有机物料对酸性红壤铝毒的缓解效应

利用盆栽试验研究了施用不等量稻草对酸性红壤旱耕地铝毒的缓解效应。结果表明,添加不等量的秸秆碳(C)后,土壤pH值显著提高,土壤交换性铝和吸附态羟基铝的含量则明显降低,土壤有机络合态铝的含量也呈增加趋势。添加铝盐并不影响秸秆碳对降低土壤交换性铝和吸附态羟基铝含量的作用。在本研究中,土壤pH值与土壤交换性铝和土壤吸附态羟基铝均呈显著负相关,方程分别为y=-2193.9x+11545,R2=0.9798**,y=-655.34x+9748,R2=0.7837**。土壤交换性铝和吸附态羟基铝与玉米主根长,地上部磷、钾含量均呈显著负相关,是抑制玉米吸收养分的主要限制因素,土壤吸附态羟基铝是次于交换性铝的又一活性较大的铝化合物。     

Spatial variability of soil solution chemistry under Hinoki cypress (Chamaecyparis obtusa) in Tama Hills

A monitoring study on precipitation and soil solution was conducted to analyze soil acidification processes at the Rolling Land Laboratory (RLL), Hachioji, Tokyo based on the spatial variability of the soil solution chemistry around the Hinoki cypress (Chamaecyparis obtusa) trunk. Soil solution samples were taken at various distances from the tree trunks and at various depths. Soil solution pH at the depth of 10 cm decreased to 4.1–4.2 on the downslope side of large tree trunks, presumably due to the heterogeneity of throughfall input and extensive infiltration of acidic stemflow. Ammonium ions brought by throughfall and stemflow were nitrified and provided large amounts of H⁺. Protons were replaced with exchangeable cations. When base cations were depleted, aluminum ion became the dominant cation species. On the average, Ca²⁺ concentration in the soil solutions at the depth of 10 cm decreased from 0.28 mmol_c L^-1 at the reference site to 0.18 mmol_c L^-1 on the downslope side and Mg²⁺ concentration decreased from 0.30 mmol_c L^-1 to 0.15 mmol_c L^-1. Arithmetic mean aluminum concentration at the depth of 10 cm on the downslope side was 0.35 mmol_c L^-1. Here aluminum dissolution was the main acid sink. Based on the spatial variability of the soil solution chemistry, soil solution acidification processes were divided into four stages.     

电解质对酸性土壤铝的溶解及铝形态在土壤溶液中的分布的影响

KCl, CaCl₂, NH₄Cl, NaCl, K₂SO₄ and KF solutions were used for studying the effects of cations and anions on the dissolution of aluminum and the distribution of aluminum forms respectively. Power of exchanging and releasing aluminum of four kinds of cations was in the decreasing order Ca²⁺ >K⁺ >NH₄⁺ >Na⁺. The dissolution of aluminum increased with the cation concentration. The adsorption affinity of various soils for aluminum was different. The aluminum in the soil with a stronger adsorption affinity was difficult to be exchanged and released by cations. The Al-F complexes were main species of inorganic aluminum at a low concentration of cations, while Al³⁺ became major species of inorganic aluminum at a high concentration of cations. The results on the effect of anions indicated that the concentrations of total aluminum, three kinds of inorganic aluminum (Al³⁺, Al-F and Al-OH complexes) and organic aluminum complexes (Al-OM) when SO₄^2- was added into soil suspension were lower than those when Cl^- was added. The dissolution of aluminum from soils and the distribution of aluminum forms in solution were affected by the adsorption of F^- on the soil. For soils with strong affinity for F^-, the concentrations of the three inorganic aluminum species in soil solution after addition of F^- were lower than those after addition of Cl^-; but for soils with weak affinity for F^-, the concentrations of Al³⁺ and Al-OM were lower and the concentrations of Al-F complexes and total inorganic aluminum after addition of F^- were higher than those after addition of Cl^-. The increase of F^- concentration in soil solution accelerated the dissolution of aluminum from soils.     

Speciation of aluminum in soil environments

Although aluminum (Al) is abundant in soil environments, it is not an essential element and it is toxic to most organisms. Since the toxicity of Al depends on their chemical forms, the importance of Al speciation has been recognized worldwide. Difficulties in Al speciation are caused by the complex coordination chemistry of Al for the hydrolysis and formation of polynuclear species with a variable degree of solubility in aqueous solution. Nondestructive analyses, such as nuclear magnetic resonance (NMR) spectroscopy, could supply primarily im-portant information on the chemical forms of Al and may enable to evaluate the results ob-tained by other methodologies. In the present report, NMR spectral characteristics of environmentally important Al-containing components, such as hydoxyaluminum ions, Alinorganic complexes, Al-organic complexes, and primary and secondary minerals, are summarized for the nuclei of ²⁷Al and ²⁹Si determined by solution NMR and solid-state magic angle spinning (MAS) NMR. Applications of NMR techniques to soil science, including speciation of phytotoxic Al in soil environments and whole soil NMR studies, are described.     

紫色土坡耕地土壤物理性质空间变异对土壤侵蚀的响应

为了研究不同坡度和坡长的耕地上土壤侵蚀对土壤物理性质空间变异的影响,通过地形测量、137 Cs示踪、土壤物理性质分析等方法对川中丘陵紫色土区土壤物理性质对土壤侵蚀的响应进行了研究,结果表明：在中等坡度（16.60%～25.10%）的梯坡地上,耕作侵蚀处于主导地位,是导致耕层土壤物理性黏粒含量和容重在梯坡地上总体差异不大（CV＜6.3%）,且与137Cs含量不相关的主要原因;在已退耕还林的陡梯坡地上（35.60%）,水蚀占据主导地位,导致耕层土壤物理性黏粒含量和容重均与137Cs的含量显著相关。在长坡耕地上(10.10%),具有分选搬运能力的水力侵蚀占据主导地位,致使耕层土壤物理性黏粒含量与137Cs的含量具有显著的相关关系,而容重却与137Cs含量没有显著的相关关系。川中丘陵区坡耕地上,耕作侵蚀和水蚀共同作用于土层深度,使土层深度在坡顶、上坡最浅,在坡脚最深,顺坡向下逐渐增加。因此,在川中丘陵区不同坡长的坡耕地上,占主导地位的土壤侵蚀类型导致坡耕地上土壤物理性质出现相应的变化。     

Identification of organically bound iodine in soil humic substances by size exclusion chromatography / inductively coupled plasma mass spectrometry (SEC / ICP-MS)

Abstract

Sulfur transformation in riee rhizosphere was investigated. Soil enzyme arylsulfatase in rhizosphere and non-rhizosphere soil, whieh is responsible for mineralization of organic sulfur to sulfate sulfur, was studied. The Michaelis constants of arylsulfatase from Maahas c1ay and Pila c1ay loam were 3.04 × 10^-4 M and 3.97 × 10^-4 M, respectively. The arylsulfatase of rhizosphere soil showed higher activity than that of non-rhizosphere soil. Applieation of sulfate had no marked elTect on the enzyme aetivity either in rhizosphere or non-rhizosphere soil under the submerged condition. This indieates that arylsulfatase activity under the submerged condition is not inhibited by applieation of sulfate. The amount of HI-reducible sulfur in the rhizosphere and non-rhizosphere soi! inereased with time. However, rhizosphere soil had a higher amount of HI-reducible sulfur than did non-rhizosphere. Thc ditl'erence in arylsulfatase activity between the rhizosphcre and non-rhizosphere soil was not directly associated with thc number of sulfur-redueing and -oxidizing bacteria.     

The sensitivity of Swiss forest soils to acidification and the risk of aluminum toxicity

In the context of pollution‐control strategies to minimize the detrimental effects of soil acidification, there is a need to know how and to what extent soils respond to acidifying substances. The purposes of this study were to assess the sensitivity of soil to acidification, in particular to a decrease in pH and in base saturation (BS), and the risk of Al toxicity for vulnerable plants using chemical indicators. These indicators were derived from soil data (pH, exchangeable cations, amount of fine earth) measured in the mineral horizons of 257 soil profiles throughout Switzerland. Based on the analysis of the distribution of pH and BS values in the soil collective, we assessed the sensitivity of soils to a decrease in pH and in BS. Soils that were considered sensitive to a decrease in pH had pH values between 4.8 and 7.0. The degree of sensitivity was estimated with the proportion of fine earth in the critical pH range to a depth of 100 cm. Soils that were considered sensitive to a decrease in BS had pH values between 3.6 and 5.5 and a BS between 10% and 95%. Since the effective cation‐exchange capacity (CEC_eff) of the fine earth might dampen the decrease in BS when acidity is added, the disposition for a decrease in BS was related to the relative amount of fine earth in the sensitive BS and to the mean CEC_eff of this fine‐earth fraction. The risk of Al toxicity for vulnerable plants was estimated using the ratio of base cations to Al at the cation‐exchange sites (BC : Al_exc). A BC : Al_exc of 0.2 was taken as a threshold value below which the risk for sensitive plants increases. The degree of risk was based on the proportion of fine earth in the critical BC : Al range (≤0.2) in the soil profile. These indicators taking into account the various aspects of soil acidification are derived from usually available data and represent therefore a cost‐effective tool to assess the sensitivity of soils to an input of acidity.     

Uncertainties in long-term predictions of forest soil acidification due to neglecting seasonal variability

Soil and soil solution response simulated with a site-scale soil acidification model (NUCSAM) was compared with results obtained by a regional soil acidification model (RESAM). RESAM is a multi-layer model with a temporal resolution of one year. In addition to RESAM, NUCSAM takes seasonal variability into account since it simulates solute transport and biogeochemical processes on a daily basis. Consequently, NUCSAM accounts for seasonal variation in deposition, precipitation, transpiration, litterfall, mineralization and root uptake. Uncertainty caused by the neglect of seasonal variability in long-term predictions was investigated by a comparison of long-term simulations with RESAM and NUCSAM. Two deposition scenarios for the period 1990–2090 were evaluated. The models were parameterized and validated by using data from an intensively monitored spruce site at Solling, Germany. Although both the seasonal and the interannual variation in soil solution parameters were large, the trends in soil solution parameters of RESAM and NUCSAM corresponded quite well. The leaching fluxes were almost similar. Generally it appeared that the uncertainty due to time resolution in long-term predictions was relatively small.     

低分子量有机酸对促进可变电荷土壤中铝溶解的影响

Low-molecular-weight （LMW） organic acids exist widely in soils and play an important role in soil processes such as mineral weathering, nutrient mobilization and A1 detoxification. In this research, a batch experiment was conducted to examine the effects of LMW organic acids on dissolution of aluminum in two variably charged soils, an Ultisol and an Oxisol. The results showed that the LMW organic acids enhanced the dissolution of A1 in the two investigated soils in the following order： citric 〉 oxalic 〉 malonic 〉 malic 〉 tartaric 〉 salicylic 〉 lactic 〉 maleic. This was generally in agreement with the magnitude of the stability constants for the Al-organic complexes. The effects of LMW organic acids on Al dissolution were greater in the Ultisol than in the Oxisol as compared to their controls. Also, the accelerating effects of citric and oxalic acids on dissolution of A1 increased with an increase in pH, while the effects of lactic and salicylic acids decreased. Additionally, when the organic acid concentration was less than 0.2 mmol L-I, the dissolution of A1 changed Iittle with increase in acid concentration. However, when the organic acid concentration was greater than 0.2 mmol L^-1,the dissolution of A1 increased with increase in acid concentration. In addition to the acid first dissociation constant and stability constant of Al-organic complexes, the promoting effects of LMW organic acids on dissolution of A1 were also related to their sorption-desorption equilibrium in the soils.     

Comparison of spatial interpolation techniques for mapping soil pH and salinity in agricultural coastal areas,northern Iran

This study attempted to characterize the spatial distributions of soil pH and electrical conductivity (EC_e) of coastal fields in the Miyandoroud region, northern Iran, for three soil layer depths by assessing spatial variability and comparing different interpolation techniques such as inverse distance weighting (IDW), ordinary kriging (OK), and conditional simulations (CS). Three soil composite samples were collected from 0–50, 50–100, and 100–150 cm depths at 105 sampling sites. At all three soil depths, pH and EC_e were best fitted by exponential and spherical models, respectively. Nugget effects were higher for soil EC_e data sets compared with soil pH at all three soil depths showing soil EC_e had a spatial variability in small distances. The prediction accuracy of the interpolation methods indicated that the minimum error for all data sets was achieved with the OK method, except for pH at 50–100 cm depth, and the CS technique revealed the largest error. The effect of different numbers of simulations (100, 500 and 1000) in the CS interpolation method resulted not in a realistic mapping for the soil EC_e and pH. Considering the high importance of irrigated agriculture in the Caspian Sea coastal areas, more subsoil salinity build-up and groundwater salinity monitoring plans are needed as a prerequisite for sustainable agricultural production systems of the future.     

Changes in soil pH due to the storage of soils

Abstract. The pH of soil samples was remeasured after storage for 20 years in the laboratory. The pH decreases were minor in acid to neutral soils (-0.3), but greater in alkaline soils (-0.63). The pH differences were statistically significant only for alkaline soils. The decreases of pH with time are probably mainly due to the decomposition of organic matter, the CO₂ produced, the hydroscopic water and the presence of CaCO₃.     

Assessment of potentially reactive pools of aluminum in Andisols using a five-step sequential extraction procedure

A five-step sequential extraction procedure was developed for the partitioning of soil aluminum (Al) into five fractions: exchangeable, weakly organic bound, strongly organic bound, inorganic non-crystalline and crystalline. The results obtained by the sequential extraction method for Al were compared with those estimated from single extractions using identical operating conditions applied in each individual sequential fraction. The Al content in the extracts was measured by inductively coupled plasma optical emission spectrometry. The results indicated that the first four steps [potassium chloride (KCl), copper chloride (CuCl₂), sodium pyrophosphate (Na₄P₂O₇), acid ammonium oxalate ((NH₄)₂C₂O₄)] in the sequential procedure could be as effective as single extraction methods at estimating exchangeable Al, weakly organic bound Al, strongly organic bound Al, and non-crystalline Al. However, the crystalline Al content by sequential procedure was not in agreement with single extraction procedures. Further, the sequential extractions resulted in more consistent estimates of the aluminum/silicon (Al/Si) molar ratio and allophane and crystalline Al contents than single extractions method. Results of X-ray diffraction on the soil samples confirm the presence of appreciable amounts of at least three types of crystalline minerals, including gibbsite, vermiculite or halloysite. Our result implies that the sequential method can be more reliable in estimating the various Al forms in Andisols.     

Using the simplified falling head technique to detect temporal changes in field-saturated hydraulic conductivity at the surface of a sandy loam soil

Determining temporal changes in field-saturated hydraulic conductivity (K_fs) is important for understanding and modeling hydrological phenomena at the field scale. Little is known about temporal variability of K_fs values measured at permanent sampling points. In this investigation, the simplified falling head (SFH) technique was used for an approximately 2-year period to determine temporal changes in K_fs at 11 permanent sampling points established at the surface of a sandy loam soil. Additional K_fs measurements were obtained by the single-ring pressure infiltrometer (PI) technique to also compare the SFH and PI techniques. The lowest mean values of K_fs, M(K_fs), were detected in December and January (20.5 ≤ M(K_fs) ≤ 146.2 mm h⁻¹), whereas higher results (190.5 ≤ M(K_fs) ≤ 951.9 mm h⁻¹) were obtained in the other months of the year. The K_fs values were higher and less variable in the dry soil (θ_i ≤ 0.21 m³ m⁻³, M(K_fs) = 340.6 mm h⁻¹, CV(K_fs) = 106%) than in the wet one (θ_i > 0.21 m³ m⁻³, M(K_fs) = 78.4 mm h⁻¹, CV(K_fs) = 185%). Both wet and dry soil were less conductive at the end of the study period than at the beginning one but a more appreciable change was detected for the dry soil (K_fs decreasing by 83.4%) than for the wet one (K_fs decreasing by 63.0%). The simple SFH technique yielded K_fs results similar to the more laborious and time-consuming PI technique (i.e., mean values differing at the most by a factor of two). It was concluded that (i) the soil water content was an important factor affecting the K_fs results obtained in a relatively coarse-textured soil, (ii) the impact of time from the beginning of the experiment on the saturated hydraulic conductivity was larger for a repeated sampling of dry soil than of wet soil and (iii) the SFH technique yielded reliable K_fs results in a relatively short period of time without the need for extensive instrumentation or analytical methodology.     

Changes in potassium availability and other soil properties due to soil ingestion by earthworms

An incubation experiment was conducted to study the changes that occur in potassium availability and other soil properties with ingestion of soil by earthworms. Two soils were used. Raumai soil with high non-exchangeable K and Milson soil with low non-exchangeable K were incubated with two species of earthworm, Aporrectodea caliginosa and Lumbricus rubellus, for 8 weeks. The casts and soil samples were analysed for exchangeable K, Ca, Mg, Na, and H, pH, organic C, and texture. The results indicated that in Raumai soil, the exchangeable K levels of the casts of both earthworm species were significantly higher than for the control soil, the effect being more marked for L. rubellus than for A. caliginosa. In Milson soil, the exchangeable K levels were significantly lower in the casts of both types of earthworm than in the control soil. The nitric acid-extractable K of the soil and casts was not markedly different for either soil type, but available non-exchangeable K values were significantly higher for the casts of L. rubellus from Milson soil than for the noningested Milson soil. In Raumai soil, the exchangeable Ca was higher in the casts of L. rubellus, exchangeable Mg and H were reduced, and exchangeable Na did not change markedly in the cast compared to the control soil. For Milson soil, the casts contained lower exchangeable Ca and H but higher Na and Mg than the control. The casts of both species of earthworm had significantly higher pH values for both soil types. There was no marked difference in the organic C content of the control soil and cast samples for Milson but a reduction in the casts of A. caliginosa for the Raumai soil. Finer fractions increased in the casts of both earthworm species in both soil types.     

盐渍化农田土壤斥水性与理化性质的空间变异性

通过对新疆玛纳斯县盐渍化土壤三个不同尺度(间距分别为50 m、5 m及0.5 m)的284个样点取样分析测定,采用经典统计学、空间自相关、地统计学和分形理论对土壤斥水性与理化性质进行空间格局分析。结果表明:1)土壤斥水性和pH符合正态分布,其余土壤属性符合对数正态分布。三尺度下土壤各属性绝大多数表现为中等变异水平。2)三尺度下土壤各属性的Moran s I系数变化具有相似性,在-0.8~0.6范围内波动。3)三尺度下土壤各属性的半方差函数理论模型大多数能用球状模型来拟合。4)在一定范围内,土壤各属性具有一定的分形特征,分形维数变化幅度为1.75~1.96。分析表明不同尺度下土壤斥水性与理化性质具有一定的差异。     

梁子湖湿地土壤养分的空间异质性

2003年10月利用地统计学方法对梁子湖湿地保护区内一块63.9km2区域的土壤养分的空间变异进行了研究。以400m400m的网格采集了101个表层(015cm)土壤样品。分析结果表明,土壤养分有较大的空间变异,土壤有机质、全氮、全磷、速效氮变异系数分别是36.0%、30.6%1、3.7%和29.3%;速效磷的变异系数最高为50.4%。土壤有机质、全氮、全磷、速效氮和速效磷的理论模型均为球状模型。土壤有机质、全氮、全磷、速效氮具有中等空间自相关性,随机变异分别是68.5%、68.3%、75%和71.5%;速效磷的自空间相关性较弱,变异为82.4%。5种养分的空间自相关距离比较接近,变程在2853m～963m之间。通过克里格插值进行土壤养分空间插值制图显示,土壤养分表现出空间分布的相似性。     

盐渍化农田土壤斥水性与理化性质的空间变异性

通过对新疆玛纳斯县盐渍化土壤三个不同尺度（间距分别为50m、5m及0.5m)的284个样点取样分析测定,采用经典统计学、空间自相关、地质统计学和分形理论对土壤斥水性与理化性质进行空间格局分析。结果表明：1）土壤斥水性和pH符合正态分布,其余土壤属性符合对数正态分布。三尺度下土壤各属性绝大多数表现为中等变异水平。2）三尺度下土壤各属性的Moran’s I系数变化具有相似性,在-0.8～0.6范围内波动。3）三尺度下土壤各属性的半方差函数理论模型大多数能用球状模型来拟合。4）在一定范围内,土壤各属性具有一定的分形特征,分形维数变化幅度为1.75～1.96。分析表明不同尺度下土壤斥水性与理化性质具有一定的差异。     

人工林代替天然林后土壤碳库的变化

Changes in soil carbon pools under Chinese fir (Cunninghamia lanceolata) and bamboo (Phyllostachys pubescent) plantations substituted for a native forest (Quercus acutissima, Cyclobalanopsis glauca, Cas-tanops~.s sclerophyUa, Platycarya strobilacea, Lithocarpus glaber) were studied on the hills with acid parent rock and soils classified as red soils (Ferrisols) in Huzhou, Zhejiang Province of east China. It was found that total soil organic carbon (TSOC), easily oxidisable carbon (EOC) and water-soluble organic carbon(WSOC) under bamboo plantation were increased, but microbial biomass carbon (MBC) was decreased. On the contrary, Chinese fir induced declines of all fractions of C including TSOC, EOC, WSOC and MBC.The percentages of the active fractions of soil C (EOC and WSOC) were increased in the plantations as compared to the native broad-leaved forest, but proportions of soil organic C as MBC were decreased. It could be concluded that bamboo plantation had a great ability of not only fixing C but also accelerating soil C pool cycle, improving nutrient and microorganism activity; therefore, it is a good ecosystem and could be recommended for wide development. Chinese fir would shrink the soil C pool and deteriorate sou biological fertility, so it did not benefit CO2 fixing and land sustainable utilization.     

菜田土壤养分空间变异特征

采用传统统计和地统计相结合的方法，对55hm^2菜田耕层土壤养分空间变异特征进行了研究。结果表明，土壤养分主要限制因子是N、P、K和Zn。不同土壤养分的变异情况各不相同。土壤养分速效含量一般呈斑块状分布；土壤NO3^- -N、P、K和Zn含量在空间分布上具有明显的空间相似性。土壤NO3^- -N、P、K含量分别与种菜历史及肥料用量（N、P2O5和K2O）之间均呈极显著的正相关。     

云南玉溪植烟土壤速效养分空间变异特征及应用

为探讨烟田土壤养分空间变异特征及利用空间变异进行分区管理的技术路线,以全国烤烟种植典型产区云南省玉溪市烟田土壤为例,形成土壤养分空间变异分析—空间分布—肥料养分推荐—分区配方的技术思路。基于烟区土壤养分数据,应用地理信息系统(GIS),采用地统计学方法研究烟区耕作层(0~20 cm)土壤碱解氮、有效磷和速效钾的变异特征和空间分布。以乡镇作为管理单元,依据烟田土壤肥力评价及养分管理指标体系,计算出乡镇烤烟养分管理的氮、磷、钾肥料推荐量。采用聚类分析方法,结合烤烟养分管理"核心是氮、品质元素是钾"的特点,提出玉溪烤烟养分管理5个管理分区、5个基肥配方、2个追肥配方。研究表明:玉溪烟田土壤速效养分为中等强度空间变异,拟合模型为指数模型,变异来源于结构性因素和施肥等人为因素;土壤有效磷的变异最大,高于速效钾和碱解氮,与氮肥和钾肥用量相对稳定,而磷肥相对随机等农艺措施相关;超过67%的土壤碱解氮、有效磷和速效钾含量处于高和极高水平,肥料氮、磷、钾推荐量低于云南省烤烟养分管理平均水平11%左右;提出5个烤烟养分管理分区及相应的基肥和追肥配方,以满足"大配方、小调整"原则,实现分类指导和分区管理。