Dissipation of metham-sodium from soil and its effect on the control of Orobanche aegyptiaca

The effect of metham-sodium on Orobanche aegyptiaca Pers. was tested in the laboratory and in soil columns. The laboratory experiment was carried out on O. aegyptiaca seeds placed in Petri dishes and germinated with GR₂₄, a synthetic strigol analogue. In soil columns, metham-sodium was applied by application of the chemical through the irrigation water to three different soils and its dissipation determined in three soil layers by gas chromatography, by a lettuce bio-assay to check the herbicide's phytotoxicity, and with a flax bioassay to check its effect on O. aegyptiaca. Results of the germination experiments showed an exponential decrease in O. aegyptiaca germination, parallel with the increase of metham-sodium concentration, with an average effective concentration (EC₅₀) of 18 mg L^?1. In a soil column, methylisothiocyanate (MIT, the metham active product) rapidly disappeared from the upper soil level (0–10 cm) within 24 h. Seven days after application only traces of MIT remained in all soil layers in all soils, except for the sandy Rehovot soil that contained low concentrations in the lower soil layer (20–30 cm). Flax bioassay confirmed the chemical analysis, showing that O. aegyptiaca tubercles developed only on plants grown in the upper soil layer of all three soils.     

Residues and fate of endosulfan on field-grown pepper and tomato

Endosulfan (Thiodan 3 EC), a mixture of α- and β-isomers, was sprayed on 92-day-old field-grown pepper and tomato at the recommended rate of 0·61 kg AI ha^-1. Plant tissue samples were collected at 1 h to 14 days after application and analysed to determine the content and dissipation rate of endosulfan isomers (α- and β-endosulfan) and the major metabolite, endosulfan sulfate. Analysis of samples was accomplished using gas chromatography-mass selective detection (GC-MSD). The results indicated the formation of endosulfan sulfate as a residue component on the plant tissues and also the relatively higher persistence of the β-isomer as compared to the α-isomer on pepper fruits. The initial total residues (α- and β-endosulfan isomers plus endosulfan sulfate) were higher on leaves than on fruits. On pepper fruits, the α-isomer, which is the more toxic to mammals, dissipated faster than the less toxic β-isomer. Total residues (α- and β-endosulfan isomers plus the sulfate metabolite) on tomato leaves revealed longer persistence (t_1/2 4·6 days) compared to the total residues detected on pepper leaves (t_1/2 2·0 days) 3–14 days following spraying. Persistence of the β-isomer on pepper fruits was high 3–14 days following spraying compared to on tomato fruits. This long persistence increases risk of exposure of the consumer. In addition, the longer persistence of the total residues on tomato foliage should be considered of importance for timing the safe entry of tomato harvesters due to the high mammalian toxicity of endosulfan. © 1998 Society of Chemical Industry     

Determination of residues of endosulfan and endosulfan sulfate on eggplant,mustard and chickpea

Extractable residues of endosulfan stereoisomers and its toxic metabolite, endosulfan sulfate, on a vegetable, an oilseed and a pulse crop were determined by gas-liquid chromatography. The study revealed that the alpha isomer degraded faster than the beta isomer. Beta-endosulfan accumulated during the first three days following the treatment. Endosulfan sulfate residues appeared a few days after application and decreased with time. The total endosulfan residues in the seeds from treated mustard ranged from 0.08 to 0.12 mg kg^?1 and were at or below the limit of determination (0.02 mg kg^?1) in chickpea seeds following harvest.     

施氮量对滴灌高产春大豆根系生长及产量的影响

为揭示施氮量对滴灌高产春大豆根系生长及产量的影响规律,在田间滴灌条件下采用挖掘取样法研究了0 kg·hm~(-2)(N_0)、75 kg·hm~(-2)(N_(75))、150 kg·hm~(-2)(N_(150))、225 kg·hm~(-2)(N_(225))4种施氮量对新大豆27号0~80 cm土层根系干物质量、侧根长度、表面积、根系活性、伤流量、根瘤数、根瘤质量及产量的影响。结果表明:随着施氮量的增加,0~80 cm土层根系总干物质量、侧根总长度、侧根总表面积呈现先增后降的变化趋势,均以N_(150)处理最高,在R_5(始粒期)期分别较N_0增加27.3%、49.46%、38.14%,其中,0~20 cm土层分别较N_0增加27.0%、29.02%、34.24%;R_5期N_(150)单株伤流量较N_0增加176.0%,R_2(盛花期)期0~20、20~40 cm土层根系活力N_(150)分别较N_0增加44.3%、25.1%;R_5期N_(150)单位面积根瘤数及质量分别较N_0减少8.74%、34.6%;施氮可增加产量,以N_(150)产量最高,为4 889.62kg·hm~(-2),氮肥农学利用效率3.58 kg·kg~(-1)。施氮增加产量主要是促进0~20 cm土层根系生长,提高0~40 cm根系活力的结果。     

Movement and persistence of imazaquin, oxyfluorfen, flurochloridone and terbacil in soil

The movement and persistence of imazaquin, oxyfluorfen, flurochloridone and terbacil residues were studied using a bioassay based on the shoot growth of Raphanus sativus L. var, radicula DC (radish) in a sandy loam soil under field conditions in 1992 and 1993. Imazaquin (0.3 kg a.i. ha^-1) was more mobile in the soil than the other three compounds. In 1992, under heavy rainfall conditions, the herbicide was distributed down to 60 cm in amounts of about 0.01 mg kg^-1. Conversely, in the dry year of 1993, the maximum depth of penetration was 20 cm and persistence in the surface soil layer (0-5 cm) was greater. After the first month in 1992, residues of terbacil were distributed in the 0-20 cm layer, and after 2, 3 and 5 months the herbicide had penetrated to a depth of 40 cm. In 1993, terbacil residues were distributed in the 0-10 cm layer only. In both years, residues of flurochloridone (1.0 kg a.i. ha^-1) were located mainly in the 0-5 cm layer, but there was some penetration to 10 cm. Oxy-fluorfen (1.2 kg a.i, ha^-1) showed least mobility in the soil profile. It was retained in the 0-5 cm layer throughout the experimental period in both. years.     

不同灌水处理对滨海盐碱地土壤阳离子组成及玉米干物质累积的影响

采用田间试验对不同灌水处理灌水后玉米地（天津滨海盐碱地）0~60 cm土层土壤K⁺/Na⁺、Ca²⁺/Na⁺及玉米干物质累积量进行研究,共设计4个处理,分别为LI₁₀（常规滴灌,灌水10 mm）、LI₂₀（常规滴灌,灌水20 mm）、FI₁₀（膜下滴灌,灌水10 mm）和FI₂₀（膜下滴灌,灌水20 mm）。结果表明：灌水后不同灌水方式下灌水量较大的处理0~60 cm各土层K⁺/Na⁺均大于灌水量较小的处理,且均表现出0~20 cm土层K⁺/Na⁺较大,40~60 cm土层K⁺/Na⁺较小;相同灌水量下膜下滴灌处理0~60 cm各土层Ca²⁺/Na⁺均较大,灌水后不同灌水处理0~60 cm各土层Ca²⁺/Na⁺差异较小,变化范围为0.10~0.22;FI₂₀处理0~20 cm土层K⁺/Na⁺和Ca²⁺/Na⁺大于其他处理,分别达到0.78和0.22;随着灌水次数的增多,LI₂₀和FI₁₀处理0~20 cm土层K⁺/Na⁺和Ca²⁺/Na⁺均逐渐增大,LI₁₀处理则均逐渐减小;灌水后各处理之间0~60 cm各土层K⁺/Na⁺和Ca²⁺/Na⁺差异均达显著水平;全生育期干物质累积量与其对应的0~20 cm土层（K⁺/Na⁺）/Ca²⁺二次拟合相关系数均达0.90以上,相同（K⁺/Na⁺）/Ca²⁺下,FI₂₀处理干物质累积量始终最大,LI₁₀处理始终最小;（K⁺/Na⁺）/Ca²⁺>1.72时,各处理干物质累积量均随（K⁺/Na⁺）/Ca²⁺的增大而增大。     

基于HYDRUS模型的暗管排水水盐运移模拟

为了探索暗管排水条件下膜下滴灌农田的水盐运移规律,本文设计了埋深1 m,间距4 m的暗管排水模型试验,研究分析灌水淋洗过程中土壤水分和盐分的动态变化规律,并利用HYDRUS模型对暗管排水条件下的水盐运移规律进行数值模拟分析与验证。结果表明：经过3次灌水淋洗后,表层0~20 cm土层内盐分含量下降至2 g·kg^-1,达到了非盐化土水平,20~60 cm土体内上层土壤脱盐效果高于下层,总盐分含量下降至8 g·kg^-1以下;经过实测值与模拟值的验证,土壤盐分和水分的均方根误差RMSE最大分别为0.632和1.324,决定系数R²最小分别为0.992和0.906,说明模拟结果与实测结果吻合度较好,HYDRUS模型能够较好地模拟暗管排水过程中水盐运移规律。通过模型模拟6次灌水（共90 d）后暗管排水条件下不同土层深度的水盐动态变化特征,模拟结果表明,0~40 cm土层内盐分含量下降至2 g·kg^-1,40~80 cm土层内盐分含量下降至4 g·kg^-1左右,基本达到轻度盐化水平;距离暗管不同间距处的土壤剖面盐分含量呈波动变化,距离暗管越远,土壤剖面含盐量越大,盐分含量在0~8 g·kg^-1范围内变化。     

GROWTH,TUBER FORMATION AND SPREAD OF CYPERUS ROTUNDUS L. FROM SINGLE TUBERS*

Summary. Single tubers of Cyperus rotundus L. were planted at intervals over the year. Plant growth was slow and sprouting of tubers was inhibited at temperatures below 20°C, but tubers overwintered at temperatures above freezing point. In the warm season, plant growth and tuber formation rate closely followed air temperature and tubers were forming within 1 month from planting. No inflorescence appeared during the cool season. In autumn-planted C. rotundus grown in containers, the ratio of aerial to subterranean weight decreased from 1·1 in December to 0·2–0·4 in summer. The weight of tubers in mid-summer was about 10 times more than that present in December. Tubers formed at ail times of year and at various locations on plants sprouted readily in laboratory tests (76–100% sprouting). C. rotundus planted in March at wide spacings was grown in field conditions free of other plant competition for 20 months. Within 2 months the plants had spread to 90 cm. At the end of the first and the second summer of growth, the mean area of one plant was 7·6 m² and 56·7 m², respectively, and patches had expanded then by 2·8 m and 5·4 m, respectively, from the initial shoot. After 20 months of growth all tubers were present within the 0–40 cm soil depth, 60–70% of them in the 0–20 cm layer. About 30% of the tubers were within 1 m and 60% within 2 m of the plant centre. Under the patch centre there were about 1000 tubers per m² with 0·3 kg dry weight; in the upper 20 cm more than 3500 tubers weighing 0·9 kg were present per m³ of soil. Croissance, formation de tubercules et propagation de Cyperus rotundus L. issu de tubercules uniques     

Influence of methyl bromide soil fumigation method on fungicidal efficacy and bromide residues

Highest inorganic bromine residues (30 ppm) were found when soil was fumigated with liquid methyl bromide (MB) introduced by conventional means into evaporating dishes. With preheated (vaporized) MB or injection of MB/chloropicrin (CP) mixtures, bromide concentrations were reduced by 50%. They were uniform throughout the soil (0 to 60 cm) except after MB/CP injection, when larger residues were found in the 30-60 cm layer. Leaching with 2000 m^p3/ha (20 cm) of water always reduced bromide content to 7.5 and 10 ppm at the 0-30 and 30-60 cm depth, respectively. Organic amendments to soils substantially increased bromide levels up to 118 ppm, most of which was found in the upper soil layers; two teachings with 2000 m^p3 /ha water were required to return the soils to their normal state.Sclerotium rolfsii andFusarium oxysporum f. sp.dianthi cultures buried in soil were eliminated from the upper 30 cm with MB applied either conventionally or preheated. At 50 cm, 500 kg/ha of the preheated gas was superior to 1000 kg/ha of the cold gas. All MB fumigations suppressed carnation flower yields compared with CP alone but were superior to no treatment. After leaching, MB-fumigated soils yielded the highest number of flowers.     

玛纳斯河流域绿洲土壤春季盐渍化研究

运用经典统计学和冗余分析方法,对玛纳斯河流域绿洲土壤全盐量（TS）、pH、电导率（EC）、钠吸附比（SAR）和盐分离子组成的空间分布特征进行了分析。结果表明：土壤全盐量呈现明显的底聚特征,各层土壤全盐量均值在5.80~9.02 g•kg^-1,表现为轻度至中度盐化;各层土壤中,pH在8.2~8.4、EC在0.70~1.38 mS•cm^-1、SAR在0.25~0.64,未出现碱化现象。冗余分析表明：不同层次土壤中,Ca ²⁺与SO ₄^2-、Na⁺与SO₄^2-保持较好的关联性。TS的空间分布,在 0 ~70 cm 全剖面上主要受控于Na^+、SO₄^2-、Ca ²⁺和Mg ²⁺;分层与全剖面的情况略有不同,但Na⁺、SO₄^2-在各个土层仍为最主要的控制离子。EC在全剖面上的空间分布受控于 Na⁺、SO₄^2-;50 ~70 cm 土层主要受Na⁺与Cl^-的控制,其他土层与全剖面相同。 pH受控于CO₃^2-;除0~10 cm土层受HCO^-₃影响外,其他土层与全剖面相同。SAR在全剖面的空间分布受环境因子的影响较小,除50~70 cm土层受Cl^-因子的制约外,0~50 cm土层未表现出明显的控制因子。     

不同覆盖方式对旱作农田土壤碳氮含量及玉米产量的影响

设置垄膜沟播(R)、平作全覆膜(P)和平作秸秆覆盖(S)3种不同覆盖栽培模式,以传统平作(CK)为对照,通过3 a大田定位试验,研究不同覆盖方式对农田土壤碳氮及其组分变化、玉米干物质积累和籽粒产量的影响。结果表明:连续覆盖3 a后,R和P处理土壤有机碳和全氮含量及储量均呈逐渐下降趋势,而S处理则呈上升趋势且每年的增幅逐渐增大;各处理0～40 cm土层土壤有机碳储量均表现为S>R>P>CK,全氮储量表现为S>CK>R>P,S处理有机碳和全氮储量分别较CK提高3.4%和7.5%;与CK相比,R和P处理可提高土壤碳氮比,在0～20 cm土层平均分别提高7.9%和9.6%(P<0.05),而S处理0～20 cm土层土壤碳氮比平均降低了9.9%(P<0.05);各覆膜处理(R和P)均较CK显著降低了0～40 cm土层土壤可溶性有机碳(DOC)和土壤可溶性有机氮(DON)含量,而S处理较CK处理0～60 cm土层DOC和DON含量2 a平均均提高6.2%;各处理收获期硝态氮含量在0～100 cm剖面中的垂直分布与CK无明显差异;各处理土壤铵态氮含量均...     

Fenbutatin oxide,fate in soil after extensive commercial use in Italy and Spain

The long-term fate of the acaricide, fenbutatin oxide, in soil has been investigated. Residues of the compound and its two principal metabolites have been determined in soil samples obtained from citrus orchards in Italy and Spain where the product had been applied commercially over a period of 6–10 years. The average fenbutatin oxide content in the upper 0–15 cm soil layer ranged from ? 1 mg kg^?1 to 5 mg kg^?1 in sites receiving single and double applications per year. The residues were located primarily (> 95%) in the top 0–30 cm layer and there was virtually no movement of the compound through the soil to lower depths. Below 0.5 m depths, the sites contained average concentrations of ? 0.01 mg kg^?1, the limit of determination. No significant build-up of residues was observed and the data indicate an approximate half-life in soil of just less than one year. Residues of the two metabolites, dihydroxy-bis(2-methyl-2-phenylpropyl)stan-nane and 2-methyl-2-phenylpropyl stannonic acid, were on average 11% and 16% of the fenbutatin oxide concentration, respectively. As with fenbutatin oxide, there was no significant movement through the soil to lower levels.     

Fate of endosulfan in rats and toxicological considerations of apolar metabolites

[¹⁴C]Endosulfan, α or β isomers separately, was administered to rats as a single oral dose and as a dietary supplement for 14 days. No appreciable differences were observed in the fate of the two isomers. Five days after the single dose, 75% of the dose had been voided in the feces and 13% in the urine. Of the total radiocarbon consumed in the diet after 14 days, 56% had been eliminated in the feces and 8% in the urine. Bile collection studies showed that up to 47% of a single oral dose was eliminated from the liver via this route; enterohepatic circulation was not apparent. Maximum [¹⁴C]endosulfan equivalents in body tissue occurred in the kidney and liver, 3 and 1 ppm, respectively, after 14 days of feeding 5 ppm of endosulfan. Apolar metabolites in the excreta and/or tissues were a minor portion of the total residues and consisted of the sulfate, diol, α-hydroxy ether, lactone, and ether derivatives of endosulfan. The sulfate was slightly more toxic to mice than endosulfan, while the other products were less toxic. Neither endosulfan nor its metabolites were active in the Salmonella mutagenicity test. Endosulfan in the diet of rats for 28 days at 50 ppm did not induce liver oxidase enzymes, alter liver or kidney weights, or influence the rate of weight gain of the animals.     

Effect of composted manure plus chemical fertilizer application on aridity response and productivity of apple trees on the loess plateau,China

Soil degradation and aridity due to long-term unbalanced fertilization and scarce precipitation limit the productivity of apple trees in the Loess Plateau of China. The aim of the present study was to investigate the effects of composted manure (CM) plus chemical fertilizer (CF) applications on the aridity response and yield of apple trees. Five treatments [CF (C), CF plus 5/10?kg?CM I per tree (CM₁-L/H), and CF plus 5/10?kg?CM II per tree (CM₂-L/H)] were applied in a 10-year-old Red Fuji apple (Malus domestica Borkh.) orchard over a 4-year study period. The application of CM plus CF increased soil organic carbon, decreased soil bulk density, and optimized porosity. Low (5?kg per tree; CM_L) and high (10?kg per tree; CM_H) CM application rates respectively increased soil water storage in the 20–60?cm layer by 1.4% and 4.8%, increased available soil water content in the 0–100?cm soil layer by 4.1%–44.8% and 10.4%–60.2%, elevated the water content of apple leaves (w%) by 1.3% and 3.7%, improved leaf potential by 15.9% and 30.0%, and decreased proline content by 16.1% and 28.5%. Thus, CM application decreased damage due to aridity and enhanced the photosynthetic capacity of apple trees, ultimately elevating apple yield by 8.8% and 13.3% under CM_L and CM_H. The application of CM plus CF is an effective fertilization strategy for mitigating aridity stress and improving apple yield in the Loess Plateau.     

Aerobic soil metabolism of metsulfuron-methyl

A laboratory study was conducted to determine the degradation rates and identify major metabolites of the herbicide metsulfuron-methyl in sterile and non-sterile aerobic soils in the dark at 20°C. Both [phenyl-U-¹⁴C]- and [triazine-2-¹⁴C]metsulfuron-methyl were used. The soil was treated with [¹⁴C]metsulfuron-methyl (0.1 mg kg⁻¹) and incubated in flow-through systems for one year. The degradation rate constants, DT₅₀, and DT₉₀ were obtained based on the first-order and biphasic models. The DT₅₀ (time required for 50% of applied chemical to degrade) for metsulfuron-methyl, estimated using a biphasic model, was approximately 10 days (9–11 days, 95% confidence limits) in the non-sterile soil and 20 days (12–32 days, 95% confidence limits) in the sterile soil. One-year cumulative carbon dioxide accounted for approximately 48% and 23% of the applied radioactivity in the [phenyl-U-¹⁴C] and [triazine-2-¹⁴C]metsulfuron-methyl systems, respectively. Seven metabolites were identified by HPLC or LC/MS with synthetic standards. The degradation pathways included O-demethylation, cleavage of the sulfonylurea bridge, and triazine ring opening. The triazine ring-opened products were methyl 2-[[[[[[[(acetylamino)carbohyl]amino]carbonyl]amino] carbonyl]-amino]sulfonyl]benzoate in the sterile soil and methyl 2-[[[[[amino[(aminocarbonyl)imino]methyl] amino]carbonyl]amino]sulfonyl]benzoate in the non-sterile soil, indicating that different pathways were operable. © 1999 Society of Chemical Industry     

Adsorption,desorption and dissipation of metolachlor in surface and subsurface soils

BACKGROUND: Variations in soil properties with depth influence retention and degradation of pesticides. Understanding how soil properties within a profile affect pesticide retention and degradation will result in more accurate prediction by simulation models of pesticide fate and potential groundwater contamination. Metolachlor is more persistent than other acetanilide herbicides in the soil environment and has the potential to leach into groundwater. Reasonably, information is needed about the dissipation and eventual fate of metolachlor in subsoils. The objectives were to evaluate the adsorption and desorption characteristics and to determine the dissipation rates of metolachlor in both surface and subsurface soil samples. RESULTS: Adsorption of metolachlor was greater in the high‐organic‐matter surface soil than in subsoils. Lower adsorption distribution coefficient (K_ads) values with increasing depth indicated less adsorption at lower depths and greater leaching potential of metolachlor after passage through the surface horizon. Desorption of metolachlor showed hysteresis, indicated by the higher adsorption slope (1/n_ads) compared with the desorption slope (1/n_des). Soils that adsorbed more metolachlor also desorbed less metolachlor. Metolachlor dissipation rates generally decreased with increasing soil depth. The first‐order dissipation rate was highest at the 0–50 cm depth (0.140 week^?1) and lowest at the 350–425 cm depth (0.005 week^?1). Degradation of the herbicide was significantly correlated with microbial activity in soils. CONCLUSION: Metolachlor that has escaped degradation or binding to organic matter at the soil surface might leach into the subsurface soil where it will dissipate slowly and be subject to transport to groundwater. Copyright © 2009 Society of Chemical Industry     

Conversion rates of aldicarb and its oxidation products in soils. II. Aldicarb sulphoxide

The loss of aldicarb sulphoxide was studied in incubation experiments with soil from four plough layers and two deeper layers. The loss during the 111 days of the experiment could be described by first-order kinetics. The half-lives at 15°C ranged from 20 days in a clay loam to 46 days in a peaty sand. The loss of sulphoxide in deeper layers was considerably slower than in the corresponding top layers of a soil profile. In soil from a silty layer at 70–90 cm depth the half-life was about 53 days. In soil from a sand layer at 90–110 cm depth a loss of only about 15% was measured after 111 days of incubation. First-order rate constants for sulphoxide conversion in a clay loam at 6, 15 and 25°C were found to be 0.009, 0.033, and 0.05 day^?1 respectively; in a greenhouse soil these rate constants were 0.0052, 0.019 and 0.04 day^?1 respectively. The fractions of aldicarb sulphoxide that were oxidised to sulphone at 15°C in soil from plough layers were computed to range from 0.52 to 0.76.     

Relationship between speed, soil movement into the cereal row and intra-row weed control efficacy by weed harrowing

Field trials were carried out at a single Danish and two Spanish locations. In Denmark, winter wheat was sown at 24‐cm row spacing allowing hoeing in the inter‐row area. Hoeing speeds of 2, 5 and 8 km h^?1 were tested at the end of tillering, at the beginning of stem elongation or on both occasions. The crop was harrowed immediately after hoeing at the same speed. At the Spanish locations the winter barley was sown at a 12‐cm row spacing and harrowed only, at either pre‐emergence plus post‐emergence, or once post‐emergence at mid‐tillering at 2, 4, 6 and 8 km h^?1. The depth of the soil layer thrown into the cereal row was measured at all locations. This layer ranged between 0.4 and 1.4 cm, depending on the site and on the treatment, but was generally higher following a single harrow treatment at all sites. The soil layer only tended to increase with faster speeds at the Danish location. On a more sandy soil and soil rolled prior to treatment, less soil was thrown into the cereal row. When two hoe + harrowing treatments were made, a finer soil structure was achieved. However, this did not affect the weed control. At the Danish location, initial intra‐row weeding efficacy of Brassica napus, based on plant number before and 7 days after treatment, was found to be low (21–41%) but increased to 74–79% when assessed after 45 days. Partial burial and bending of B. napus, together with crop competition, probably suppressed weed growth and enhanced final mortality. Uprooting was probably a more important cause of mortality for Stellaria media. At the Spanish locations, weeding efficacy of Papaver rhoeas was similar, ranging between 58% and 83% and this was achieved soon after harrowing. A thicker soil layer did not result in a greater weed kill. It was therefore suggested that burial alone could not be the main factor responsible for weed control in any of the cases studied. No reduction in wheat biomass, measured at the end of May, was found with increasing speed, or with repeated passes of the harrow. The results suggested that faster harrowing, which is economically more attractive for farmers, could be recommended. The soil layer thrown into the row was not found to be a useful parameter to predict the weed control efficacy in the cases presented.     

基于HYDRUS-2D的雨水集聚深层入渗系统土壤水分运移模拟

为了解雨水集聚深层入渗(RWCI)系统土壤水分的入渗规律,设置不同灌水量(10 L、21 L和36 L)和RWCI设计坑深(40 cm和60 cm)的室内土箱试验,观测不同灌水量与不同水头变化情况土壤含水率变化和土壤湿润锋在径向和垂直方向上运移过程,依据非饱和土壤水动力学理论,建立HYDRUS-2D变水头边界条件土壤水分二维入渗模型。通过与实测数据对比,结果表明模型模拟值和实测值具有较好一致性:垂向湿润锋相对均方差(R_E)、平均绝对误差(MAE)和纳什系数(NE)分别为0.019、0.011 cm和0.994,径向湿润锋R_E、MAE和NE分别为0.018、0.851 cm和0.977,土壤含水率R_E、MAE和NE分别为0.188、0.016 cm~3·cm~(-3)和0.916。相比于设计深度为40 cm的RWCI系统, 60 cm RWCI系统在不同灌水量下能够更有效地增加果树根系分布层的土壤含水率,增加土壤水分入渗深度;相同灌水量下RWCI系统设计深度的径向湿润锋分布间无明显差异,而垂直方向的分布具有明显差异;RWCI系统在相同的设计深度下,随着灌水量增大湿润锋在垂向与径向的运移距离差异逐渐增大。     

Characterization of triadimefon sorption in soils using supercritical fluid (SFE) and accelerated solvent (ASE) extraction techniques

Sorption–desorption of the fungicide triadimefon in field‐moist silt loam and sandy loam soils were determined using low‐density supercritical fluid extraction (SFE). The selectivity of SFE enables extraction of triadimefon from the soil water phase only, thus allowing calculation of sorption coefficients (K_d) at field‐moist or unsaturated conditions. Triadimefon sorption was influenced by factors such as soil moisture content and temperature; sorption increased with increased moisture content up to saturation, and decreased with increased temperature. For instance, K_d values for triadimefon on the silt loam and the sandy loam soils at 40 °C and 10% water content were 1.9 and 2.5 ml g⁻¹, respectively, and at 18% water content, 3.3 and 6.4 ml g⁻¹, respectively. Isosteric heats of sorption (ΔH_i) were −42 and −7 kJ mol⁻¹ for the silt loam and sandy loam soils, respectively. Sorption–desorption was also determined using an automated accelerated solvent extraction system (ASE), in which triadimefon was extracted from silt loam soil by 0.01 M CaCl₂. Using the ASE system, which is basically a fast alternative to the batch equilibration system, gave a similar ΔH_i value (−29 kJ mol⁻¹) for the silt loam soil (K_f = 27 µg^{1 − 1/n} ml^1/n g⁻¹). In order to predict transport of pesticides through the soil profile more accurately on the basis of these data, information is needed on sorption as a function of soil water content. © 2000 Society of Chemical Industry