Oxygen, Silicon, and Aluminum in Lunar Samples by 14 MeV Neutron Activation

Abundances of oxygen, silicon, and altiminutm in 27 lunar rocks and C aliquants of lunar soil have been determined by 14 MeV neutron activation. Mean abundances and standard deviations of individual abundances (in weight percent) within each type are: type A (2 rocks), 38.5 +/- 1.2 oxygen, 18.9 +/- 0.8 silicon, and 4.0 +/- 0.4 aluminum; type B (7 rocks), 39.4 +/- 1.0 oxygen, 18.7 +/- 0.8 silicon, and 5.0 +/- 0.6 aluminum; type C (18 rocks), 41.1 +/- 1.0 oxygen, 19.7 +/- 0.7 silicon, and 6.6 +/- 0.5 aluminum; soil (3 aliquants), 40.8 +/- 1.2 oxygen, 20.2 +/- 0.2 silicon, and 7.2 +/- 0.1 aluminum. Oxygen abundances are lower than those in most common terrestrial rocks and are comparable to those found in certain types of stony meteorites. From these results the lunar soil is most similar to the type C lunar rocks.     

Galilean satellites of jupiter: 12.6-centimeter radar observations

Observations of the Galilean satellites with the radar system at the Arecibo Observatory, Puerto Rico, show that their surfaces are highly diffuse scatterers of radio waves of length 12.6 centimeters; spectra of the radar echoes are asymmetric and broad. The geometric radar albedos for the outer three satellites-0.42 +/- 0.10, 0.20 +/- 0.05, and 0.09 +/- 0.02 for Europa, Ganymede, and Callisto, respectively-show about the same relative decreases as do the optical albedos, although the latter presumably bear only on material much nearer the surface. Radii of 1420 +/- 30, 2640 +/- 80, and 2360 +/- 70 kilometers for Europa, Ganymede, and Callisto were determined from the radar data and are in good agreement with the corresponding optically derived values. Io, observed successfully only once, appears to have an albedo comparable to Ganymede's, but no radius was estimated for it.     

Infrared observations of the saturnian system from voyager 2

During the passage of Voyager 2 through the Saturn system, infrared spectral and radiometric data were obtained for Saturn, Titan, Enceladus, Tethys, Iapetus, and the rings. Combined Voyager 1 and Voyager 2 observations of temperatures in the upper troposphere of Saturn indicate a seasonal asymmetry between the northern and southern hemispheres, with superposed small-scale meridional gradients. Comparison of high spatial resolution data from the two hemispheres poleward of 60 degrees latitude suggests an approximate symmetry in the small-scale structure, consistent with the extension of a symmetric system of zonal jets into the polar regions. Longitudinal variations of 1 to 2 K are observed. Disk- averaged infrared spectra of Titan show little change over the 9-month interval between Voyager encounters. By combining Voyager 2 temperature measurements with ground-based geometric albedo determinations, phase integrals of 0.91 +/- 0.13 and 0.89 +/- 0.09 were derived for Tethys and Enceladus, respectively. The subsolar point temperature of dark material on Iapetus must exceed 110 K. Temperatures (and infrared optical depths) for the A and C rings and for the Cassini division are 69 +/- 1 K (0.40 +/- 0.05), 85 +/- 1 K (0.10 +/- 0.03), and 85 +/- 2 K (0.07 +/- 0.04), respectively.     

Aluminum-26 in deep-sea sediment

The activity of (26)A1 in a North Pacific core was found to be 0.081 +/- 0.046 disintegration per minute per kilogram of dry sediment, which corresponds to a (26)A1/(10)Be ratio of 0.018 +/- 0.011 (or 0.019 +/- 0.012 when this ratio is corrected for decay). This ratio is in good agreement with that measured in Greenland ice, 0.017 +/- 0.008. These ratios are also in agreement with the calculated values for the production of these isotopes by cosmic rays in the atmosphere: 0.013 +/- 0.006. The contribution of cosmic dust bearing (26)Al seems small in comparison with the production of this nuclide in the atmosphere.     

Venus: global surface radar reflectivity

Observations of the surface of Venus, carried out by the Pioneer Venus radar mapper at a wavelength of 17 centimeters, reveal a global mean reflectivity at normal incidence of 0.13 +/- 0.03. Over the surface, variations from a low of 0.03 +/- 0.01 to a high of 0.4 +/- 0.1 are found, with Theia Mons, previously identified as possibly volcanic, showing a value of 0.28 +/- 0.07. Regions of high reflectivity may consist of rocks with substantial inclusions of highly conductive sulfides.     

Discovery of sodium and potassium vapor in the atmosphere of the moon

Spectra of the region just above the bright limb of the Moon show weak emission features that are attributed to resonant scattering of sunlight from sodium and potassium vapor in the lunar atmosphere. The maximum omnidirectional emission flux above the bright limb is 3.8 +/- 0.4 kilorayleighs for sodium and 1.8 +/- 0.4 kiloray-leighs for potassium. The zenith column densities above the subsolar point are estimated to be 8 +/- 3 x 10(8) atoms cm(-2) for sodium 1.4 +/- 0.3 x 10(8) atoms cm(-2) for potassium. Corresponding surface densities are 67 +/- 12 atoms cm(-3) and 15 +/- 3 atoms cm(-3), respectively. The scale height for the sodium atmosphere is 120 +/- 42 kilometers, and for potassium 90 +/- 20 kilometers, which implies that the effective temperature of the sodium and potassium is close to the lunar surface temperature. The sodium density at the south polar region was found to be similar to that at the subsolar point, indicating wide-spread distribution of sodium vapor over the lunar surface. The ratio of the density of sodium to the density of potassium is (6 +/- 3) to 1, which is close to the sodium to potassium ratio in the lunar surface, suggesting that the atmosphere originates from the vaporization of surface minerals.     

Erratum

In the report by L. D. Fetcher and Z. Annau [197, 680 (1977)], the values for whole brain dopamine levels in 1-day-old rats were given as 5.47 +/- 1.62 and 3.01 +/- 0.81, microg/g (wet weight) in air and CO subjects injected with L-dopa. The correct values are 5.47 +/- 0.38 and 3.01 +/- 0.20 microg/g. The difference between the groups is significant at P < .01 as reported.     

Observations of nuclear reactors on satellites with a balloon-borne gamma-ray telescope

Gamma rays at energies of 0.3 to 8 megaelectron volts (MeV) were detected on 15 April 1988 from four nuclear-powered satellites including Cosmos 1900 and Cosmos 1932 as they flew over a double Compton gamma-ray telescope. The observations occurred as the telescope, flown from a balloon at an altitude of 35 kilometers from Alice Springs, Australia, searched for celestial gamma-ray sources. The four transient signals were detected in 30 hours of data. Their time profiles show maxima with durations of (21 +/- 1) and (27 +/- 1) seconds (half-width at half maximum) for the lower two satellites and (85 +/- 5) and (113 +/- 7) seconds for the remaining two. Their durations place the origin of the two shorter signals at orbital radii of 260(+40)(-60) and 260 +/- 60 km above the earth and the two longer at 800(+100)(-300) and 800(+250)(-300) kilometers. Their luminosities for energies >0.3 MeV are then (6.1 +/- 1.5) x 10(15), (3.9 +/- 1.0) x 10(15), (1.10 +/- 0.28) x 10(16), and (1.30 +/- 0.32) x 10(16) photons per second. The imaging of the strongest signal indicates a southeastern direction passing nearly overhead. The energy spectrum can be fit to an exponential with index 2.4 +/- 1.4. These transient events add to the already large backgrounds for celestial gamma ray sources.     

Measurement of single-molecule resistance by repeated formation of molecular junctions

The conductance of a single molecule connected to two gold electrodes was determined by repeatedly forming thousands of gold-molecule-gold junctions. Conductance histograms revealed well-defined peaks at integer multiples of a fundamental conductance value, which was used to identify the conductance of a single molecule. The resistances near zero bias were 10.5 +/- 0.5, 51 +/- 5, 630 +/- 50, and 1.3 +/- 0.1 megohms for hexanedithiol, octanedithiol, decanedithiol, and 4,4' bipyridine, respectively. The tunneling decay constant (betaN) for N-alkanedithiols was 1.0 +/- 0.1 per carbon atom and was weakly dependent on the applied bias. The resistance and betaN values are consistent with first-principles calculations.     

Botanical and geological significance of potassium-argon dates from the juan fernandez islands

Potassium-argon dating of five basalts from the three main islands of the Juan Fernández (or Robinson Crusoe) Islands of Chile in the southeastern Pacific gives ages of 1.01 +/- 0.12 and 2.44 +/- 0.14 million years for Masafuera, 3.79 +/- 0.20 and 4.23 +/- 0.16 for Masatierra, and 5.8 +/- 2.1 for Santa Clara. These ages are much younger than that of the underlying oceanic plate and are consistent with the origin of the island-seamount chain from a mantle hot spot beneath the eastward moving Nazca plate. The young age for the archipelago suggests that speciation within endemic genera has occurred within the past 4 to 5 million years. Endemic genera of apparently more ancient origins, such as Lactoris and Thyrsopteris, have apparently dispersed to the islands and survive refugially.     

Garnet-like structures of high-pressure cadmium germanate and calcium germanate

Crystals of CdGeO(3) grown at a pressure of 65 kilobars are tetragonal and have an ordered, garnet-like crystal structure with cadmium occupying the dodecahedral and octahedral sites, and germanium the octahedral and tetrahedral sites. The crystal structure (a = 12.406 +/- 1 angstroms, c = 12.256 +/- 1 angstroms, and space group 14,/a) has been refined by least-squares analysis to an R (discrepancy index) of 0.073. Two high-pressure phases of CaGeO(3) were synthesized, one isotypic with tetragonal CdGeO(3) (a = 12.514 +/- 3 angstroms, c = 12.358 +/- 3 angstroms), and the other isotypic with perovskite.     

Infrared observations of the uranian system

The infrared interferometer spectrometer (IRIS) on Voyager 2 recorded thermal emission spectra of Uranus between 200 and 400 cm(-1) and of Miranda and Ariel between 200 and 500 cm(-1) with a spectral resolution of 4.3 cm(-1). Reflected solar radiation was also measured with a single-channel radiometer sensitive in the visible and near infrared. By combining IRIS spectra with radio science results, a mole fraction for atmospheric helium of 0.15 +/- 0.05 (mass fraction, 0.26 +/- 0.08) is found. Vertical temperature profiles between 60 and 900 millibars were derived from average polar and equatorial spectra. Temperatures averaged over a layer between 400 to 900 millibars show nearly identical values at the poles and near the equator but are 1 or 2 degrees lower at mid-latitudes in both hemispheres. The cooler zone in the southern hemisphere appears darker in reflected sunlight than the adjacent areas. An upper limit for the effective temperature of Uranus is 59.4 kelvins. Temperatures of Miranda and Ariel at the subsolar point are 86 +/- 1 and 84 +/- 1 kelvins, respectively, implying Bond albedos of 0.24 +/- 0.06 and 0.31 +/- 0.06, respectively. Estimates of phase integrals suggest that these satellites have unusual surface microstructure.     

Dentochronological separation estimates for pacific rim populations

Dental morphology of American Indians, Asians, and Pacific islanders is used with a multivariate statistic to estimate when genetic separation occurred between several populations. These estimates generally match independent estimates of separation. This method, called dentochronology, gives an American Indian fission date from Asians of about 13,000 +/- 3,000 years ago, which agrees with archeological data and rules out a European origin because of temporal priority. Polynesians split from Southeast Asians 5,000 +/- 2,200 years ago and are not derived from Melanesians. Ainu-Jomon originated in Sundaland 14,000 +/- 3,300 years ago. Africans have been separated from Asian-Americans 60,000 +/- 6,100 years.     

Matanchen complex: new radiocarbon dates on early coastal adaptation in west Mexico

Samples of marine shell from archeological context on the coast of Nayarit, Mexico, have given radiocarbon determinations of 1810 +/- 80 B.C., 2000 +/- 100 B.C., and 2100 +/- 100 B.C. Even with maximum correction for upwelling these are the earliest dates for coastal occupation in West Mexico north of Acapulco, Guerrero. Analysis of the midden contents has provided new insights regarding early coastal adaptation.     

Anomalous nitrogen isotope ratio in comets

High-resolution spectra of the CN B2 summation operator +-X2 summation operator + (0,0) band at 390 nanometers yield isotopic ratios for comets C/1995 O1 (Hale-Bopp) and C/2000 WM1 (LINEAR) as follows: 165 +/- 40 and 115 +/- 20 for 12C/13C, 140 +/- 35 and 140 +/- 30 for 14N/15N. Our N isotopic measurements are lower than the terrestrial 14N/15N = 272 and the ratio for Hale-Bopp from measurements of HCN, the presumed parent species of CN. This isotopic anomaly suggests the existence of other parent(s) of CN, with an even lower N isotopic ratio. Organic compounds like those found in interplanetary dust particles are good candidates.     

Mariner 9 celestial mechanics experiment: gravity field and pole direction of Mars

Analysis of the Mariner 9 radio-tracking data shows that the Martian gravity field is rougher than that of Earth or the moon, and that the accepted direction of Mars's rotation axis is in error by about 0.5 degrees . The new value for the pole direction for the epoch 1971.9, referred to the mean equatorial system of 1950.0, is right ascension alpha= 317.3 degrees +/- 0.3 degrees , declination delta = 52.6 degrees +/- 0.2 degrees . The values found for the coefficients of the low-order harmonics of Mars's gravity field are as follows: J(2)=(1.96+/-0.01)x10(-3), referred to an equatorial radius of 3394 kilometers; C(22) = -(5 +/- 1) x 10(-5); and S(22) = (3 +/- 1) x 10(-5). The value for J(2) is in excellent agreement with the result from, Wilkins' analysis of the observations of Phobos. The other two coefficients imply a value of (2.5 +/- 0.5) x 10(-4) for the fractional difference in the principal equatorial moments of inertia; the axis of the minimum moment passes near 105 degrees W.     

Crystal Structure of the High-Pressure Phase of Solid CO2

X-ray diffraction study of solid CO(2) at room temperature has shown that the powder pattern of the high-pressure phase, which supersedes the low-pressure cubic Pa3 phase at about 10 gigapascals, is consistently interpreted in terms of an orthorhombic Cmca structure. The orthorhombic cell at 11.8 gigapascals has dimensions of 4.330 +/- 0.015, 4.657 +/- 0.005, 5.963 +/- 0.009 angstroms for its a, b, and c faces, respectively, and a volume of 120.3 +/- 0.5 cubic angstroms. Four molecules contained in the unit cell are located at the base-centered positions with their molecular axes inclined at about 52 degrees with respect to the crystallographic c axis. The volume change associated with the Pa3-Cmca transition is close to zero. The structural dimensions obtained for the high-pressure crystalline phase of CO(2) are of great importance for a theoretical understanding of the role of intermolecular interactions, including quadrupole-quadrupole interactions, in molecular condensation.     

Xenon as a nucleophile in gas-phase displacement reactions: formation of the methyl xenonium ion

Xenon undergoes reaction with protonated methyl fluoride in the gas phase to form abundant quantities of the stable methyl xenonium ion, CH(3)Xe(+). Estimated values for the xenon-carbon and krypton-carbon bond strengths in the rare gas-methyl molecular ions are 43 +/- 8 and 21 +/- 15 kilocalories per mole, respectively.     

Voyager radio science observations of neptune and triton

The Voyager 2 encounter with the Neptune system included radio science investigations of the masses and densities of Neptune and Triton, the low-order gravitational harmonics of Neptune, the vertical structures of the atmospheres and ionospheres of Neptune and Triton, the composition of the atmosphere of Neptune, and characteristics of ring material. Demanding experimental requirements were met successfully, and study of the large store of collected data has begun. The initial search of the data revealed no detectable effects of ring material with optical depth tau [unknown] 0.01. Preliminary representative results include the following: 1.0243 x 10(26) and 2.141 x 10(22) kilograms for the masses of Neptune and Triton; 1640 and 2054 kilograms per cubic meter for their respective densities; 1355 +/- 7 kilometers, provisionally, for the radius of Triton; and J(2) = 3411 +/- 10(x 10(-6)) and J(4) = -26(+12)(-20)(x10(-6)) for Neptune's gravity field (J>(2) and J(4) are harmonic coefficients of the gravity field). The equatorial and polar radii of Neptune are 24,764 +/- 20 and 24,340 +/- 30 kllometers, respectively, at the 10(5)-pascal (1 bar) pressure level. Neptune's atmosphere was probed to a pressure level of about 5 x 10(5) pascals, and effects of a methane cloud region and probable ammonia absorption below the cloud are evident in the data. Results for the mixing ratios of helium and ammonia are still being investigated; the methane abundance below the clouds is at least 1 percent by volume. Derived temperature-pressure profiles to 1.2 x 10(5) pascals and 78 kelvins (K) show a lapse rate corresponding to "frozen" equilibrium of the para- and ortho-hydrogen states. Neptune's ionosphere exhibits an extended topside at a temperature of 950 +/- 160 K if H(+) is the dominant ion, and narrow ionization layers of the type previously seen at the other three giant planets. Triton has a dense ionosphere with a peak electron concentration of 46 x 10(9) per cubic meter at an altitude of 340 kilometers measured during occultation egress. Its topside plasma temperature is about 80 +/- 16 K if N(2)(+) is the principal ion. The tenuous neutral atmosphere of Triton produced distinct signatures in the occultation data; however, the accuracy of the measurements is limited by uncertainties in the frequency of the spacecraft reference oscillator. Preliminary values for the surface pressure of 1.6 +/- 0.3 pascals and an equivalent isothermal temperature of 48 +/- 5 K are suggested, on the assumption that molecular nitrogen dominates the atmosphere. The radio data may be showing the effects of a thermal inversion near the surface; this and other evidence imply that the Triton atmosphere is controlled by vapor-pressure equilibrium with surface ices, at a temperature of 38 K and a methane mixing ratio of about 10(-4).     

Evolution of planetary cores and the Earth-Moon system from Nb/Ta systematics

It has been assumed that Nb and Ta are not fractionated during differentiation processes on terrestrial planets and that both elements are lithophile. High-precision measurements of Nb/Ta and Zr/Hf reveal that Nb is moderately siderophile at high pressures. Nb/Ta values in the bulk silicate Earth (14.0 +/- 0.3) and the Moon (17.0 +/- 0.8) are below the chondritic ratio of 19.9 +/- 0.6, in contrast to Mars and asteroids. The lunar Nb/Ta constrains the mass fraction of impactor material in the Moon to less than 65%. Moreover, the Moon-forming impact can be linked in time with the final core-mantle equilibration on Earth 4.533 billion years ago.