Changes in soil properties and soil solution nutrients due to conservation versus conventional tillage in Vertisols

Understanding of tillage effects on soil chemical properties and cations in soil solution dynamics is essential for making appropriate land-management decisions. Measurements were made after more than 25 years of different tillage treatments: conventional tillage (CT) and conservation tillage, which includes no-till (NT) and minimum tillage (MT). pH and bulk density did not show important changes but exchangeable cations and cations in soil solution were affected by depth and different tillage. The highest concentration of exchangeable Ca²⁺ and Mg²⁺ was found in NT, decreased in MT and the lowest concentration was found in CT (mean values were 26.0, 24.4 and 23.3 cmol_c kg^?1 for exchangeable Ca²⁺ and 4.2, 3.7 and 3.3 cmol_c kg^?1 for exchangeable Mg²⁺ in NT, MT and CT, respectively). In addition, the highest concentration of exchangeable Na⁺ was found in NT, decreased in CT and the lowest concentration was found in MT. However, the highest concentration of exchangeable K⁺ was found in MT. A significant depth effect was observed for cations in soil solution: Na⁺ increased with depth whereas K⁺ and Ca²⁺ decreased with depth. This study aims to demonstrate the effect of tillage on the distribution and concentration of certain chemical soil properties.     

Lime and Cattle Manure in Soil Fertility and Soybean Grain Yield Cultivated in Tropical Soil

Most tropical soils have high acidity and low natural fertility. The appropriate application of lime and cattle manure corrects acidity, improves physical and biological properties, increases soil fertility, and reduces the use of chemical and/or synthetic fertilizers by crops, such as soybean, the main agricultural export product of Brazil. This study aimed to assess the effects of the combination of the application of dolomite limestone (0, 5, and 10 Mg ha^?1) and cattle manure (0, 40, and 80 Mg ha^?1) on grain yield and the chemical properties of an Oxisol (Red Latosol) cultivated with soybean for two consecutive years. The maximum grain yield was obtained with the application of 10 Mg ha^?1 of lime and 80 Mg ha^?1 of cattle manure. Liming significantly increased pH index, the concentrations of calcium (Ca²⁺) and exchangeable magnesium (Mg²⁺), and cation exchange capacity (CEC) of soil and reduced potential acidity (H⁺ + Al³⁺), while the application of cattle manure increased pH level; the concentrations of potassium (K⁺), Ca²⁺, and exchangeable Mg²⁺; and CEC of the soil. During the 2 years of assessment, the greatest grain yields were obtained with saturation of K⁺, Ca²⁺, and Mg²⁺ in CEC at the 4.4, 40.4, and 17.5 levels, respectively. The results indicated that the ratios of soil exchangeable Ca/Mg, Ca/K, K/Mg, and K/(Ca+Mg) can be modified to increase the yield of soybean grains.     

Spatial Distribution of Surface Soil Acidity,Electrical Conductivity,Soil Organic Carbon Content and Exchangeable Potassium,Calcium and Magnesium in Some Cropped Acid Soils of India

Land degradation is a global problem. Best management of degraded land can be done by evaluating the spatial variability of soil properties including chemical properties of degraded land and mapping such variations. Since, a significant portion of arable land in India is chemically degraded due to soil acidity; the present study was conducted to study the spatial variability of soil acidity (pH), electrical conductivity (EC), soil organic carbon (OC) content, exchangeable potassium (K⁺), calcium (Ca²⁺) and magnesium (Mg²⁺) contents in some cropped acid soils of India. A total of four hundred (one hundred from each series) representative surface (0–0.15 m depth) soil samples were collected from arable soils representing four soil series namely Hariharapur, Debatoli, Rajpora and Neeleswaram situated in Orissa, Jharkhand, Himachal Pradesh and Kerala states of India, respectively, and were analyzed. Soil acidity (pH between 3.90 and 6.45) showed a low variability, in contrast to other soil properties, which showed moderate variability. The coefficients of variation varied from 32.4 to 74.3, 31.2 to 50.9, 45.6 to 100, 71.9 to 93.0 and 59.0 to 79.8% for EC (mean between 0.05 and 0.09 dS m⁻¹), OC (mean between 0.29 to 1.86%), exchangeable K⁺ (mean between 39.1 and 77.7 mg kg⁻¹), Ca²⁺ (mean between 148 and 293 mg kg⁻¹) and Mg²⁺ (mean between 111 and 191 mg kg⁻¹), respectively. Soil pH and OC content were positively and significantly correlated with exchangeable K⁺, Ca²⁺ and Mg²⁺ content. Geostatistical analysis revealed that the best fit models were gaussian, exponential and spherical for different soil properties with moderate to strong spatial dependency. Copyright © 2014 John Wiley & Sons, Ltd.     

Effect of low energy-consuming biochars in combination with nitrate fertilizer on soil acidity amelioration and maize growth

Purpose

We evaluated the ameliorative effects of crop straw biochars either alone or in combination with nitrate fertilizer on soil acidity and maize growth.

Materials and methods

Low energy-consuming biochars were prepared from canola and peanut straws at 400 °C for 2 h. Incubation experiment was conducted to determine application rate of biochars. Afterward, maize crop was grown in pots for 85 days to investigate the effects of 1 % biochars combined with nitrate fertilizer on soil pH, exchangeable acidity, and maize growth in an Ultisol collected from Guangdong Province, China.

Results and discussion

Application of 0.5, 1.0, and 1.5 % either canola straw biochar (CSB) or peanut straw biochar (PSB) increased soil pH by 0.15, 0.27, 0.34, and 0.30, 0.58, 0.83 U, respectively, after 65-day incubation. Soil pH was increased by 0.49, 0.72, 0.78, and 0.88 U when 1 % CSB or PSB was applied in combination with 100 and 200 mg N/kg of nitrate, respectively, after maize harvest in greenhouse pot experiment. These low-cost biochars when applied alone or in combination with nitrate not only reduced soil exchangeable acidity, but also increased Ca²⁺, Mg²⁺, K⁺, Na⁺, and base saturation degree of the soil. A total of 49.91 and 80.58 % decreases in exchangeable acidity were observed when 1 % CSB and PSB were incubated with the soil for 65 days, compared to pot experiment where 71.35, 78.64, 80.2, and 81.77 % reductions of exchangeable acidity were observed when 1 % CSB and PSB were applied in combination with 100 and 200 mg N/kg of nitrate, respectively. The higher contents of base cations (Ca²⁺, Mg²⁺, K⁺, Na⁺) in biochars also influenced the plant growth. The higher biomass in CSB-treated pots was attributed to the higher K content compared to PSB. The higher percent reduction in exchangeable Al³⁺ by applying 1 % CSB combined with 200 mg N/kg of nitrate consistently produced maximum biomass (129.65 g/pot) compared to 100 mg N/kg of nitrate and 1 % PSB combined with 100 and 200 mg N/kg of nitrate. The exchangeable Al³⁺ mainly responsible for exchangeable acidity was decreased with the application of biochars and nitrate fertilizer. A highly significant negative relationship was observed between soil exchangeable Al³⁺ and plant biomass (r ²?=?0.88, P?<?0.05).

Conclusions

The biochars in combination with nitrate fertilizer are cost-effective options to effectively reduce soil acidity and improve crop growth on sustainable basis.

     

Yield,Nutrient Uptake,and Soil Chemical Properties as Influenced by Liming and Boron Application in Common Bean in a No‐Tillage System

Abstract

In Oxisols, acidity is the principal limiting factor for crop production. In recent years, because of intensive cropping on these soils, deficiency of micronutrients is increasing. A field experiment was conducted on an Oxisol during three consecutive years to assess the response of common bean (Phaseolus vulgaris L.) under a no‐tillage system to varying rates of lime (0, 12, and 24 Mg ha^?1) and boron (0, 2, 4, 8, 12, 16, and 24 kg ha^?1) application. Both time and boron (B) were applied as broadcast and incorporated into the soil at the beginning of the study. Changes in selected soil chemical properties in the soil profile (0- to 10‐ and 10- to 20‐cm depths) with liming were also determined. During all three years, gain yields increased significantly with the application of lime. However, B application significantly increased common bean yield in only the first crop. Only lime application significantly affected the soil chemical properties [pH; calcium (Ca²⁺); magnesium (Mg²⁺); hydrogen (H⁺)+ aluminum (Al³⁺); base saturation; acidity saturation; cation exchange capacity (CEC); percent saturation of Ca²⁺, Mg²⁺, and potassium (K⁺); and ratios of exchangeable Ca/Mg, Ca/K, and Mg/K] at both soil depths (0–10 cm and 10–20 cm). A positive significant association was observed between grain yield and soil chemical properties. Averaged across two depths and three crops, common bean produced maximum grain yield at soil pH_w of 6.7, exchangeable (cmol_c kg^?1) of Ca²⁺ 4.9, Mg²⁺ 2.2, H⁺+Al³⁺ 2.6, acidity saturation of 27.6%, CEC of 4.1 cmol_c kg^?1, base saturation of 72%, Ca saturation of 53.2%, Mg saturation of 17.6%, K saturation of 2.7%, Ca/Mg ratio of 2.8, Ca/K ratio of 25.7, and Mg/K ratio of 8.6. Soil organic matter did not change significantly with addition of lime.     

水溶性阳离子在工程黄土中的扩散特性

该文采用水平扩散池观测了水溶性盐阳离子在工程黄土中的扩散过程。结果表明：水溶性盐阳离子在土壤中的扩散性因离子种类而异,Ｃａ＾２＋的扩散系数最高,Ｍｇ＾２＋,Ｎａ＾＋,Ｋ＾＋依次降低,其由两个模型测定的平均值分别为２．６９２８×１０＾－６,２．３１２７×１０＾－６,１．６７３０×１０＾－６,０．４５０４×１０＾０－６ｃｍ＾２／ｓ。在距源溶液较近时,土壤胶体交换性Ｋ＾＋,Ｎａ＾＋,Ｍｇ６２＋均明显升高     

Can highly saline irrigation water improve sodicity and alkalinity in sodic clayey subsoils?

Purpose

The concept of irrigating crops with saline irrigation water is not new, but impacts of this practice on soil properties remain debatable, particularly the use of highly saline water. In this work, key soil chemical properties were assessed to a depth of 300 cm following 2.5 years of application of highly saline irrigation to a sodic texture-contrast soil (Brown Sodosol) in south-eastern Tasmania, Australia.

Materials and methods

Control plots (rainfall only) were compared to irrigation treatments of low (0.8 dS/m) and high salinity (16 dS/m) waters at application rates of both 200 and 800 mm/year.

Results and discussion

Whilst significant increases in both electrical conductivity and chloride concentration occurred throughout the soil profile in the high salinity treatment, these values were well below those of the irrigation water, indicating effective deep leaching. In the upper soil profile, 0–50 cm, of the high salinity treatments both the exchangeable Na⁺ and its ratio to total base cations (ESP) were significantly increased whilst the lower soil profile between 50 and 200 cm, was improved via both reduced alkalinity and sodicity. Leaching of the exchangeable base cations Ca²⁺, Mg²⁺ and K⁺ was significant in the upper soil profile (0–50 cm). As expected, the low salinity treatment (0.8 dS/m) had minimal impacts on soil chemical properties. The upper topsoil (0–10 cm) total organic carbon was significantly reduced in the high salinity plots and was negatively correlated with Cl^? concentration.

Conclusions

The data confirms the general concerns about application of saline irrigation, namely increased whole profile salinisation and upper soil profile (0–50 cm) sodicity, but they also show unexpected and desirable reductions in the lower soil profile (>?50 cm) alkalinity and sodicity. It appears the Na⁺ ions present in the saline waters led to differential leaching of base cations from the rooting zone, especially Ca²⁺ which then ameliorate the alkalinity and sodicity deeper in the soil profile (>?50 cm). Thus, surface application of gypsum may help sustain the application of highly saline waters; alternatively, subsurface irrigation above the sodic clayey subsoils could be trailed.

     

Dynamics of Sodium in Saline and Sodic Soils

Abstract

Soil salinization and sodication affect large areas of agricultural land in the world. Amelioration of these soils to make them suitable for agricultural production depends on understanding sodium dynamics and chemical interactions governing nutrient availability. Three locations in eastern Croatia were characterized to the 5‐m depth. The two solonetz‐solonchak soils were alkaline, whereas the solonetz soil had near‐neutral A/E horizon and alkaline deeper horizons. Electrical conductivity of the saturated extract (ECe) was greater than 4 dS m^?1 in the top horizons in the solonetz‐solonchak soils. The solonetz soil had 2.8–4.7 dS m^?1 in shallow A/E, CG, and G horizons and up to 6.3 dS m^?1 below 1.5 m. Highly alkalinized sodic horizons (exchangeable sodium percentage, ESP >20) had 24–47% Ca²⁺ and 27–33% Mg²⁺ on the cation exchange complex. Sodium adsorption ratio (SAR) was high (18–26) in the P horizon and even more so in Bt,na horizon (35–36) of solonetz‐solonchak soils. A strong negative exponential relationship existed between soluble Ca²⁺ and SAR (SAR increased greatly when Ca²⁺ dropped to around 3 mg dm^?3). An increase in pH to greater than 8.4 resulted in an exponential increase in SAR. Leaching of Na⁺ with successive volumes of water was similarly effective for the P and Bt,na horizons in the solonetz‐solonchak soils, but SAR remained greater than 15 even after six successive cycles of leaching. In conclusion, extensive amelioration of tested soils with gypsum and leaching will be required to overcome poor physical and chemical characteristics caused by various degrees of alkalization and sodication to bring these soils into production.     

Soil Fertility,Sugarcane Yield Affected by Limestone,Silicate, and Gypsum Application

The aim of this study was to verify if the application of silicate or lime, in association with gypsum, on sugarcane residue can lead to amendment of subsurface soil acidity, increasing sugarcane yield and profitability. The treatments were: 1 – control (without application of amendments), 2 – gypsum, 3 – dolomitic limestone, 4 – silicate, 5 – dolomitic limestone + gypsum, and 6 – silicate + gypsum. The surface application of gypsum led to reduction in Al (aluminum) contents and Al saturation, and increase in Mg⁺², Ca⁺², K⁺, S–SO₄^?, and base saturation in deeper soil layers, as well as increased yield of stalks, sugar, trash, bagasse, and energy, and greater profit. The application of limestone and silicate, alone or in association with gypsum, amend soil acidity throughout the soil profile. It likewise leads to an increase in stalk, sugar, trash, bagasse, and energy yield, however, application of silicate in association with gypsum leads to the greatest profitability.     

通过施用碱性矿渣和作物残茬生物炭以促进酸性老成土中盐基饱并降低土壤酸度

This investigation was conducted by using alkaline slag and crop straw biochars to reduce acidity of an acidic Ultisol through incubation and pot experiments with lime as a comparison. The soil was amended with different liming materials： lime（1 g kg^-1）,alkaline slag（2 and 4 g kg^-1）, peanut straw biochar（10 and 20 g kg^-1）, canola straw biochar（10 and 20 g kg^-1） and combinations of alkaline slag（2 g kg^-1） and biochars（10 g kg^-1） in the incubation study. A pot experiment was also conducted to observe the soybean growth responses to the above treatments. The results showed that all the liming materials increased soil p H and decreased soil exchangeable acidity. The higher the rates of alkaline slag, biochars, and alkaline slag combined with biochars, the greater the increase in soil p H and the reduction in soil exchangeable acidity. All the amendments increased the levels of one or more soil exchangeable base cations. The lime treatment increased soil exchangeable Ca^2＋, the alkaline slag treatment increased exchangeable Ca^2＋ and Mg^2＋ levels, and the biochars and combined applications of alkaline slag with biochars increased soil exchangeable Ca^2＋, Mg^2＋ and K^＋ and soil available P. The amendments enhanced the uptake of one or more nutrients of N, P, K, Ca and Mg by soybean in the pot experiment. Of the different amendments, the combined application of alkaline slag with crop straw biochars was the best choice for increasing base saturation and reducing soil acidity of the acidic Ultisol. The combined application of alkaline slag with biochars led to the greatest reduction in soil acidity, increased soil Ca, Mg, K and P levels, and enhanced the uptake of Ca, Mg, K and P by soybean plants.     

Simple techniques for monitoring and predicting the movement of chemicals in a field soil

Abstract

Vertical leaching of Na⁺ and Br^‐ in a yellow podzolic soil has been studied in the field following an application of 370 kg ha^‐1 NaBr. Soil cores to a depth of SO cm were collected on three occasions. Each core was divided into 2.5‐cm segments, and solution and exchangeable ions (Na⁺, Ca²⁺, Mg²⁺, K⁺, Br^‐and Cl^‐) were extracted from each segment using a centrifuge technique. The extraction technique was easy to use, and provided valuable information on the mechanisms influencing cation and anion distributions in the solution and exchange phases as a function of depth. The resulting distribution of exchangeable Na⁺ with depth was satisfactorily predicted using a simple mathematical model.     

REACTIONS OF AMMONIA WITH SOIL. I

Heats of adsorption and adsorption isotherms of ammonia gas were measured at 300 K (27 °C) on outgassed soil saturated with Na⁺, K⁺, NH₄⁺, Ca²⁺, or Mg²⁺ ions. The Ca and Mg soils adsorbed apparently one more NH₂ molecule per exchangeable ion than the Na and K soils, mostly in the relative pressure range o to 0.005, but not much more than the NH₄ soil. The initial heat of adsorption was c. 75 kJ mol^-1 on the Ca and Mg soils and c. 60 kJ mol^-1 on the other soils. The results suggest that most NH, is sorbed on these soils through reactions not involving exchangeable cations.     

Nutrient Element Contents and Cation Exchange Capacity in Fine Fractions of Southeastern Nigerian Soils in Relation to Their Stability

Abstract

Soils collected from 15 locations from SE Nigeria at the 0‐ to 20‐cm depth were studied for the nutrient elements of fine fractions and their role in the stability of the soils. The objective was to understand the role of these elements in the stability of the aggregates. The fine fractions were clay and silt, and elements measured in the fine fractions were exchangeable sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), magnesium (Mg²⁺), exchangeable acidity (EA), cation exchange capacity (CEC), and available phosphorus (P). The aggregate stability was measured at the microlevel with clay dispersible indices and water‐stable aggregate (WSA) <0.25 mm, and at macrolevel with other WSA indices and mean‐weight diameter (MWD). Soils varied from loamy sand to sandy clay. There were more exchangeable cations, CEC, EA, and available P in clay than in the silt fraction. Whereas EA values ranged from 2.8 to 10.4 cmol kg^?1, they were between 1.6 and 9.2 cmol kg^?1 in silt. The CEC in the clay fraction was from 7.4 to 70 cmol kg^?1 and between 4.0 and 32.8 cmol kg^?1 in the silt fraction. The WDC were from 50 to 310 g kg^?1 while the average dispersion ratio (DR) was generally higher than the corresponding clay‐dispersion ratio (CDR), and the MWD ranged from 0.45 to 2.68 mm. Soils with WSA skewed mostly to higher WSA (>2–1.00 mm) had a higher MWD. Exchangeable Ca²⁺ in clay correlated significantly with CDR and WSA sizes 1.0–0.5 mm and 0.5–0.25 mm (r=0.45,* 0.51,* and 0.60*), respectively, but negatively correlated with clay flocculation index (CFI) (r=?0.45*). Also, available P in clay correlated respectively with CDR and CFI (r=0.45*, ?0.45*), whereas K⁺ in silt correlated significantly with WDSi (r=0.64*), CFI (r=0.62*), and CDR (r=?0.65*). Principal component analysis revealed that elemental contents in the silt fraction can play very significant roles in the microaggregate stability.     

Mutual relationships of biochar and soil pH,CEC, and exchangeable base cations in a model laboratory experiment

Purpose

The majority of biochar studies use soils with only a narrow range of properties making generalizations about the effects of biochar on soils difficult. In this study, we aimed to identify soil properties that determine the performance of biochar produced at high temperature (700 °C) on soil pH, cation exchange capacity (CEC), and exchangeable base cation (Ca²⁺, K⁺, and Mg²⁺) content across a wide range of soil physicochemical properties.

Materials and methods

Ten distinct soils with varying physicochemical properties were incubated for 12 weeks with four rates of biochar application (0.5, 2, 4, and 8% w/w). Soil pH, CEC, and exchangeable base cations (Ca²⁺, K⁺, and Mg²⁺) were determined on the 7th and 84th day of incubation.

Results and discussion

Our results indicate that the highest biochar application rate (8%) was more effective at altering soil properties than lower biochar rates. Application of 8% biochar increased pH significantly in all incubated soils, with the increment ranging up to 1.17 pH unit. Biochar induced both an increment and a decline in soil CEC ranging up to 35.4 and 7.9%, respectively, at a biochar application rate of 8%. Similarly, biochar induced increments in exchangeable Ca²⁺ up to 38.6% and declines up to 11.4%, at an 8% biochar application rate. The increment in CEC and exchangeable Ca²⁺ content was found in soils with lower starting exchangeable Ca²⁺ contents than the biochar added, while decreases were observed in soils with higher exchangeable Ca²⁺ contents than the biochar. The original pH, CEC, exchangeable Ca²⁺, and texture of the soils represented the most crucial factors for determining the amount of change in soil pH, CEC, and exchangeable Ca²⁺ content.

Conclusions

Our findings clearly demonstrate that application of a uniform biochar to a range of soils under equivalent environmental conditions induced two contradicting effects on soil properties including soil CEC and exchangeable Ca²⁺ content. Therefore, knowledge of both biochar and soil properties will substantially improve prediction of biochar application efficiency to improve soil properties. Among important soil properties, soil exchangeable Ca²⁺ content is the primary factor controlling the direction of biochar-induced change in soil CEC and exchangeable Ca²⁺ content. Generally, biochar can induce changes in soil pH, CEC, and exchangeable Ca²⁺, K⁺, and Mg²⁺ with the effectiveness and magnitude of change closely related to the soil’s original properties.

     

Changes in soil organic carbon and nutrient pools in aggregate-sized fractions along a chronosequence of wolfberry (Lycium barbarum L.) plantations in arid areas of Northwest China

Different land use and management actions can affect soil aggregates (SAs) and nutrient stocks, which are crucial for sustainable agriculture. The impacts of various chrono-sequences on the soil aggregate structure, soil organic carbon (SOC) and nutrients associated with aggregate fractions in wolfberry (Lycium barbarum L.) plantations are still not fully understood. This study examined the composition and stability of SAs, SOC, total nitrogen (TN), available phosphorus (AP) and exchangeable cations (K⁺, Na⁺, Ca²⁺ and Mg²⁺) in bulk soil and various aggregate-size fractions from five wolfberry plantations with varying ages (1, 4, 6, 10 and 13 years) and a corn field (0 years) in the arid region of northwest Ningxia in China. The results indicated that silt–clay (<53 μm) fractions were dominant in the soil, accounting for 51%–66%, under different plantation ages. The proportion of the macro-aggregates (>250 μm) increased significantly, by 40%–47%, over the 4 years of wolfberry plantation. Likewise, the soil aggregate stability was improved, and total exchangeable bases (TEB) along with numerous cations concentrations (K⁺, Na⁺, Ca²⁺ and Mg²⁺) in SAs were significantly reduced as the wolfberry plantings became older. Both concentrations of SOC and TN in the soil aggregates peaked in the 13th year. The silt–clay fractions stored a considerable amount of SOC and nutrients. However, short-term (under 6 years) cultivation of wolfberry reduced the stocks of SOC, TN and AP in the soil, while long-term (over 10 years) cultivation increased them, particularly in macro-aggregates. These findings indicated that long-term wolfberry farming had several advantages, such as enhancing soil structure, accumulating SOC and nutrients and ameliorating alkaline soils, especially after 10 years, in the arid northwest of China.     

Soil Solution as Affected by Plant Residues and Nitrogen Rates

Cation mobility in acidic soils with low organic‐matter contents depends not only on sorption intensity but also on the solubility of the species present in soil solution. In general, the following leaching gradient is observed: potassium (K⁺) > magnesium (Mg²⁺) > calcium (Ca²⁺) > aluminum (Al³⁺). To minimize nutrient losses and ameliorate the subsoil, soil solution must be changed, favoring higher mobility of M²⁺ (metal ions) forms. This would be theoretically possible if plant residues were kept on the soil surface. An experiment was conducted in pots containing a Distroferric Red Latosol, with soil solution extractors installed at two depths. Pearl millet, black oat, and oilseed radish residues were laid on the soil surface, and nitrogen (as ammonium nitrate) was applied at rates ranging from 0 to 150 mg kg^?1. Corn was grown for 52 days. Except for K⁺ and ammonium (NH₄ ⁺), nitrogen rates and plant residues had little effect upon the concentrations and forms of the elements in the soil solution. Presence of cover crop residues on soil surface decreased the effect of nitrogen fertilizer on Ca leaching. More than 90% of the Ca²⁺, Mg²⁺, and K⁺ were found as free ions. The Al³⁺ was almost totally complexed as Al(OH₃)⁰. Nitrogen application increased the concentrations of almost all the ions in soil solution, including Al³⁺, although there was no modification in the leaching gradient.     

Influence of surface‐applied poultry manure on topsoil and subsoil acidity and salinity: A leaching column study

It has been suggested that surface applications of animal manure can ameliorate both top and subsoil acidity. For that reason, the effects of surface incorporation (0–5 cm) of a high rate of poultry manure to an acid soil on pH and exchangeable and soluble Al in the top‐ and subsoil were investigated in a leaching column study. During the experimental period of 108 d, columns received a total of 875 mm with leaching events occurring after 9, 37, 58, and 86 d. Incorporation of poultry manure into the surface 5 cm resulted in a large rise in pH measured in both 1M KCl and in soil solution. This liming effect was attributed primarily to the substantial CaCO₃ content of poultry manure. In the 15–45 cm layer, pH_KCl was not significantly different between poultry manure and control treatments but surprisingly, soil‐solution pH was substantially less in the poultry‐manure treatments. Exchangeable Al was significantly less in poultry manure than in control in all soil layers although the effect was most marked in the 0–5 cm layer. However, although concentrations and activities of monomeric Al (Al_mono), and the proportion of total Al present as Al_mono, in soil solution were lower under poultry manure than in control in the 0–5 cm layer, the reverse was, in fact, the case in lower soil horizons. This was attributed to a soluble‐salt effect, originating from the large cation content of poultry manure, displacing exchangeable Al³⁺ and H⁺ back into soil solution. Indeed, electrical conductivity and concentrations of Ca²⁺, Mg²⁺_, K⁺, and Na⁺ in soil solution were substantially higher in the poultry‐manure than in the control treatments at all soil depths. Poultry‐manure applications also resulted in substantial increases in the concentrations of Ca²⁺_, Mg²⁺_, K⁺, Na⁺, Al_mono, NH , and NO in leachates, particularly at the fourth leaching. It was concluded that although surface application of poultry manure can raise soil pH in the topsoil, increases in soluble‐salt concentrations in soil solution can greatly modify this effect in the subsoil.     

Clay Dispersion of Hardsetting Inceptisols in Southeastern Nigeria as Influenced by Soil Components

Abstract

Hardsetting soil properties are undesirable in agricultural soils because they hamper moisture movement and soil aeration. The soils of the floodplain of Niger River in eastern Nigeria hardsets upon drying, following dispersion, puddling, and slaking during the waterlogged period. Ten soil samples collected from a depth of 0–20 cm were analyzed for their properties. The soils are classified as Fluvaquentic Eutropepts or Dystric Gleysol (FAO). The objective was to investigate the influence of some soil properties on water‐dispersible clay (WDC) of the soils, which is the precursor of the hardsetting process. The total clay content (TC) correlated significantly with WDC (r=0.94??), whereas the water‐dispersible silt (WDSi) was higher than its corresponding total silt content. The WDC showed a positive correlation with dithionite extractable Fe (Fed), Al (Ald), and oxalate extractable Fe (Feo) (r=0.75?, 0.89??, and 0.76? respectively). Exchangeable Mg²⁺ correlated significantly with WDSi (r=0.70). Principal component analysis of the soil variables indicates that 15 soil components, which influence WDC as hardsetting properties, were reduced to 5 orthogonal components. The parameters that influence hardsetting properties are exchangeable Na⁺, K⁺, Ca²⁺, Mg²⁺, Fed, Alo, and Feo. Other soil properties are kaolinite, smectite, illite, and WDC, including soil organic carbon (OC), electrical conductivity (EC), and ESP. Therefore, those soil properties, which explain hardsetting characteristics most, are exchangeable Na⁺, Fed, OC, Mg²⁺, and Alo. There are negative consequences on the erodibility, runoff, infiltration and tillage of the soils at both submerged and dry conditions due to clay dispersion, low OC, and hardsetting behavior of the soil.     

Effect of Primary Biomethanated Spentwash on Soil Properties,Nutrient Uptake,and Yield of Wheat on Sodic Soil

The experiment on the effect of primary biomethanated spentwash (PBSW) on soil properties, nutrient uptake and yield of wheat on sodic soil was carried out at a research farm of Post Graduate Institute, Mahatma Phule Krishi Vidyapeeth, Rahuri, Maharashtra state, India, during the post-monsoon season. The experimental soil was sodic calcareous having Sawargaon series of isohyperthermic family of Vertic Haplustepts. The experiment was laid out in a randomized block design with nine treatments and three replications. The treatments consisted of varying doses of PBSW (100, 200, 300, 400 and 500 m³ ha^?1), absolute control, farmyard manure (FYM) 5 t ha^?1 + RDF-AST (recommended dose of fertilizer as per soil test), FYM 5 t ha^?1 + 50% GR (gypsum requirement) + RDF-AST and FYM 5 t ha^?1 + 100% GR + RDF-AST. The results revealed that the physical properties, namely bulk density and hydraulic conductivity, were improved in sodic soil due to the application of increased doses of PBSW. A significant reduction in pH, calcium carbonate and exchangeable sodium percentage (ESP) and an increase in organic carbon, cation-exchange capacity (CEC) and electrical conductivity (EC) were observed in the soil, due to the addition of PBSW. The available soil nitrogen (N), phosphorus (P), potassium (K) and micronutrient iron, manganese, copper and zinc (Fe, Mn, Cu and Zn) content after the harvest of wheat was the highest in the 500 m³ ha^?1 treatment compared with all the other treatments. The exchangeable calcium (Ca²⁺), magnesium (Mg²⁺) increased significantly and exchangeable Sodium (Na⁺) reduced significantly with increased doses of PBSW. The saturation paste extract analysis also showed the same trend. A significant increase in the EC of the saturation paste of extract of the soil was observed in all PBSW treatments and it was the highest (4.75 dS m^?1) in PBSW application @ 500 m³ ha^?1. The application of PBSW @ 500, 400, 300 and 200 m³ ha^?1 resembled the treatments of FYM + gypsum @ 100 GR + RDF-AST, FYM + gypsum @ 50 GR + RDF-AST and FYM + RDF-AST, respectively, regarding the biological properties of sodic soil. The PBSW application @ 500 m³ ha^?1 had recorded the highest grain (47.33 q ha^?1) and straw (72.72 q ha^?1) yield and the maximum total uptake of N, P, K, Fe, Mn, Cu, and Zn by wheat, which was at par with the treatment of FYM (5 t ha^?1) + gypsum @ 100% GR + RDF-AST.     

Nutrient Fluxes in Planted Norway Spruce Stands of Different Age in Southern Poland

The fluxes of N–NO ₃ ^? , N–NH ₄ ⁺ , S–SO ₄ ^2? , Na⁺, K⁺, Ca²⁺ and Mg²⁺ from bulk precipitation to throughfall, stemflow and soil water surface flows were studied during 1999–2003 in planted Norway spruce forest stands of different ages (11, 24, 91 and 116 years in 1999). Also, runoff from the corresponding Potok Dupniański Catchment in the Silesian Beskid Mts was studied. N deposition was above the critical load for coniferous trees. The interception increased with stand age as well as leaf area index and so did the leaching from the canopy of almost all the analysed elements, but especially S–SO ₄ ^2? , H⁺ and K⁺. The nutrient fluxes varied with age of the spruce stands. Throughfall showed a high amount of S and of the strong acids (S–SO ₄ ^2? and N–NO ₃ ^? ) deposited to the soil, especially in older spruce age classes. Decomposition of organic matter caused a rise in water acidity and an increase in the concentrations of all the analysed ions; the leaching of minerals, however, was low (under 1%). The horizontal soil water flow showed an increase in the amount of water and amount of ions and contributed to a further decrease of pH at the soil depth of 20 cm. Element concentrations and their amounts increased with water penetrating vertically and horizontally on the slopes. Considerable amounts of ions, especially S and alkaline cations, were carried beyond the reach of the root system and then left the catchment. In the long term, these mineral losses will adversely affect health and growth of the spruce stands, and the increased acidity with stand age will presumably have negative effects on the runoff water ecosystem.