共查询到20条相似文献,搜索用时 15 毫秒
1.
Continuous photografting/crosslinking of polyethyleneglycol dimethacrylate oligomers onto cotton using a water-soluble benzophenone
photoinitiator was investigated. Photografting increased with increasing irradiation dose, oligomer concentration and photoinitiator
concentration. Maximum grafting efficiency of DM 400 and 600 were 83% and 79%, respectively. The photografting increased the
wrinkle resistance of cotton implying surface crosslinking of cotton. Both surface crosslinking and bulk crosslinking of cotton
were accomplished via dual curing of a mixed formulation containing both a thermally curable component (BTCA/SHP) and a UV-curable
component. The wrinkle resistance of the crosslinked cotton was found to be higher when cured by thermal curing after UV curing
rather than by UV curing after thermal curing due to the facile post-polymerization of the UV active component. The presence
of crosslinks in the dually crosslinked cotton was verified with FT-IR and thermogravimetric analysis. 相似文献
2.
Nano-ZnO assembled cotton fibers, with excellent UV blocking property and good water-wash durability, have been successfully
fabricated using microwave assisted precipitation and crystallization process synchronously in situ for the first time. Here,
zinc nitrate hexahydrate was used as zinc resource and sodium hydroxide was used as precipitate. The asobtained samples were
characterized by powder X-ray diffractometer (XRD), filed emission scanning electron microscopy (FESEM), and energy-dispersive
spectrometry (EDS), UV/Visible spectroscopy and Fourier transformation infrared spectroscopy (FTIR). Wurtzite ZnO with about
30–40 nm in diameter was fabricated in the lumen as well as in mesoporous structures of cotton fibers. The as-prepared samples
have excellent UV absorbing activity over a broad range in the region from 225 nm to 380 nm. The crystallinity and UV blocking
properties keep unchangeable as the former after being washed for 60 min in 33 l water. FTIR results reveal that there is no peak shift and new peak occurred, which indicates that no chemical bond exist
between nano-ZnO and cotton fibers. Mechanical force is the only way to bond nano-ZnO to cotton fibers in the experimental
condition. ZnO nanoparticles and wax existing in cotton fibers can combine to a firmly hybrid layer in the surface and the
inner of cotton fibers during microwave treatment, which may bring the good water-wash durability. 相似文献
3.
Phosphorus-nitrogen (P-N) or sulfur (S) containing compounds are well known for their effectiveness as flame retardant additives for many polymeric systems. When either phosphorus or nitrogen is combined with sulfur, the new systems prove to be successful combinations. This research aims to learn the impact of two systems, P-N and S-P-N, on the flammability and thermal properties of cotton fabrics. The process includes the synthesis of two compounds, tetraethyl piperazine-1,4-diyldiphosphonate (TEPP) and O,O,O',O'-tetramethyl piperazine-1,4-diyldiphosphonothioate (TMPT), and the evaluation of flammability, thermal degradation, and surface morphology of the treated fabrics. Both compounds exhibit similar burning behavior and show improved flame retardancy and thermal properties when used on various cotton fabrics. Some unique flame retardant properties for the two compounds are also disclosed. 相似文献
4.
安徽省宿松县是国家优质棉基地县,常年棉花种植面积20km^2左右。尽管抗虫棉的种植缓解了棉铃虫的为害,但抗虫棉不是无虫棉,且抗虫棉棉株在不同的发育时期对棉铃虫的抗性不同,棉株的不同部位、不同器官的抗虫能力也不同,因此,还需要化学药剂辅助防治。 相似文献
5.
The influence of water vapor plasma on the adsorption of UV absorber during the reactive dyeing of bleached and mercerized cotton fabric was examined. Exhaust dyeing of untreated and plasma-treated cotton was performed using a reactive dye Cibarcon Deep Red S-B and a commercial UV absorber Tinofast CEL. Blank dyeing was performed as a control experiment. Fourier transform infrared spectroscopy (FTIR) was used to identify the presence of the UV absorber on the cotton fabric, whereas scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to analyze surface changes of untreated and plasma-treated dyed samples. The CIELAB color values and ultraviolet protection factor (UPF) of the samples were determined spectrophotometrically. Wash and light fastness of samples was performed also. The results reveal that the UPF of cotton increases after UV absorber treatment and that plasma treatment increases the adsorption of UV absorber during dyeing process, especially at higher dye concentrations. The enhanced adsorption of UV absorber onto plasma-treated cotton is the result of the increased concentration of oxygen containing functional groups on the cotton surface after plasma treatment, confirmed by XPS. The UPF of plasma-treated cotton samples is decreased after washing and increased after exposure to xenon light. 相似文献
6.
Chencen Guo Ting Li Chuankai Wang Yabo Wang Yongkui Zhang 《Fibers and Polymers》2017,18(10):1882-1890
Alkaline pectinase was one of the most effective enzymes to treat cotton as alternative agent to replace the conventional alkaline method. Removal of pectin and cutin was considered the explanation for improvement of wettability as well as water adsorption on cotton fiber. However, degradation kinetics of pectin is unclear, and the influence of fiber shape on property changes after enzymatic treatment was ignored. The main objective of this work was to reveal interactions between pectinase and cotton fiber for mechanism study. A heterogeneous catalysis kinetic equation, which is associated with Langmuir adsorption model and enzyme deactivation, was used to describe the heterogeneous catalysis. The enzymatic process conditions were optimized. Raw cotton fibers, pectinase-treated and alkali-treated fibers were characterized by impurities content determination, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscope (SEM). Mechanism of water adsorption enhancement on treated fibers was discussed. In addition to elimination of the outer impurities, flat fibers with less twist and shape changes of lumen were also obtained to ensure better accessibility and water adsorption after enzymatic treatment. 相似文献
7.
基于新疆北疆主要植棉区10个气象站1961—2017年棉花生育期月平均气温、≥10 ℃积温、≥15 ℃积温、≥20 ℃积温、无霜期气象资料和棉花产量数据,采用线性趋势分析、突变检验等方法,对北疆主要植棉区的热量资源及产量变化进行分析。研究表明:(1)生育期月平均气温呈现自东向西升高趋势,相差较小;≥10 ℃、≥15 ℃、≥20 ℃积温和无霜期也呈现自东向西增多趋势,其中无霜期相差19.4 d。(2)生育期月平均气温呈波动性上升趋势,气候倾向率为0.30 ℃·(10 a)-1;≥10 ℃、≥15 ℃和≥20 ℃积温均呈现明显的波动上升趋势,累积距平最小值分别出现在1994年、1995年和2004年,气候倾向率分别为94.1 ℃·(10 a)-1、66.7 ℃·(10 a)-1和99.3 ℃·(10 a)-1;≥10 ℃、≥15 ℃、≥20 ℃积温的持续时间呈现增加趋势;初霜期延后,终霜期提前。(3)生育期月平均气温在1994年发生了突变;无霜期在1992年前后发生了突变,突变后延长了11.1 d;≥10 ℃积温在1995年发生突变,突变后增加了319.2 ℃;≥15 ℃积温突变不明显;≥20 ℃积温在2004年前后发生突变,突变后增加了418.7 ℃。(4)棉花单产与趋势产量呈明显上升趋势,气象产量波动性较大,单产与热量资源的相关性较高;热量资源的增加对棉花产量的增加具有正效应。(5)热量资源对棉花产量提升起重要作用:丰收年景普遍表现为积温较常年多,光热条件好;歉收年景表现为热量减少,无霜期缩短,光热条件差,降水量略偏少;平常年景表现为降水量接近常年,日照时间略多于常年,整体光热条件一般。 相似文献
8.
Waste cotton fibers were used to produce activated carbon fiber (ACF) via chemical activation method with phosphoric acid. The effect of different operational parameters on the adsorption capacity and yield of activated carbon fibers was studied by Taguchi experimental design. Optimized conditions were: Activation temperature of 450 °C, activation time of 0.5 h, impregnation ratio of 2, and the rate of temperature rising of 10 °C min?1. The activated carbon fiber produced under optimized conditions was characterized by pore structure analysis, scanning electron microscopy (SEM), X-ray energy-dispersion spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction analysis (XRD). The obtained results showed that the produced activated carbon has developed porous structure, fibrous shape, predominantly amorphous structure, large number of oxygen functional groups, and acidic nature. 相似文献
9.
Jelena?Vasiljevi? Marija?Gorjanc Ivan?Jerman Brigita?Tom?i? Martina?Modic Miran?Mozeti? Boris?Orel Barbara?Simon?i?
Oxygen plasma pre-treatment was applied to cotton fabric with the aim of improving the water repellency performance of an inorganic-organic hybrid sol-gel perfluoroalkyl-functionalized polysilsesquioxane coating. Cotton fabric was pre-treated with low-pressure oxygen plasma for different treatment times and operating powers. Afterward, 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) was applied to the cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and modified cotton fibers were characterised using Fourier transform infrared spectroscopy, Xray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy. The water repellency of the SiF-coated fabric samples was evaluated using static and sliding contact angle measurements with water. The results show that the plasma treatment with the shortest treatment time (10 s) and the lowest operating current (0.3 A) increased the atomic oxygen/carbon ratio of the cotton fiber surface from 0.6 to 0.8 and induced the formation of a nano-sized grainy surface. Increasing the plasma treatment time and/or operating current did not intensify the surface changes of the cotton fibers. Such saturation effects were explained by the large influence of reactive oxygen atoms during the plasma treatment. The measured static water contact angles on the surface of the untreated and plasma pre-treated and SiF-coated cotton fabrics showed that the oxygen plasma pre-treatment enabled the increase of the water contact angle from 135° to ≈150°, regardless of the applied plasma treatment time and discharge power. This improvement in the hydrophobicity of the SiF coating was followed by a decrease in the sliding angle of water droplets by more than 10° compared to the plasma untreated and SiF-coated sample characterized by a water sliding angle of 45°. Additionally, measurements of the water sliding angle revealed that the increase of the static contact angle from 149° to 150° corresponded to a drop of the water sliding angle from 33 to 24°, which suggests that the plasma pre-treatment of 20 s at an operating current of 0.3 A produced the best water-repellent performance of the SiF-coated cotton fabric. 相似文献
10.
An attempt was made to correlate the polymerization temperature and rheological and thermal properties of acrylonitrile (AN)-acrylamide
(AM) copolymers. The copolymers were synthesized at different polymerization temperature. The copolymer structure was characterized
by gel permeation chromatography (GPC) and Infrared spectrum (IR). The rheological and thermal properties were investigated
by a viscometer and differential scanning calorimeter-thermogrametric (DSCTG) analysis, respectively. When the polymerization
temperature increased from 41 °C to 65 °C, the molecular weight
([`(M)] w )(\overline M _w )
of copolymers decreased from 1,090,000 to 250,000, while its conversion increased from 18% to 63%, and the polymer composition
changed slightly. To meet the requirements of carbon fibers, the rheological and thermal properties of products were also
investigated. It was found that the relationship between viscosity and
[`(M)] w\overline M _w
was nonlinear and the viscosity index (n) decreased from 3.13 to 2.69, when the solution temperature increased from 30 °C
to 65 °C. This suggests the dependence of viscosity upon
[`(M)] w\overline M _w
is higher at lower solution temperature. According to the result of activation energy, the sensivity of viscosity to solution
temperature is higher for AN-AM copolymers synthesized at higher polymerization temperature. The result of thermal analysis
shows that the copolymers obtained at higher polymerization temperature are easier to cyclization evidenced from lower initiation
temperature. The weight loss behavior changed irregularly with polymerization temperature due to irregular change of liberation
heat. 相似文献
11.
棉蚜和棉叶螨是河西走廊棉区两种主要虫害,在棉花整个生育期均造成为害,防治过程中化学药剂广泛持续的使用,使害虫抗性增加,为害逐年加重,造成的损失和防治成本呈逐年加大的趋势,致使植棉户植棉效益下降.文中通过对两种主要虫害防治技术影响因素的比较和分析,总结了经济有效的防治方法,从而为实际生产中高效防治棉蚜和棉叶螨提供依据. 相似文献
12.
Mohaddeseh Naeimi Mansoureh Ghanbar Afjeh Ali Akbar Gharehaghaji Fatemeh Zeighami 《Fibers and Polymers》2017,18(9):1724-1733
Polyacrylonitrile nanofibers were produced using the electrospinning method and dyed with a basic dye alongside regular polyacrylonitrile fibers. In order to investigate the effect of high surface area to volume ratio of nanofibers on their adsorption behavior in comparison with regular fibers, the dyeing conditions for both types of fibers were kept just the same. Physiochemical parameters of dyeing such as adsorption isotherm, standard affinity, enthalpy change, rate of dyeing constant, diffusion coefficient, and activation energy of diffusion were investigated for both types of fibers. The results showed that the adsorption process can be well described with the Langmuir adsorption isotherm for both types of fibers whereas the standard affinity of dye to nanofibers was higher than regular fibers and the higher negative values of enthalpy changes were obtained for regular fibers. The nanofibers rate of dyeing was faster than regular fibers with higher amounts of diffusion coefficients and lower amounts of activation energy of diffusion. This study also revealed that in spite of the approximately same amount of dye exhaustion for both types of fibers, the color strength of regular fibers was noticeably higher than nanofibers. 相似文献
13.
Huizhen Ke 《Fibers and Polymers》2016,17(8):1198-1205
In this paper, novel electrospun LA-PA/PET/Ag phase change composite fibers with different amount of Ag nanoparticles were prepared via the technique of electrospinning followed by UV irradiation method. The morphological structure, thermal energy storage properties, thermal energy storage and release rates of prepared LA-PA/PET/AgNO3 and LA-PA/PET/Ag composite fibers were investigated by scanning electron microscope (SEM), high-resolution transmission electron microscope (HR-TEM), differential scanning calorimeter (DSC), and the measurement of melting and freezing times, respectively. The SEM images revealed that electrospun LA-PA/PET/AgNO3 and LA-PA/PET/Ag composite fibers possessed the smooth morphologies with cylindrical shape. The corresponding average fiber diameters gradually decreased with increasing content of the AgNO3 in the solutions, and slightly smaller than those of the LA-PA/PET composite fibers with oblate morphology and wrinkled surfaces. Yellow-brown coloration of electrospun LA-PA/PET/Ag phase change composite fibers were observed after UV irradiation treatment, which demonstrated that Ag ions were successfully reduced to Ag nanoparticles. The TEM images revealed that these reduced Ag nanoparticles were homogenously dispersed within the composite fibers. The results from DSC measurements indicated that the phase change temperatures and enthalpies of electrospun LA-PA/PET/Ag phase change composite fibers with different Ag content have not be influenced by the UVirradiation treatment. The thermal energy storage and release rates of electrospun LA-PA/PET/Ag phase change composite fibers were also improved due to the combination of reduced Ag nanoparticles. These UV-irradiated electrospun phase change composite fibers with excellent thermal energy storage properties can be acted as a novel form-stable PCMs for the applications related to storage and retrieval of thermal energy. 相似文献
14.
Dongmei Xu Quan Ji Liwen Tan Guangxiu Tian Fengyu Quan Yanzhi Xia 《Fibers and Polymers》2014,15(2):220-225
Cellulose-Na and cellulose-K fibers are obtained by alkalization and etherification of viscose fiber. Flame retardancy and thermal degradation of cellulose-Na and cellulose-K fibers are investigated using limiting oxygen index (LOI), cone calorimetry (CONE), thermal gravimetry (TG), and differential TG (DTG). The LOI values of cellulose-Na and cellulose-K fibers are 33 and 30, compared with about 20 for viscose fiber. In CONE studies, cellulose-Na and cellulose-K fibers show much lower heat release rates, total heat release and effective heats of combustion than viscose fiber does. In addition, TG and DTG studies reveal that the second initial degradation temperature, the temperature of maximum degradation rate and the maximum degradation rate for cellulose-Na and cellulose-K fibers are much lower than those of viscose fiber. Cellulose-Na and cellulose-K fibers generate much more residue or carbonaceous char than viscose fiber does. Scanning electron microscopy studies of combustion residues after LOI testing indicate that cellulose-Na and cellulose-K fibers produce massive, thick residue crusts. 相似文献
15.
Unfilled polypropylene and polyropylene/ZnO nanocomposite fibers were produced using a melt spinning apparatus; then the fibers were exposed to UV irradiation. The structure and properties of the fibers were examined using scanning electron microscopy, tensile measurements, wide angle X-ray diffraction (WAXD), Fourier transform infrared (FTIR) spectroscopy, birefringence measurements and differential scanning calorimetry (DSC). Following 150 hours of exposure to UV irradiation, some transverse cracks on the surface of unfilled polypropylene fibers were observed. It was observed that both carbonyl and hydroperoxide indexes, which are the criteria for the detection of UV degradation of the fibers, were increased due to the increase in the UV irradiation exposure time and the increase in these indexes was smaller for nanocomposite fibers than those of unfilled Polypropylene fibers. It was also observed that crystallinity, crystallite size and total molecular orientation of UV irradiated nanocomposite fibers were increased in comparison with non-irradiated nanocomposite fibers. It was also found that the extent of increase in molecular orientation of the fibers was higher comparing to that for the nanocomposite fibers due to the UV irradiation exposure for the unfilled polypropylene fibers. Tensile properties of both unfilled and nanocomposite fibers were decreased after UV irradiation; this reduction correlated with the extent of the increase in molecular degradation of the fibers, as determined by measuring carbonyl and hydroperoxide indexes. 相似文献
16.
Debora Puglia Marco Monti Carlo Santulli Fabrizio Sarasini Igor Maria De Rosa Josè Maria Kenny 《Fibers and Polymers》2013,14(3):423-427
The effect of different treatments on the mechanical (tensile), thermal behavior (TGA), FTIR, and morphology of Phormium tenax fibers has been studied with the aim to investigate methods to improve their compatibility with polymer matrices. Applied treatments included sodium hydroxide (NaOH), silane (APTES, 3-aminopropyltriethoxysilane), and the combined application of silane treatment after NaOH. The effectiveness of the treatments in the removal of non-structural matter from the fibers was confirmed by FTIR investigation and TGA measurements, suggesting also that the alkali treatment has a strong effect on their thermal behavior. The study of tensile properties of the fibers performed using Weibull statistics indicates that the tensile properties are somewhat reduced by chemical treatment. The morphological investigation of treated fibers through scanning electron microscopy indicates that silane treatments, both on raw fibers and on alkalized ones, result in limited fiber degradation. 相似文献
17.
Amine-functionalized supports were prepared by chemical modification of cotton fibers using amino compounds namely diethylenetriamine (DET) and 1,4-diaminobutane (DB) in order to be loaded with copper ions. Evidence of attaching amine groups onto cellulosic fibers was confirmed through nitrogen and SEM analysis. Adsorption behavior of Acid Blue 25 from aqueous solutions onto [Cu(II)/DET-cotton] and [Cu(II)/DB-cotton] has been evaluated via batch and column mode systems. During the batch experiments, the effects of temperature and type of adsorbent on dye removal were investigated. Results revealed the formation of ternary complexes of the type [AB25/Cu(II)/adsorbent] with a [5/2:3:1] stoichiometry for DET-cotton and a [1:1:1] stoichiometry for DB-cotton at 20 °C. In the isotherm studies, Langmuir, Freundlich, and Jossens equations were applied and it was found that the experimental data conformed to Jossens model. Thermodynamic parameters such as change in free energy (ΔG 0), enthalpy (ΔH 0), and entropy (ΔS 0) have also been calculated in this paper, and it was found that the adsorption process was exothermic and spontaneous. The column experiments were conducted to study the effect of bed height on adsorption performance of both adsorbents. Results exhibited that the column capacity of [Cu(II)/DET-cotton] complex was found to be higher than that of [Cu(II)/DB-cotton] as was obtained in batch process. BDST model was applied to experimental data in order to predict the breakthrough curves and determine the characteristics parameters of the column useful for process design. Results revealed that the used model was appropriate to fit the experimental data. Desorption studies to recover the adsorbed dye from both adsorbents were performed with NaOH and NH4Cl solutions. 相似文献
18.
Rajendran R Sundaram SK Radhai R Rajapriya P 《Pakistan journal of biological sciences: PJBS》2011,14(9):519-525
The conventional scouring process involving the harsh environment is slowly being replaced with environment friendly approach using enzymes. These enzymes remove the non cellulosic impurities present in the fabric. Such a process would enhance the absorbency of the fabric without appreciable strength loss and also would help in the proper dyeing and finishing of the fabric. In the present work pectinase enzyme was isolated from Fusariumn sp. and was optimized under different cultural conditions. The partially purified pectinase enzyme was used in the scouring of cotton fabric. The efficiency of the bioscoured cotton fabric was compared with that of the conventionally scoured fabric. It was found that the water absorbing character of the bioscoured fabric was found to be considerably higher than that of the conventionally scoured fabric. Also, the tensile strength of the cotton fabric was found to be higher for the sample treated using pectinase enzyme than the sample treated conventionally. The results of FTIR confer that the pectin and wax impurities were removed from the cotton surface in both the conventionally scoured and bioscoured fabrics. 相似文献
19.
Guangxiu Tian Quan Ji Dongmei Xu Liwen Tan Fengyu Quan Yanzhi Xia 《Fibers and Polymers》2013,14(5):767-771
The study employs limiting oxygen index (LOI) measurements, cone calorimetry (CONE) and thermogravimetric analysis (TGA) to examine the catalytic effect of zinc ion content on the flame retardance and thermal degradation of alginate fibers. LOI results show that all zinc alginate fibers are intrinsically flame retardant, with LOI values of over 27.0, as compared with about 24.5 for alginic acid fiber. The heat release rate (HRR) and total heat release values of zinc alginate fibers (obtained from CONE) are significantly less than those of alginic acid fiber, and decrease with increasing zinc ion content. TGA indicates that char formation increases and maximum thermal weight-loss rate is reduced when zinc content in the fibers is increased. The residues of zinc alginate fibers keep their shapes better than those of the alginic acid fiber. Further discussion of the combustion process and flame retardant mechanism is presented. 相似文献
20.
The thermal stabilization stage of polyacrylonitrile (PAN) fibers is characterized by a steady and continuous reduction in fiber diameter and linear density values together with color changes from reddish brown to shiny black with increasing stabilization time. Thermally stabilized PAN fibers acquire infusible and nonburning characteristics prior to the carbonization stage. Structural characterization of thermally stabilized polyacrylonitrile fibers was carried out using an indepth analysis of equatorial X-ray diffraction traces. Curve fitting of X-ray diffraction traces provided accurate peak parameters which were subsequently used for the evaluation of apparent crystallinity, apparent crystallite size and X-ray stabilization index. The results showed the loss of crystallinity due to the amorphization processes together with a steady and continuous decrease in lateral crystallite size with increasing stabilization time. With the progress of thermal stabilization, a new amorphous phase with a crosslinked and aromatized structure is formed which is expected to withstand high carbonization temperatures. Mechanical properties of the thermally stabilized PAN precursor fibers were found to be adversely affected with the progress of stabilization time. Due to the influence of thermal degradation mechanisms heavily involving chain scission along the fiber axis direction, tensile strength and tensile modulus values were found to decrease by significant proportions with the prolonged stabilization times. 相似文献