Phosphorus losses from arable land in England

Abstract. Concentrations and annual loadings of molyhdate reactive P (MRP) and total (including particulate) P (TP) are reported from field drainage, catchment and erosion experiments in England. Annual losses through field drains and in catchment runoff were 0.037-0.74 kg MRP/ha and 0.37-2.64 kg TP/ha, but those in surface runoff from experimental plots measuring erosion were generally much greater (often > 3 kg MRP/ha and up to 32 kg TP/ha in a wet year). Amounts of TP in drainflow and catchment runoff depended upon factors influencing soil dispersibility, such as particle size distribution and calcium carbonate content. The results to date suggest that P losses in surface runoff and erosion from arable fields to water are best limited by: (a) maximizing crop cover, using minimal cultivation practices and where possible planting crop rows across rather than up and down the slope, (b) avoiding cultivation practices that result in dispersion of soil particles, and (c) avoiding application of P fertilizer to wet soils when rainfall is likely soon after application. Consideration should he given to maintaining field drains below peak efficiency to reduce subsurface P losses.     

Increased predicted losses of phosphorus to surface waters from soils with high Olsen-P concentrations

Abstract. Diffuse soluble reactive P (SRP) & total P (TP) loads from over 50 major river catchments in Northern Ireland were predicted using an export coefficient modelling approach. Phosphorus export coefficients for each CORINE land cover class, derived from satellite imagery, allowed the prediction of P loads from a breakdown of the CORINE land cover classes by catchment using a GIS. This approach was validated using observed P loads calculated from flow and concentration data. Mean measured Olsen-P concentrations in the soil A-horizon were also determined on a catchment basis. Plots of P loads to the watercourse versus Olsen-P concentrations in the soil showed a breakpoint around 22 mg Olsen- P l⁻¹ for both SRP & TP data. Below Olsen-P concentrations of 22 mg l⁻¹, SRP & TP losses were essentially independent of Olsen-P at 0.28 and 0.63 kg P ha⁻¹ yr⁻¹, respectively. Above Olsen-P concentrations of 22 mg l⁻¹, there was considerable spread in the P loss data. Nevertheless, significant upward trends in SRP and TP losses to watercourses were detected with increasing Olsen-P at a rate of approximately 0.5 and 1.0 kg P ha⁻¹ yr⁻¹, for SRP and TP respectively, for each 10 mg l⁻¹ increase in Olsen-P.     

The use of porous ceramic cup water samplers to measure solute leaching on chalk soils

Abstract. This paper reports results from a four year study to investigate the suitability of porous ceramic cups to measure solute leaching on shallow chalk soils. Measurements were carried out in one field following surface applications of nitrate and bromide tracers and in two fields after only bromide was applied. Soil water samples were collected from porous cups at 30,60 and 90cm depth after every 25 mm of drainage, and soil samples from 0–30, 30–60 and 60–90 cm were collected monthly eachwinter. Soil matric suctions andvolumetric moisture content were measured in one winter. Leaching losses, measured with ceramic cups were compared with those measured by soil analysis. Porous cups installed in chalk at 60 and 90 cm depth were only able to collect samples regularly when soil matric suctions were less than 15 kPa. Water held at such low suctions is likely to move quickly through relatively large fissures in the chalk. The slow rate of equilibration between solute concentrations in water moving in macrofissures and those in water moving through micropores of the chalk matrix, means that porous cups may not provide good estimates of leaching losses if they are installed in chalk rock.     

Assessment of potassium in soils

Abstract

Potassium in soils from selected plots of the Broadbalk Experiment at Rothamsted, and Rotation I experiment at Saxmundham, U.K. was measured by five methods: the boiling nitric acid extractions of Haylock and Maclean, electro‐ultrafiltration, release to Ca‐saturated ion exchange resin, and a new procedure using extraction by HCl under reflux. All. the methods showed clearly the Gifferences between the two soil types, and between the differently fertilized plots on the basis of amounts, and 1n some cases rates of release, of different categories of soil K (exchangeable, fixed and native). The quantity of exchangeable K measured by each method, except that by Ca‐resin, gave significant correlations with the K balance of the soils, and yield and/or K offtake of winter wheat grown on the plots. The new HCl ‐reflux method gave the closest correlations. The amount and rate of release of fixed (available but not exchangeable) K estimated by HCl‐reflux was also correlated with yield and offtake.     

Simple phosphorus saturation index to estimate risk of dissolved P in runoff from arable soils

Abstract. There is increasing evidence that phosphorus has been accumulating in the surface horizons of agricultural soils to the extent that some soils represent a potential diffuse source of pollution to surface waters. The relationships between equilibrium phosphorus concentration at zero sorption (EPC ₀) of soil and a number of soil physicochemical variables were investigated in the surface layers of arable and grassland agricultural soils sampled from the Thame catchment, England. Soil EPC₀ could be predicted from an equation including soil test (Olsen) P, soil phosphate sorption index (PSI) and organic matter content (OM) (R²=0.88; P <0.001) across a range of soil types and land use. The simple index Olsen P/PSI was found to be a good predictor of EPC₀ (R²=0.77; P <0.001) and readily desorbable (0.02 m KCl extractable) P (R²=0.73; P <0.001) across a range of soil types under arable having soil organic matter contents of <10%.     

Phosphorus loss from agricultural catchments: pathways and implications for management

Abstract. The contribution non-point P sources make to the total P loading on water bodies in agricultural catchments has not been fully appreciated. Using data derived from plot scale experimental studies, and modelling approaches developed to simulate system behaviour under differing management scenarios, a fuller understanding of the processes controlling P export and transformations along non-point transport pathways can be achieved. One modelling approach which has been successfully applied to large UK catchments (50-350km² in area) is applied here to a small, 1.5 km² experimental catchment. The importance of scaling is discussed in the context of how such approaches can extrapolate the results from plot-scale experimental studies to full catchment scale. However, the scope of such models is limited, since they do not at present directly simulate the processes controlling P transport and transformation dynamics. As such, they can only simulate total P export on an annual basis, and are not capable of prediction over shorter time scales. The need for development of process-based models to help answer these questions, and for more comprehensive UK experimental studies is highlighted as a pre-requisite for the development of suitable and sustainable management strategies to reduce non-point P loading on water bodies in agricultural catchments.     

Estimation of carbon losses by cultivation from soils of the Argentine Pampa using the Century Model

Abstract. The Century model was used for estimating soil carbon levels under grassland at the regional scale in the Pampean Region of Argentina. Predicted values were compared with observed soil carbon contents obtained from soil surveys and the differences considered to be the results of cropping on soil organic matter. The Pampean Region was divided into five major sub-regions and carbon in the top 20 cm of each estimated by Century using aggregated soil and climatic data. In four of the sub-regions small differences between predicted and observed carbon contents were obtained which suggested little land use effect on soils. In the Rolling Pampa, a northern portion of the Pampean Region, observed carbon content was about half of Century prediction. In this sub-region, the main agricultural area of the country, cropping intensity, rainfall and temperature are higher than in the rest of the Pampas. A degradation index constructed by a multiplicative approach, taking into account percentage of surface cropped, rainfall and temperature was 2–5 times higher in the Rolling Pampa than in the other pampean sub-region. The difference between predicted C and observed C in the Rolling Pampa was attributed to carbon losses by cropping in a warm and wet climate.     

Evaluation of leaching and runoff losses of selenium from seleniferous soils through simulated rainfall

Experiments were conducted to study drainage and runoff losses of selenium (Se) from two seleniferous soils (from Simbly containing total Se 850 μg [kg soil]^–1 and from Barwa containing 1310 μg [kg soil]^–1) under simulated rainfall (250–260 mm in three rainstorms) conditions. Rainfall intensities ranged from 56 to 120 mm h^–1 with uniformity coefficients ranging from 70.6% to 84.2%. Selenium lost through drainage (sum of drainage from initially saturated soil for 24 h and through dry and wet runs) was 0.15% and 0.11% of total Se content in the two soils. In soils having similar pH and organic‐C content, losses of Se through drainage as well as runoff were defined by total Se, water‐soluble Se, CaCO₃ content, and texture of the soils. The amount of runoff water was almost two times in the soil with fine texture and less infiltration rate than in the other and that same trend was observed with respect to loss of sediment. The soil with higher CaCO₃ content and water‐soluble Se lost more Se with moving water both through leaching and runoff, whereas the other soil with fine texture lost greater amount of Se with the sediment. Total Se lost through drainage as well as runoff was 0.29% of the native Se present in both the soils suggesting that significant amount of Se could be lost from seleniferous soils during irrigation and rainfall events.     

土壤中磷、钾、钙、镁的同时提取以及对巴西南部作物的钾肥推荐

Simultaneous multi-element extraction has been increasing worldwide to improve soil laboratory testing quality and effciency. This study sought to investigate the applicability of the Mehlich-1, Mehlich-3, and resin methods for simultaneous extraction of soil available P, K, Ca, and Mg as well as the effect of using conversion equations on nutrient recommendations for crops. Topsoil (0-20 cm) samples were taken from the most representative soil types used for crop production in southern Brazil with a wide range of chemical, physical, and mineralogical properties. Soil P, K, Ca, and Mg were simultaneously extracted using 1.0 mol L-1 KCl, Mehlich-1 and Mehlich-3 solutions, and membrane resin. The amounts of P extracted with the Mehlich-1 method were, on average, 50% lower than those extracted with the resin and Mehlich-3 methods. However, the resin method extracted the lowest amounts of K, Ca, and Mg. The use of conversion equations was suitable and it did not a?ect negatively the K recommendations for crops grown on soils of southern Brazil.     

Progress in studies of nitrate leaching from grassland soils

Abstract. The large input of research effort on aspects of nitrate leaching over the last two decades has produced many innovative scientific and practical results. The MAFF Nitrate Programme has enabled considerable progress to be made in unravelling much of the complexity of the grassland nitrogen (N) cycle, and identifying gaps as essential first stages in providing improved managements for N in grassland systems. From a practical standpoint, there have been key outputs which have allowed the identification of options for policy, and which should allow grassland farmers to increase the efficiency of N use throughout their farming system and thereby improve the sustainability of their enterprises. As well as quantifying N transformations, transfers and losses, other important outcomes have been the development of user-friendly models of N cycling (NCYCLE and variants) and an easy to use field kit to determine mineral N in pasture soils. The use of modelling to produce fertilizer recommendations with a Decision Support System and of new approaches developed within the Programme, in particular system synthesis desk studies, and 'farmlet' investigations to determine the consequences of modifying N flows and losses, have allowed us to produce solutions to satisfy the dual aims of meeting environmental and economic production targets.     

Factors affecting potassium fixation in calcareous soils of southern Iran

Potassium fixation capacity and mineralogical analysis of 24 representative soils, collected from southern Iran, were studied. Potassium fixation analysis was performed by adding six rates of K from 0 to 1000 mg kg^?1 soil in a plastic beaker and shaking for 24 h. Mineralogical analysis showed that the clay fractions were dominated by smectite, chlorite, mica, palygorskite, vermiculite and quartz. In general, the studied soils fixed 8.5–55% of the added K. The potassium fixation capacity of the studied soils was significantly correlated with smectite content (r ² = 0.87), clay content (r ² = 0.60), cation-exchange capacity (r ² = 0.79) and NH₄OAc-K. Wetting and drying treatment and incubation time had significant effects on K fixation. The average percentage increase in K fixation following the wetting and drying treatment was 24 and 30% for surface and subsurface soils, respectively. The average percentage increase in K fixation with increasing residence time was 79 and 56% for surface and subsurface soils, respectively. Because K fixation is a diffusion process, time and increased concentration of soluble K (because of soil drying) are factors affecting the rate of K diffusion from a soil solution to the interlayer positions of the expansible 2:1 clay minerals.     

Phosphorus cycling in UK agriculture and implications for phosphorus loss from soil

Abstract. Phosphorus (P) use in UK agriculture is reviewed and a P balance sheet presented. The productive grassland and arable area has accumulated an average P surplus of c. 1000 kg ha^–1 over the last 65 years. Over the period 1935–1970, the annual P surplus more than doubled due to an increase in animal numbers and associated requirements for inorganic fertilizers and livestock feeds. Since 1970, surplus P has declined by c . 40% as crop yields and P offtake have continued to increase while fertilizer and manure P inputs have remained relatively constant. In 1993, P use efficiency (P imports/P exports) in UK agriculture was estimated at 25% leading to an average annual surplus of 15 kg P ha^–1 yr^–1, although the latter has since decreased slightly due to reduced fertilizer use. Intensification and specialization of agriculture has also increased the range in P surpluses that are likely between livestock and arable dominated systems. The largest P surpluses occur in the relatively limited areas of arable soils which receive manure from intensive pig and poultry units, whilst farms without manure inputs generate only small surpluses, or are in balance. The cumulative P surplus has led to a build-up of soil total and easily-exchangeable P, especially in areas receiving both fertilizers and manures. Fundamental differences in P use efficiency, surplus P accumulation and the potential for P loss to water, exist between arable and grassland farms and it is important to separate these, due to the marked regionalization of UK agriculture. More judicial use of feeds and fertilizers is required to further reduce the P surplus and minimize the long-term risk of water eutrophication.     

Thin section studies of Calluna heathland soils subject to prescribed burning

Abstract. Soil microstructures and biological activity were studied in thin sections of Culluna heathland soils subject to periodic burning. Freely drained Brown Podzolic soils from a species-rich heath at Dinnet Muir, Aberdeenshire, Scotland were compared with shallow Humo-ferric Podzols with a thick humus layer (5–10 cm) supporting a species-poor heath at Balmenach, Aberdeenshire.
Structures with greater porosity occurred in all Dinnet soils and the most recently burned Balmenach soil. Burning led to an increase in soil porosity which gradually disappeared after a period of 2–3 years. Soils of the recently burned site had more enchytraeid worms than those burned ten years previously. Most of the Dinnet soil samples were dominated by extremely fine granular structure which could have been produced by flocculation of well decomposed organic matter or by enchytraeid worms. In recently burned sites the increase in soil macro- and microbial activities may lead to the formation of composite structures.
Regular burning every 10–15 years has been the land management practice in Scottish heathlands to ensure the production of fresh browse of nutritious heather shoots for herbivores. The near-ground microclimate and regeneration mechanisms of heathland plants are well adjusted to the periodic disturbance by fire. We found that the gradual decrease in surface soil porosity over time can be restored by prescribed burning. Soil structure and the distribution and continuity of pores in the soil profile directly affect soil water movement and retention. These factors have important ecological implications for post-fire vegetation recovery.     

Effects of liming on soil magnesium on some soils in New Zealand

Abstract

Results from 2 pastoral field lime trials showed that liming reduced exchangeable Mg. This effect increased with increasing rate of lime and with time following lime application, and was greatest in the top 0–50 mm depth. Soil solutions, sampled 2 years after liming, showed that solution Mg increased in increasing rate of lime. This effect was greatest in the top 20 mm of soil.

Lime incubation studies indicated that Mg fixation did occur on some of the soil studied, at pH >6.2. However, this did not account for the size of the observed effects of liming on exchangeable Mg in the field or explain the observed effects of liming at pH <6.2.

It is suggested therefore, that the major mechanism by which liming reduces exchangeable Mg, on these soils, is through displacement of exchangeable Mg into solution by the added Ca in lime, and subsequent leaching.

Results from other field trials suggest that liming will decrease exchangeable Mg if the change in pH‐dependent CEC (?ECEC) per unit change in soil pH is <15 me 100 g‐¹.     

紫色土发育成的水稻土微团粒结构中有机－无机复合体的性质

This paper deals with characteristics of organo-mineral complexing of microaggregates in the paddy soils developed from purple soils in Sichuan, China. Results show that the contents of organic matter in microaggregates are in the order of 1-0.25 mm > smaller than 0.05 mm > 0.05-0.25 mm. But the organic matter in 1-0.01 mm microaggregates accounts for 68.1%-78.7% of that in soil. The organic matter in < 0.05 mm microaggregates is complexed humus on the whole, of which the degree of organo-mineral complexing varies between 96.1% and 99.5%, which is higher than that of the soil or > 0.05 mm microaggregates. The contents of loosely combined humus and the ratios of loosely and tightly combined humus markedly decline with the size of microaggregates. Flesh soil humus formed from semi-decomposed organic material or organic manure added is combined first with < 0.001 mm clay, and then aggregated with other organic and mineral particles to form larger microaggregates, in which the aging of humus happens at the same time; whereas organic matter of the light fraction is mainly involved in the formation of > 0.05 mm microaggregates.     

Nutrient losses by surface run-off from soils with winter cover crops and spring-ploughed soils in the south of Sweden

Winter cover crops are used as a method of reducing nitrogen (N) losses from arable land in several countries, but their effect on phosphorus (P) losses is poorly documented. Run-off and losses of nutrients and soil were measured from a clay loam with autumn-ploughed and spring-ploughed plots and from plots with winter wheat during three winter seasons (1993–1996) in Holland County in south western Sweden. The run-off water was collected in troughs dug into the soil at the end of collecting slopes placed in the experimental plots. As a result of the weather, there was only one winter in which surface run-off occurred to any great extent. On average, 75% of P was in particulate form (P_part). Neither winter wheat (Triticum aestivum L.) nor catch crops of English ryegrass (Lolium perenne L.) reduced losses of P_part when compared with losses from autumn-ploughed soil; and losses from spring-ploughed soil containing stubble and weeds were no lower than those from autumn-ploughed soil. Losses of P_part from all treatments were moderate considering its low bio-availability. Concentrations of phosphate phosphorus (PO₄-P) were low, with a mean 0.04 mg 1⁻¹. Despite a significant increase in losses of PO₄-P from spring-ploughed soil covered with stubble and catch crops or weeds compared with that in autumn-ploughed soil, the extra input from this P source was at most 2 g ha⁻¹ yr⁻¹. This mass loss was equal to 0.5 g kg⁻¹ of the total mass of P in the vegetation. Thus, only very small extra P surface losses were found with winter cover crops compared with those with bare soils. N losses in run-off were low in all treatments.     

Potassium release from sand,silt and clay fractions in calcareous soils of southern Iran

The release of non-exchangeable potassium from 24 calcareous soils of divergent mineralogy, from southern Iran, was examined. Sand, silt and clay particles were fractionated after dispersion with an ultrasonic probe. Samples were extracted with 0.01 M CaCl₂ for 30 successive 2-h periods. The clay fraction released the largest amount of K in each soil. Cumulative K released ranged from 175 to 723, 35 to 128, and 71 to 146 mg kg^?1 contributing 20–90, 4–39 and 2–54% for clay, silt and sand fractions, respectively. The lower proportion of K released from sand and silt fractions can be explained by the presence of a high content of CaCO₃ and quartz in these fractions. The release kinetics for the non-exchangeable K data showed that parabolic diffusion and power function were the best fitting kinetic models. This indicated that slow diffusion of K from the mica interlayer positions is the main rate-controlling process. Cumulative K released and constant b values of parabolic diffusion model correlated significantly with the mica content of the clay fraction.     

Estimation of nitrogen and phosphorus losses to surface water and groundwater through the implementation of the SWAT model for Norwegian soils

Scope and Background

It is acknowledged that diffuse sources cause the most important nitrogen (N) and phosphorus (P) losses to the river system and substantially enrich the groundwater in nitrates. These losses arise primary from agricultural activities mainly fertilizer applications, and they are determined by soil attributes. In cold climates, winter conditions and freezing of soils may influence the infiltration capacity of the soil and thereby can have a serious effect on the partitioning of excess precipitation and subsequently on the soil and nutrient transportation. The purpose of this article is to investigate the behaviour of six widespread and different textured soil types, on nutrient (N, P) losses under cold climate conditions. The investigation was conducted in the Norwegian Vansjø-Hobølv catchment through the application of a physical model named Soil and Water Assessment Tool (SWAT), taking into consideration the additional aspect of freezing soils during winter, which distinguishes Scandinavian from other European soils.

Methods

SWAT is a physical river basin model that was developed for the U.S.D.A. Agricultural Research Service, by the Blackland Research Center in Texas. In the current modeling approach the catchment was divided into 43 Hydrologic Response Units (HRUs) which consist of different combinations of the existed landcover and soil types. Nitrogen and phosphorus losses arising from these HRUs were estimated for the period 1990–2001 through the simultaneous simulation of water and sediment processes that are closely linked to the nutrient processes. The model took into account soil temperature in order to quantify water and nutrient transport to deeper layers, considering negligible downward movement when the soil temperature was under 0°C. It also simulated the aboveground development of the snowpack and the snowmelt processes on a daily basis. The six different soil types were distinguished in two groups according to their similarity in texture and other physical properties, one group of fine-textured soils and a group of coarse soils. The results were evaluated for different crop cultivations (barley, oats and wheat) of the aforementioned soils. Finally, the model was calibrated and validated by comparing predicted results with measured data.

Results and Discussion

Fine-textured soils caused significant runoff, sediment, total nitrogen (TN) and total phosphorus (TP) yields to the river system while coarser soils were characterized by high water drainage and nitrates leaching. The first soil group caused a mean of 517 mm of runoff in annual basis, 200 mm higher than this arising from coarse soils. Moreover, 3 tonnes of sediments per hectare, 24.6 kgN/ha and 0.54 kgP/ha were lost annually to surface water from fine soils while the average respective losses originating from coarse soils were only 1.3 tn of sediments/ha, 13.6kgN/ha and 0.17kgP/ha. The sensitivity ranking of the soil types to TN and TP losses was silty-clay-loam>silty-loam>clay>loamy>sandy-loam>sandy. An average of 277 mm of water was percolated annually under the bottom of the soil profile in coarse soils causing the additional leaching of 5.6 kgN-NO₃/ha whereas the losses originating from fine-textured soils were 153 mm and 2.5 kg/ha respectively. According to their sensitivity in nitrates leaching, the six soil types were ranked in the following order: sandy>loamy>sandy-loam>silty-loam>silty-clay-loam>clay.

Conclusions and Perspectives

The results showed that even though under cold climate conditions, with monthly periods of average air-temperatures below zero, the overall amounts of annual TN and TP losses to surface waters as well as nitrates leaching to groundwater were considerable. This demonstrates that the cold climate conditions did not affect the long-term behavior of the six widespread Norwegian soils, which on an annual basis responded similarly to the respective European soils. According to the model’s estimations, infiltration with N and P transport still occur in wintertime, and comparing to other studies that reported similar results, different possible explanations were considered. The results demonstrate the need of considering the soil differentiation in Scandinavian countries similarly to the rest of Europe in order to apply mitigation measures against nitrogen and phosphorus losses to surface and groundwater.

     

Nitrate Sensitive Areas: a study of large scale control of nitrate loss in England

Abstract. The Pilot Nitrate Sensitive Areas Scheme was set up in England in 1990 to test measures aimed at reducing nitrate losses from agricultural land. Ten groundwater catchments were chosen to typify the geology and farming of areas where nitrate concentrations in abstracted water were high. Voluntary and compensated controls on farming, based on recent research, were introduced. Scheme membership was for 5 years from 1990 or 1991, and 86% of the agricultural land entered the Scheme. On all farms entering the Scheme, manure and fertilizer use were restricted and green cover crops were required over winter (Basic Scheme). Additional payments were available for conversion of arable land to zero or low-input grassland (Premium Scheme). Intensive pig and poultry farmers were assisted with the costs of transporting manure for spreading over a wider area. The most effective changes were improved management of livestock manures, especially of the very large local quantities from housed pig or poultry units; conversion of arable land to low-input grassland; and use of cover crops. There were no indications of reduced crop yields but some requirements increased costs and management complexities. Estimates based on both model calculations and measurements indicated that nitrate losses from agricultural land decreased by about 30%, with considerable variation between areas.