Soil ecological study on dynamics of K,Mg, and Ca,and soil acidity in shifting cultivation in Northern Thailand

Abstract

Soil degradation caused by excessive land use is presently one of the major constraints on sustainable agriculture in the mountainous area of northern Thailand. In order to obtain basic information about soil fertility problems involved in the transition from traditional shifting cultivation to more intensive upland farming, the dynamics of K, Mg, and Ca, and soil acidity in the farming systems of both Karen and Hmong/Thai peoples were investigated. In the fields that lay fallow for more than 5 y, the soils were highly acidic and poor in exchangeable bases, mainly due to the fact that the fallow vegetation rapidly absorbed inorganic bases (K, Mg, and Ca) in the soils. In the fields both under fallow and cropping within 3 y after the slash and burn practice, the high acidity observed in the soils at the fallow stage seemed to be alleviated by ash input with high alkalinity. The aboveground biomass ranged from 9 to 10 t ha^?1 in the 8 y fallow field and the sum of inorganic bases and alkalinity, which were expected to be added to the soils with ash input, ranged from 3 to 4 kmol( + ) ha^?1 or kmol(-) ha^?1 , respectively. In the fields under continuous cultivation for more than 4 y after the slash and burn practice, the subsoils showed a more acidic nature than in the fields immediately after burning. Judging from the high concentrations of inorganic bases in the soil solution from the subsoils, the decrease of the content of exchangeable bases and resulting soil acidification might have proceeded through leaching loss of these bases. Among the exchangeable bases in the soils, Ca and Mg were generally predominant and K occurred as trace. Comparison of the total contents of the bases with the contents of exchangeable ones showed that most of Ca occurred in an exchangeable form while most of K and Mg occurred in the nonexchangeable forms in the soils. Therefore, Ca was likely to be readily depleted along with soil acidification in continuous cultivation.     

Liming and sulfur amendments improve growth and yields of maize in Rubona Ultisol and Nyamifumba Oxisol

Aluminum toxicity is a major limitation to crop production on highly weathered and leached soils in Rwanda. Moreover, sulfur though widely deficient in Rwanda acidic soils has received little attention by soil fertility researchers. A field experiment on maize response and soil nutrients status to liming materials of travertines at 3.4 t ha^?1, ash wood 1.2 t ha^?1 of CaO equivalent and sulfur at 10 kg ha^?1 combined with NPK at 80, 60, and 45 kg ha^?1 respectively was conducted in Rubona Ultisol and Nyamifumba Oxisol. Results revealed that travertine and wood ash increased the soil pH from 4.7 to 5.8 or higher and decreased exchangeable Al³⁺ and H⁺ to near 0 cmolc kg^?1. Soil nutrients generally increased to high or medium ranges for crop production. Leaf dry biomass, plant height and maize grain yields were significantly higher in Rubona Ultisol than in Nyamifumba Oxisol. Plots that received wood ash, with NPKS or with NPK, generally had higher maize yields, followed by those which received travertines and NPKS or NPK which had maize growth response as compared to the control plots which received NPK only. Thereby, a combination of wood ash with NPKS or NPK, travertines with NPKS was found to neutralize soil aluminum toxicity, increase soil nutrients status to required levels for plant growth and increase maize yields significantly.     

Effect of wood ash on soil chemistry of a pine stand in Northern Germany

Addition of wood ash to acid soils will affect the soil chemistry of forests in a number of ways which were assessed for a pine stand in northern Germany. A field experiment was carried out in a fifty‐year old pine stand on a sandy Podzol at Fuhrberg (Lüneburger Heide, Lower Saxony/Germany) which involved depositing wood ash (2.4 t ha^—1) on the surface. Soil solution chemistry was investigated monthly at different depths for 24 months. Prior to and 19 months after the ash addition, exchangeable cations and amounts of heavy metals were determined at different depths. Two to four months after addition of wood ash, maximum mean concentrations in the soil solution of Ca were 240 μmol l^—1 at 0 cm (surface of mineral soil) and 100 μmol l^—1 at 100 cm and of K 980 μmol l^—1 and 140 μmol l^—1, respectively. The pH values in soil solutions dropped temporarily by 0.3 units at 0 and 10 cm depth. Nitrate concentrations increased at all depths and maximum mean concentration was 230 μmol l^—1 at 100 cm. Concentrations of Pb and Cr in soil solution did not change significantly (p < 0.05) after ash addition. Concentrations of Cd and Zn increased significantly at some depths but stayed well below the legal limit for drinking water and below the limits given by the German recommendation for soil conservation. Nineteen months after ash addition, the cation exchange capacity (corrected for the release of cations from the ash) of the upper 6 cm of the organic layer was almost doubled and amounts of exchangeable Ca and Mg increased significantly in the upper 8 cm of the organic layer. Amounts of Zn were increased in the entire organic layer, but changes were significant only in the upper 4 cm. The results of this study suggest that ash from untreated wood (using modest additions) may be recommended for amelioration of forest soils.     

Acidity,nutrient stocks,and organic‐matter content in soils of a temperate deciduous forest with different abundance of European beech (Fagus sylvatica L.)

The production and composition of leaf litter, soil acidity, exchangeable nutrients, and the amount and distribution of soil organic matter were analyzed in a broad‐leaved mixed forest on loess over limestone in Central Germany. The study aimed at determining the current variability of surface‐soil acidification and nutrient status, and at identifying and evaluating the main factors that contributed to the variability of these soil properties along a gradient of decreasing predominance of European beech (Fagus sylvatica L.) and increasing tree‐species diversity. Analyses were carried out in (1) mature monospecific stands with a predominance of beech (DL 1), (2) mature stands dominated by three deciduous‐tree species (DL 2: beech, ash [Fraxinus excelsior L.], lime [Tilia cordata Mill. and/or T. platyphyllos Scop.]), and (3) mature stands dominated by five deciduous‐tree species (DL 3: beech, ash, lime, hornbeam [Carpinus betulus L.], maple [Acer pseudoplatanus L. and/or A. platanoides L.]). The production of leaf litter was similar in all stands (3.2 to 3.9 Mg dry matter ha^–1 y^–1) but the total quantity of Ca and Mg deposited on the soil surface by leaf litter increased with increasing tree‐species diversity and decreasing abundance of beech (47 to 88 kg Ca ha^–1 y^–1; 3.8 to 7.9 kg Mg ha^–1 y^–1). The soil pH_(H2O) and base saturation (BS) measured at three soil depths down to 30 cm (0–10 cm, 10–20 cm, 20–30 cm) were lower in stands dominated by beech (pH = 4.2 to 4.4, BS = 15% to 20%) than in mixed stands (pH = 5.1 to 6.5, BS = 80% to 100%). The quantities of exchangeable Al and Mn increased with decreasing pH and were highest beneath beech. Total stocks of exchangeable Ca (0–30 cm) were 12 to 15 times larger in mixed stands (6660 to 9650 kg ha^–1) than in beech stands (620 kg ha^–1). Similar results were found for stocks of exchangeable Mg that were 4 to 13 times larger in mixed stands (270 to 864 kg ha^–1) than in beech stands (66 kg ha^–1). Subsoil clay content and differences in litter composition were identified as important factors that contributed to the observed variability of soil acidification and stocks of exchangeable Ca and Mg. Organic‐C accumulation in the humus layer was highest in beech stands (0.81 kg m^–2) and lowest in stands with the highest level of tree‐species diversity and the lowest abundance of beech (0.27 kg m^–2). The results suggest that redistribution of nutrients via leaf litter has a high potential to increase BS in these loess‐derived surface soils that are underlain by limestone. Species‐related differences of the intensity of soil–tree cation cycling can thus influence the rate of soil acidification and the stocks and distribution of nutrients.     

Nutrient storage in termite (Macrotermes bellicosus) mounds and the implications for nutrient dynamics in a tropical savanna Ultisol

The role of mounds of the fungus-growing termite Macrotermes bellicosus (Smeathman) in nutrient recycling in a highly weathered and nutrient-depleted tropical red earth (Ultisol) of the Nigerian savanna was examined by measuring stored amounts of selected nutrients and estimating their rates of turnover via the mounds. A study plot (4?ha) with a representative termite population density (1.5?mounds?ha^?1) and size (3.7?±?0.4?m in height, 2.4?±?0.2?m in basal diameter) of M. bellicosus mounds was selected. The mounds were found to contain soil mass of 9249?±?2371?kg?ha^?1, composed of 7502?±?1934?kg?ha^?1 of mound wall and 1747?±?440?kg?ha^?1 of nest body. Significant nutrient enrichment, compared to the neighboring topmost soil (Ap1 horizon: 0–16?cm), was observed in the nest body for total nitrogen (N) and exchangeable calcium (Ca), magnesium (Mg) and potassium (K), and in the mound wall for exchangeable K only. In contrast, available (Bray-1) phosphorus (P) content was found to be lower in both the mound wall and the nest body than in the adjacent topmost soil horizon. Consequently, the mounds formed by M. bellicosus contained 1.71?±?0.62?kg?ha^?1 of total N, 0.004?±?0.003?kg?ha^?1 of available P, 3.23?±?0.81?kg?ha^?1 of exchangeable Ca, 1.11?±?0.22?kg?ha^?1 of exchangeable Mg and 0.79?±?0.21?kg?ha^?1 of exchangeable K. However, with the exception of exchangeable K (1.2%), these nutrients amounted to less than 0.5% of those found in the topmost soil horizon. The soil nutrient turnover rate via M. bellicosus mounds was indeed limited, being estimated at 1.72?kg?ha^?1 for organic carbon (C), 0.15?kg?ha^?1 for total N, 0.0004?kg?ha^?1 for available P, 0.15?kg?ha^?1 for exchangeable Ca, 0.05?kg?ha^?1 for exchangeable Mg, and 0.06?kg?ha^?1 for exchangeable K per annum. These findings suggest that the mounds of M. bellicosus, while being enriched with some nutrients to create hot spots of soil nutrients in the vicinity of the mounds, are not a significant reservoir of soil nutrients and are therefore of minor importance for nutrient cycling at the ecosystem scale in the tropical savanna.     

Eucalyptus biochar application enhances Ca uptake of upland rice,soil available P,exchangeable K,yield, and N use efficiency of sugarcane in a crop rotation system

It was hypothesized that the application of eucalyptus biochar enhances nutrient use efficiencies of simultaneously supplied fertilizer, as well as provides additional nutrients (i.e., Ca, P, and K), to support crop performance and residual effects on subsequent crops in a degraded sandy soil. To test this hypothesis, we conducted an on‐farm field experiment in the Khon Kaen province of Northeastern Thailand to assess the effects of different application rates of eucalyptus biochar in combination with mineral fertilizers to upland rice and a succeeding crop of sugarcane on a sandy soil. The field experiment consisted of three treatments: (1) no biochar; (2) 3.1 Mg ha^?1 biochar (10.4 kg N ha^?1, 3.1 kg P ha^?1, 11.0 kg K ha^?1, and 17.7 kg Ca ha^?1); (3) 6.2 Mg ha^?1 biochar (20.8 kg N ha^?1, 6.2 kg P ha^?1, 22.0 kg K ha^?1, and 35.4 kg Ca ha^?1). All treatments received the same recommended fertilizer rate (32 kg N ha^?1, 14 kg P ha^?1, and 16 kg K ha^?1 for upland rice; 119 kg N ha^?1, 21 kg P ha^?1, and 39 kg K ha^?1 for sugarcane). At crop harvests, yield and nutrient contents and nitrogen (N) use efficiency were determined, and soil chemical properties and pH₀ monitored. The eucalyptus biochar material increased soil Ca availability (117 ± 28 and 116 ± 7 mg kg^?1 with 3.1 and 6.2 Mg ha^?1 biochar application, respectively) compared to 71 ± 13 mg kg^?1 without biochar application, thus promoting Ca uptake and total plant biomass in upland rice. Moreover, the higher rate of eucalyptus biochar improved CEC, organic matter, available P, and exchangeable K at succeeding sugarcane harvest. Additionally, 6.2 Mg ha^?1 biochar significantly increased sugarcane yield (41%) and N uptake (70%), thus enhancing N use efficiency (118%) by higher P (96%) and K (128%) uptake, although the sugar content was not increased. Hence, the application rate of 6.2 Mg ha^?1 eucalyptus biochar could become a potential practice to enhance not only the nutrient status of crops and soils, but also crop productivity within an upland rice–sugarcane rotation system established on tropical low fertility sandy soils.     

Coal Fly Ash and Phospho‐gypsum Mixture as an Amendment to Improve Rice Paddy Soil Fertility

Abstract

Rice is a plant that requires high levels of silica (Si). As a silicate (SiO₂) source to rice, coal fly ash (hereafter, fly ash), which has an alkaline pH and high available silicate and boron (B) contents, was mixed with phosphor‐gypsum (hereafter, gypsum, 50%, wt wt^?1), a by‐product from the production of phosphate fertilizer, to improve the fly ash limitation. Field experiments were carried out to evaluate the effect of the mixture on soil properties and rice (Oryza sativa) productivity in silt loam (SiL) and loamy sand (LS) soils to which 0 (FG 0), 20 (FG 20), 40 (FG 40), and 60 (FG 60) Mg ha^?1 were added. The mixture increased the amount of available silicate and exchangeable calcium (Ca) contents in the soils and the uptake of silicate by rice plant. The mixture did not result in accumulation of heavy metals in soil and an excessive uptake of heavy metals by the rice grain. The available boron content in soil increased with the mixture application levels up to 1.42 mg kg^?1 following the application of 60 Mg ha^?1 but did not show toxicity. The mixture increased significantly rice yield and showed the highest yields following the addition of 30–40 Mg ha^?1 in two soils. It is concluded that the fly ash and gypsum mixture could be a good source of inorganic soil amendments to restore the soil nutrient balance in rice paddy soil.     

Relationship between chemical and mineralogical properties and the rapid response to acid load of soils in humid Asia: Japan,Thailand and Indonesia

Abstract

It is essential to determine the relationship between soil chemical and mineralogical properties and soil response to acid load to understand the acid-neutralizing capacity and cation behavior of different ecosystems. For 46 soil samples from a subsurface horizon in humid Asia, that is, Japan, Thailand and Indonesia, exchangeable cations, total bases and oxalate-extractable Al (Al_o) were determined, and acid titration was conducted to investigate the rapid soil response to acid load. The acid titration experiment indicated three types of soil response: (1) the release of base cations (particularly Ca and Mg) strongly correlated with exchangeable bases, which dominated the tropical soil samples, (2) the release of Al correlated with Al_o content, which dominated the Japanese soil samples, (3) acid and anion adsorption in soil samples with low acid-neutralizing capacity. To gain further information on the source of soil alkalinity, a column experiment with HCl was conducted using eight selected soil samples in which first-order kinetics were assumed to simulate the time-courses of cation release. In the column experiment, the amounts of Ca and Mg released were close to the exchangeable amounts, and Al_o dissolved more rapidly than Al in crystalline minerals. The rate constants of cation release were large for Ca and Mg, and small for Al, clearly indicating a difference between the exchange and dissolution reactions. Thus, rapid soil response to acid load differed among the soils. A cation exchange reaction was dominant in the tropical soils. In some tropical soils, Ca and Mg were present in exchangeable forms at a higher ratio in the total amounts and they were considered to be easily utilized by plants, but leached out from the soils. In the Japanese soils, including the Andisols, secondary mineral dissolution was conspicuous, resulting in a large acid-neutralizing capacity. In both the tropical and Japanese soils with low acid-neutralizing capacity, anion adsorption mainly contributed to acid neutralization.     

Leaching of heavy metals and nutrients from calcareous sandy‐loam soil receiving municipal solid sewage sludge

Leaching column experiments were conducted to determine the degree of mobility of heavy metals (HMs) and nutrients after the addition of municipal solid sewage sludge (MSS) in a sandy‐loam soil. Treatments were (1) soil application of low metal content MSS, (2) soil application of metal‐enriched municipal solid sewage sludge (EMSS), and (3) control. The MSS application represented a dose of 200 Mg dry weight (dw) ha^–1. Soil columns were incubated at room temperature for 15 d and were irrigated daily with distilled water to make a total of 557 mm. Leachates were collected and analyzed for HMs and nutrients. The Ni and Pb added to soil via MSS and EMSS were found to be leached through the 20 cm columns of calcareous sandy soil although Ni and Pb concentrations in the percolate were small relative to the total amounts of metals applied. Losses of K⁺ from the EMSS, MSS, and control were 92.5, 82.0, and 52.5 kg ha^–1, respectively. Losses of Mg²⁺ were in the range from 104.4 (control treatment) to 295.2 kg ha^–1 (EMSS), while the loss of Ca²⁺ was in the range from 265.0 (control treatment) to 568.2 kg ha^–1 (EMSS). The results showed that the amounts of P leached from EMSS (3.02 kg ha^–1) and MSS (2.97 kg^–1 ha^–1) were significantly larger than those from the control treatment (1.54 kg ha^–1). The geochemical code Visual MINTEQ was used to calculate saturation indices. Leaching of P in different treatments was controlled by rate‐limited dissolution of hydroxyapatite, β‐tri‐Ca phosphate, and octa‐Ca phosphate. The results indicate that application of MSS to a sandy soil, at the loading rate used in this study, may pose a risk in terms of groundwater contamination with Ni, Pb, and the studied nutrients.     

The hydrolysis of kaolinitic soils as affected by the type of the exchangeable cation

The hydrolysis of four kaolinitic soils from the Transvaal (RSA), and the effects of exchangeable Na, Ca and Mg were studied by monitoring the changes in the electrical conductivity of the soil suspension with time. The rate of the hydrolysis was found to be linearly related to the square root of time. The rates of the hydrolysis of the Half-Way House and Krugersdorp soils were appreciably lower than those of the Potchefstroom and Amsterdam soils, and rates reported in the literature for smectite soils. This was probably because of the low content of hydrolysable bases in the Half-Way House and Krugersdorp soils, resulting from the low cation exchange capacity of their clay fraction. The extensive hydrolysis observed in the Potchefstroom and Amsterdam soils could be ascribed to the presence of significant amounts of smectite in the former and high silt content in the latter; both factors are known to enhance the rate of weathering and hydrolysis. With the exception of the Potchefstroom soil, the rate of hydrolysis was not affected by the cationic composition of the adsorbed phase. Contrary to expectations, exchangeable Mg did not inhibit hydrolysis in the soils studied, probably because of the limited isomorphic substitutions in kaolinite which lead to very small amounts of octahedral Mg in the crystal. The hydrolysis of the Potchefstroom soil was enhanced in the presence of exchangeable Mg compared to exchangeable Ca; the reason for this is not fully understood.     

C and N accumulation in arable soils of West Germany and its influence on the environment — Developments 1970 to 1998

During the last three decades, large amounts of soil organic matter (SOM) and associated nutrients have been accumulated in arable soils of Western Germany (former FRG) due to deepening of the plough layers (from < 25 to > 35 cm) and to fertilizer application rates which have exceeded the amounts of nutrients removed in harvested crops. Organic carbon and total nitrogen balances (1970—1998) on 120 plots from 16 farms in southern Lower Saxony yielded a cumulative increase of up to 16 t C ha⁻¹ and 1 t N ha⁻¹ in loess soils used for cash crop production and up to 26 t C ha⁻¹ and 2.4 t N ha⁻¹ in sandy soils under livestock production. The buffering capacity for reactive compounds, particularly of C, N, S and P and of other (organic or inorganic) pollutants will reach its limits in the near future, after organic matter ”︁equilibria” have been re‐established. An immediate adaptation of the current fertilizer application rates to the nutrient export by field crops is therefore urgently needed.     

Performance of Slag-Based Gypsum on Maize Yield and Available Soil Nutrients over Commercial Gypsum under Acidic and Neutral Soil

ABSTRACT

Effect of slag-based gypsum (SBG) and commercial gypsum (CG) on maize was investigated in acidic and neutral soils. A randomized complete block design (RCBD) with seven treatments consisting of three levels (150, 450, and 750 kg ha^?1) of SBG and CG with recommended dose of fertilizer (RDF) and one control was maintained. Application of SBG @750 kg ha^?1 recorded significantly higher (8.61 and 8.69 t ha^?1, respectively) cob yield of maize compared to CG and control treatments in both soil condition. Increased levels of SBG application increased soil pH and EC in both the soils, but decreased with the application of CG. Application of 750 kg SBG ha^?1 recorded significantly higher soil available nutrients like phosphorus in acidic soil and potassium in neutral soil. Higher exchangeable calcium and magnesium in acidic soil and exchangeable calcium in neutral soil were recorded with the application of CG @750 kg ha^?1. Available sulfur was significantly higher with CG @750 kg ha^?1 applied treatment in both soils. CaCl₂Si content in acidic soil varied significantly and recorded higher with application of SBG, while CaCl₂Si content in neutral soil and AASi in both soils had no significant effect by application of SBG. Significantly higher DTPA extractable micronutrients in acidic and neutral soil were noticed in SBG @750 kg ha^?1 applied treatment. However, application of SBG had no significant effect on iron and copper content in neutral soil. Higher uptake of nutrients was recorded with 750 kg SBG ha^?1 compared CG applied and other treatments.     

Evaluation of Nutrient Release in Salt‐Saturated Soils

Abstract

The effects of irrigating with saline water on native soil fertility and nutrient relationships are not well understood. In a laboratory experiment, we determined the extent of indigenous nutrient [calcium (Ca), magnesium (Mg), potassium (K), manganese (Mn), and zinc (Zn)] release in salt-saturated soils. Soils were saturated with 0, 75, and 150 mmolc L^?1 sodium chloride (NaCl) solution and incubated for 1, 5, 10, and 15 days. The saturation extracts were analyzed for pH, ECe, and water‐soluble Ca, Mg, K, Mn, and Zn, and the remainder soil samples were analyzed for exchangeable forms of these elements. In a subexperiment, three soil types (masa, red‐yellow, and andosol) were saturated individually either with 100 mmolc L^?1 of NaCl, sodium nitrate (NaNO₃), or sodium sulfate (Na₂SO₄) salt. These salts were also compared for nutrient release. Soils treated with NaCl released higher amounts of water‐soluble than exchangeable nutrients. Except for Zn, the average concentrations of these nutrients in the soil solution increased significantly with time of incubation, but concentrations of the exchangeable forms varied inversely with time of incubation. The masa soil exhibited the highest concentrations of Ca and Mg, whereas K was highest in andosol. The extract from soils treated with NaCl contained greater amounts of soluble cations, whereas soils treated with Na₂SO₄ produced the lowest concentration of these elements irrespective of the type of soil used.     

Effects of Wood Ash Dose and Formulation on Soil Chemistry at Two Coniferous Forest Sites

Harvesting stem biomass from the forest inevitably involves exporting nutrients from the ecosystem. The amount exported is increased when the logging residues are also removed for use as fuel. Recycling of the resulting wood ash has been advocated as a measure to compensate for the nutrient losses and to sustain future forest production. The physical formulation of the wood ash may have an important influence on its effects on soil properties. In this paper, we report effects of two different types of wood ash (one self-hardened and crushed, the other pelleted), with differences in solubility, on soil chemistry in the humus layer and upper 15 cm of the mineral soil, at two coniferous sites in south-central Sweden, 5 yr after their application. The crushed ash was applied at three doses (3, 6 and 9 ton ha^–1), while the pelleted ash was applied at only one dose (3 ton ha^–1). At both sites the soil was podzolized. The two sites differed with respect to soil conditions, despite being situated only a few kilometers apart. The application of wood ash increased both soil pH and base-cation content in the humus layer at both sites. In the mineral soil, the effects were less pronounced. Treatment effects on soil chemistry did not differ between the two ash formulations. The retention (i.e. the extractable amount of nutrients found in the soil that could be attributed to the ash application) of nutrients varied strongly between the two sites, and K retention (ca. 10%) was generally lower than that of Ca and Mg.     

Evaluation of fly ash as a soil amendment for the Atlantic Coastal Plain: II. Soil chemical properties and crop growth

Crop yields in the Atlantic Coastal Plain of the U.S.A. are limited by the low moisture-holding capacities of the sandy soils common to the region. Corn was grown in a Hammonton loamy sand soil amended with fly ash (0, 5, 10, 20, 30, and 40%) to determine if the ash rates required to improve soil moisture holding capacity would adversely affect plant growth, or soil and plant levels of nutrients and heavy metals. Fly ash increased soil test levels of P, K, Ca, Mg, Mn, Cu, Zn, B, Cd, Cr, Ni, and Pb. Nutrient concentrations in plants grown in the ash-amended soils, except P, Mn, and B, remained within established sufficiency ranges. The 20 and 40% ash rates increased soil soluble salt (EC) levels from 0.2 to 1.1–1.5 and 1.7–2.1 mmho cm^?1, soil pH from 5.6 to 6.0–6.4 or 6.3–6.9, and extractable B from 0.2 to 2.2–5.9 and 2.2–9.0 mg kg^?1. Fly ash reduced corn germination, delayed seedling emergence, and reduced root and shoot dry weights. Plant B concentrations at the 40% ash rate were in the phytotoxic range (136–189 mg kg^?1). Management practices that allow for pre-leaching of B and soluble salts will likely be required to attain satisfactory corn growth in ash-amended soils.     

CARBON BUDGET AND SEQUESTRATION POTENTIAL IN A SANDY SOIL TREATED WITH COMPOST

The effects of compost application on soil carbon sequestration potential and carbon budget of a tropical sandy soil was studied. Greenhouse gas emissions from soil surface and agricultural inputs (fertiliser and fossil fuel uses) were evaluated. The origin of soil organic carbon was identified by using stable carbon isotope. The CO₂, CH₄ and N₂O emissions from soil were estimated in hill evergreen forest (NF) plot as reference, and in the corn cultivation plots with compost application rate at 30 Mg ha⁻¹ y⁻¹ (LC), and at 50 Mg ha⁻¹ y⁻¹ (HC). The total C emissions from soil surface were 8·54, 10·14 and 9·86 Mg C ha⁻¹ y⁻¹ for NF, HC and LC soils, respectively. Total N₂O emissions from HC and LC plots (2·56 and 3·47 kg N₂O ha⁻¹ y⁻¹) were significantly higher than from the NF plot (1·47 kg N₂O ha⁻¹ y⁻¹). Total CO₂ emissions from fuel uses of fertiliser, irrigation and machinery were about 10 per cent of total CO₂ emissions. For soil carbon storage, since 1983, it has been increased significantly (12 Mg ha⁻¹) under the application of 50 Mg ha⁻¹ y⁻¹ of compost but not with 30 Mg ha⁻¹ y⁻¹. The net C budget when balancing out carbon inputs and outputs from soil for NF, HC and LC soils were +3·24, −2·50 and +2·07 Mg C ha⁻¹ y⁻¹, respectively. Stable isotope of carbon (δ¹³C value) indicates that most of the increased soil carbon is derived from the compost inputs and/or corn biomass. Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of acidic precipitation,O3, and soil Mg status on throughfall,soil, and seedling loblolly pine nutrient concentrations

The individual and combined impacts of acidic precipitation, O₃, and soil Mg status on nutrient concentrations of throughfall, soil solution, soil, and seedling components were evaluated after one growing season. Loblolly pine seedlings were planted in a sandy loam soil having approximately 15 or 35 mg kg^?1 of exchangeable Mg and were exposed to subambient, ambient, or twice ambient concentrations of O₃ in open top chambers from May through October. Seedlings also received ambient amounts of simulated precipitation at pH 4.0 or 5.3 during this period. Concentrations of nutrients analyzed increased slightly in throughfall, but did not respond significantly to precipitation pH treatments. No increased nutrient leaching and no soil acidification were evident in soil exposed to low pH precipitation after one growing season. Ozone treatments had no significant effects on tissue nutrient concentrations. Interaction responses were very limited and do not suggest any significant synergisms.     

The short-term effects of wood-ash amendment on forest soils

In the heavily forested regions of the northeastern U.S. the potential for producing electricity from wood-fired boilers is also creating a growing supply of wood-ash requiring disposal. Landfill space is expensive and limited, which has resulted in an interest in spreading wood-ash on forest sites. This greenhouse study was designed to provide information on soil and seedling response to wood-ash applications. Red maple (Acer rubrum) seedlings were grown in either O or B horizon forest soil material and amended with six levels of ash (0, 4, 8, 12, 16, and 20 Mg ha^?1) and two levels of N fertilizer (0 and 224 kg ha^?1). Ash amendments increased pH and exchangeable base cations, and decreased extractable Al and Fe concentrations, in both soil materials. Ash treatments increased seedling foliar K and Na concentrations in O horizon soils, but had little effect on growth. No significant effects on seedling properties from ash in B horizon soils were found. Fertilizer N treatments did not improve seedling growth in either soil material. Soil and seedling response to N were notably different for the different soils used. Based on this short-term study it appears that (a) land applications of wood-ash at the rates used may be a viable approach to recycling this solid waste, and (b) long-term studies are required to evaluate this practice under field conditions.     

Crop yield and SOC responses to biochar application were dependent on soil texture and crop type in southern Quebec,Canada

Changes to soil nutrient availability and increases for crop yield and soil organic C (SOC) concentration on biochar‐amended soil under temperate climate conditions have only been reported in a few publications. The objective of this work was to determine if biochar application rates up to 20 Mg ha^?1 affect nutrient availability in soil, SOC stocks and yield of corn (Zea mays L.), soybean (Glycine max L.), and switchgrass (Panicum virgatum L.) on two coarse‐textured soils (loamy sand, sandy clay loam) in S Quebec, Canada. Data were collected from field experiments for a 3‐y period following application of pine wood biochar at rates of 0, 10, and 20 Mg ha^?1. For corn plots, at harvest 3 y after biochar application, 20 Mg biochar ha^?1 resulted in 41.2% lower soil NH on the loamy sand; the same effect was not present on the sandy clay loam soil. On the loamy sand, 20 Mg biochar ha^?1 increased corn yields by 14.2% compared to the control 3 y after application; the same effect was not present on the sandy clay loam soil. Biochar did not alter yield or nutrient availability in soil on soybean or switchgrass plots on either soil type. After 3 y, SOC concentration was 83 and 258% greater after 10 and 20 Mg ha^?1 biochar applications, respectively, than the control in sandy clay loam soil under switchgrass production. The same effect was not present on the sandy clay loam soil. A 67% higher SOC concentration was noted with biochar application at 20 Mg ha^?1 to sandy clay loam soil under corn.     

Short‐term effect of biochar and compost on soil fertility and water status of a Dystric Cambisol in NE Germany under field conditions

Crop growth in sandy soils is usually limited by plant‐available nutrients and water contents. This study was conducted to determine whether these limiting factors could be improved through applications of compost and biochar. For this purpose, a maize (Zea mays L.) field trial was established at 1 ha area of a Dystric Cambisol in Brandenburg, NE Germany. Five treatments (control, compost, and three biochar‐compost mixtures with constant compost amount (32.5 Mg ha^–1) and increasing biochar amount, ranging from 5–20 Mg ha^–1) were compared. Analyses comprised total organic C (TOC), total N (TN), plant‐available nutrients, and volumetric soil water content for 4 months under field conditions during the growing season 2009. In addition, soil water‐retention characteristics were analyzed on undisturbed soil columns in the laboratory. Total organic‐C content could be increased by a factor of 2.5 from 0.8 to 2% (p < 0.01) at the highest biochar‐compost level compared with control while TN content only slightly increased. Plant‐available Ca, K, P, and Na contents increased by a factor of 2.2, 2.5, 1.2, and 2.8, respectively. With compost addition, the soil pH value significantly increased by up to 0.6 (p < 0.05) and plant‐available soil water retention increased by a factor of 2. Our results clearly demonstrated a synergistic positive effect of compost and biochar mixtures on soil organic‐matter content, nutrients levels, and water‐storage capacity of a sandy soil under field conditions.