Stability of the martian atmosphere

A detailed chemical dynamic model is presented for a moist martian atmosphere. Recombination of carbon dioxide is catalyzed by trace amounts of water. The abundances of carbon monoxide and molecular oxygen should vary in response to changes in atmospheric water and atmospheric mixing.     

Isotopic composition of nitrogen: implications for the past history of mars' atmosphere

Models are presented for the past history of nitrogen on Mars based on Viking measurements showing that the atmosphere is enriched in (15)N. The enrichment is attributed to selective escape, with fast atoms formed in the exosphere by electron impact dissociation of N(2) and by dissociative recombination of N(2)(+). The initial partial pressure of N(2) should have been at least as large as several millibars and could have been as large as 30 millibars if surface processes were to represent an important sink for atmospheric HNO(2) and HNO(3).     

Thermal tides in the dusty martian atmosphere: a verification of theory

Major features of the daily surface pressure oscillations observed by the Viking landers during the two great dust storms on Mars in 1977 can be explained in terms of the classical atmospheric tidal theory developed for the earth's atmosphere. The most dramatic exception is the virtual disappearance of only the diurnal tide at Viking Lander 1 just before the second storm. This disappearance is attributed to destructive interference between the usually westward-traveling tide and an eastward-traveling diurnal Kelvin mode generated by orographically induced differential heating. The continuing Viking Lander 1 pressure measurements can be used with the model to monitor future great dust storms.     

Infrared thermal mapping of the martian surface and atmosphere: first results

The Viking infrared thermal mapper measures the thermal emission of the martian surface and atmosphere and the total reflected sunlight. With the high resolution and dense coverage being achieved, planetwide thermal structure is apparent at large and small scales. The thermal behavior of the best-observed areas, the landing sites, cannot be explained by simple homogeneous models. The data contain clear indications for the relevance of additional factors such as detailed surface texture and the occurrence of clouds. Areas in the polar night have temperatures distinctly lower than the CO(2) condensation point at the surface pressure. This observation implies that the annual atmospheric condensation is less than previously assumed and that either thick CO(2) clouds exist at the 20-kilometer level or that the polar atmosphere is locally enriched by noncondensable gases.     

Composition and structure of the martian atmosphere: preliminary results from viking 1

Results from the aeroshell-mounted neutral mass spectrometer on Viking I indicate that the upper atmosphere of Mars is composed mainly of CO(2) with trace quantities of N(2), Ar, O, O(2), and CO. The mixing ratios by volume relative to CO(2) for N(2), Ar, and O(2) are about 0.06, 0.015, and 0.003, respectively, at an altitude near 135 kilometers. Molecular oxygen (O(2)(+)) is a major component of the ionosphere according to results from the retarding potential analyzer. The atmosphere between 140 and 200 kilometers has an average temperature of about 180 degrees +/- 20 degrees K. Atmospheric pressure at the landing site for Viking 1 was 7.3 millibars at an air temperature of 241 degrees K. The descent data are consistent with the view that CO(2) should be the major constituent of the lower martian atmosphere.     

Composition and structure of the martian upper atmosphere: analysis of results from viking

Densities for carbon dioxide measured by the upper atmospheric mass spectrometers on Viking 1 and Viking 2 are analyzed to yield height profiles for the temperature of the martian atmosphere between 120 and 200 kilometers. Densities for nitrogen and argon are used to derive vertical profiles for the eddy diffusion coefficient over the same height range. The upper atmosphere of Mars is surprisingly cold with average temperatures for both Viking 1 and Viking 2 of less than 200 degrees K, and there is significant vertical structure. Model calculations are presented and shown to be in good agreement with measured concentrations of carbon monoxide, oxygen, and nitric oxide.     

Temperatures of the martian surface and atmosphere: viking observation of diurnal and geometric variations

Selected observations made with the Viking infrared thermal mapper after the first landing are reported. Atmospheric temperatures measured at the latitude of the Viking 2 landing site (48 degrees N) over most of a martian day reveal a diurnal variation of at least 15 K, with peak temperatures occurring near 2.2 hours after noon, implying significant absorption of sunlight in the lower 30 km of the atmosphere by entrained dust. The summit temperature of Arsia Mons varies by a factor of nearly two each day; large diurnal temperature variation is characteristic of the south Tharsis upland and implies the presence of low thermal inertia material. The thermal inertia of material on the floors of several typical large craters is found to be higher than for the surrounding terrain; this suggests that craters are somehow effective in sorting aeolian material. Brightness temperatures of the Viking 1 landing area decrease at large emission angles; the intensity of reflected sunlight shows a more complex dependence on geometry than expected, implying atmospheric as well as surface scattering.     

Mariner 9 s-band martian occultation experiment: initial results on the atmosphere and topography of Mars

A preliminary analysis of 15 radio occultation measurements taken on the day side of Mars between 40 degrees S and 33 degrees S has revealed that the temperature in the lower 15 to 20 kilometers of the atmosphere of Mars is essentially isothermal and warmer than expected. This result, which is also confirmed by the increased altitude of the ionization peak of the ionosphere, can possibly be caused by the absorption of solar radiation by fine particles of dust suspended in the lower atmosphere. The measurements also revealed elevation differences of 13 kilometers and a range of surface pressures between 2.9 and 8.3 millibars. The floor of the classical bright area of Hellas was found to be about 6 kilometers below its western rim and 4 kilometers below the mean radius of Mars at that latitude. The region between Mare Sirenum and Solis Lacus was found to be relatively high, lying 5 to 8 kilometers above the mean radius. The maximum electron density in the ionosphere (about 1.5 x 10(5) electrons per cubic centimeter), which was found to be remarkably constant, was somewhat lower than that observed in 1969 but higher than that observed in 1965.     

Isotopic composition of neodymium in waters from the drake passage

The isotopic composition of neodymium has been determined in seawaters from the Drake Passage. The Antarctic Circumpolar Current, which controls interocean mixing, flows through this passage. The parameter epsilon(Nd)(0) which is a function of the ratio of neodymium-143 to neodymium-144, is found to be uniform with depth at two stations with a value which is intermediate between the values for the Atlantic and the Pacific and indicates that the Antarctic Circumpolar current consists of about 70 percent Atlantic water. Cold bottom water from a site in the south central Pacific has the neodymium isotopic signature of the waters in the Drake Passage. By using a box model to describe the exchange of water between the Southern Ocean and the ocean basins to the north together with the isotopic results, an upper limit of approximately 33 million cubic meters per second is calculated for the rate of exchange between the Pacific and the Southern Ocean. Concentrations of samarium and neodymium were also determined and found to increase approximately linearly with depth. These results suggest that neodymium may be a valuable tracer in oceanography and may be useful in paleo-oceanographic studies.     

Isotopic composition of rare gases in lunar samples

Data from total melt and step-by-step heating experiments on the Apollo 11 lunar samples suggest a close affinity between lunar and meteoritic rare gases. Trapped neon-20/neon-22 ratios range from 11.5 to approximately 15, resembling those for the gas-rich meteorites. Trapped krypton and xenon in the lunar fines and in the carbonaceous chondrites are similar except for an interesting underabundance of the heavy isotopes in both lunar gases which suggests that the fission component found in carbonaceous chondrites is depleted in lunar material. Spallation gases are in most cases quite close to meteoritic spallation gases in isotopic composition.     

Isotopic composition of strontium in volcanic rocks from oahu

Analysis of several well-documented specimens from each of the three volcanic series on Oahu gives the following mean ratios of Sr(87) to Sr(86): the Waianae series, 0.7030 +/- 0.00010 (sigma); the Koolau series, 0.70385+/- 0.00009 (sigma); and the Honolulu series, 0.7029 ++/- 0.00006 ( sigma). The mean ratio of Sr(87) to Sr(86) of the Koolau series specimens is significantly higher than the means of the other two series. With one exception, significant differences in Sr(87)/ Sr(86) within a series were not found, even though some large compositional differences existed.     

Isotopic composition and origin of the red sea and salton sea geothermal brines

Abstract. Deuterium and oxygen-18 measurements show that the Red Sea and Salton Sea brines are the results of a single process, the leaching of sediments by surface water circulating downward to a geothermal reservoir. The Salton Sea brine is derived from local precipitation but the Red Sea brine originates 1000 kilometers south of its basin, on the shallow sill which controls the circulation of the Red Sea. On this sill sea water penetrates a thick evaporite sequence to a depth of 2000 meters, and, driven by its increased density relative to sea water, flows northward to emerge in the brine-filled deeps.     

The martian surface

With the scarcity of factual data and the difficulty of applying crucial tests, many of the properties of the Martian surface remain a mystery; the planet may become a source of great surprises in the future. In the following, the conclusions are enumerated more or less in the order of their reliability, the more certain ones first, conjectures or ambiguous interpretations coming last. Even if they prove to be wrong, they may serve as a stimulus for further investigation. Impact craters on Mars, from collisions with nearby asteroids and other stray bodies, were predicted 16 years ago (5-7) and are now verified by the Mariner IV pictures. The kink in the frequency curve of Martian crater diameters indicates that those larger than 20 kilometers could have survived aeolian erosion since the "beginning." They indicate an erosion rate 30 times slower than that in terrestrial deserts and 70 times faster than micrometeorite erosion on the moon. The observed number, per unit area, of Martian craters larger than 20 kilometers exceeds 4 times that calculated from the statistical theory of interplanetary collisions with the present population of stray bodies and for a time interval of 4500 million years, even when allowance is made for the depletion of the Martian group of asteroids, which were more numerous in the past. This, and the low eroded rims of the Martian craters suggest that many of the craters have survived almost since the formation of the crust. Therefore, Mars could not have possessed a dense atmosphere for any length of time. If there was abundant water for the first 100 million years or so, before it escaped it could have occurred only in the solid state as ice and snow, with but traces of vapor in the atmosphere, on account of the low temperature caused by the high reflectivity of clouds and snow. For Martian life there is thus the dilemma: with water, it is too cold; without, too dry. The crater density on Mars, though twice that in lunar maria, is much smaller than the "saturation density" of lunar highlands. Many primeval craters, those from the last impacts which formed the planet, must have become erased, either by late impacts of preferentially surviving large asteroids or by a primeval atmosphere which rapidly escaped. The tenuous Martian atmosphere may have originated entirely from outgassing of surface rocks by asteroidal impacts, which also could have produced some molten lava. The role of genuine volcanism on Mars must have been insignificant, if any. The large amplitude in temperature indicates that the Martian upper soil, equally in the bright and the dark areas, is of a porous unconsolidated structure, with a thermal conductivity as low as that of atmospheric air. Limb darkening at full phase in green, yellow, and red light indicates absorption by atmospheric haze, aerosols, and dust. The loss of contrast in the blue and violet is caused by stronger absorptivity of the haze, which is almost as dark as soot, and not by a true decrease in contrast of the surface markings. Photometric measurementsin the blue reveal a residual contrast of 5 to 7 percent between the markings in 1958, invisible to the eye at a time when there was no "blue clearing." The surface brightness of the maria was surprisingly uniform in 1958 (late summer in the southern hemisphere), while the continentes showed considerable variation. In view of the spotty microstructure of the Martian surface as revealed by Mariner IV, and the lack of a sharp border between a mare and a continens, it seems that all the difference consists in the relative number of small dark and bright areas in the surface mosaic. If there is vegetation on Mars, it should be concentrated in the darkarea elements, measuring 10 to 100 kilometers. Vegetation is the best hypothesis to account for seasonal changes in the maria and for the persistence of these formations despite dust storms of global extent. Survival of vegetation in the extreme dryness of the Martian climate could depend on the low night-time temperature and deposition of hoarfrost, which could melt into droplets after sunrise, before evaporating. If not vegetation, it must be something thing specifically Martian; no other hypothesis hitherto proposed is able to account for the facts. However, the infrared bands which at one time were thought to be associated with the presence of organic matter, belong to heavy water in the terrestrial atmosphere. The conversion of a former bright area into a dark one in 1954, over some 1 million square kilometers, is the largest recorded change of this kind. Even on the vegetation hypothesis, it eludes satisfactory explanation. Relatively bright areas observed in the blue and violet in polar regions and elsewhere on the limb can be explained by a greater transparency of the atmosphere,its dust content being decreased by a downward (anticyclonic) current. The surface, of a greater reflecting power than the atmospheric smoke, then becomes visible. The sudden explosion-like occurrence of yellow or gray clouds, reducing atmospheric transparency and surface contrast, could be due to impacts of asteroids; in such a case, however, the number of unobservable small asteroids, down to 30 to 40 meters in diameter, should greatly exceed the number extrapolated from the larger members of the group. A "meteoritic" increment in numbers, instead of the asteroidal one, would be required. special observations with large Schmidt telescopes could settle this crucial question. The Martian "oases," centers of "canal" systems, could be impact creters. The canals may be real formations, without sharp borders and 100 to 200 kilometers wide, due to a systematic alignment. of the dark surface elements. They may indicate cracks in the planet's crust, radiating from the point of impact.     

Venus upper atmosphere neutral gas composition: first observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120 degrees , and to 112 K at the antisolar point.     

Venus upper atmosphere neutral composition: preliminary results from the pioneer venus orbiter

Measurements in situ of the neutral composition and temperature of the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. The presence of many gases, incluiding the major constituents CO(2), CO, N(2), O, and He has been confirmed. Carbon dioxide is the most abundant constituent at altitudes below about 155 kilometers in the terminator region. Above this altitude atomic oxygen is the major constituent, with O/CO(2) ratios in the upper atmosphere being greater than was commonly expected. Isotope ratios of O and C are close to terrestrial values. The temperature inferred from scale heights above 180 kilometers is about 400 K on the dayside near the evening terminator at a solar zenith angle of about 69 degrees . It decreases to about 230 K when the solar zenith angle is about 90 degrees .     

Carbon dioxide clathrate in the martian ice cap

Measurements of the dissociation pressure of carbon dioxide hydrate show that this hydrate (CO(2) . 6H(2)O) is stable relative to solid CO(2) and water ice at temperatures above about 121 degrees K. Since this hydrate forms from finely divided ice and gaseous CO(2) in several hours at 150 degrees K, it is likely to be present in the martian ice cap. The ice cap can consist of water ice, water ice + CO(2) hydrate, or CO(2) hydrate + solid CO(2), but not water ice + solid CO(2).