale rural catchment in Kenya. The study applies the revised universal soil loss equation (RUSLE) and a developed hillslope sediment delivery distributed (HSDD) model embedded in a geographical information system (GIS). The HSDD model estimates the sediment delivery ratio (SDR) on a cell‐by‐cell basis using the concept of runoff travel time as a function of catchment characteristics. The model performance was verified by comparing predicted and measured plot runoff and sediment yield. The results show a fairly good relationship between predicted and measured sediment yield (R²=0·82). The predicted results show that the developed modelling approach can be used as a major tool to estimate spatial soil erosion and sediment yield at a catchment scale. Copyright © 2006 John Wiley & Sons, Ltd.     

Preliminary modelling of sediment production and delivery in the Xihanshui River basin, Gansu, China

This paper outlines an analysis of the spatial distribution of sediment production, delivery and yield in the Xihanshui River basin, South Gansu, China, using the modelling tools of SedNet (Prosser et al., 2001). This model can assess the delivery efficiency to downstream locations, as well as identifying locations with high rates of sediment production. Preliminary model experiments assist understanding of the spatial dynamics of these sediment processes and evaluation of the effectiveness of soil conservation practices since the mid-1980s. Three scenario years (dry, average and wet) from the 1983–2005 record are identified and modelled, and land use and management are represented in the model to reflect known changes since the 1980s. Results show hillslope erosion to be a dominant source of sediment supply, causing the latter to decrease ten-fold between 1984 and 1997/2000. Estimated bank erosion and floodplain deposition rates are sensitive to parameter values, but bank erosion appears less sensitive than hillslope supply to rainfall. The model can be used to assess net changes in floodplain storage; for default parameters, floodplain deposition rates are 25–200 times the rates of bank erosion depending on the climate scenario. Comparing simulation results with measured sediment yields at the three gauging stations indicates encouraging agreement in 2000. In 1984 (the wet year), the model under-predicts, suggesting that additional unmodelled sediment production processes, especially mass movement and gully erosion, may be important in wet years. Mass movement inventory data could close the gap between the high yields measured in the wet scenario year and the estimated yield due to hillslope erosion alone. In 1997 (the dry year), the model over-predicts; this suggests that the land use change parameters required to reflect the effects of conservation may not have been sufficient, implying that conservation has been generally effective, and that evidence of declining sediment yield is not simply a reflection of drier conditions.     

Estimate of sediment yield in a basin without sediment data

In this study, three mathematical models for the estimate of sediment yield, due to soil and stream erosion, at the outlet of a basin are presented. Each model consists of three submodels: a rainfall-runoff submodel, a soil erosion submodel and a sediment transport submodel for streams. The rainfall-runoff and the stream sediment transport submodels are identical in the three mathematical models. The rainfall-runoff submodel that is used for the computation of the runoff in a sub-basin is a simplified water balance model for the soil root zone. For the estimate of soil erosion in a sub-basin, three different submodels are used alternatively, owing to the fact that erosion or sediment yield data are not available. The soil erosion submodels are (a) a modified form of the classical Universal Soil Loss Equation (USLE, [Foster, G.R., Meyer, L.D., Onstad, C.A., 1977. A runoff erosivity factor and variable slope length exponents for soil loss estimates. Transactions of the ASAE, 20 (4), 683–687]) taking into account both the rainfall erosion and the runoff erosion, (b) the relationships of Poesen [Poesen, J., 1985. An improved splash transport model. Zeitschrift für Geomorphologie, 29, 193–211] quantifying the splash detachment, as well as the upslope and downslope splash transport, (c) the relationships of Schmidt [Schmidt, J., 1992. Predicting the sediment yield from agricultural land using a new soil erosion model. Proceedings of the 5th International Symposium on River Sedimentation. Karlsruhe, Germany, pp. 1045–1051] including the momentum flux exerted by the droplets and the momentum flux exerted by the runoff. The sediment transport submodel for streams aims to estimate the sediment yield at the outlet of a sub-basin. This quantity results by comparing the available sediment amount in the main stream of a sub-basin with the sediment transport capacity by stream flow, which is computed by the relationships of Yang and Stall [Yang, C.T., Stall, J.B., 1976. Applicability of unit stream power equation. Journal of the Hydraulics Division, ASCE, 102, 559–568]. The mathematical models were applied to the basin of Kompsatos River, in northeastern Greece, with an area of about 565 km². The whole basin was divided into 18 natural sub-basins for more precise calculations. Monthly rainfall data were available for 27 years (1966–1992); therefore, the calculations were performed on a monthly basis. The deviation between the three mean annual values of sediment yield at the basin outlet, for 27 years, resulting from the three mathematical models is relatively small.     

Soil and sediment contamination by persistent organic pollutants in the Moravian and Slovakian parts of the danube catchment area and some Bohemian sites in the elbe catchment area

Polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins and dibenzofurans, HCBs and p, p'-DDE were determined in soil and sediment samples from selected sites in Czecho-Slovakia. for the first three groups of chemicals soil pollution in Czecho-Slovakia is very high. in general, The pollution is higher in the Elbe than in the Danube catchment sediments.     

Spatial delineation of organic carbon-rich Colluvial soils in Chernozem regions by Terrain analysis and fuzzy classification

Colluvial soils are considered to be the direct result of accelerated soil erosion, resulting in accumulation of humus-rich soil material in terrain depressions and base parts of slopes. The organic carbon concentration in these soils and their depth make them an important organic carbon storage. Mapping the Colluvial soils, therefore, represents an important contribution in total carbon stock estimation. A method of delineating Colluvial soils is proposed by applying a combination of high resolution digital elevation model analysis and detailed field survey. Two models based on fuzzy classification of soil units were created using different topographic derivatives as the only input parameters to predict the Colluvial soil area on a morphologically diverse study site in the Southern Moravia, Czech Republic. The model that considers only the derivatives with a strong relationship to Colluvial soil occurrence reached 71% accuracy in Colluvial area delineation, while the model combining six commonly used derivatives showed less favorable results. The main advantage of the method lies in a low demand of input soil data and its relatively high accuracy.     

In search for the ecological and toxicological relevance of sediment re-mobilisation and transport during flood events

In response to increasing concerns about the potential toxicological impacts of (extreme) flood events, scientists from several disciplines have joined to form the interdisciplinary research project named FLOODSEARCH. FLOODSEARCH is one of the recent Pathfinder Projects supported by the German Excellence Initiative via the Exploratory Research Space at RWTH Aachen (ERS). FLOODSEARCH aims to combine methodologies of hydraulic engineering and ecotoxicology in a new interdisciplinary approach to assess the risks associated with the re-mobilisation of particulate bound contaminants often observed after severe flood events. Impacts of extreme flood events and aspects of re-mobilisation of sediment-bound toxic compounds will be characterised and evaluated in controlled experiments fusing flood simulation technologies with biological effects assessment. The overall goal is to establish a novel and more realistic approach towards flood event testing that can be applied to a number of different questions and species. Specifically, model aquatic species such as rainbow trout (Onchorhynchus mykiss) will be exposed to particle-bound contaminants in flood-like conditions in a specifically designed annular flume that permits monitoring of both physical/chemical and biological parameter. Ultimately, this approach will assist to further our understanding of the potential biological risks associated with increasingly frequent extreme flood events, e.g., as a consequence of climate change, by bridging the gap between the physical (re-)mobilisation of contaminants and resulting toxicological impacts on aquatic organisms. Thus, it is the objective of the project to derive relationships between the hydrodynamic parameters such as velocities and turbulences, the parameters associated to sediment transport such as sediment concentration and grain sizes and the biological parameters.     

Statistical distribution of soil loss and sediment yield at Sparacia experimental area,Sicily

An analysis of the statistical distribution of event soil loss was carried out using the data collected in the period 1999–2008 at the microplots and plots of the Sparacia experimental area (Sicily, Italy). For a given microplot size, the analysis allowed to establish that the soil loss frequency distribution was skewed. Using the soil loss normalized by the event mean value, the analysis also showed that the frequency distributions corresponding to different microplot and plot sizes were overlapping, i.e. all distributions were extracted by the same statistical population. The developed analysis allowed to suggest that the soil loss of a given return period can be estimated using a scale and a frequency factor. Finally the sediment yield data collected in two basins of the Sparacia area were used to compare the frequency distributions of normalized soil erosion data collected at different spatial scales (plot, basin). The overlapping of the two distributions was satisfactory, and the conclusion was that the mean value of the measured variable is expressive of the characteristics of the sediment source area.     

Assessment of soil erosion hazard in Kilie catchment,East Shoa,Ethiopia

This paper reports on a field study conducted in Kilie catchment, East Shoa Zone, Ethiopia to assess the rate of soil erosion by employing a soil loss prediction model (Universal Soil Loss Equation) integrated with in remote sensing and geographical information systems (RS/GIS), environment and gully measurement techniques. The final soil erosion risk map was produced after multiplication of the six factors involved in the USLE and RS/GIS. Gully measurement showed that the erosion rate is higher for the upland areas than the lowlands due to inappropriate soil and water conservation measures, free grazing by animals and conversion of hillside areas into farmlands. About 97·04 per cent of the study catchment falls within a range of 0–10 t ha⁻¹ yr⁻¹ sheet/rill erosion rate. We found that 2·17 per cent of the study area in the uplands has a soil erosion rate falling between 10 and 20 t ha⁻¹ yr⁻¹. About 0·8 per cent of the study area in the uplands is hit by severe sheet/rill erosion rate within the range of 20–60 t ha⁻¹ yr⁻¹. Gully erosion extent in the study area was evaluated through gully measurement and quantification methods. Gully density of 67 m ha⁻¹ was recorded in the catchment. The gully to plot area ratio was found to be 0·14 on average. Hence, in the upland areas, sustainable land management practices are required in order to reduce the rate of soil erosion. Copyright © 2011 John Wiley & Sons, Ltd.     

Modelling of snowmelt erosion and sediment yield in a small low-mountain catchment in Germany

Temporal variability and spatial heterogeneity of surface runoff generation triggers the dynamics of source areas of sediment and sediment-associated nutrient transport. Reliable modelling of hydrological special situations i.e. snowmelt is of high importance for the quality of erosion and sediment yield modelling. Data from the research catchment Schäfertal demonstrate the individuality of snowmelt events in terms of runoff coefficient and delivery ratio. This 1.44 km² low mountain catchment is characterised by a high portion of arable land with a winter grain/winter rape crop rotation. The integrated winter erosion and nutrient load model (IWAN) considers these dynamic aspects by coupling a hydrological model with a sediment load model. Cell size of this raster-based approach is 10 × 10 m². Additionally, snowmelt rill erosion is simulated with a newly developed physically based model that is firstly applied on a catchment scale. A sensitivity analysis of this model system component demonstrates the plausibility of the model approach and the overall robustness of the model system IWAN. The results of the long-term hydrological modelling from 1991 to 2003 are reliable and form the basis for the simulation of six snowmelt events which were observed in the Schäfertal catchment. The estimated total runoff volumes for these events match the observations well. The modelled overland runoff coefficients vary from 0.001 to 0.72. The mean values of cell erosion, which were modelled with one set of parameters for all six events range from 0.0006 to 0.96 t ha^− 1. The total modelled erosion for the events with unfrozen soil and low amount of surface runoff is of a factor 50 below those with partly frozen soil. In addition to these distinctions, the major differences are caused by flow accumulation in shallow depressions in variable parts of the catchment. However, the validation of these results on the single event scale is restricted due to limited spatial data. Total simulated sediment yield at the catchment outlet was as high as 13.84 t which underestimates the observed values, with the exception of one event. Oversimplification of the modelled channel processes may be a reason. The temporal variability and spatial heterogeneity of the surface roughness parameter, which was identified to be sensitive, also causes uncertainty in the parameter estimation. Despite these findings, the model system IWAN was applied successfully on the catchment scale and the simulated results are reliable.     

Using Local Archive Sources to Reconstruct Historical Landslide Occurrence in Selected Urban REgions of the Czech Republic: Examples from Regions with Different Historical Development

Historical documentary sources from two regions with contrasting historical and social development were examined for information about landslide occurrence and characteristics. The archive search was complemented with limited field work to acquire information about the degree of recent landslide activity and land use. The results from two study areas (Ústí nad Labem in North Bohemia and Zlín in East Moravia) show considerable differences in the types of historical documentary source, their availability and the information they record. It is concluded that local newspapers that include special sections focusing on regional events are the best data sources for the landslide study. The reliability of the acquired historical landslide occurrence frequencies is generally not very good, but it does show notable regional differences caused by not only the availability of documentary sources but also the dynamics of the natural processes responsible for the landslide events. A reconstruction of the landslide activity during the last 70 or more years was carried out for selected sites. The reconstruction showed that the occurrence of historical landslides is only rarely respected in recent land use within both studied urban areas. Historical landslide information could be well used for site‐specific landslide hazard assessment. Nevertheless, the use of this information to construct a historical landslide database on the regional or country level is limited only to certain regions of the Czech Republic. Copyright © 2013 John Wiley & Sons, Ltd.     

Effect of time resolution of rainfall measurements on the erosivity factor in the USLE in China

Rainfall erosivity, one of the factors in the Universal Soil Loss Equation, quantifies the effect of rainfall and runoff on soil erosion. High-resolution data are required to compute rainfall erosivity, but are not widely available in many parts of the world. As the temporal resolution of rainfall measurement decreases, computed rainfall erosivity decreases. The objective of the paper is to derive a series of conversion factors as a function of the time interval to compute rainfall erosivity so that the R factor computed using data at different time intervals could be converted to that computed using 1-min data. Rainfall data at 1-min intervals from 62 stations over China were collected to first compute the ‘true’ R factor values. Underestimation of the R factor was systematically evaluated using data aggregated at 5, 6, 10, 15, 20, 30, and 60-min to develop conversion factors for the R factor and the 1-in-10-year storm EI₃₀ values. Compared with true values, the relative error in R factor using data at fixed intervals of ≤10min was <10% for at least 44 out of 62 stations. Errors increased rapidly when the time interval of the rainfall data exceeded 15 min. Relative errors were >10% using 15-min data for 66.1% of stations and >20% using 30-min data for 61.3% of stations. The conversion factors for the R factor, ranging from 1.051 to 1.871 for 5 to 60-min data, are higher than those for the 1-in-10-years storm EI₃₀, ranging from 1.034 to 1.489 for the 62 stations.     

Fly-ash distribution to assess erosion and deposition in an Illinois landscape

Fly ash, the particulate matter resulting from high temperature combustion of coal, was historically dispersed into the atmosphere and settled as fly-ash spheres on the surface soil from a variety of boilers, including those of steam locomotives and steam-powered farm machinery. In Central Illinois, fly ash provides a time marker extending back to 1850s, coinciding with the development of railroads and cultivation. Two railroads, the primary sources of fly ash, were constructed just south of the Cahokia study site in 1852 and 1854. The objectives of this study were to determine: (1) the distribution, depth of occurrence and the total amount of fly ash present in soil profiles on stable, cultivated and uncultivated summit sites with little or no soil erosion; (2) the effects of elevation, aspect, slope gradient, landscape position, distance from source, past vegetation and time on the amount and depth of fly ash; (3) the effects of erosion on sloping sideslopes; and (4) the amount of deposition of fly-ash rich sediment on footslopes and toeslopes. Total fly-ash content of soil was similar for stable, cultivated and uncultivated summits. Two mound sideslopes maintained a high amount of fly ash because of a lack of cultivation and erosion for the past 80 or more years. Erosion reduced the depth of occurrence and the amount of fly ash present on cultivated sideslopes. It appeared that fly-ash content was initially deposited uniformly within the local landscape even though there were slight variations in the aspect, elevation, slope gradient, and distance from the source. The erosion phases of the soils on all landscape positions were determined based on the amount of fly ash remaining in soil surface layers. Accelerated erosion of cultivated sideslopes resulted in the deposition of fly-ash rich sediment on the adjacent footslopes or toeslopes. The proposed fly-ash method provides a tool to assess the extent of soil translocation from a cultivated landscape and subsequent deposition.     

Biogeochemistry of aluminum in a forest catchment in the Czech Republic impacted by atmospheric inputs of strong acids

The Lysina catchment in the Czech Republic was studied to investigate the biogeochemical response of Al to high loadings of acidic deposition. The catchment supports Norway spruce plantations and is underlain by granite and podzolic soil. Atmospheric deposition to the site was characterized by high H⁺ and SO₄ ^2– fluxes in throughfall. The volume-weighted average concentration of total Al (Al_t) was 28 mol L^–1 in the O horizon soil solution. About 50% of Al_t in the O horizon was in the form of potentially-toxic inorganic monomeric Al (Al_i). In the E horizon, Al_t increased to 71 mol L^–1, and Al_i comprised 80% of Al_t. The concentration of Al_t (120 mol L^–1) and the fraction of Al_i (85%) increased in the lower mineral soil due to increases in Al_i and decreases in organic monomeric Al (Al_o). Shallow ground water was less acidic and had lower Al_t concentration (29 mol L^–1). The volume-weighted average concentration of Al_t was extremely high in stream water (60 mol L^–1) with Al_i accounting for about 60% of Al_t. The major species of Al_i in stream water were fluorocomplexes (Al-F) and aquo Al³⁺. Soil solutions in the root zone were undersaturated with respect to all Al-bearing mineral phases. However, stream water exhibited Al_i concentrations close to solubility with jurbanite. Acidic waters and elevated Al concentrations reflected the limited supply of basic cations on the soil exchange complex and slow weathering, which was unable to neutralize atmospheric inputs of strong acids.