Characterization of the products resulting from ethylene glycol liquefaction of cellulose

The composition of liquefied cellulose in the presence of ethylene glycol (EG) was studied. The liquefied products were fractionated and analyzed with highperformance liquid chromatography and nuclear magnetic resonance. EG-glucosides were detected as the only saccharides and 2-hydroxyethyl levulinate as the highly decomposed compound derived from cellulose. Quantitative analysis of the EG-glucosides and levulinic acid that comes from the levulinate shows the presence of the following mechanism in the EG-liquefaction of cellulose. First, cellulose is degraded and produces considerable amounts of EG-glucosides during the early stage of liquefaction. Then, when liquefaction is prolonged, the glucosides are decomposed, leading to a large quantity of levulinates.     

木材的液化及其在高分子材料中的应用

木材是固态的天然高分子材料，通过液化可将其转化为具有反应活性的液态分子，进一步可制备新型高分子材料如胶粘剂、注模塑料、泡沫塑料、纤维材料等，具有广泛的应用前景，是木材化学和木材利用技术新开辟的研究领域。本文综述了近二十年来木材液化技术的发展状况，内容涉及木材液化方法，液化反应机理，液化产物的开发利用。     

Behavior of the cellulose microfibril in shrinking woods

We measured the longitudinal and tangential shrinking processes in wood specimens from Chamaecyparis obtuse Endl. with different microfibril angles (MFAs). The shape of the shrinking curve was compared with the MFA. Only the longitudinal shrinking process of specimens with a small MFA clearly showed nonlinearity, and the degree of nonlinearity increased as the MFA decreased. In contrast, the tangential shrinking process and the longitudinal shrinking process of compression wood with a large MFA were linear. The nonlinearity is probably caused by the longitudinal shrinkage of the noncrystalline region of the cellulose microfibril (CMF) in regions of low moisture content during water desorption. When the moisture content is high, the matrix substance in the cell wall begins to dry; however, the shrinkage in the chain direction is restrained by the rigid CMF. As the wood dries further, the noncrystalline region of the CMF embedded in the matrix substance begins to shrink. Because the longitudinal mechanical behavior of wood with a small MFA is greatly affected by a rigid CMF, longitudinal shrinkage increases suddenly at about 10% moisture content; as a result, the shrinking process shows nonlinearity.     

Crystallinity of wood and the size of cellulose crystallites in Norway spruce (<Emphasis Type="Italic">Picea abies</Emphasis>)

X-ray diffraction was used to study variations in the crystallinity of wood and the average thickness and length of the crystallites of cellulose as a function of the number of the year ring in Norway spruce [Picea abies (L.) Karst.]. The crystallinity increased from ring 4 to ring 10 from the pith and was constant after ring 10. The crystallinity of mature wood was about 30% ± 5%. The average thickness and average length of the crystallites were 3.2 ± 0.1nm and 28 ± 2nm, respectively; and no systematic variation of these values with the number of the year ring was observed. The mean microfibril angle decreased near the pith but was constant in the mature wood.     

An analysis of Greek wood and wood product imports: Evidence from the linear quadratic aids

The consumption of wood and wood products in Greece is based greatly on imports necessitating every year a great proportion of public expenditures. The study of wood and wood product imports consequently, is important to the national economy and can be a useful guide for the forest farms, wood industries and wood firms. In this paper the Greek aggregate import demand for Unprocessed wood (such as logs) Processed wood (such as sawn wood), Veneer Crafts (such as veneer sheets) and Wood Manufactures during the period 1969–2001 is empirically analysed using the linear approximation of quadratic AIDS (QUAIDS) model. Imports of Unprocessed wood, Veneer Crafts and Wood Manufactures are found to be price-elastic, in contrast to Processed wood imports. Processed wood, Veneer Crafts and Wood Manufacture imports are found to be expenditure-elastic while Unprocessed wood is found to be an inferior good. Substitution possibilities are found to be significant between Veneer Crafts and all the remaining wood imports and between Processed wood and Unprocessed wood.     

聚乙二醇月桂酸酯的制备及其在化纤油剂中的应用

研究了聚乙二醇月桂酸酯的制备,对聚乙二醇８００,１０００以对甲苯磺酸作为催化剂,４－甲基－２,６－二叔丁基苯酚为抗氧剂,与月桂酸反应的条件进行了探讨,并分析了其有关性质及在化纤油剂中的应用     

江苏木材加工产业市场集中度统计与分析

基于集中度指标,分别对江苏木材加工企业和木材加工产品的市场集中度进行了统计分析。结果表明:江苏木材加工企业的集中度处于低度位或极低度位,但木材加工产品已经形成了一定的区域集聚;在此基础上提出促进江苏木材加工产业规模效益提升的具体建议。     

Application of the stock change and the production approach to Harvested Wood Products in the EU-15 countries: a comparative analysis

With the analytical tool: Frankfurt Harvested Wood Products (HWP) Model, carbon stocks and carbon stock changes of HWP, either in USE or in LANDFILLS, have been evaluated from the readily available statistical data base of the FAO, FAOSTAT, on the wood commodities: “Sawnwood and Wood-based Panels” and the paper commodities: “Paper and Paperboard”. Essential differences have been found between the individual 15 EU countries in the comparison of the Stock Change Approach and the Production Approach, as well as in the comparison of the stock changes of HWP with the National Greenhouse Gas (GHG) budgets. The stock changes for the HWP in USE within the EU-15 Community have been calculated to be 10.83 Mt C/a (39.71 Mt CO₂/a) based on the Stock Change Approach and 9.81 Mt C/a (35.97 Mt CO₂/a) for the Production Approach, respectively. These numbers can be compared to the total GHG Inventory of the EU-15 of 4,095 Mt CO₂ equivalents, including all six Kyoto gases, which shows that the carbon sequestration of HWP in USE is of the order of 1% relative to GHG Inventory. The GHG balance for the carbon stock changes of HWP in LANDFILLS is of similar magnitude as for the HWP in USE, and therefore a sink when methane outgasing is disregarded. However, when methane outgasing is considered, which is formed as a 1:1 mixture with CO₂ under the prevailing anaerobic conditions the GHG balance results in minus 10.0 Mt C equivalent/a and minus 10.6 Mt C equivalent/a for the Stock Change Approach and the Production Approach under the parameters chosen in this study. Presented in Dublin, October 6–9, 2004, COST-21 Plenary Session.     

Digital image analysis of cross-sectional tracheid shapes in Japanese softwoods using the circularity index and aspect ratio

Image analysis was used in this study to develop a faster, more objective method for quantitatively measuring tracheid shapes on cross section. The morphological features were measured automatically using the circularity index and aspect ratio based on the skeletonized images. The rectangular and hexagonal similarities were introduced to evaluate the tracheid shapes. The results for 18 species of Japanese softwoods showed that the difference in tracheid shapes among the species could be successfully estimated using the quantitative method. In addition, the boundary of latewood might be evaluated based on the change in circularity indexes.The abstract of this study was presented at the 48th annual meeting of the Japan Wood Research Society, Shizuoka, April 1998     

Identification of Armillaria species in Japan using PCR-RFLP analysis of rDNA intergenic spacer region and comparisons of Armillaria species in the world

Armillaria species from Japan were characterized using polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) of the intergenic spacer region-1 (IGS-1) of ribosomal DNA (rDNA). Eleven different digestion patterns by restriction endonuclease Alu I were found among 70 isolates of seven Armillaria species in Japan. Isolates within Armillaria nabsnona, A. ostoyae, A. cepistipes, and Japanese biological species E showed the same Alu I digestion patterns. Five Alu I patterns were detected for A. gallica, three patterns for A. mellea, and two patterns for A. tabescens. Seven Armillaria species in Japan were clearly distinguished by using the profiles obtained when PCR products were digested with Alu I, Msp I, and Hae III restriction enzymes. There was considerable variability of Alu I restriction sites within the IGS-1 between the isolates of five Armillaria species, A. gallica, A. nabsnona, A. cepistipes, A. mellea, and A. tabescens, in Japan and those of their European and North American counterparts.     

Spatio-temporal analysis of forest fire events in the Margalla Hills,Islamabad,Pakistan using socio-economic and environmental variable data with machine learning methods

Most forest fires in the Margalla Hills are related to human activities and socioeconomic factors are essential to assess their likelihood of occurrence.This study consid-ers both environmental (altitude,precipitation,forest type,terrain and humidity index) and socioeconomic (popula-tion density,distance from roads and urban areas) factors to analyze how human behavior affects the risk of forest fires.Maximum entropy (Maxent) modelling and random forest (RF) machine learning methods were used to predict the probability and spatial diffusion patterns of forest fires in the Margalla Hills.The receiver operating characteristic(ROC) curve and the area under the ROC curve (AUC) were used to compare the models.We studied the fire history from 1990 to 2019 to establish the relationship between the prob-ability of forest fire and environmental and socioeconomic changes.Using Maxent,the AUC fire probability values for the 1999s,2009s,and 2019s were 0.532,0.569,and 0.518,respectively;using RF,they were 0.782,0.825,and 0.789,respectively.Fires were mainly distributed in urban areas and their probability of occurrence was related to acces-sibility and human behaviour/activity.AUC principles for validation were greater in the random forest models than in the Maxent models.Our results can be used to establish preventive measures to reduce risks of forest fires by consid-ering socio-economic and environmental conditions.     

Determination of dehydroevodiamine in Evodia rutaecarpa (Juss.) Benth by high performance liquid chromatography and classification of the samples by using hierarchical clustering analysis

A simple, sensitive and accurate liquid chromatographic method with photodiode-array detection was developed for determination of dehydroevodiamine with detection wavelength at 368 nm and column temperature at 30 °C. The separation was carried out on an Agilent Zorbax SB-C₁₈ column (250 mm × 4.6 mm, 5 µm) together with a C₁₈ guard column. The mobile phase was acetonitrile–water (containing 30 mM sodium acetate trihydrate and 0.15% acetic acid) in the ratio of 30:70 (v/v) delivered at a flow rate of 1 mL/min. Excellent linear behavior was observed over the concentration range investigated, with correlation coefficient (R²) = 0.9998. This validated method was applied to determine the contents of dehydroevodiamine in 36 samples from different regions of China, and hierarchical clustering analysis was firstly used to classify and differentiate Evodia rutaecarpa samples. The analysis is specific and can be successfully applied to analyze E. rutaecarpa which is helpful for quality control of the herb.