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1.
A new charring agent, a derivative of cyanuric chloride, mono-substituted, dimethyl (4,6-dichloro-1,3,5-triazin-2-yloxy)methylphosphonate (CN), was synthesized in good yield and characterized. Its flame retardant and thermogravimetric properties were compared to those of the di-substituted compound, tetramethyl (6-chloro-1,3,5-triazine-2,4-diyl)bis(oxy)bis (methylene)diphosphonate (CN-1), which was prepared in previous work. All untreated fabric showed limiting oxygen index (LOI) values of about 18 vol% oxygen in nitrogen. Fabrics treated with CN at 5?C21 wt% add-ons had high LOI values of 30?C40 vol%, while fabrics treated with CN-1 at 5?C19 wt% add-ons had low to high LOI value of 20?C36 vol%. In 45° angle flammability tests, all treated fabrics with CN and CN-1 were passed and some fabrics were not igniting at all. Thermal degradation revealed that onset of degradation and the char yield of CN compound is higher than that of CN-1. Treated fabric with CN, 21 wt% add-on, had an onset of degradation of 240 °C, while fabric treated with CN-1, 19 wt% add-on displayed an onset of degradation of 230 °C. Despite the differences in onset temperature, the two samples provided almost the same char yield at 600 °C, 35 and 36 %. With Fourier transform infrared (FTIR), samples of treated/unburned and treated/burned of CN and CN-1 showed the same functional groups and revealed the disappearance of triazine group and P-O-methyl after burning. Additionally, scanning electron microscopy (SEM) showed that both CN and CN-1 acted as flame retardants by the same mechanism and characterized the surface morphology of the flame retardant treated twill fabrics. 相似文献
2.
Ching-Wen Lou 《Fibers and Polymers》2008,9(3):286-292
A double-layer nonwoven fabric containing Tencel, cotton, and chitosan was prepared by the immersion-precipitation phase-inversion
method and evaluated as a wound covering. Macroporous structure of the chitosan membrane could control evaporative water loss,
promote fluid drainage, and inhibit exogenous micro-organisms invasion due to inherent antimicrobial property of the chitosan.
The chitosan membrane was hemostatic and could accelerate the healing of the wound. Histological examination showed that epithelialization
rate was increased and the deposition of collagen in the dermis was well organized by covering the wound with the membrane.
These results indicate that the chitosan-coated Tencel/cotton nonwoven fabric can be a potential material employed as a wound
dressing. 相似文献
3.
N-halamine precursor 2,2,6,6-tetramethyl piperidinol (TMP), a hindered amine light stabilizer, was bonded onto cotton fabric by using 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. A variety of treating conditions including TMP concentration, curing temperature and time, and catalyst were studied. The treated fabrics were characterized using FTIR spectra and scanning electron microscope (SEM). The cotton fabric treated with TMP precursor could be rendered biocidal upon exposure to dilute household bleach. The chlorinated cotton swatches showed great efficacy and inactivated 100 % of Staphylococcus aureus with 7.1 log reduction with 5 min of contact and 83.25 % of E. coli O157:H7 at 10 min of contact. In addition, the wrinkle recovery angle of the treated cotton fabrics increased from 229 ° of untreated cotton fabrics to 253 °. This study provided a practical finishing process to produce cotton fabrics with easy care and antibacterial functionalities at the same time. 相似文献
4.
SeChin Chang Brian Condon Elena Graves Minori Uchimiya Chanel Fortier Michael Easson Phillip Wakelyn 《Fibers and Polymers》2011,12(3):334-339
The flame retardant behavior of cotton fabric treated with phosphorus-nitrogen containing triazine compound was evaluated.
It was found that cyanuric chloride (2,4,6-trichloro-1,3,5-triazine) is an excellent starting material for the preparation
of phosphonate flame retardants that interact well with cotton to improve flame resistance (FR) performance. Tetraethyl 6-chloro-1,3,5-triazine-2,4-diyldiphosphonate
(TECTDP) has been prepared by a simple one-step reaction in high yield (98.0 %). Cotton fabrics treated with TECTDP result
in covalent bond formation between TECTDP and hydroxyl groups in cotton fabrics. This FR system provides an efficient flame
retardant for cotton textiles at low cost to meet government mandates. In this study, the FR material was synthesized and
characterized by 1H and 13C nuclear magnetic resonance (NMR), and LC-MS spectroscopy. The chemical structure of cotton twill fabric treated with TECTDP
by pad-dry-cure method was analyzed by FT-MIR and SEM. Furthermore, the thermal and flammability properties were evaluated
by thermogravimetric analysis (TGA), limiting oxygen index (LOI, ASTM D-2863-09), and a vertical flame test (ASTM D-6413-08). 相似文献
5.
This paper was focused on comparing the effect of urea/NaOH aqueous system with that of single urea or NaOH treating system on cotton fabric morphology and properties. Optical microscopy (OM), scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (FT-IR), and wide X-ray diffraction (WAXD) were used to study cotton fabric morphology and properties before and after treatment by urea/NaOH, single urea, and single NaOH treating systems. Results showed that the cotton fabric treated by urea/NaOH aqueous system had better dyeability than the samples untreated and treated by single urea or single NaOH treating systems. Obvious differences were observed in appearance and morphology of cotton fabrics before and after treatment by urea/NaOH aqueous system. The composition and the structure of urea/NaOH treated cotton fiber had no distinct changes, only except the reduced hydrogen bonding between cellulosic macromolecules. Tensile strength and elongation at break of cotton fabric showed a slight decrease after treatment by urea/NaOH system. In addition, shrinkage of area and weight reduction of urea/NaOH treated samples were higher than those of the samples untreated and treated by single urea or single NaOH treating system. 相似文献
6.
Fluorinated polyacrylate latexes are preferably potential materials for use in the textile finishing due to their special surface property and especially economical, low-toxic characteristics compared to fluorinated polyacrylate solutions. A novel cationic fluorine-containing polyacrylate soap-free latex (CFMBD) with core-shell structure was accordingly developed by co-polymerizing dodecafluoroheptyl methacrylate (DFMA), methyl methacrylate (MMA), butyl acrylate (BA), and dimethylaminoethyl methacrylate (DM) using a cationic reactive emulsifier, maleic acid double ester-octadecyl poly(ethyleneoxy)20 ether-ethylene trimethyl ammonium chloride (R303). Then CFMBD was utilized to treat the cotton fabric. Results showed that the as-prepared latex had due structure and its particles had uniform spherical core-shell structure with an average diameter of 125 nm. The core-shell CFMBD latex film thus had two T g and its thermal property was improved due to the introduction of DFMA. CFMBD could form a smooth resin film on the treated fabric/fiber surface under FESEM observation. XPS analysis indicated the fluoroalkyl groups had the tendency to enrich at the film-air interface. Hydrophobicity of the CFMBD treated fabric was slightly superior to that of the fabric treated by general emulsion but their oleophobicity was identical. Contact angles of water and diiodomethane on the CFMBD treated fabric surface could attain 133.5 ° and 105.5 °, respectively. However, washing durability of the treated fabric by CFMBD showed improvement compared to the general emulsion. In addition, CFMBD didn’t influence whiteness of the treated fabric but would make it slightly stiff at high doses. 相似文献
7.
8.
The aim of this paper is to study the possibility and effectiveness of applying LTP treatment to enhance the performance of
pre-treatment paste containing sodium alginate so as to improve the properties of the ink-jet printed cotton fabric. Experimental
results revealed that the LTP pre-treatment in couple with the ink-jet printing technique could improve the final printed
properties of cotton fabric. 相似文献
9.
1全球棉价走势
全球棉价的长期平均值为每磅72美分。自1995年WTO农业协议生效以来,全球棉价持续走低,2001年跌至每磅42美分左右,是29年以来的最低水平(见图1)。仅在2003年11月棉价才在短期内突破76美分(见图2)。随后又急剧下跌,于2004年12月跌至每磅43美分。棉价上涨的主要原因是棉价触底后。全球棉花库存持续减少,供需失衡造成的。近期棉价(2005年11月17日)维持在每磅56美分左右。 相似文献
10.
Various shapes of ZnO — multi-petals, rod and spherical — were prepared and then applied on cotton fabric for UV-blocking
and anti-bacterial properties. The ZnO particles were investigated by XRD and SEM. The as-prepared suspension was applied
onto cotton fabrics via the pad-dry-cure process at 150 °C. The characteristics of the fabric coating were investigated by
SEM, XRD and Atomic Absorption Spectroscopy (AAS). The UV-blocking effectiveness was measured with a UV-Vis spectrophotometer
whilst the antibacterial activity was determined using the AATCC 147 method. The results of XRD and SEM on the ZnO powders
show that we can produce various shapes of ZnO. The investigation by SEM and AAS clearly revealed that ZnO was effectively
deposited on the cotton surface and that the adhesion was retained after washing ten cycles. The sphericals-shaped ZnO and
multi-petals shaped ZnO coated fabrics show excellent UV-blocking properties. All treated samples showed good antibacterial
activity against Staphylococcus Aureus. The shape of ZnO shows no considerable effect on antibacterial properties. 相似文献
11.
100 % cotton light-weight plain knitted fabrics were treated with resin using different concentration by conventional pad-dry-cure method so as to influence their physical properties such as wrinkle-resistant, smoothness, dimensional properties and bursting strength. After resin treatment, the wrinkle-resistant property, smoothness and dimension stability of the four fabrics were consequently improved even after simulated domestic laundering process. The experimental results were reported and discussed thoroughly. 相似文献
12.
A quaternary ammonium compound, 2-hydroxypropyltrimethylammonium chloride amino-terminated hyper-branched polymer (HBP-HTC),
was synthesized from an amino-terminated hyperbranched polymer (HBP-NH2) and 2,3-epoxypropyltrimethylammonium chloride (EPTAC) as a grafting agent in aqueous solution. Its molecular weight and
possible structure were characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR)
and nuclear magnetic resonance spectroscopy (1H-NMR). The cotton fabric was treated with 2 g/l HBP-HTC aqueous solution for 30 min at room temperature to provide the cotton fabric with antimicrobial properties. The antimicrobial
activities of the HBP-HTC aqueous solutions and the HBP-HTC treated cotton fabrics were evaluated quantitatively. The results
indicated that the HBP-HTC treated cotton fabric showed 99.92 % reduction of bacteria S. aureus and 99.66 % reduction of bacteria E. coli, respectively. The antimicrobial activities of the HBP-HTC treated cotton fabrics were maintained at over 99.00 % reduction
level even after being exposed to 20 consecutive home laundering conditions. 相似文献
13.
14.
Mine Akgun 《Fibers and Polymers》2014,15(2):405-413
The effects of some yarn properties (i.e. type, count, twist level, ply number, unevenness and crimp) and fabric constructional properties (i.e. cover, thickness and balance) on surface roughness values of cotton woven fabrics were investigated. A general overview of the results showed that surface roughness values of fabrics were affected from yarn and fabric properties and the effects were related to fabric balance, fabric cover (not cover factor), fabric thickness and crimp values of yarns in fabric structures. Surface roughness values of fabrics decreased as yarn fineness and yarn twist levels increased but as yarn ply number decreased. Also, surface roughness values gradually decreased from open-end yarn constituting fabrics to combed yarn constituting fabrics. Results showed that different properties of yarns caused changes in yarn crimps in fabric structure and also governed the changes in fabric balance, as well as changes in roughness of fabric surfaces. The changing properties of yarns and impact of these properties on fabric construction affected the formation of cotton fabric surfaces from smooth to coarse. 相似文献
15.
A carefully designed surface modification technique for the preparation of multifunctional cotton fabric was successfully developed by the functionalization of cotton fabric with nano attapulgite (ATP) colloidal particles. The dispersion of the nano ATP colloidal particles, the morphology, microstructure, thermal stability, ultraviolet resistance, antibacterial activity and air permeability of the treated cotton fabric were characterized. The results showed that the particle size of the ATP particle distributed between 100 nm to 150 nm after dispersion. The SEM (scanning electron microscopy) and FTIR (Fourier transform infrared spectra) analysis demonstrated that the ATP particles were successfully introduced to surface of the cotton fabric. The structural and thermal stability of the treated fabric were higher than those of the untreated fabric. The ATP treated cotton fabric possessed excellent ultraviolet resistance and antibacterial activity. Furthermore, the treatment did not affect the wear ability of the cotton fabric. The multifunctional cotton fabric meets the market demand for natural products. 相似文献
16.
In this paper, artificial neural network (ANN) model was used for predicting colour properties of 100 % cotton fabrics, including
colour yield (in terms of K/S value) and CIE L, a, and b values, under the influence of laser engraving process with various combination of laser processing parameters. Variables
examined in the ANN model included fibre composition, fabric density (warp and weft direction), mass of fabric, fabric thickness
and linear density of yarn (warp and weft direction). The ANN model was compared with a linear regression model where the
ANN model produced superior results in prediction of colour properties of laser engraved 100 % cotton fabrics. The relative
importance of the examined factors influencing colour properties was also investigated. The analysis revealed that laser processing
parameters played an important role in affecting the colour properties of the treated 100 % cotton fabrics. 相似文献
17.
Following our previous research [1], an extensive investigation on the effects of four mercerization treatment parameters namely, alkali concentration, time of treatment, bath temperature, and mercerization tension on dimensional properties of plain knitted fabric produced from cotton yarn is presented in this paper. Numerical values of constant geometry of the dry relaxed, wet relaxed, and mercerized samples were calculated according to Munden’s equations. Study shows that the area geometry constant values (K s ) achieved after mercerization treatment was higher than values obtained for the samples subjected to dry and wet relaxations. Also, ANOVA test confirmed significant effects of each parameter itself and their interactions on dimensional properties of the fabric samples. Based on the results, applying less value of tension improves dimensional stability of the fabric but not for the samples mercerized in higher values of three other parameters. The alkali concentration had an optimum value in mercerization treatment. In mercerizing conditions carried out in high temperature and long time, lower alkali concentration is more efficient. Increasing time of treatment leads to achieve higher K s value when lower value of alkali concentration is used. Most of the samples mercerized in bath temperature of 40 °C had the highest K s . At the end of the research a statistical model was derived to predict the area geometry constant of the fabric. 相似文献
18.
In this study salt-free dyeing cotton fabric was achieved by grafting thiourea to cotton fibers, where the thiourea grafted
cotton fabric (TUGCF) was prepared by epoxidizing cotton fibers with epichlorohydrin in water and subsequently grafting in
aqueous solution of thiourea. Fourier transform infrared spectra (FTIR) and XPS of the TUGCF indicated that a great amount
of epoxy groups from the epoxidized cotton fibers reacted with amino groups from thiourea. The TUGCF fabric prepared at the
optimum condition and subsequently dyed with reactive dyes in the absence of salt displayed significantly enhanced color strength,
showing better dyeing properties when compared with the untreated cotton fabric dyed with conventional methods, in terms of
washing fastness, rubbing fastness, and levelness. It was found that the dyeing performance of Reactive Red B-3BF followed
a Langmuir-type adsorption curve when used to salt-free dye the TUGCF. 相似文献
19.
The influence of water vapor plasma on the adsorption of UV absorber during the reactive dyeing of bleached and mercerized cotton fabric was examined. Exhaust dyeing of untreated and plasma-treated cotton was performed using a reactive dye Cibarcon Deep Red S-B and a commercial UV absorber Tinofast CEL. Blank dyeing was performed as a control experiment. Fourier transform infrared spectroscopy (FTIR) was used to identify the presence of the UV absorber on the cotton fabric, whereas scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to analyze surface changes of untreated and plasma-treated dyed samples. The CIELAB color values and ultraviolet protection factor (UPF) of the samples were determined spectrophotometrically. Wash and light fastness of samples was performed also. The results reveal that the UPF of cotton increases after UV absorber treatment and that plasma treatment increases the adsorption of UV absorber during dyeing process, especially at higher dye concentrations. The enhanced adsorption of UV absorber onto plasma-treated cotton is the result of the increased concentration of oxygen containing functional groups on the cotton surface after plasma treatment, confirmed by XPS. The UPF of plasma-treated cotton samples is decreased after washing and increased after exposure to xenon light. 相似文献
20.
The presented research deals with modifying the chemical structure of the bioscoured cotton fabric by acrylonitrile, acrylonitrile/acetone, and acrylonitrile/ethanol mixture. The modified cellulose was tested for weight gain, shrinkage, and wicking height and characterized by X-ray diffraction (XRD), thermal analysis (TG/DTA), elemental analysis, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The weight gain and shrinkage % show increased value for modified fabrics. The wicking height increases with addition of solvent. The crystallinity and thermal studies show a significant change. FTIR analysis confirms the modification by the occurrence of -C??N stretching and -CONH2 stretching. The SEM morphology of modified fabric shows uniform swelling of fibers with better smoothness. The AFM topography reveals that the addition of solvent affects the particle size. Clear surface morphology of modified fabric reveals that this processing method can be used for preparation of medical textiles with more swelling. 相似文献