Mars and Earth: origin and abundance of volatiles

Mars, like Earth, may have received its volatiles in the final stages of accretion, as a veneer of volatile-rich material similar to C3V carbonaceous chondrites. The high (40)Ar/(36)Ar ratio and low (36)Ar abundance on Mars, compared to data for other differentiated planets, suggest that Mars is depleted in volatiles relative to Earth-by a factor of 1.7 for K and 14 other moderately volatile elements and by a factor of 35 for (36)Ar and 15 other highly volatile elements. Using these two scaling factors, we have predicted martian abundances of 31 elements from terrestrial abundances. Comparison with the observed (36)Ar abundance suggests that outgassing on Mars has been about four times less complete than on Earth. Various predictions of the model can be checked against observation. The initial abundance of N, prior to escape, was about ten times the present value of 0.62 ppb, in good agreement with an independent estimate based on the observed enhancement in the martian (15)N/(14)N ratio (78,79). The initial water content corresponds to a 9-m layer, close to the value of >/=13 m inferred from the lack of an (18)O/(16)O fractionation (75). The predicted crustal Cl/S ratio of 0.23 agrees exactly with the value measured for martian dust (67); we estimate the thickness of this dust layer to be about 70 m. The predicted surface abundance of carbon, 290 g/cm(2), is 70 times greater than the atmospheric CO(2) value, but the CaCO(3) content inferred for martian dust (67) could account for at least one-quarter of the predicted value. The past atmospheric pressure, prior to formation of carbonates, could have been as high as 140 mbar, and possibly even 500 mbar. Finally, the predicted (129)Xe/(132)Xe ratio of 2.96 agrees fairly well with the observed value of 2.5(+2)(-1) (85). From the limited data available thus far, a curious dichotomy seems to be emerging among differentiated planets in the inner solar system. Two large planets (Earth and Venus) are fairly rich in volatiles, whereas three small planets (Mars, the moon, and the eucrite parent body-presumably the asteroid 4 Vesta) are poorer in volatiles by at least an order of magnitude. None of the obvious mechanisms seems capable of explaining this trend, and so we can only speculate that the same mechanism that stunted the growth of the smaller bodies prevented them from collecting their share of volatiles. But why then did the parent bodies of the chondrites and shergottites fare so much better? One of the driving forces behind the exploration of the solar system has always been the realization that these studies can provide essential clues to the intricate network of puzzles associated with the origin of life and its prevalence in the universe. In our own immediate neighborhood, Mars has always seemed to be the planet most likely to harbor extraterrestrial life, so the environment we have found in the vicinity of the two Viking landers is rather disappointing in this context. But the perspective we have gained through the present investigation suggests that this is not a necessary condition for planets at the distance of Mars from a solar-type central star. In other words, if it turns out that Mars is completely devoid of life, this does not mean that the zones around stars in which habitable planets can exist are much narrower than has been thought (114). Suppose Mars had been a larger planet-the size of Earth or Venus-and therefore had accumulated a thicker veneer and had also developed global tectonic activity on the scale exhibited by Earth. A much larger volatile reservoir would now be available, there would be repeated opportunities for tapping that reservoir, and the increased gravitational field would limit escape from the upper atmosphere. Such a planet could have produced and maintained a much thicker atmosphere, which should have permitted at least an intermittently clement climate to exist. How different would such a planet be from the present Mars? Could a stable, warm climate be maintained? It seems conceivable that an increase in the size of Mars might have compensated for its greater distance from the sun and that the life zone around our star would have been enlarged accordingly.     

Morphology and composition of the surface of Mars: Mars Odyssey THEMIS results

The Thermal Emission Imaging System (THEMIS) on Mars Odyssey has produced infrared to visible wavelength images of the martian surface that show lithologically distinct layers with variable thickness, implying temporal changes in the processes or environments during or after their formation. Kilometer-scale exposures of bedrock are observed; elsewhere airfall dust completely mantles the surface over thousands of square kilometers. Mars has compositional variations at 100-meter scales, for example, an exposure of olivine-rich basalt in the walls of Ganges Chasma. Thermally distinct ejecta facies occur around some craters with variations associated with crater age. Polar observations have identified temporal patches of water frost in the north polar cap. No thermal signatures associated with endogenic heat sources have been identified.     

Catalytic processes in the atmospheres of Earth and venus

Photochemical processes in planetary atmospheres are strongly influenced by catalytic effects of minor constituents. Catalytic cycles in the atmospheres of Earth and Venus are closely related. For example, chlorine oxides (CIOx) act as catalysts in the two atmospheres. On Earth, they serve to convert odd oxygen (atomic oxygen and ozone) to molecular oxygen. On Venus they have a similar effect, but in addition they accelerate the reactions of atomic and molecular oxygen with carbon monoxide. The latter process occurs by a unique combination of CIOx catalysis and sulfur dioxide photosensitization. The mechanism provides an explanation for the very low extent of carbon dioxide decomposition by sunlight in the Venus atmosphere.     

Electrical breakdown caused by dust motion in low-pressure atmospheres: considerations for Mars

Electrification of agitated dust can cause visible breakdown in a carbon dioxide atmosphere at low pressure in a laboratory experiment. Dust storms on earth become electrified, with accompanying breakdown phenomena. Martian dust storms may reduce the atmospheric conductivity by capturing fast ions on particles, and, by electrifying, may cause discharges in the relatively low pressure atmosphere.     

Origin and evolution of outer solar system atmospheres

The atmospheres of bodies in the outer solar system are distinct in composition from those of the inner planets and provide a complementary set of clues to the origin of the solar system. This article reviews current understanding of the origin and evolution of these atmospheres on the basis of abundances of key molecular species. The systematic enrichment of methane and deuterated species from Jupiter to Neptune is consistent with formation models in which significant infall of icy and rocky planetesimals accompanies the formation of giant planets. The atmosphere of the Saturnian satellite Titan has been strongly modified by photochemistry and interaction with the surface over 4.5 billion years; the combined knowledge of this moon's bulk density and estimates of the composition of the surface and atmosphere provide some constraints on this body's formation. Neptune's satellite Triton is a poorly known object for which it is hoped that substantial information will be gleaned from the Voyager 2 encounter in August 1989. The mean density of the Pluto-Charon system is well known and suggests an origin in the rather water-poor solar nebula. The recent occultation of a star by Pluto provides evidence that carbon monoxide, in addition to methane, may be present in its atmosphere.     

Solar rotation effects on the thermospheres of Mars and Earth

The responses of Earth's and Mars' thermospheres to the quasi-periodic (27-day) variation of solar flux due to solar rotation were measured contemporaneously, revealing that this response is twice as large for Earth as for Mars. Per typical 20-unit change in 10.7-centimeter radio flux (used as a proxy for extreme ultraviolet flux) reaching each planet, we found temperature changes of 42.0 +/- 8.0 kelvin and 19.2 +/- 3.6 kelvin for Earth and Mars, respectively. Existing data for Venus indicate values of 3.6 +/- 0.6 kelvin. Our observational result constrains comparative planetary thermosphere simulations and may help resolve existing uncertainties in thermal balance processes, particularly CO2 cooling.     

Internal structure and early thermal evolution of Mars from Mars Global Surveyor topography and gravity

Topography and gravity measured by the Mars Global Surveyor have enabled determination of the global crust and upper mantle structure of Mars. The planet displays two distinct crustal zones that do not correlate globally with the geologic dichotomy: a region of crust that thins progressively from south to north and encompasses much of the southern highlands and Tharsis province and a region of approximately uniform crustal thickness that includes the northern lowlands and Arabia Terra. The strength of the lithosphere beneath the ancient southern highlands suggests that the northern hemisphere was a locus of high heat flow early in martian history. The thickness of the elastic lithosphere increases with time of loading in the northern plains and Tharsis. The northern lowlands contain structures interpreted as large buried channels that are consistent with northward transport of water and sediment to the lowlands before the end of northern hemisphere resurfacing.     

Stochastic late accretion to Earth, the Moon, and Mars

Core formation should have stripped the terrestrial, lunar, and martian mantles of highly siderophile elements (HSEs). Instead, each world has disparate, yet elevated HSE abundances. Late accretion may offer a solution, provided that ≥0.5% Earth masses of broadly chondritic planetesimals reach Earth's mantle and that ~10 and ~1200 times less mass goes to Mars and the Moon, respectively. We show that leftover planetesimal populations dominated by massive projectiles can explain these additions, with our inferred size distribution matching those derived from the inner asteroid belt, ancient martian impact basins, and planetary accretion models. The largest late terrestrial impactors, at 2500 to 3000 kilometers in diameter, potentially modified Earth's obliquity by ~10°, whereas those for the Moon, at ~250 to 300 kilometers, may have delivered water to its mantle.     

Mars surface diversity as revealed by the OMEGA/Mars Express observations

The Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) investigation, on board the European Space Agency Mars Express mission, is mapping the surface composition of Mars at a 0.3- to 5-kilometer resolution by means of visible-near-infrared hyperspectral reflectance imagery. The data acquired during the first 9 months of the mission already reveal a diverse and complex surface mineralogy, offering key insights into the evolution of Mars. OMEGA has identified and mapped mafic iron-bearing silicates of both the northern and southern crust, localized concentrations of hydrated phyllosilicates and sulfates but no carbonates, and ices and frosts with a water-ice composition of the north polar perennial cap, as for the south cap, covered by a thin carbon dioxide-ice veneer.     

Venus: a contrast in evolution to Earth

Of the planets, Venus and Earth are by far the most similar in primary properties, yet they differ markedly in secondary properties. A great impact into Earth is believed to have created its moon and removed its atmosphere; the lack of such an impact into Venus apparently led to a greatly differing atmospheric evolution. The lack of an ocean on Venus prevents the recycling of volatiles and inhibits subduction, so that its crust is probably more voluminous than Earth's, although distorted and quite variable in thickness. Venus's upper mantle appears to be depleted in both volatiles and energy sources because, in addition to the lack of volatile recycling, melts of mantle rocks are more dense than their solid matrix at pressures above 8 gigapascals and hence sink if they occur at depths below 250 kilometers. Appreciable energy sources persist at great depths to sustain the few great mountain complexes. The greatest current problem is reconciling the likelihood of a voluminous crust with indications of considerable strength at shallow depths of 20 to 100 kilometers.     

Mars: is the surface colored by carbon suboxide?

The reflection spectrum of Mars can be well matched from 0.2 through 1.6 microns (and farther) by polymers of carbon suboxide, reflection spectra for which have now been measured. We propose that the reddish color of Mars might be attributed to carbon suboxide, not the commonly considered limonite or other iron-bearing minerals.     

Solar cycle variation of exospheric temperatures Mars and venus: a prediction for mariner 6 and 7

Calculations have been made to determine the effects of variations in the extreme ultraviolet solar radiation on the upper atmospheres of mars and Venus. The results indicate that the exospheric temperature from 300 degrees K to 600 degrees K during the solar cycle, with a corresponding range on Venus of 450 degrees K to 850 degrees K. At the present time, the temperature of the Martain exosphere should be approximately 500 degrees K.     

A low temperature transfer of ALH84001 from Mars to Earth

The ejection of material from Mars is thought to be caused by large impacts that would heat much of the ejecta to high temperatures. Images of the magnetic field of martian meteorite ALH84001 reveal a spatially heterogeneous pattern of magnetization associated with fractures and rock fragments. Heating the meteorite to 40 degrees C reduces the intensity of some magnetic features, indicating that the interior of the rock has not been above this temperature since before its ejection from the surface of Mars. Because this temperature cannot sterilize most bacteria or eukarya, these data support the hypothesis that meteorites could transfer life between planets in the solar system.