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1.
《Communications in Soil Science and Plant Analysis》2012,43(9):911-932
Summary A simple, single‐step extraction with LiEDTA for the estimation of CEC and exchangeable bases in soils has been developed. Multivalent cations are stripped from the soil adsorption sites by the strongly chelating agent EDTA, and are replaced by Li. In soils without CaCO3 or water soluble salts, exchangeable divalent cations (Ca, Mg) are chelated by EDTA and exchangeable monovalent cations (Na, K) are replaced in a single extraction step using 0.25–2.5 g of soil and 10.0 ml of extractant. In calcareous soils the CEC can be determined in the same way, but for the extraction of exchangeable Ca and Mg, another separate extraction is needed because dissolution of calcite by EDTA is unavoidable. This extraction is done with as much NaEDTA as needed to extract only exchangeable Ca and Mg in a 1:2 (m/V) soil/alkaline‐50% (V/V) aethanolic solution to minimize dissolution of calcite. In gypsiferous soils gypsum is transformed into insoluble BaSO4 and soluble CaEDTA by LiBaEDTA thus avoiding interference of Ca from dissolution of gypsum, which renders the traditional methods for determining CEC unsuitable for such soils. To determine exchangeable Ca and Mg, Na4EDTA is used as for calcareous soils. In saline/sodic soils replacement of Na by Li is incomplete but the Na/Li‐ratio at the complex after extraction is proportional to the molar Na/Li‐ratio in the extracts, so that the CEC and original exchangeable sodium (ESP) content can be calculated. Additional analysis of Cl and, if necessary, SO4 in the extracts of saline soils can be used to correct for the effect of dissolution of the salts on the sum of exchangeable cations. This new method is as convenient as the recently developed AgTU (silverthiourea), but is better suitable for calcareous and gypsiferous soils. 相似文献
2.
《Communications in Soil Science and Plant Analysis》2012,43(7):683-695
Abstract A simple single‐extraction procedure for measuring exchangeable cations and effective CEC (ECEC, the CEC at natural pH and ionic strength) has been developed for routine advisory soil analysis. The method is based on the use of Sr (1.26M SrCl2) to displace exchangeable cations and effective CEC is taken as the sum of the exchangeable cations. A ten minute shaking time at 5 g:80 ml, soil solution ratio, was found to be optimum. Good agreement was found between the proposed method and the standard neutral IN ammonium acetate leaching procedure with correlation coefficients (r) for the individual cations Mg, Ca, Na and K of 0.99***, 0.99***, 0.83*** and 0.96*** respectively. Strontium chloride extracted more Al but less Mn (P<0.01) than IN KC1, but because of the low levels of these cations in relation to the total cations present, there was still a good relationship (r= 0.99) between ECEC determined by 1.26M SrCl2 and that determined as the sum of ammonium acetate extractable Mg, Ca, Na and K plus IN KCl‐extracted Al and Mn. 相似文献
3.
D. R. BOULDIN 《European Journal of Soil Science》1989,40(2):309-319
A model is developed which describes uptake of Ca, Mg, K, NO3 , Cl, and SO4 . The electrical neutrality of plant and soil are maintained through exchange of H or OH at the root-soil interface, constant partial pressure of CO2 and non-exchangeable H reaction with the soil cation exchange complex.
An important innovation in this model is the inclusion of electrical neutrality as a condition for plant, soil and soil solution. The uptake of cations is a function of both concentration of anions in solution and the suite of exchangeable cations. The model emphasizes an important role for CO2 in soil chemistry and plant nutrition. Presently, the model is most useful for generating research hypotheses. Perhaps the most important hypothesis is that something about as complicated as the present model will be required to model multiple ion uptake and crop yields. 相似文献
An important innovation in this model is the inclusion of electrical neutrality as a condition for plant, soil and soil solution. The uptake of cations is a function of both concentration of anions in solution and the suite of exchangeable cations. The model emphasizes an important role for CO
4.
《Communications in Soil Science and Plant Analysis》2012,43(6):739-753
Abstract The relationship between water soluble and exchangeable cations (Ca, Mg, Na, and K) was investigated for surface horizons of 195 soils including many taxonomic categories and a wide range in physical and chemical properties from around the world. This will provide information on exchangeable soil cation solubility for use in estimating plant uptake and leaching potential. Amounts of water soluble and exchangeable cations were not consistently related (r2 of 0.50, 0.08, 0.77, and 0.49 for Ca, Mg, Na, and K). High correlations were biased by high water soluble and exchangeable cation levels of a few soils that had 3.8‐ and 2.5‐fold greater mean than median values. The ratio of exchangeable to water soluble cations was closely related to cation saturation (r2 of 0.87, 0.95, 0.95, and 0.93 for Ca, Mg, Na, and K, respectively). As the degree of saturation of the exchange complex by a certain cation increased, solubility Increased. A change in saturation had less effect on K than on Na, Mg, and Ca solubility. Only exchangeable soil cations (NH4OAc extractable) are routinely measured and reported in soil survey reports, thus, water soluble levels may be determined from cation saturation. This will allow estimation of the amounts of cation that can potentially move in solution through the soil or be taken up by plants. Use of cation saturation, in addition to exchangeable content, will better characterize soil cation availability by representing quantity, intensity, and buffer factors. 相似文献
5.
设施蔬菜大棚土壤氮磷钾养分富积降低土壤钙素的有效性 总被引:5,自引:2,他引:3
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7.
Assessing phosphorus 'Change-Points' and leaching potential by isotopic exchange and sequential fractionation 总被引:4,自引:0,他引:4
Abstract. There is increasing evidence that phosphorus (P) can be transferred to surface waters by leaching as well as by erosion and surface runoff. Recently it has been suggested that P soluble in 0.01 m CaCl2 may be a good indicator of the specific Olsen-P concentration (usually termed the 'Change Point') at which the rate of P leaching from soil suddenly increases and poses a greater threat of eutrophication to standing waters. We know that these 'Change Points' vary from soil to soil but, so far, we do not fully understand the mechanism(s) involved. Here, we combine methods for assessing isotopically exchangeable P and P sequential fractionation to gain an insight into the processes which cause this sudden increase in P solubilization. We suggest that Change-Points simply define the asymtote of rapid desorption isotherms relating to that P which is most readily isotopically exchangeable (i.e at 24 h –33 P24 ) with the soil solution. This involves ligand exchange at hydroxyl sites associated with Fe and Al cations, which is kinetically governed by the concentration of surface complexes on soil minerals. Individual Change-Points reflect the mineralogy and surface chemistry of different soil types. Laboratory and field measurements of the Olsen-P Change-Point reflect these surface phenomena and are similar. Olsen-P extracts the portion of the exchangeable pool that most readily controls solution P, and the Olsen-P/33 P24 ratio is linearly related to Olsen-P Change-Points. This may provide a method for estimating P Change-Points where gradients of soil P are not available. 相似文献
8.
《Communications in Soil Science and Plant Analysis》2012,43(11-12):1773-1790
Abstract Simultaneous extraction of nutrients using ammonium bicarbonate–diethylene triamine penta acetic acid (ABDTPA) extractant has been successful for highland soils, but its potential for lowland soils is still uncertain. This study evaluated the suitability of ABDTPA extractant to determine available phosphorus (P), potassium (K), sodium (Na), calcium (Ca), magnesium (Mg), iron (Fe), manganese (Mn), zinc (Zn), and copper (Cu) in lowland rice soils of Sri Lanka. Available nutrients were analyzed both by conventional and ABDTPA methods, using the original ABDTPA (1∶2 soil–extractant) method as well as a modified (1∶4 soil–extractant) method. Conventional methods tested were Olsen, Bray 1, and FeO strip for available P; neutral NH4OAc extraction for exchangeable Ca, Na, K, and Mg; and DTPA extraction for available Zn, Cu, Fe, and Mn. Nutrient content and uptake by plants were determined by a pot experiment with rice (Oryza sativa). Nutrients extracted by the conventional methods and ABDTPA methods correlated well, in general, for all nutrients. Highly significant correlations were observed between plant uptake and extractable nutrients by 1∶2 and 1∶4 ABDTPA methods for P (r=0.85***and 0.73***, respectively), K (r=0.79*** and 0.66***, respectively), Na (r=0.86*** and 0.78***, respectively), Zn (r=0.66*** and 0.60***, respectively), Mn (r=0.72*** and 0.84***, respectively), and Fe (r=0.74*** and 0.68***, respectively). Calcium and Mg extracted by ABDTPA showed a poor relationship with their respective plant uptake. The ABDTPA method was as effective as or even better than the conventional methods in evaluating fertility status of lowland rice soils with respect to most nutrients. Replacing the conventional methods by the single ABDTPA multielement extractant will reduce the time and cost of soil analysis. 相似文献
9.
The rates of extraction of Na, K, Mg, Ca, and Al with 1M NH4 NO3 from the mineral-and organic-rich layers of some Park Grass (Rothamsted) soils were measured at the pH of the soil. Below pH 3.7 exchangeable Al, derived from the kinetics curve, increases with decreasing soil pH and is less in the organic-rich layer. The sum of the basic exchangeable cations, ∑(Na + K + Mg + Ca), increases with increasing soil pH and is more in the organic-rich layer. The extraction of exchangeable Al obeys first order kinetics, the rate constant being similar for all the soils (mean value 36 ± 7 × 10?6|s?1), which implies that exchangeable Al is released from surfaces with similar properties for the adsorption of Al, and that the rate is not affected by soil pH and organic matter. The rate of extraction of non-exchangeable Al is the same in the mineral-and organic-rich layers of each soil, and is maximal at about pH 3.7, decreasing sharply at more and less acid pH values. 相似文献
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11.
Monrawee Fukuda Anabela da Conceição Lopes Fonseca Hisashi Nasukawa Momade Mamudo Ibraimo Kazuhiro Naruo 《Communications in Soil Science and Plant Analysis》2017,48(12):1462-1472
Accurate soil testing procedures contribute to agricultural development of Mozambique. The Mehlich 3 (M-3) procedure has not been evaluated for Mozambican soils despite its wide applicability. Results showed M-3 solution could extract exchangeable calcium (Ca), magnesium (Mg), and potassium (K) as well as 1 M ammonium acetate (NH4OAc), while M-3 was not appropriate for extraction of exchangeable sodium (Na). M-3 was an alternative procedure to Bray-I for available phosphorus (P) extraction. Although M-3 extracted 1.6 times more P than Bray-I, determination coefficient between the two procedures showed significantly high value. P content in M-3 extracts can determine using inductively coupled plasma spectrophotometers (ICP) to maximize the merits of M-3. In conclusion, M-3 is applicable for determination of exchangeable Ca, Mg, K, and available P, in a single determination using ICP, and should contribute to development of effective and accurate soil diagnosis in Mozambique. 相似文献
12.
Laboratory investigations of the dissolution of North Carolina phosphate rock (PR) in soil, as affected by soil texture, were conducted using soils created by mixing various proportions of the <45 μm and >45 μm fractions of a lateritic soil. The dissolution of PR in soil, and the resulting changes in plant available P, were estimated by measuring increases in exchangeable Ca (ΔCa) and NaHCO3 -extractable P (ΔPb ), respectively. The total fertilizer phosphate dissolved (ΔP) was calculated from δCa values based on the assumption that dissolution of PR released amounts of Ca and P in a constant ratio determined by the stoichiometry of the PR. δP increased with increasing content of <45 μm particles. APb also increased with the percentage of <45μ fraction, with about 20% of AP being recovered as APb . A smaller proportion of dissolved P was soluble in NaHCO3 for the soil comprising only the <45μ particles. The increase in δP with increased percentage of <45 μn soil was probably due inter alia to the greater P-sorption, Ca-sorption and the pH buffering capacity of the fine grained soil constituents. 相似文献
13.
D.K. Pal P.R. Kadu P.H. Vaidya S.S. Balpande P.L.A. Satyavathi D.K. Pal 《Soil Use and Management》2003,19(3):208-216
Abstract. Detailed morphological, physical, chemical, mineralogical and micromorphological studies were carried out to identify properties that influence the yield of deep-rooted crops in 29 Vertisols of semiarid central India, since existing land evaluation methods are not adequate to explain the yield of cotton obtained by farmers. The studies indicated that among the soil parameters, CaCO3 in the clay fraction, the exchangeable Ca/Mg ratio, exchangeable sodium percentage (ESP) and saturated hydraulic conductivity (HC) were the yield-influencing factors. The pedogenetic relationships between the semiarid climate, formation of pedogenic calcium carbonate, exchangeable Ca/Mg, ESP and HC have been established. In view of the pedogenetic processes that ultimately impair the drainage of soils, evaluation of Vertisols for deep-rooted crops on the basis of HC alone may help in planning and management of soils, not only in the Indian semiarid tropics, but also in similar climatic areas elsewhere. 相似文献
14.
Toxic trace metals may percolate to the ground water from sewage sludge disposed onto land. Analyses are presented of the soil solution from a slightly acid loamy soil treated 7 years earlier with single applications of digested sewage sludge in amounts equivalent to 0, 150 & 330 t dry matter ha−1
These very heavy dressings correspond to 2 & 4.5 times the recommended 30–year limit. Samples of soil and soil solution from four depths to 80 cm were analysed for Al, B, Ba, Ca, Cl, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, S, Sr, V, Zn, together with the OM of the soil, and the pH, alkalinity, dissolved organic carbon, and absorbance at 350 nm of the solutions.
These very heavy sludge applications were apparently still releasing substantial quantities of NO3 , and some SO4 even after 7 years. Nitrate, SO4 , Mg, Ca, Sr, B, and possibly Ba are still moving through the profile, possibly to the ground water. Solution concentrations of Cu and Zn are considerably higher at all depths than those in the untreated plot, but they fall off sharply with depth. It is unlikely that any Cu or Zn is now reaching the ground water.
The paper also presents a set of published solution analyses for soils, sludge–treated soils and digested sludge, as a basis for further studies. 相似文献
These very heavy dressings correspond to 2 & 4.5 times the recommended 30–year limit. Samples of soil and soil solution from four depths to 80 cm were analysed for Al, B, Ba, Ca, Cl, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, S, Sr, V, Zn, together with the OM of the soil, and the pH, alkalinity, dissolved organic carbon, and absorbance at 350 nm of the solutions.
These very heavy sludge applications were apparently still releasing substantial quantities of NO
The paper also presents a set of published solution analyses for soils, sludge–treated soils and digested sludge, as a basis for further studies. 相似文献
15.
《Communications in Soil Science and Plant Analysis》2012,43(17):2524-2534
Lack of microelements is a major problem in crop production in tropical peatland. For their efficient application, the fate of copper (Cu), iron (Fe), manganese (Mn), and zinc (Zn) in a Histosol was investigated in a 3-month column experiment. Leaching of Cu, Fe, Mn, and Zn accounted for 2, –2 to 7, 28 to 32, and 21 to 23% of the amounts applied, respectively, in both the flooded and upland soils. The microelement application enhanced the leaching of calcium (Ca), potassium (K), magnesium (Mg), sodium (Na), and phosphorus (P). Replacement of exchangeable cations by the microelements was suggested in the successive extraction of elements from the soils after incubation. Under the upland conditions, 31–33% of the Cu and Fe increased in soil was extracted with diethylenetriaminepentaacetic acid?/?triethanolamine (bound to humus), whereas 26–31% of the Mn and Zn increased was exchangeable. Extractability was smaller under the flooded conditions for all the microelements, suggesting that fertilization in the dry season is more effective. 相似文献
16.
《Soil Science and Plant Nutrition》2013,59(6):856-869
Abstract It is essential to determine the relationship between soil chemical and mineralogical properties and soil response to acid load to understand the acid-neutralizing capacity and cation behavior of different ecosystems. For 46 soil samples from a subsurface horizon in humid Asia, that is, Japan, Thailand and Indonesia, exchangeable cations, total bases and oxalate-extractable Al (Alo) were determined, and acid titration was conducted to investigate the rapid soil response to acid load. The acid titration experiment indicated three types of soil response: (1) the release of base cations (particularly Ca and Mg) strongly correlated with exchangeable bases, which dominated the tropical soil samples, (2) the release of Al correlated with Alo content, which dominated the Japanese soil samples, (3) acid and anion adsorption in soil samples with low acid-neutralizing capacity. To gain further information on the source of soil alkalinity, a column experiment with HCl was conducted using eight selected soil samples in which first-order kinetics were assumed to simulate the time-courses of cation release. In the column experiment, the amounts of Ca and Mg released were close to the exchangeable amounts, and Alo dissolved more rapidly than Al in crystalline minerals. The rate constants of cation release were large for Ca and Mg, and small for Al, clearly indicating a difference between the exchange and dissolution reactions. Thus, rapid soil response to acid load differed among the soils. A cation exchange reaction was dominant in the tropical soils. In some tropical soils, Ca and Mg were present in exchangeable forms at a higher ratio in the total amounts and they were considered to be easily utilized by plants, but leached out from the soils. In the Japanese soils, including the Andisols, secondary mineral dissolution was conspicuous, resulting in a large acid-neutralizing capacity. In both the tropical and Japanese soils with low acid-neutralizing capacity, anion adsorption mainly contributed to acid neutralization. 相似文献
17.
《Communications in Soil Science and Plant Analysis》2012,43(9-10):2197-2212
Abstract A study was conducted with the purpose of comparing the efficiency of Mehlich 1, Mehlich 3, and calcium acetate lactate (CAL) extractants for the deter‐ mination of available phosphorus (P) and exchangeable cations [potassium (K), calcium (Ca), magnesium (Mg), and sodium (Na)] on 22 Ethiopian and 10 German agricultural soils. The Olsen and NH4OAc extractants were used as standards against which P and exchangeable cations values were compared. Results showed that, in general, highly significant correlations were found between all of the methods for available P and exchangeable cations determination on the Ethiopian soils. The highest correlation was, however, found with the Mehlich 3 extractant. On the ten soils from Germany, the Olsen method did not give significant cor‐ relation with the CAL method for P determination. The CAL and Mehlich 3 extrac‐ tants were also not good indicators of Na availability when compared with the NH4OAc method. It can be generalized that the Mehlich 3 is a suitable extractant for P, K, Ca, Mg, and Na in Ethiopian soils, but further study is recommended to confirm these findings under field conditions. 相似文献
18.
耕地土壤交换性钙镁比值的研究 总被引:19,自引:1,他引:19
对沈阳市郊区1994个耕地表土(0~20cm)样点和4个典型剖面中交换性Ca/Mg的比值进行了对比研究。结果表明:不同土属耕层土壤中Ca、Mg交换量有较大差别,交换性Ca/Mg的比值主要受母质等成土因素的影响;棕壤的各个土属的Ca/Mg在4左右,石灰性草甸土和草甸沼泽土的Ca/Mg则在8以上。棕壤和草甸土典型剖面不同层次中的Ca/Mg比值有着随深度加深而降低的趋势;由于Ca的植物返还率较Mg高,同一土壤类型中Ca/Mg比值的最大值出现在表土层,母质层中的Ca/Mg则相对稳定。对土壤Ca/Mg进行研究可以丰富土壤离子交换性能研究和土壤发生学特性研究的内容。 相似文献
19.
Theodore Karyotis Davis D. Onduru Christos Noulas Louis N. Gachimbi Fred N. Muchena 《Soil Science and Plant Nutrition》2005,51(5):645-648
The nutrients status and properties in Kenyan soils (Kiambu, Mbeere Districts) are reported with the aim to elucidate the factors of productivity decline. According to the FAO (1988) system the studied soils were classified as humic Nitisols, haplic Acrisols or luvic Arenosols. The soils were found acidic, as a result of leaching of exchangeable cations and they are poor in organic carbon. Cation exchange capacity was extremely low in the sandy soils of Mbeere. Available phosphorus and exchangeable K+ were low inducing a crucial problem of soil fertility. Among the micronutrients, manganese extracted by DTPA was most abundant element, while micronutrients extracted by 4 M HNO3 ranked as follows: Fe>Mn>Zn>Cu. Copper (DTPA) was low and manganese was extremely high in Kiambu. Iron content varied greatly, while decreased zinc was observed in Mbeere. Nitrogen mineralization over an incubation period of 30 weeks ranged from 54.64 to 145.50 mg kg−1 and represents 4.53–21.09% of the total soil nitrogen. Soil nitrogen was associated to soil organic carbon and was strongly correlated to total soil N. Water harvesting, liming, and improved management of composting and manure are amongst the measures to restore soil fertility. 相似文献
20.
Keuk-Ki Lee Suhas Pralhad Wani Kanwar Lal Sahrawat Nunna Trimurtulu Osamu Ito 《Soil Science and Plant Nutrition》2013,59(1):117-126
The effects of nitrogen (N) and/or phosphorus (P) fertilizers on the nutritional status in the rhizosphere were studied by monitoring throughout the growth period the concentrations of organic carbon (C), inorganic N, NaHCO3 extractable P, exchangeable K, Ca, and Mg in sorghum (Sorghum bicolor L. Moench) down in an Alfisol field, and of all these elements except for extractable P, and exchangeable Ca in a Vertisol field in semi-arid tropical India. These concentrations were compared between the rhizosphere soil and bulk soil of sorghum grown in both fields. Organic C content of the rhizosphere soil increased with plant age and was significantly higher than that in the bulk soil throughout the growth of sorghum, but it was not affected by the rates of N or P fertilizer. Inorganic N concentration in the rhizosphere soil was significantly higher than that in the bulk soil until maturity in sorghum. The content of available P in the rhizosphere soil was significantly higher than in the bulk soil after the middle of the growth stage. Its average concentration in the rhizosphere soil across growth stages was significantly higher than in the bulk soil, which contradicts the observation in many reports that there is a depletion of P in the rhizosphere soil. The concentration of three exchangeable cations, K, Ca, and Mg, showed different patterns in the rhizosphere and the bulk soils. The concentration of K was almost constantly higher in the rhizosphere soil than in the bulk soil, Ca concentration was not different between the two soils, and Mg concentration was significantly higher in the bulk soil than in the rhizosphere soil. The reasons for these discrepancies cannot be explained at present. The concentrations of these cations were not affected by the rate of N or P fertilizer except for Mg at a later growth stage. The differences between rhizosphere and bulk soils in Alfisol were similar to those in Yertisol with respect to the concentration of organic C, inorganic N, and exchangeable K and Mg. 相似文献