一种溶质运移数学模型的应用研究

土壤中溶质运移的过程、规律和机理是土壤溶质运移研究的主要内容。本文的目的是对模拟非饱和介质中水分和溶质迁移的二维数值模型SWMS－2D进行研究和验证。以硝酸盐形式存在的溶解氮是地下水中最常见的污染物，将硝态氮视为土壤溶质，考虑其根系吸收、生物固持、吸附、解吸、硝化和反硝化等作用，土壤表面即上边界条件用大气边界条件描述，下边界条件定为第一类边界条件，在田间条件下对模型作了检验。     

畦灌施肥条件下地表水流溶质运移模型研究

以零惯性量模型作为畦灌施肥水流模型,一维的对流扩散方程ADE作为地表溶质运移方程,分别采用隐式格式有限差和特征线法分别进行数值求解,建立了畦灌施肥地表溶质运移模型,并利用田间试验数据对模型进行了试验验证,以期为实现畦灌施肥技术参数优化组合提供合理可行的模型工具.研究结果显示:建立的畦灌施肥地表溶质运移模型是合理可行的,可作为畦灌施肥技术要素优化组合的模拟工具.     

农田生态系统中的物质迁移研究进展

农田生态系统中的物质迁移涉及了系统中各部分水分、溶质、养分及侵蚀过程中泥沙的运动,在农业、水资源、环境等领域都起着重要的作用,一直是人们关注的焦点。对近年来国内外农田生态系统中的水分、溶质和养分迁移的研究工作进行了评述,并指出了需进一步研究的问题。     

Modelling the kinetics of ethyl formate sorption by wheat using batch experiments

BACKGROUND: Ethyl formate formulations are being considered to replace methyl bromide for fast grain disinfestation. Grain adsorbs ethyl formate rapidly, which can result in inadequate fumigation concentrations and unacceptable grain residues. A model of ethyl formate sorption kinetics will enable fumigation approaches to be determined that meet disinfestation and food safety requirements. RESULTS: This paper identifies all mass transport processes involved in ethyl formate sorption by wheat from published and experimental evidence. The model accounts for reaction losses of ethyl formate in air and grain using first‐order kinetics, transport in the gas and solid phases with linear mass transfer coefficients and uses a linear partition relationship representation of sorption equilibrium. Batch experimental data were measured to determine model coefficients. Novel gaseous breakdown data for ethyl formate in air were measured, and first‐order kinetics was demonstrated, although the specific reactions involved were not identified. CONCLUSION: The model predicts air and grain fumigant concentrations relevant for grain disinfestation and food residue contamination successfully. The form of the model should be applicable to all fumigant–grain systems, as it accounts for the diffusion and reaction influences known to occur with all modern fumigants under concentration and exposure conditions relevant to industry. Copyright © 2009 CSIRO, Australia. Published by John Wiley & Sons, Ltd.     

Recent developments in our understanding of the plant cuticle as a barrier to the foliar uptake of pesticides†

The plant cuticle is a highly complex membrane which forms the outer surface of the aerial portion of plants. The nature of the plant cuticle is reviewed with particular regard to its action as a potential barrier to the penetration of pesticide molecules; the role of the cuticular waxes is highlighted. The physicochemical properties of the cuticle influence the behaviour of spray droplets and, in turn, may affect the rate and efficiency of cuticle penetration. The permeation of active ingredients is influenced by their solubility characteristics as indicated by octanol/water (log K_ow) and cuticle/water (K_cw) partition coefficients. Penetration of hydrophilic compounds (low log K_ow) may be enhanced by hydration of the cuticle, while transcuticular transport of non-polar solutes (high log K_ow) is increased by factors which reduce wax viscosity. The use of in-vitro models involving isolated cuticle membranes, isolated cuticle waxes, or isolated leaves has helped to focus on the activities of the cuticle in the absence of other physiological factors. Using these systems, the role of the waxes as a transport-limiting barrier has been identified and the factors influencing sorption, permeance and desorption examined. The action of surfactants, in vitro and in vivo, has been briefly addressed in regard to their role in facilitating cuticle penetration; other steps involving surfactant/solute/cuticle are complex, and synergy appears to depend on a number of factors including test species, concentration of active ingredient, surfactant type and concentration. Adjuvants may greatly influence the surface properties of the droplet, predispose the cuticle to solute transport, and enhance pesticide activity. The nature of these complex inter-relationships is discussed. © 1999 Society of Chemical Industry     

层状土壤水盐动态研究与分析

针对我国西北地区土壤剖面多呈层状结构和土壤的盐渍化面积逐年增加的实际情况,概述了国内外入渗和蒸发条件下非均质层状土壤水盐运移的研究动态,总结了其主要研究成果,明晰了成果之间的相互关系及其实际应用价值,探讨了研究中目前存在的主要问题,为灌溉和排水等措施的拟定以及进一步的研究提供参考信息。     

土壤水动力学模型在SPAC系统中应用研究进展

从土壤水动力学典型的裸地蒸发模型、蒸发蒸腾量模型、土壤水分入渗模型出发,综述了SPAC系统下国内外现行的植物根系吸水模型、溶质运移模型、农业生态系统模型等研究进展,归纳和讨论了目前土壤水动力学模型在SPAC系统建模中存在的问题与不足。并对该领域的研究方向和应用前景进行了展望：建立准确的数值模型来解决实际问题是蒸发蒸腾量模型未来研究的趋势;入渗模型从点至区域的动态扩展,并结合土壤侵蚀、污染物运移等因素的农业倾向性研究为潜在的重要分支方向;根系吸水模型应更多被用于监测土壤水分动态、设计合理的灌溉制度及干旱预警等体系;利用计算机、遥感等技术手段建立农业生态系统物能循环的机理性模型将为模型的实用性和精度提供有力支撑。     

非线性扩散和变分模型在矢量图像去噪中的应用

分析了非线性扩散、基于整体变分方法的ROF模型以及矢量图像耦合技术的原理,比较了这些扩散、去噪模型的优缺点。根据矢量图像耦合思想将TV流运用到矢量图像扩散中,并参考ROF模型逼近项变分模型的优点,提出了基于非线性扩散、ROF模型和矢量图像耦合原理的改进TV流矢量图像耦合扩散模型,目地是在彩色图像中,去噪同时更好地保留图像轮廓、边缘等重要信息。实验对比分析了改进前后模型的去噪效果,并分析了改进模型下正、逆向扩散在彩色图像去噪中的作用。实验结果表明,改进的矢量图像耦合扩散模型能有效地保持彩色图像中的边缘信息,同时具有良好的去噪性能,且改进模型下,正、逆向扩散的性质在彩色图像去噪工作中仍能保持。     

Testing MACRO (version 5.1) for pesticide leaching in a Dutch clay soil

Testing of pesticide leaching models against comprehensive field-scale measurements is necessary to increase confidence in their predictive ability when used as regulatory tools. Version 5.1 of the MACRO model was tested against measurements of water flow and the behaviour of bromide, bentazone [3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide] and imidacloprid [1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine] in a cracked clay soil. In keeping with EU (FOCUS) procedures, the model was first calibrated against the measured moisture profiles and bromide concentrations in soil and in drain water. Uncalibrated pesticide simulations based on laboratory measurements of sorption and degradation were then compared with field data on the leaching of bentazone and imidacloprid. Calibrated parameter values indicated that a high degree of physical non-equilibrium (i.e. strong macropore flow) was necessary to describe solute transport in this soil. Comparison of measured and simulated bentazone concentration profiles revealed that the bulk of the bentazone movement in this soil was underestimated by MACRO. Nevertheless, the model simulated the dynamics of the bentazone breakthrough in drain water rather well and, in particular, accurately simulated the timing and the concentration level of the early bentazone breakthrough in drain water. The imidacloprid concentration profiles and its persistence in soil were simulated well. Moreover, the timing of the early imidacloprid breakthrough in the drain water was simulated well, although the simulated concentrations were about 2-3 times larger than measured. Deep groundwater concentrations for all substances were underestimated by MACRO, although it simulated concentrations in the shallow groundwater reasonably well. It is concluded that, in the context of ecotoxicological risk assessments for surface water, MACRO can give reasonably good simulations of pesticide concentrations in water draining from cracking clay soils, but that prior calibration against hydrologic and tracer data is desirable to reduce uncertainty and improve accuracy.     

Solute transport characteristics of a deep soil profile in the Loess Plateau,China

Understanding solute transport behaviors of deep soil profile in the Loess Plateau is helpful for ecological construction and agricultural production improvement. In this study, solute transport processes of a deep soil profile were measured by a conservative tracer experiment using 25 undisturbed soil cores(20 cm long and 7 cm diameter for each) continuously sampled from the surface downward to the depth of 500 cm in the Loess Plateau of China. The solute transport breakthrough curves(BTCs) were analyzed in terms of the convection-dispersion equation(CDE) and the mobile-immobile model(MIM). Average pore-water velocity and dispersion coefficient(or effective dispersion coefficient) were calculated using the CDE and MIM. Basic soil properties and water infiltration parameters were also determined to explore their influence on the solute transport parameters. Both pore-water velocity and dispersion coefficient(or effective dispersion coefficient) generally decreased with increasing depth, and the dispersivity fluctuated along the soil profile. There was a good linear correlation between log-transformed pore-water velocity and dispersion coefficient, with a slope of about 1.0 and an average dispersivity of 0.25 for the entire soil profile. Generally speaking, the soil was more homogeneous along the soil profile. Our results also show that hydrodynamic dispersion is the dominant mechanism of solute transport of loess soils in the study area.     

Evaluation of groundwater sustainability based on groundwater age simulation in the Zhangye Basin of Heihe River watershed,northwestern China

Water resources, as the primary limiting factor, constrain the economic and social development in arid inland areas. The Zhangye Basin is a representative area of inland river basins, which is located in the middle parts of the Heihe River watershed, northwestern China. Facing with the huge water shortage, people exploited ground- water at a large scale in recent years. The reducing recharge from surface water and over-exploitation of ground- water led to the decline of groundwater levels and threatened the sustainability of water resources. This study con- structed a conceptual and numerical groundwater flow model and calibrated the model based on the observed wells. A solute transport model was built using MT3DMS to calculate the groundwater age distribution in the Zhangye Basin. The simulated result shows that the youngest groundwater is distributed near the most upstream areas in the model domain, which is less than 1,000 a, older groundwater is distributed in deeper parts of the aquifer and near the discharge outlets, ranging from 6,000 a to over 20,000 a. Spatial variation of groundwater ages in the middle area indicates the recharge diversity between unconfined and confined aquifer. Groundwater age can serve as an indicator to evaluate groundwater’s renewal capacity and sustainability. The formation of groundwater resources in the lower stream area would spend 10,000 a or even more than 20,000 a, so exploitation of groundwater in these areas should be restrained.     

Comparisons of simulated with measured transport and transformation of methyl bromide gas in soils

A simulation model is described for the transport of the fumigant, methyl bromide gas, away from injection chisels within the field. The injected methyl bromide is assumed to form cylindrical, parallel sources at the depth of injection. Transport of the methyl bromide is described by radial diffusion from the injection cylinders. The dissolution-distillation of methyl bromide gas in the soil water and on soil particles is accounted for by a first-order reversible kinetic equation or by an equilibrium relationship. The hydrolysis of methyl bromide gas to bromide anion is considered to occur according to a first-order irreversible equation. The model considers cases where the soil surface is and is not covered with an impermeable barrier to the diffusion of the gas. Simulated methyl bromide concentrations in the soil air, and bromide concentrations in the soil, compared reasonably well with measured values from several field sites. Comparison of the results of calculations, with and without plastic barriers at the soil surface, with experimental data, indicate that plastic barriers are ineffective in preventing diffusion of gas from the soil to the atmosphere. Calculations of mass balances show that as much as 70% of the applied methyl bromide had escaped to the atmosphere by 14 days after fumigation.     

Field leaching of pesticides at five test sites in Hawaii: modeling flow and transport

BACKGROUND: Physically based tier‐II models may serve as possible alternatives to expensive field and laboratory leaching experiments required for pesticide approval and registration. The objective of this study was to predict pesticide fate and transport at five different sites in Hawaii using data from an earlier field leaching experiment and a one‐dimensional tier‐II model. As the predicted concentration profiles of pesticides did not provide close agreement with data, inverse modeling was used to obtain adequate reactive transport parameters. The estimated transport parameters of pesticides were also utilized in a tier‐I model, which is currently used by the state authorities to evaluate the relative leaching potential. RESULTS: Water flow in soil profiles was simulated by the tier‐II model with acceptable accuracy at all experimental sites. The observed concentration profiles and center of mass depths predicted by the tier‐II simulations based on optimized transport parameters provided better agreements than did the non‐optimized parameters. With optimized parameters, the tier‐I model also delivered results consistent with observed pesticide center of mass depths. CONCLUSION: Tier‐II numerical modeling helped to identify relevant transport processes in field leaching of pesticides. The process‐based modeling of water flow and pesticide transport, coupled with the inverse procedure, can contribute significantly to the evaluation of chemical leaching in Hawaii soils. Copyright © 2011 Society of Chemical Industry     

干旱区稳定蒸发条件下土壤盐溶质迁移的动态预测

<正> 1.导言土壤盐碱化是世界干旱区共同性的问题,也是人类遇到的最古老的环境问题。近30年来,迫于人口压力和食物需求,许多容易开发的土地均已得到利用,人们正在将注意力转向干旱区。由于干旱区自身的特征,土地开发和盐渍化防治,在强烈蒸发条件下土壤盐溶质浓度目标C(Z,t)及迁移预测已成为近代土壤—水环境研究热点之一,成为中国北     

基于HYDRUS模型的盐碱地土壤水盐运移模拟

为了解陕西卤泊滩盐碱地的水盐运移情况,基于当地2009—2013年田间水盐监测资料,应用饱和-非饱和土壤水分及溶质运移理论,利用HYDRUS-1D数值模型对当地土壤水分、盐分运移规律进行数值模拟,分析了盐碱地的水盐变化状况,确定合理的田间灌水定额。结果表明:在玉米整个生育期内,不同灌溉处理的土壤含水量变化趋势基本一致,从节水控盐的综合标准衡量,农田灌水定额为500 m3·hm-2时有利于控制土壤盐分的累积。采用HYDRUS-1D模型对盐碱地农田土壤水盐运移的模拟结果与田间试验实测结果基本吻合,该研究结果可为类似盐碱化地区农田水盐管理提供科学依据。     

土壤水与地下水溶质运移联合模型

土壤水溶质运移模型着重解决入渗与蒸发条件下盐份在非饱和含水层中的垂向运移问题 ,地下水溶质运移模型着重解决盐份在饱和含水层中的横向运移问题 ,它们都不能全面描述区域盐份迁移的规律。分别建立地下水、土壤水的溶质运移模型子系统 ,耦合集成并进行联合运行是理想的解决方案。     

Application of the Root Zone Water Quality Model (RZWQM) to pesticide fate and transport: an overview

Pesticide transport models are tools used to develop improved pesticide management strategies, study pesticide processes under different conditions (management, soils, climates, etc) and illuminate aspects of a system in need of more field or laboratory study. This paper briefly overviews RZWQM history and distinguishing features, overviews key RZWQM components and reviews RZWQM validation studies. RZWQM is a physically based agricultural systems model that includes sub-models to simulate: infiltration, runoff, water distribution and chemical movement in the soil; macropore flow and chemical movement through macropores; evapotranspiration (ET); heat transport; plant growth; organic matter/nitrogen cycling; pesticide processes; chemical transfer to runoff; and the effect of agricultural management practices on these processes. Research to date shows that if key input parameters are calibrated, RZWQM can adequately simulate the processes involved with pesticide transport (ET, soil-water content, percolation and runoff, plant growth and pesticide fate). A review of the validation studies revealed that (1) accurate parameterization of restricting soil layers (low permeability horizons) may improve simulated soil-water content; (2) simulating pesticide sorption kinetics may improve simulated soil pesticide concentration with time (persistence) and depth and (3) calibrating the pesticide half-life is generally necessary for accurate pesticide persistence simulations. This overview/review provides insight into the processes involved with the RZWQM pesticide component and helps identify model weaknesses, model strengths and successful modeling strategies.