Influence of Damping on the Bending and Twisting Modes of Flax Fibre-reinforced Polypropylene Composite

The effects of damping on the bending and twisting modes of flax fibre-reinforced polypropylene composites are investigated. The laminate was manufactured by a vacuum bagging process; its dynamic behaviour was then found from the vibration measurements of a beam test specimen using an impulse hammer technique to frequencies of 1 kHz. The frequency response of a sample was measured, and the bending and twisting responses at resonance were used to estimate the natural frequency and loss factor. The single-degree-of-freedom circle-fit method and Newton’s divided differences formula were used to estimate the natural frequencies as well as the loss factors. The damping estimates were also investigated using a “carpet” plot. The results show significant variations in loss factors depending on the type of mode. The loss factor generally lies in the range of 1.7-2.2 % for the bending modes, while 4.8 % on average for the twisting modes. Numerical estimates of the response, and in particular the natural frequencies, were made using a Mechanical APDL (ANSYS parametric design language) finite element model, with the beam being discretised into a number of shell elements. The natural frequencies from the finite element analysis show reasonably good agreement (errors < 5 %) with the measured natural frequencies.     

On energy absorption capacity,flexural and dynamic properties of flax/epoxy composite tubes

In this study, energy absorption capacity, flexural and dynamic properties of flax fibre reinforced epoxy polymer composite (FFRP) tubes are investigated. The energy absorption capacity of the tubes is investigated under uniaxial compression. Flexural behaviour of the tubes is studied under four-point bending and the dynamic properties (i.e., natural frequency and damping characteristics) are evaluated by impact hammer vibration testing of the tube specimens. The damping characteristics of the tubes are determined by using both a logarithmic decrement curve and the half-peak bandwidth method. The influence of tube laminate thickness and specimen size on the mechanical properties of FFRP tubes is determined. Compressive testing indicates that the FFRP tube provides a specific absorbed energy of 22 J/g, which is close to the conventional metal energy absorption materials, i.e. stainless steel and aluminium tubes. Flexural study shows that the FFRP tube exhibits a brittle failure as similar to that of the FFRP composites in a flat-coupon tension. The load carrying capacity and deflection of the tube increase with an increase in the tube thickness. Impact loading test concludes that an increase in tube thickness leads to a reduction in natural frequency and damping ratio of the tubes. The FFRP tubes have sizedependent dynamic properties, i.e. an increase in tube size increased the natural frequency but reduced the damping ratio of the specimens remarkably. However, all FFRP tubes have high damping ratios, thus reducing the effect of dynamic loading on the structural response. Therefore, this study suggests that FFRP tubes could be used in several structural applications, i.e. in automotive as energy absorbers and in civil infrastructure as poles.     

Damping properties and transmission loss of polyurethane. II. PU layer and copolymer effect

Polyurethane (PU) layer and copolymer consisted of the different molecular weights (1000 and 2000 g/mol) of poly(propylene glycol) (PPG) were prepared. The damping and mechanical properties of these materials were compared with PU1000 made by PPG having the molecular weight of 1000 g/mol. The optimum composition of PU2000 used for PU layer and copolymer was diphenylmethane diioscynate (MDI)/propylene glycol (PPG)/butanediol (BD) (1/0.3/0.7) based on the damping and mechanical properties. The damping peak of PU copolymer was higher than those of PU layer and PU1000 in low temperature range (−30–10 °C). For application in noise reduction, the transmission loss of the mechanical vibration through solid structure was measured. PU layer and copolymer were used as a damping layer. The transmission loss of PU copolymer was more effective than those of PU layer and PU1000 in the experimental frequency range.     

A comparison of flax shive and extracted flax shive reinforced PP composites

In this study, flax shive (FS) and extracted flax shive (EFS) were fully characterized. The results showed that EFS presented lower noncellulose content, smaller porous tunnels and better thermal stability than FS. The 5 % weight loss temperature of EFS was over 200 °C, which can meet the requirements of the processing conditions for the natural fiber reinforced polymer composites. Consequently, the flax shive and extracted flax shive reinforced PP composites were prepared and characterized. It was found that the thermal stability of EFS/PP composites was better than that of FS/PP composites, and both FS and EFS behaved as nucleation agents, which could accelerate the crystallization process of PP in the composites. Mechanical test showed that EFS could be used as a reinforcing material for PP composite when compatibilizer was applied. The flexural strength and modulus of the composites containing 30 % EFS were about 8 % and 100 % higher than that of pure polypropylene, respectively.     

Mechanical properties of flax-g-poly(methyl acrylate) reinforced phenolic composites

In order to develop composites with better mechanical properties and environmental performance, it becomes necessary to increase the hydrophobicity of the natural fibers and to improve the interface between matrix and natural fibers. Graft copolymerization of natural fibers is one of the best methods to attain these improvements. Only few workers have reported the use of graft copolymers as reinforcing material in the preparation of composites. So in the present paper, we report the preparation of graft copolymers of flax fibers with methyl acrylate (MA) using Fenton’s reagent (FAS-H₂O₂) as redox system. Synthesized flax-g-poly(MA) was characterized with FTIR, TGA/DTA, scanning electron microscopy (SEM), and X-ray diffraction (XRD) techniques. Composites were prepared using flax-g-poly(MA) as a reinforcement and phenolformaldehyde (PF) as the binding material. Mechanical properties of phenol-formaldehyde composites were compared and it has been found that composites reinforced with flax-g-poly(MA) showed improvement in mechanical properties. Composites reinforced with flax-g-poly(MA) showed better tensile strength (235 N) and compressive strength (814 N) in comparison to composites reinforced with original flax fiber which showed lesser tensile strength (162 N) and compressive strength (372 N). Composites reinforced with flax-g-poly(MA) shows the improved MOR, MOE, and SP.     

Evaluation of flax accessions for high value textile end uses

Due to recent changes in EC subsidies for flax cultivation it has been difficult to grow short fibre flax profitably in the UK. The Texflax project aimed to demonstrate that high quality flax fibre can be produced and processed on short fibre cotton spinning systems. Initially 92 flax accessions were cultivated on test sites in the UK over three growing seasons to explore the range of fibre diameter found in fibre flax. The efficacy of applying a translocating herbicide at different stages of plant maturity for optimum fine fibre production was explored. A range of factors indicated that application at the midpoint of flowering stage is favourable for the desiccation of flax and onset of retting. Fibre was caustic extracted using a laboratory method developed at De Montfort University, and fibre evaluated in terms of diameter, length, consistency and cleanliness. At the end of the project five accessions from the original 92 were chosen as producing optimal quality fibre suitable for high value textile end uses. Improved agronomy and subsequent processing enabled yarns with a 50:50 cotton:flax blend to be spun at 26 N m yarn count, the normal blend ratio for this count being 70:30. The yarn properties show an improvement when compared to standard products and finer quality fabrics have been prepared using the yarns.     

High resin content natural matrix–natural fibre biocomposites

Composites of good performance formed from non-woven mats of flax and hemp fibres and natural resin matrices have been prepared. Both higher density thin composites as well as lower density thicker composites have been prepared. Two natural matrices types were used: (i) commercial mimosa flavonoid tannin extract with 5% hexamine added as hardener and (ii) a mix of mimosa tannin + hexamine with glyoxalated organosolv lignin of low molecular weight, these two resins mixed 50/50 by solids content weight. The composites prepared were tested for MOE in bending and in tension and for maximum breaking strength in tension. Some of the mats were corona treated and the optimum length of corona treatment determined to improve the composites MOEs and breaking strength. These were related to the morphology of the treated fibre. Thermomechanical analysis (TMA), Brinell surface hardness and contact angle tests were also carried out with good results. The composites made with the mix of tannin and lignin resins as a matrix remained thermoplastic after a first pressing. The flat sheets prepared after the first pressing were then thermoformed into the shape wanted.     

A method of estimating the single flax fibre fineness using data from the LaserScan system

This paper establishes a new method for estimating the single flax fibre diameter using the LaserScan instrument. The method is based on the mathematical modelling of the experimental fibre and fibre bundle width distribution and enables the flax fibre sample composition to be analysed in terms of proportions of single fibre and fibre bundles. The method can also be applied for the analysis of flax fibre fineness distribution produced by the Optical Fibre Diameter Analyser (OFDA) instrument. This method can be used as a tool for classification of flax accessions according to the estimated single fibre diameter, for evaluation of the efficiency of chemical and biochemical treatments aimed at the modification of flax fibre, and for evaluation of the suitability of flax fibre for spinning and manufacture of composites. The method was applied for the characterisation of 83 accessions from the Linum core collection produced by CGN at Wageningen, The Netherlands. The mean and standard deviation of single fibre diameter and proportion of single fibre and fibre bundles in the sample was estimated. Experimental results were in good agreement with theoretically expected relationships between the estimated mean diameter of single fibre and characteristics of fibre width distribution such as the mode and the overall average.     

赤霉素对亚麻纤维发育及产量的影响

在亚麻纤维的快速生长期，向叶片喷施不同浓度的赤霉素溶液，随着亚麻植株的生长，观察其纤维发育情况，通过对获得数据进行分析，证明赤霉素对亚麻纤维的生长及产量具有较大影响，可使亚麻纤维产量得到显著提高。     

Analysis of deflection and dynamic plant characteristics of Cyperus malaccensis Lam

ABSTRACT

In this study, flexural rigidity, natural frequency, and damping coefficient of Cyperus malaccensis Lam. with long stems were measured for application for fluid–structure interaction simulation in a field. Numerical solutions of deflection and natural frequency were calculated by ANSYS with finite element method (FEM). The triangular cross-section shape of C. malaccensis stem has a big neighbourhood of the root and the cross-section has taper structure to become small towards tip direction. Two numerical simulation models for FEM have Model A with a triangular prism shape and Model B with a truncated trigonal pyramidal shape to evaluate the effects of stem tapering. Because of large C. malaccensis stem deflection, an equation for nonlinear deflection was introduced to solve a problem regarding flexural rigidity. Natural frequencies of the stem were estimated using amplitude ratio during stem swinging by forced vibration, captured using a high-speed camera. The Model B corresponded with the measurement, and the results suggested that the stem characteristics were affected by cross-section shape. Damping coefficient was calculated using free vibration response, which was consistent with the analytical solution and numerical data calculated using measured characteristics.     

Elasticity, microstructure and thermal stability of foliage and fruit fibres from four tropical crops

A comparative analysis of the elasticity, microstructure and thermal stability of fibres (thickness ranging from 43.4 to 189.4 µm) isolated from pineapple leaves (PALF), coconut coir (COIR), banana leaf-stem (BAN) and oil palm empty fruit bunch (OPEFB) reported in this study. Statistical analysis of the mechanical properties derived from tensile test to rupture reveals significant differences (P<0.05) in the fibre strength (σ), stiffness (E) and extensibility (parameterized by the strain to rupture, ?). It is observed that COIR fibres yield the smallest strength, σ (=99.8±22.5 MPa), and stiffness, E (= 0.5±0.1 GPa), while PALF fibres yield the largest σ (=639.5±301.6 MPa) and E (=7.1±3.1 GPa); PALF fibres exhibit the smallest ? (=0.11±0.03) but OPEFB fibres yield the largest ? (=2.0±1.3). From scanning electron micrographs, it is observed that cellulose fibril rupture predominates in OPEFB, COIR and BAN fibres; a large proportion of the cellulose fibrils fail by pullout in PALF fibres. Thermogravimetric analysis reveals that all fibres are thermally stable up to 250 °C; the fibre residue ranges from 30 to 80 wt% after heating to 500 °C. In particular, BAN experiences the highest weight loss and PALF experiences the lowest weight loss. The findings lend to a simple approach for determining the performance of the composites by assessing the type of natural fibres for reinforcing polymeric matrices.     

一种估测亚麻出麻率的简便方法

统计分析显示亚麻茎中段的出麻率与单株出麻率相关极显著，可以在育种的单株选择过程中，利用茎中段的出麻率来快速估算单株出麻率，以减轻工作量，提高工作效率。     

The effect of gelation and curing temperatures on mechanical properties of pultruded kenaf fibre reinforced vinyl ester composites

Process parameters such as gelation and curing temperatures are parameters that influence the pultruded kenaf reinforced vinyl ester composites profile quality and performance. The effect of gelation and curing temperatures on mechanical (tensile, flexural and compression properties) and morphological properties of pultruded kenaf reinforced vinyl ester composites were analyzed. Obtained results indicated that increase of gelation and curing temperatures during the pultrusion process of kenaf reinforced vinyl ester composites influenced the mechanical properties of the composites. When the gelation and curing temperatures were increased, tensile strength, tensile modulus, flexural strength, flexural modulus and compressive strength were affected and they were either increased or decreased. The factors that influenced these results include improper curing, excessive curing, water diffusion, and the problems associated with interfacial bonding between fibre and matrices. The optimum values of the tensile strength for gelation and curing temperatures of kenaf pultruded composites were at 100 °C and 140 °C, tensile modulus at 80 °C and 180 °C, flexural strength at 100 ° and 140 °, flexural modulus at 120 ° and 180 °, and compressive strength at 120 °C and 180 °C, respectively. The scanning electron micrographs of tensile fractured samples clearly show that with the increase in gelation temperature, it creates the lumens between matrix and kenaf fibre thus reducing tensile properties whereas increasing the curing temperature caused less fibre pull out and enhanced fibre/matrix interfacial bonding.     

一种估测亚麻出麻率的简便方法

统计分析显示亚麻茎中段的出麻率与单株出麻率相关极显著 ,可以在育种的单株选择过程中 ,利用茎中段的出麻率来快速估算单株出麻率 ,以减轻工作量 ,提高工作效率。     

Synthesis of polypropylene carbonate polyol-based waterborne polyurethane modified with polysiloxane and its film properties

Waterborne polyurethane (WPU) prepolymer was synthesized using polypropylene carbonate polyol as the soft segment, dimethylolpropionic acid as a hydrophilic chain extender and isophorone diisocyanate. The prepolymer was modified with aminoethyl aminopropyl dimethicon (AEAPS) to prepare a series of WPU emulsions and films. The structures and the films properties of the WPUs were characterized by Fourier transform infrared spectrometry, gel permeation chromatography, atomic force microscopy, X-ray diffraction, thermogravimetric analysis, dynamic thermomechanical analysis, X-ray photoelectron spectroscopy, water contact angles and water absorption. It was found that pure polypropylene carbonate WPU had a wide molecular weight distribution and its microphase separation was not apparent between its hard and soft segments. The WPU also had a high glass transition temperature (24.5 °C) and its film had a high damping property (tan δ>0.40) from 12 °C to 42 °C. Modification with polysiloxane had enlarged the molecular weight, narrowed the molecular weight distribution and resulted in the microphase separation between the hard and soft segments of WPUs, and this amplified the damping temperature of the WPU films. Along with the increasing utilization of polysiloxane the thermolysis, water resistance and water contact angles of WPU films were improved while the orientation of their structure regularity declined.     

Tear properties and meso-scale mechanism of multi-axial warp-knitted fabric from various architectures: Studied by photography

Tear properties tests of three kinds of multi-axial warp-knitted (MWK) fabric: triaxial fabrics (?45 °/90 °/+45 ° and ?45 °/0 °/+45 °) and biaxial fabric (?45 °/+45 °) were respectively implemented along the orientations of 0 °, 45 ° and 90 °. Load-displacement curves were well obtained. The high-speed camera was employed to observe the whole tear damage process and series of still images were picked up to analyze the meso-scale mechanism of the extension and displacement of tows on oriented layers. The results indicated the tear properties of MWK fabric are closely related to the orientations of the layers and the deformation mechanism of the layers. Stitching yarns incarnated significant effects in restricting the deformation procedures of tows.     

Application of reactive UV-absorbers for increasing protective properties of cellulose fabrics during standard laundering process

A number of water-soluble colourless fibre-reactive UV-absorbers derivatives of symmetrical triazine were used as additives during commercial laundering process. UV-protection factor (UPF) of such treated cotton tricot samples was measured. Changes in protection properties of modified textiles after repeated standard laundering process were determined. Carried-out experiments gave evidence of covalent bond formation between applied absorbers and cellulose fibre during standard washing process at 40 °C or 60 °C. Textiles modified by this method have provided UV-protective properties for prolonged time.     

Physical and chemical properties of flax fibres from stand-retted crops desiccated at different stages of maturity

Dessication of flax at the mid-point of flowering, followed by stand-retting and high-speed decortication, yielded finer, stronger fibres with lower acid-insoluble lignin content and lighter colour than desiccation at later timings of two weeks after mid-flower and six weeks after mid-flower. Although fibres from all desiccation timings could be carded and blended with wool for spinning on woollen or worsted spinning systems, only the fine fibre from the earliest desiccated flax was suitable for carding, drawing, blending with cotton and spinning on cotton-processing systems.It was concluded that the lower lignin content at mid-flower allowed more complete retting of fibre bundles to give a higher yield of fine elementary fibres. This cotton-compatible fibre was produced at a competitive cost compared with cotton. It is suggested that further optimisation of desiccation timing may permit increased yields of cotton-compatible fibre.     

环境条件对亚麻纤维品质的影响

品种区域试验结果显示,黑龙江省不同地区的气候、土壤环境条件差异极大,亚麻纤维强度在不同(区域)间、品种间和两者的互作均达到极显著水平,因此有必要对黑龙江省亚麻(种植)进行优质区划,选择适宜的品种在适宜的区域种植,全面提高黑龙江省亚麻纤维的品质。相关分析表明,土壤缓效钾和速效钾含量与纤维强度和可挠度均呈正相关,其它指标与两个品质指标间呈负相关。土壤全磷和速效磷含量与可挠度呈显著负相关,速效磷与纤维强度呈较大的负相关,有机质含量、全氮含量与之呈较大的正相关,二者与可挠度呈负相关。3个品种的纤维强度与开花前后的气象因子的关系比较复杂,开花前日照时数与强度负相关;开花后较多的积温、日照时数和降雨量有利于提高纤维的纤维强度和可挠度。     

旱地胡麻同化物积累和分配与产量形成对轮作模式的响应

合理轮作对作物生产有积极的促进作用.为明确不同轮作模式和前茬作物对旱地胡麻生长发育和籽粒产量的影响,通过田间长期定位试验,研究了胡麻-胡麻-胡麻-胡麻(FFFF)、胡麻-小麦-马铃薯-胡麻(FWPF)、胡麻-马铃薯-胡麻-小麦(FPFW)、胡麻-胡麻-小麦-马铃薯(FFWP)、胡麻-小麦-胡麻-马铃薯(FWFP)和胡麻...