Impact of stone content on water movement in water-repellent sand

Soils are commonly stony, especially in steep upland or heavily degraded sites. The hydrological effect of large stone contents has been previously investigated in wettable but not in water-repellent soils. For the latter, the focus has instead been on the impact of other soil characteristics (e.g. cracks and macropores) likely to promote water percolation. This paper investigates stone effects on water flow in water-repellent sand under laboratory conditions. Seventy-five experiments were performed on a water-repellent sand mixed with a range of quantities of different-sized wettable and water-repellent stones. The time taken for water to pass through each sand–stone mix, the percolated water volumes and numbers of dry and wet stones following each 60-minute experiment were recorded. At large stone contents (> 55% or > 65% by weight, depending on stone wettability), percolation occurred relatively quickly and in comparatively large quantities. At intermediate stone contents (45–65%) percolation response was variable and at stone contents < 45% for wettable and < 55% for water-repellent soils no water percolation occurred. We argue that with large stone contents flow pathways develop along sand–stone interfaces and a continuous preferential flow path can form provided there are sufficient stone-to-stone connections. The distribution and alignment of the stones, especially at intermediate stone contents, are important for promoting water movement. Water repellency determinations based only on the fine sediment component in stony soils could therefore be misleading as regards determining their hydrological response: the influence of the clastic component must also be considered.     

Conservation tillage and macropore factors that affect water movement and the fate of chemicals

A thorough understanding of how conservation tillage influences water quality is predicated on knowledge of how tillage affects water movement. This paper summarizes the effects of conservation tillage on water movement and quality mainly based on long-term experiments on Luvisols at the North Appalachian Experimental Watershed near Coshocton, OH, USA. Conservation tillage can have a much larger effect on how water moves through the soil than it does on the total amount percolating to groundwater. Soil macroporosity and the proportion of rainfall moving through preferential flow paths often increase with the adoption of conservation tillage and can contribute to a reduction in surface runoff. In some medium- and fine-textured soils most of the water that moves to the subsoil during the growing season (May–October) is probably transmitted by macropores. If a heavy, intense storm occurs shortly after surface application of an agricultural chemical to soils with well-developed macroporosity, the water transmitted to the subsoil by the macropores may contain significant amounts of applied chemical, up to a few per cent, regardless of the affinity of the chemical for the soil. This amount can be reduced by an order of magnitude or more with the passage of time or if light rainstorms precede the first major leaching event. Because of movement into the soil matrix and sorption, solutes normally strongly adsorbed by the soil should only be subject to leaching in macropores in the first few storms after application. Even under extreme conditions, it is unlikely that the amount of additional adsorbed solute transported to groundwater will exceed a few per cent of the application when conservation tillage is used instead of conventional tillage. In the case of non-adsorbed solutes, such as nitrate, movement into the soil matrix will not preclude further leaching. Therefore, when recharge occurs during the dormant season thorough flushing of the soil, whether macropores are present or not, can move the remaining solutes to groundwater. Thus, the net effect of tillage treatment on leaching of non-adsorbed solutes should be minimal.     

石砾参数对土壤水流和溶质运移影响研究进展

土壤水流和溶质运移一直是土壤学研究的热点,溶质运移理论主要应用于地下水污染、污染物运移、土壤重金属污染研究等方面。溶质主要通过优先流和基质流进行运移,影响溶质运移因素很多,主要包括土壤结构、质地、水力传导率、体积质量、初始含水量、根系、石砾等。石砾作为土壤质地中的一个分级单位,与溶质运移关系较为复杂。本文综合介绍了石砾基本内涵以及石砾对土壤水流和溶质运移影响研究进展;系统阐述了石砾内部参数(石砾覆盖度、含量、粒径、空间异质性等)和外部参数(根石结构、干湿冻融、耕作等),指出目前研究主要量化土壤表面及土壤表层石砾参数对水文效应、土壤侵蚀、入渗以及径流的影响,然而石砾参数对溶质运移影响研究不够系统,石砾参数与溶质运移关系研究尚处于初步阶段,对土壤深层石砾研究缺乏;归纳了石砾参数研究技术手段及模型;探讨了目前石砾参数对土壤水流和溶质运移影响研究存在的问题以及今后研究趋势。     

Uneven moisture patterns in water repellent soils

In the Netherlands, water repellent soils are widespread and they often show irregular moisture patterns, which lead to accelerated transport of water and solutes to the groundwater and surface water. Under grasscover, spatial variability in soil moisture content is high due to fingered flow, in arable land vegetation and microtopography play a dominant role. Examples are given of uneven soil moisture patterns in water repellent sand, loam, clay and peat soils with grasscover, and in cropped water repellent sandy soils. In addition, the influence of fungi on inducing soil moisture patterns is illustrated as well.     

Salt-Water Dynamics in Soils: Ⅰ. Salt-Water Dynamics in Unsaturated Soils Under Stable Evaporation Condition

A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers were used to monitor salt and water variation in soils.The experiment revealed that in the process of fresh groundwater moving upwards by capillary rise in the column,the salts in subsoil were brought upwards and accumulated in the surface soil,and consequently the salinization of surface soil took place.The rate of salt accumulation is determined mainly by the volume of capillary water flow and the conditions of salts contained in the soil profile.Water flux in soils decreased obviously when groundwater depths fell below 1.5m.When there was an interbedded clay layer 30cm in thickness in the silty loam soil profile or a clay layer 100cm in thickness at the top layer,the water flux was 3-5 times less than in the soil profile of homogeneous silty loam soil.Therefore,the rate of salt accumulation was decreased and the effect of variation of groundwater depth on the water flux in soils was weakened comparatively.If there was precipitation or irrigation supplying water to the soil,the groundwater could rarely take a direct part in the process of salt accumulation in surface soil,especially,in soil profiles with an interbedded stratum or a clayey surface soil layer.     

Solute recycling by crops and leaching in a drained arable soil

Preferential flow, as it bypasses the soil matrix, can greatly enhance the leaching of chemicals. When a soil is drained there is the risk that such short‐circuiting results in more or less direct passage of polluting chemicals from the soil to the groundwater. If the groundwater table is shallow the chemicals could be transferred back into the surface soil by hydraulic lift through roots and subsequent release by exudation or from decaying plant residues and again become exposed to leaching by preferential flow, thus strongly enhancing the chance of export via the drains. We investigated the leaching of bromide in a tile‐drained arable field over 2 years of crop rotation. The site was a former wetland, artificially drained a century ago for agriculture. Bromide was applied over 1.6 ha at a dosage of 10 g Br per m² in August 1995 after the harvest of wheat. During the 2 years 18% of the applied bromide was exported via the drainage system, most of it in preferential flow events and more than half of it in a single winter storm 5 months after the application. Within 7 months 56% of the applied tracer was leached out of the main root zone into the groundwater. Subsequently the tracer re‐emerged in water taken up by sugar beet in the following season. The beet accumulated 50% of the initially applied bromide in their leaves and released it again after harvest when the leaves were left as green manure on the field. Our results show that this recycling of solutes to the topsoil can have an important influence on their leaching as the solutes are thus again exposed to preferential transport into drains in the course of preferential flow events.     

Short‐term transport of cadmium during a heavy‐rain event simulated by a dual‐continuum approach

The transport of solutes in soils, and its intensification due to preferential flow, plays crucial role when problems related to the groundwater pollution are dealt with. The objective of this study was to examine transport of cadmium (Cd) in response to an extreme rainfall event for three different soils using numerical modeling. The ^115mCd²⁺ concentration profile had been measured in the Bodiky reference site (Danubian Lowland, Slovakia) by the radioactive‐tracer technique and used for the calibration of the dual‐continuum model S1D. The Cd transport during a single rain event was predicted with the S1D model for light, medium‐heavy, and heavy soil in the same region. The Cd transport through the soil profile was simulated by the one‐dimensional dual‐permeability model, which assumes the existence of two pore domains: the soil‐matrix domain and the preferential‐flow domain. The model is based on Richards' equation for water flow and advection‐dispersion equation for solute transport. A modified batch technique enables to distinguish process of adsorption in the matrix domain and the preferential pathways. Modeling with classical single‐permeability approach and dual‐continuum approach without considering the particle‐facilitated transport led to negligible Cd penetration. The rainfall event with extremely high rainfall intensity induced deep penetration of Cd in the medium‐heavy and heavy soil, which may indicate increased vulnerability to shallow groundwater pollution for the respective sites in Danubian Lowland region. The highest Cd leaching was predicted for heavy clay soil, where the preferential particle‐facilitated transport of Cd through the soil profile was significant due to the contrasting properties of the soil‐matrix domain and the preferential‐flow domain. The results of the sensitivity analysis suggested only slight effect of the transfer rate coefficients on simulated Cd leaching.     

蒸发条件下粘土层对土壤水和溶质运移影响的模拟

以土壤水和溶质运移的动力学原理为基础 ,采用数值模拟方法 ,研究了在浅层地下水和蒸发条件下含有粘土层土壤的水和Cl-的运移状况 ,重点探讨了两种粘土的层位和层厚对水和Cl-运移影响的差别及原因。研究结果表明 ,粘土层对土壤的水和溶质运移影响的程度 ,与层状土壤中该粘土及其组合土壤的水力学性质有关。本文模拟的重粘土 (简称Y粘土 )与轻壤土所组成的层状土壤 ,其基本情况为 ,随粘土层层位的升高和层厚加大 ,土壤水分蒸发和地下水补给速率降低 ,Cl-积累减少。而轻粘土 (简称R粘土 )与轻壤土所组成的层状土壤 ,由于它们的导水率曲线在压力水头h约 - 10 0 0cm处相交 ,当h低于此值时 ,R粘土的导水率就大于轻壤土的。因此 ,蒸发、补给速率和Cl-积累强度出现以顶位最高 ,甚至高于均质轻壤土 ,其次为底位 ,最低为中部层位的现象。在蒸发条件下Cl-在剖面中的积聚部位主要是土表。粘土层的存在 ,起到了阻滞作用 ,而阻滞程度则与该粘土水力学性质、层位、厚度和地下水埋深有关     

Adsorptionsisothermen als Regelgrößen beim Transport von Schwermetallen in Böden

Adsorption isotherms as regulators controlling heavy metal transport in soils The adsorption and desorption of Pb²⁺ and Cd²⁺ from equilibrium solutions with heavy metal contents up to 5000 μg/1 were determined in bulk experiments for soil samples from an acid Braunerde developed in loess loam, taken from the humic surface layer of the mineral soil (0–10 cm) and from the subsoil fairly free from organic matter (30–40 cm). Pb and Cd in solutions were determined by flameless atomic absorption spectroscopy. Pb was more strongly retained in the solid phase than Cd, and higher amounts of heavy metals were retained in the humic surface soil than in the subsoil free of organic matter. In the case of Pb adsorption/desorption showed slight hysteresis in the subsoil. The quantity/intensity (Q/I) relationships found in the experiments could be described by the Freundlich equation. The Q/I-relationships were substituted in the general transport equation. With a simulation model the transport of Pb and Cd through the soil with vertical water flow was calculated by the use of the Continuous Simulation Programming Language (CSMP). Two different cases were considered: a small, continuous increase in the heavy metal input of the soil surface, and a high, instantaneous peak input. Simulation of the transport and distribution mechanisms induced by the inputs over a period of 10 years showed strong retention of lead in the surface layer and consequently a strong damping of the concentration peak in the soil solution. In contrast, cadmium is distributed more quickly over the whole profile, yet the concentration peak in the solution phase is, too, damped considerably in the surface layer by temporary retention in the solid phase. The results of the simulation runs are in accordance with the situation in real soils where often strong accumulation of Pb is found in the top soil, while Cd is accumulated only slightly.     

Identification of Lateral Macropore Flow in a Forested Riparian Wetland through Numerical Simulation of a Subsurface Tracer Experiment

Understanding wetland hydrogeology is important as it is coupled to internal geochemical and biotic processes that ultimately determine the fate of potential contaminant inputs. Therefore, there is a need to quantitatively understand the complex hydrogeology of wetlands. The main objective of this study was to improve understanding of saturated groundwater flow in a forested riparian wetland located on a golf course in the Lower Pee Dee River Basin in South Carolina, USA. Field observations that characterize subsurface wetland flow critical to solute transport originating from storm-generated runoff are presented. Monitoring wells were installed, and slug tests were performed to measure permeabilities of the wetland soil. A field-scale bromide tracer experiment was conducted to mimic the periodic loading of nutrients caused by storm runoff. This experiment provided spatial and temporal data on solute transport that were analyzed to determine travel times in the wetland. Furthermore, a 3-D numerical, steady-state flow model (MODFLOW) was developed to simulate subsurface flow in the wetland. A particle tracking model was subsequently used to calculate solute travel times from the wetland inlet to the outlet based on flow modeling results. It was evident that observed tracer breakthrough times were not typical of these measured wetland soil matrix conductivity values. Based on surface water sampling results at the wetland outlet, tracer arrival time was about 9 h after the injection of the tracer. These results implied an apparent mean K value of 2,050 m/day, which is 152 times larger than the mean of the measured values using slug tests (13.4 m/day). Modeling efforts clearly demonstrated this implied preferential flow behavior; particle travel times resulting from the calibrated flow model were in the order of hundreds of days, while actual travel times in the wetland were in the order of hours to a few days. This significant difference in travel times was attributed to the presence of macropores in the form of dead root channels and cavities forming a pipe-flow network. The analyses presented in this study resulted in an estimate of the ratio of matrix permeability to matrix plus macropore permeability of approximately 1/150. Eventually, the tracer test and resulting travel times between various points in the wetland were critical to understanding the true wetland flow dynamics. The final conceptual model of the hydraulic properties of the wetland soils comprised a low permeability matrix containing a web of high K macropores. Simulation of tracer transport in this system was possible using a flow model with significantly elevated K values.     

Wasser- und Elementtransport in einem Stagnogley am Hang der Bärhalde (Schwarzwald,Deutschland)

Water and Element Movement in a Stagnogley on the Slope of the Bärhalde Range (Black Forest, Germany) The soil water balance of this stagnogley (planosolic humic gleysol) is dominated by the very humid and cool climate, by the indurated subsoil and the solid parent granite as well as by its position on the lower slope of the Bärhalde ridge. Inspite of the high saturated water conductivity the drainage is impeded causing permanent waterlogging (average watertable at 55 cm below surface). Lateral flow through the soil exceeds seepage by 150 times. Inspite of the high input by lateral flow from the higher podzol area most of the major elements show reasonable losses throughout the profile. Other elements have losses in the topsoil which are compensated in the subsoil by gain from the lateral flow (Al, Be, Si). Especially elements with a mobility independent from redoxpotential have been accumulated throughout the entire period of soil formation (Pb, Zn). Some other trace elements accumulate recently because of increasing immissions (Cd, Cu, Co). Over all elements lateral flow through the profile exceeds vertical transport by 30 to 400 times.     

Bromide and herbicide transport under steady-state and transient flow conditions

The dynamics of water flow in soils influences the transport behaviour of solutes. Transport of bromide and herbicides through undisturbed soil columns was investigated under conditions of unsaturated steady-state and transient water flow. Effective transport parameters were obtained from fitting the convection–dispersion equation to curves of concentration against cumulative drainage, and these enabled us to interpret the observed behaviour. Under both steady-state and transient flow bromide and herbicides were transported through similar parts of the pore volume of a homogeneous single grain soil (Bv horizon). However, in aggregated Ah and Ap horizons preferential transport occurred during transient flow but not during steady-state flow. For preferential flow the mean transport volume seemed to depend on the prevailing pore system and the fraction of preferentially flowing water. Solute leaching was more efficient under steady-state than under transient flow for bromide in all soils and for herbicides in the Bv horizon. However, when transient flow caused preferential transport, herbicide loss was greater under transient flow than during steady-state flow. Under preferential flow conditions a three-step herbicide concentration development recurred in successive drainage events. This behaviour was not observed for the non-reactive tracer. It seemed to be caused by sorption. A steady-state model with cumulative drainage as independent variable instead of time can predict the transport of non-reactive and adsorbed solutes in homogeneous soils without features of preferential flow. Otherwise constant effective input parameters cannot be assessed a priori.     

A stochastic-empirical approach to modelling nitrate leaching

Abstract. Techniques for determining the probability density function (pdf) of travel times of solute molecules through a defined volume of soil, following a pulse or step-change input to the soil surface, are described. A stochastic transfer function model (TFM) based on the pdf of nitrate travel times works satisfactorily when the nitrate originates from a pulse input of soluble fertilizer to the soil surface. However, a TFM based on the pdf of a surface-applied tracer, such as chloride or tritiated water, is less satisfactory for simulating the leaching of indigenous soil nitrate. The main problems seem to be the difficulty of estimating mean nitrate concentrations because of the spatial variability of nitrate in field soils, accounting for denitrification during leaching, and the uncertain reproducibility of the soil's transport characteristics, as embodied in its operationally defined fractional transport volume, θ _st , Nevertheless, for many practical applications, a simplified empirical model which treats the soil's transport volume as a well mixed reactor of average initial concentration C, can provide satisfactory predictions of the quantity of nitrogen leached over extended periods. Irrespective of which model is used, a comprehensive treatment of nitrate leaching, particularly for soil generated nitrate, requires a detailed knowledge of transfers of labile nitrogen within the transport volume, and across its boundaries other than those monitored at the input and output surfaces.     

Simulation of hydrology following various volumes of irrigation to soil with different depths to the water table

Vertical water fluxes at the water table and in the subsoil need to be quantified because of their significance for the supply of water to crops and the control of soil salinization in areas with shallow groundwater. A soil–water–atmosphere–plant (SWAP) model was calibrated using measured values of soil water content and the water fluxes at the water table. The measurements were taken in a field experiment where the depth to groundwater and the volume of irrigation water applied were controlled. The calibrated SWAP model was then used to simulate the soil water content and fluxes at the water table and in the subsoil under different irrigation and groundwater conditions. The predicted values provided a quantitative insight into specific terms in the water balance equation together with soil water fluxes in the subsoil that cannot be measured directly by field instruments. Crops utilized significant amounts of water from deeper soil layers and directly from groundwater, when the volume of irrigation decreased and the depth to the water table was <3.0 m. Depth to the water table significantly influenced water fluxes occurring in the soil profile over the period when evaporation dominated the hydrological cycle. Shallow groundwater is a very significant water resource for meeting the water requirement of crops. In practice, the frequency and quantity of irrigation need to be varied according to groundwater conditions.     

再生水水质对斥水和亲水土壤水分特征曲线的影响

为探求再生水灌溉对斥水和亲水土壤水力特性的影响,该文选用有代表性的斥水黏壤土和亲水黏壤土、斥水砂土和亲水砂土,测定其在自来水、再生水和其他4种生活污水条件下的土壤水分特征曲线,采用主成分分析法得到不同水质综合指标,分析水质综合指标对不同土壤水分特征曲线的影响,采用van Genuchten-Mualem模型对黏壤土土-水曲线的参数进行拟合,并分析水质综合指标对黏壤土累积当量孔径分布、比水容量和水分常数的影响。结果表明:在相同基质吸力情况下,黏壤土含水率随水质综合指标增加(水质变差)而减小,砂土的含水率随水质变化不大;在低吸力段,斥水和亲水黏壤土的比水容量随水质综合指标的增加而增加;土壤进气值与水质综合指标呈显著负线性相关关系(R~2分别为0.94和0.78);相同水质条件下,斥水土壤的进气值比亲水土壤小;随着水质综合指标的增加,斥水和亲水黏壤土的极微孔隙降低,而中等孔隙和大孔隙增加,小于某当量孔径的累积百分比增加;随着水质综合指标的增加,斥水和亲水黏壤土的田间持水率、凋萎系数、有效水和易利用水比例均减小,但再生水对田间持水率和易利用水比例降低作用不显著。研究结果可为大面积再生水灌溉及其管理提供一定的理论依据。     

地下水浅埋条件下包气带水和溶质运移数值模拟研究述评

地下水浅埋条件下包气带水和溶质运移规律是解决土壤盐渍化、地下水污染等环境与生态问题的基本理论基础,基于多孔介质水和溶质运移基本方程的数值模型是研究包气带物质运移的重要手段。通过深入分析土壤水和地下水之间的相互关系,强调在地下水埋深小于其极限埋深的情况下应把地下水作用耦合到包气带水和溶质运移模型中。该文概括总结了现有研究把地下水作用与土壤水模型相耦合的方法,并分析了各种方法的优缺点。在回顾现有土壤水分运动参数和溶质运移参数确定方法的基础上,归纳了包气带水和溶质运移模型从“点”尺度向“田块”尺度扩展的途径,随机方法仍将是今后的研究热点,并有望应用于实践。     

地面灌溉技术参数对氮素运移分布影响的研究进展

地面灌溉是应用最广泛的灌水方法，通过优化地面灌溉设计和管理减少水氮淋失，正在成为研究的热点问题，该文对有关成果进行了综述。由于地面灌溉的尺度较大，加之土壤水力参数和溶质运移参数的空间变异，使得地面灌溉施肥条件下溶质(N)运移分布的田间试验研究，无论在技术上还是在投入上都具有一定难度。有关沟灌、畦灌和水平畦田灌溉施肥时水氮分布的田间试验结果指出，肥料(N)分布没有入渗水深分布均匀，且与土壤初始含水率、流量、土壤入渗参数、田面糙率和施肥时机等因素密切相关。在模拟研究方面，文献中报道的模型有纯对流模型、对流-弥散模型、基于活塞流的水平衡模型和传递函数模型等。鉴于地面灌溉条件下水氮运移的复杂性，在水氮运移分布的数学模拟、灌水技术参数和施肥方式对水氮淋失的影响以及灌溉施肥质量评价指标体系等方面尚需要进一步研究。     

Heterogeneous solute flow in a sandy soil under a pine forest: evaluation of a modeling concept

This study investigated the heterogeneous water characteristic functions and hydraulic conductivities for a gleyic podzol under a coniferous forest 40 km northeast of Hannover, Germany. The hydraulic properties were parameterized with the van Genuchten model. Reference functions and sets of scaling factors were derived for every horizon. The scaling factors showed correlation lengths of about 0.2 m. Along a 10 m long transect the spatially variable rain throughfall as the upper boundary and the groundwater level as the lower boundary was measured. A tracer experiment was conducted for the period of main groundwater recharge. Using the independent measurements of heterogeneous hydraulic properties, we simulated the solute transport for this period with a conventional model that solves the Richards' equation for water flow and the convective dispersive equation for solute transport. We found qualitative agreement between some features of the measured and modeled solute transport such as its channel‐like structure. However, the partly preferential flow of solutes and the correspondingly large dispersivities could not be modeled.     

Simulation of chromium transport in the unsaturated zone for predicting contaminant entries into the groundwater

Heavy metal contaminations in the top‐soil layers can impose serious threats to groundwater quality. A seepage water prognosis of probable future contaminant entries at the groundwater surface has to take into account the emission characteristics of the source zone and the reactive transport of the contaminated leachate through the unsaturated zone. Here, a possible approach is presented, exemplarily for a site contaminated with chromium, encompassing batch elution experiments, unsaturated soil column leaching experiments with flow interruption, soil monolith lysimeter experiments, and numerical modeling of non‐equilibrium solute transport. The prognosis provides a long‐term prediction of Cr concentrations at the groundwater surface. It must be emphasized, that the modeling results are uncertain, because several of the parameters in the simulations can be determined only with significant errors. Additionally, the approach is not applicable routinely for every hazardous waste site. Our study reveals, however, that reactive contaminants can possibly reach the groundwater at hazardous concentrations within very short time.     

斥水土壤中的水热运动规律与数值模型

斥水土壤很难被雨水湿润，影响种子发芽出苗而造成农业减产。由于地表干燥而引起风蚀水蚀，造成土地退化。这一问题在澳大利亚、荷兰、新西兰与美国引起重视。斥水土壤中水分分布往往是无规律的“指状”，到目前为止，没有成功的数学模型。作者从研究斥水土壤地区的耕作工程实践出发，采用沟种之后，水分的分布就有了规律性。开沟播种时，耕作机械把表层斥水性特别强的土壤推到垄上而形成几乎不透水的垄，下雨时雨水只能从沟中渗入形