Lead isotopic ages of chondrules and calcium-aluminum-rich inclusions

The lead-lead isochron age of chondrules in the CR chondrite Acfer 059 is 4564.7 +/- 0.6 million years ago (Ma), whereas the lead isotopic age of calcium-aluminum-rich inclusions (CAIs) in the CV chondrite Efremovka is 4567.2 +/- 0.6 Ma. This gives an interval of 2.5 +/- 1.2 million years (My) between formation of the CV CAIs and the CR chondrules and indicates that CAI- and chondrule-forming events lasted for at least 1.3 My. This time interval is consistent with a 2- to 3-My age difference between CR CAIs and chondrules inferred from the differences in their initial 26Al/27Al ratios and supports the chronological significance of the 26Al-26Mg systematics.     

Supra-canonical 26Al/27Al and the residence time of CAIs in the solar protoplanetary disk

The canonical initial 26Al/27Al ratio of 4.5 x 10(-5) has been a fiducial marker for the beginning of the solar system. Laser ablation and whole-rock multiple-collector inductively coupled plasma-source mass spectrometry magnesium isotope analyses of calcium- and aluminum-rich inclusions (CAIs) from CV3 meteorites demonstrate that some CAIs had initial 26Al/27Al values at least 25% greater than canonical and that the canonical initial 26Al/27Al cannot mark the beginning of solar system formation. Using rates of Mg diffusion in minerals, we find that the canonical initial 26Al/27Al is instead the culmination of thousands of brief high-temperature events incurred by CAIs during a 10(5)-year residence time in the solar protoplanetary disk.     

Calcium-aluminum-rich inclusions from enstatite chondrites: indigenous or foreign?

The primary mineral assemblages and initial (26)Al/(27)Al ratios of rare calcium-aluminum-rich inclusions (CAIs) from enstatite (E) chondrites are similar to those of CAIs from other chondrite classes. CAIs from all chondrite classes formed under oxidizing conditions that are much different from the reducing conditions under which the E chondrites formed. Either CAIs formed at an earlier, more oxidizing epoch in the region where E chondrites ultimately formed, or they formed at a different place in the solar nebula and were transported into the E chondrite formation region.     

Evidence for a late supernova injection of 60Fe into the protoplanetary disk

High-precision 60Fe-60Ni isotope data show that most meteorites originating from differentiated planetesimals that accreted within 1 million years of the solar system's formation have 60Ni/58Ni ratios that are approximately 25 parts per million lower than samples from Earth, Mars, and chondrite parent bodies. This difference indicates that the oldest solar system planetesimals formed in the absence of 60Fe. Evidence for live 60Fe in younger objects suggests that 60Fe was injected into the protoplanetary disk approximately 1 million years after solar system formation, when 26Al was already homogeneously distributed. Decoupling the first appearance of 26Al and 60Fe constrains the environment where the Sun's formation could have taken place, indicating that it occurred in a dense stellar cluster in association with numerous massive stars.     

Short-lived nuclides in hibonite grains from Murchison: evidence for solar system evolution

Records of now-extinct short-lived nuclides in meteorites provide information about the formation and evolution of the solar system. We have found excess 10B that we attribute to the decay of short-lived 10Be (half-life 1.5 million years) in hibonite grains from the Murchison meteorite. The grains show no evidence of decay of two other short-lived nuclides-26Al (half-life 700,000 years) and 41Ca (half-life 100,000 years)-that may be present in early solar system solids. One plausible source of the observed 10Be is energetic particle irradiation of material in the solar nebula. An effective irradiation dose of approximately 2 x 10(18) protons per square centimeter with a kinetic energy of >/=10 megaelectronvolts per atomic mass unit can explain our measurements. The presence of 10Be, coupled with the absence of 41Ca and 26Al, may rule out energetic particle irradiation as the primary source of 41Ca and 26Al present in some early solar system solids and strengthens the case of a stellar source for 41Ca and 26Al.     

Ancient asteroids enriched in refractory inclusions

Calcium- and aluminum-rich inclusions (CAIs) occur in all classes of chondritic meteorites and contain refractory minerals predicted to be the first condensates from the solar nebula. Near-infrared spectra of CAIs have strong 2-micrometer absorptions, attributed to iron oxide-bearing aluminous spinel. Similar absorptions are present in the telescopic spectra of several asteroids; modeling indicates that these contain approximately 30 +/- 10% CAIs (two to three times that of any meteorite). Survival of these undifferentiated, large (50- to 100-kilometer diameter) CAI-rich bodies suggests that they may have formed before the injection of radiogenic 26Al into the solar system. They have also experienced only modest post-accretionary alteration. Thus, these asteroids have higher concentrations of CAI material, appear less altered, and are more ancient than any known sample in our meteorite collection, making them prime candidates for sample return.     

Chondrulelike objects in short-period comet 81P/Wild 2

The Stardust spacecraft returned cometary samples that contain crystalline material, but the origin of the material is not yet well understood. We found four crystalline particles from comet 81P/Wild 2 that were apparently formed by flash-melting at a high temperature and are texturally, mineralogically, and compositionally similar to chondrules. Chondrules are submillimeter particles that dominate chondrites and are believed to have formed in the inner solar nebula. The comet particles show oxygen isotope compositions similar to chondrules in carbonaceous chondrites that compose the middle-to-outer asteroid belt. The presence of the chondrulelike objects in the comet suggests that chondrules have been transported out to the cold outer solar nebula and spread widely over the early solar system.     

Origin and metamorphic redistribution of silicon, chromium, and phosphorus in the metal of chondrites

Chromium, silicon, and phosphorus concentrations of 0.1 to 1 percent by weight are common in metal grains in the least metamorphosed ordinary and carbonaceous chondrites. These concentrations are fairly uniform within single chondrules (but different from chondrule to chondrule) and are inversely correlated with the fayalite concentrations of the chondrule olivines. This relation shows that these chromium, silicon, and phosphorus concentrations could not have been established by condensation or equilibration in the solar nebula but are the result of metal-silicate equilibration within chondrules. Two generations of inclusions made by the exsolution of those elements have been identified: One formed during chondrule cooling and the other formed during metamorphism. The distribution and composition of the latter in type 3 to type 5 chondrites are consistent with increasing metamorphism relative to type 2 and type 3.0 material.     

The formation conditions of chondrules and chondrites

Chondrules, which are roughly millimeter-sized silicate-rich spherules, dominate the most primitive meteorites, the chondrites. They formed as molten droplets and, judging from their abundances in chondrites, are the products of one of the most energetic processes that operated in the early inner solar system. The conditions and mechanism of chondrule formation remain poorly understood. Here we show that the abundance of the volatile element sodium remained relatively constant during chondrule formation. Prevention of the evaporation of sodium requires that chondrules formed in regions with much higher solid densities than predicted by known nebular concentration mechanisms. These regions would probably have been self-gravitating. Our model explains many other chemical characteristics of chondrules and also implies that chondrule and planetesimal formation were linked.     

92Nb-(92)Zr and the Early Differentiation History of Planetary Bodies

The niobium-92-zirconium-92 ((92)Nb-(92)Zr) extinct radioactive decay system (half-life of about 36 million years) can place new time constraints on early differentiation processes in the silicate portion of planets and meteorites. Zirconium isotope data show that Earth and the oldest lunar crust have the same relative abundances of (92)Zr as chondrites. (92)Zr deficits in calcium-aluminum-rich inclusions from the Allende meteorite constrain the minimum value for the initial (92)Nb/(93)Nb ratio of the solar system to 0.001. The absence of (92)Zr anomalies in terrestrial and lunar samples indicates that large silicate reservoirs on Earth and the moon (such as a magma ocean residue, a depleted mantle, or a crust) formed more than 50 million years after the oldest meteorites formed.     

The provenances of asteroids, and their contributions to the volatile inventories of the terrestrial planets

Determining the source(s) of hydrogen, carbon, and nitrogen accreted by Earth is important for understanding the origins of water and life and for constraining dynamical processes that operated during planet formation. Chondritic meteorites are asteroidal fragments that retain records of the first few million years of solar system history. The deuterium/hydrogen (D/H) values of water in carbonaceous chondrites are distinct from those in comets and Saturn's moon Enceladus, implying that they formed in a different region of the solar system, contrary to predictions of recent dynamical models. The D/H values of water in carbonaceous chondrites also argue against an influx of water ice from the outer solar system, which has been invoked to explain the nonsolar oxygen isotopic composition of the inner solar system. The bulk hydrogen and nitrogen isotopic compositions of CI chondrites suggest that they were the principal source of Earth's volatiles.     

Discovery of ancient silicate stardust in a meteorite

We have discovered nine presolar silicate grains from the carbonaceous chondrite Acfer 094. Their anomalous oxygen isotopic compositions indicate formation in the atmospheres of evolved stars. Two grains are identified as pyroxene, two as olivine, one as a glass with embedded metal and sulfides (GEMS), and one as an Al-rich silicate. One grain is enriched in 26Mg, which is attributed to the radioactive decay of 26Al and provides information about mixing processes in the parent star. This discovery opens new means for studying stellar processes and conditions in various solar system environments.     

Early irradiation of matter in the solar system: magnesium (proton, neutron) scheme

The occurrence of positive and negative (26)Mg anomalies in inclusions of the Allende meteorite is explained in terms of proton bombardment of a gas of solar composition. A significant fraction of (26)Mg in the irradiated gas is stored temporarily in the form of radioactive (26)Al by the reaction (26)Mg(p,n) (26)Al. Proton fluxes of 10(17) to 10(19) protons per square centimeter per year at l million electron volts are inferred. Aluminum-rich materials condensing from the gas phase have positive (26)Mg anomalies, whereas magnesium-rich materials have negative (26)Mg anomalies. The proton flux required to account for the observed magnesium anomalies is used to investigate possible isotopic anomalies in the elements from oxygen to argon. Detectable isotopic anomalies are predicted only for neon. The anomalous neon is virtually pure (22)Ne from (22)Na decay. The predicted amount of anomalous (22)Ne is about 10(-8) cubic centimeter (at standard temperature and pressure) per milligram of sodium.     

A nebular origin for chondritic fine-grained phyllosilicates

Hydrated minerals occur in accretionary rims around chondrules in CM chondrites. Previous models suggested that these phyllosilicates did not form by gas-solid reactions in the canonical solar nebula. We propose that chondrule-forming shock waves in icy regions of the nebula produced conditions that allowed rapid mineral hydration. The time scales for phyllosilicate formation are similar to the time it takes for a shocked system to cool from the temperature of phyllosilicate stability to that of water ice condensation. This scenario allows for simultaneous formation of chondrules and their fine-grained accretionary rims.     

The formation of chondrules at high gas pressures in the solar nebula

High-precision magnesium isotope measurements of whole chondrules from the Allende carbonaceous chondrite meteorite show that some aluminum-rich Allende chondrules formed at or near the time of formation of calcium-aluminum-rich inclusions and that some others formed later and incorporated precursors previously enriched in magnesium-26. Chondrule magnesium-25/magnesium-24 correlates with [magnesium]/[aluminum] and size, the aluminum-rich, smaller chondrules being the most enriched in the heavy isotopes of magnesium. These relations imply that high gas pressures prevailed during chondrule formation in the solar nebula.     

Zodiacal dust and deep-sea sediments

The recent detection of radioactive Al(26) in marine sediments has led to the conclusion that it is brought into the earth's atmosphere by micrometeorites which have been exposed, in interplanetary space, to solar high-energy protons. The Al(26) method is not precise enough to yield directly a reliable value for the mass accretion rate to the earth to better than about 3 orders of magnitude, but is sufficiently accurate to allow a crucial decision between two widely differing of interplanetary dust which have been proposed to explain observations of the zodiacal light. The two models lead to Al(26) concentrations which would differ by about 5 orders of magnitude. Thus, the presence of Al(26) is consistent with the zodiacal dust model with particles of some tens of microns rather then with submicron particles. From this model a mass accretion to the earth then be calculated which is set at 1250 (upper limit, 2500; lower limit, 250) tons per day, or 2.8 x 10(-15) g/cm(2) sec, or 4.5 x 10(11) g over the earth per This value does not depend on the flux of the solar high-energy particles, which may be uncertain by an order of magnitude or more. The presence of Al(26) supports the idea that an important fraction of the dust is stony in composition material density, and thus eliminates some more exotic dust models, as such one consisting entirely of carbon grains. We may also conclude that the accreted dust particles have been in the solar system and exposed to protons from solar high-energy particles for a time interval which is greater than a significant of the Al(26) half-life (0.74 x 10(6) years).     

Droplet Chondrules: Jetting on high-velocity collision of small meteoritie particles may have produced droplet chondrules

I have proposed that droplet chondrules were formed by jetting during collision of meteoritic particles with diameters ranging in order of magnitude from 0.5 mm to 20 cm. This conclusion, based on a dynamic model for the collision process, supports the hypotheses of Wasson (2) (based on geochemical considerations) and Whipple (35) and Cameron (36) (based on dynamic model considerations) that chondrules were formed from objects less than 1 m in radius. In this model, the formation of chondrules is viewed as a textural, but not substantial chemical, change in the material of the early solar system. Droplets of melt produced by jetting are mixtures of material derived from two parent grains. Jets are probably not appreciably fractionated (except in volatile elements) either in the short duration of the shock events (several microseconds) or in subsequent cooling. This model for the formation of droplet chondrules implies that they were formed at a time in the history of the solar system when particle sizes were small. The most likely time for this condition is early in the process of accretion of nebular dust to planetary matter. Since velocities less than approximately 1.5 km/sec are required for the agglomeration and accretion of particles (37), the relatively higher velocities indicated for droplet chondrule-forming collisions indicate an early high-velocity destructive epoch amidst the general trend toward accretion of material.     

Existence of an 16O-rich gaseous reservoir in the solar nebula

Carbonaceous chondrite condensate olivine grains from two distinct petrographic settings, calcium-aluminum-rich inclusion (CAI) accretionary rims and amoeboid olivine aggregates (AOAs), are oxygen-16 (16O) enriched at the level previously observed inside CAIs. This requires that the gas in the nebular region where these grains condensed was 16O-rich. This contrasts with an 16O-poor gas present during the formation of chondrules, suggesting that CAIs and AOAs formed in a spatially restricted region of the solar nebula containing 16O-rich gas. The 16O-rich gas composition may have resulted either from mass-independent isotopic chemistry or from evaporation of regions with enhanced dust/gas ratios, possibly in an X-wind environment near the young Sun.     

Iodine-129/xenon-129 age of magnetite from the orgueil meteorite

Magnetite from the Orgueil C1 chondrite is only 2.0 +/- 2.4 million years older by the iodine-xenon method than the next oldest meteorite, the Karoonda C4 chondrite. This age ties the primitive C1 chondrites to the extensive iodine-xenon chronology of normal chrondrites. If Karoonda and Orgueil magnetite formed from similar material, then the age difference is an upper limit to the formation time of these meteorites-and by customary extension, the solar system. Condensation, chondrule formation, accretion, and metamorphism of the Karoonda parent body all seem to have been completed within a few million years.     

Solar particle tracks in glass from the surveyor 3 spacecraft

A glass filter from Surveyor 3 has a surface density of approximately 1 x 10(6) tracks per square centimeter from heavy solar flare particles. The variation with depth is best fitted with a solar particle spectrum dN/dE = 2.42 x 10(6) E(-2) [in particles per square centimeter per year per steradian per (million electron volts per nucleon)], where E is the energy and N is the number of particles, from 2 million electron volts per nucleon to approximately 7 million electron volts per nucleon and dN/dE = 1.17 x 10(7) E(-3) at higher energies. Not much difference is observed between 0.5 and 5 micrometers, an indication that there is a lack of track-registering particles below 0.5 million electron volts per nucleon. The Surveyor data are compatible with track results in lunar rocks, provided an erosion rate of approximately 10(-7) centimeter per year is assumed for the latter. The results also suggest a small-scale erosion process in lunar rocks.