The fate of soyabean photosynthetic carbon varies in Mollisols differing in organic carbon

The fate of photosynthetically‐fixed carbon (C) in the plant–soil–microbe continuum has received much interest because of its relevance to soil C and the global C cycle. However, information on the flow of this plant C below ground and its contribution to soil C sequestration in soils with contrasting organic C (C_org) is limited. In this study, soyabean (Glycine max L. Merr.) was grown in three Mollisols with low (1.04%), medium (2.90%) and high (5.05%) C_org, respectively. Plants were labelled with ¹³CO₂ to trace the photosynthetic C dynamics in the plant–soil system for up to 288 hours. The total amount of net fixed ¹³C by plants ranged from 66 to 78 mg pot^?1, and there was no difference between soils. The amount of ¹³C in soil organic matter (SOM) increased from 1.9 to 6.1 mg pot^?1 over time in the high‐C_org soil, while it showed a non‐significant change with 2.2 mg pot^?1 (on average) in the medium‐C_org soil, and decreased from 2.9 to 0.1 mg pot^?1 in the low‐C_org soil. In the low‐C_org soil, the amount of ¹³C in soil microbes decreased markedly over time, showing a fast turnover, and had a significant correlation (P ≤ 0.01) with ¹³C in the SOM pool. However, such a relationship was not significant in the soil with high or medium C_org. These results indicate that most of the root‐derived C in the low‐C_org soil is degraded quickly by microbial activity, while the greater input of the photosynthetic C to SOM in the high‐ and/or medium‐C_org soil can probably be attributed to physical sorption of root‐derived C by SOM and minerals, thus protecting it against microbial decomposition.     

Indications for soil organic matter quality in soils under different management

Changes in management practice are reflected by soil carbon and nitrogen status, in particular by the proportion of soil organic matter (SOM) being easily transformed (active SOM). We describe SOM quality for three management practices, Organic Farming system (OF), Integrated Crop Production (ICP) and pasture sites (G), which intend to achieve sustainable management practice. The experimental sites were conventionally farmed until 1992. SOM quality was examined by describing active SOM pools, such as the decomposed ‘young soil organic matter’ (YSOM), ratio of microbial biomass carbon (C_mic) to organic carbon (C_org), ecophysiological status of the microbial biomass (qCO₂), and the ratio of light particulate organic matter (POM-LF) to C_org. Ratios of soil microbial biomass (C_mic/C_org) and POM-LF (POM-LF/C_org) and the amount of decomposed YSOM were relatively similar to each other, despite differences in management practice and soil texture. Soil microbial parameters (C_mic, C_mic/C_org and qCO₂) were significantly (p<0.05) affected by the amount of decomposed YSOM and the silt content in the OF. In the ICP, soil microbial parameters depended only on the amount of decomposed YSOM, which was considered to be a consequence of the more heterogeneous texture at the OF-sites. Management effects were detectable for no-tillage in the ICP leading to an accumulation of active SOM in the surface soil (0–10 cm). The ratio POM-LF/C_org showed no difference between G and OF despite markedly higher C_org-contents at the G-sites. Conclusively, all methods used indicate comparable SOM qualities for the three management systems, despite differences in soil texture and soil management during 7 years. Management practices seem to be well adapted to the site conditions.     

Turnover of soil organic matter (SOM) and long-term balances — tools for evaluating sustainable productivity of soils

Using data from long-term experiments at the Loess-Chernozem site, Bad Lauchstädt und 12 other European sites, the carbon (C) and nitrogen (N) dynamics in soils, the determination of decomposable soil organic matter (SOM), the effect on yield of SOM as well as carbon and nitrogen balances are discussed. Both C and N in SOM have to be divided into an inert and a decomposable fraction. The inert C is strongly correlated with clay content, while most changes in both C and N occur in the readily decomposable fraction. In the experiments considered the latter ranges between 0.2 to 0.6% C and 0.02 to 0.06% N. The annual changes of the C_org content amount only to about 0.01% C_org corresponding to 500 kg/ha, even under extreme changes of the fertilizing system. Hot water extractable C (C_hwe) has proved to be an appropriate criterion for the calculation of the decomposable C and thus for the N release from soil. Different methods to maintain a SOM balance are compared and first guideline values for an agronomically and ecologically justified SOM content of arable soils are recommended. In arable soils the exceeding of an upper C_org value influences neither crop yield nor the C and N balance in a positive way. In terms of ecology and environment, set-aside-programmes or fallows in a crop rotation affect the balances negatively. Atmospheric N deposition can amount to about 50 kg/ha·yr.     

Determination of the fate of C labelled maize and wheat rhizodeposit-C in two agricultural soils in a greenhouse experiment under C-CO2-enriched atmosphere

A deeper understanding of the contribution of carbon (C) released by plant roots (rhizodeposition) to soil organic matter (SOM) can help to increase our knowledge of global C-cycling. These insights can eventually lead to sustainable management of SOM especially in agricultural systems. This study was conducted to determine the fate of ¹³C labelled rhizodeposit-C of maize and wheat plants. They were grown in a greenhouse in permeable nylon bags filled with upper soil material from two agricultural soils of the same location, but with different crop yields. The bags were placed into pots, which were also filled with soil surrounding the bags. Soil inside the bags was considered as rhizosphere soil, wheras the one outside the bags represented bulk soil. The contributions of rhizodeposits to water extractable organic carbon (WEOC), microbial biomass-C (MB-C), CO₂-C evolution, and total organic carbon (C_org) were investigated during a 7-week growing period. The WEOC, MB-C, CO₂-C, C_org contents and the respective δ¹³C values were determined regularly, and a newly developed method for determining δ¹³C values in soil extracts was applied.In both soils, regardless of crop yield potential, significant incorporation of rhizodeposition-derived C was observed in the MB-C, CO₂-C, and C_org pool, but not in the WEOC. The pattern of C incorporation into the different pools was the same for both soils with both plants, and rhizodeposit-derived C was recovered in the order MB-C<C_org<CO₂-C. This showed that rhizodeposits were mainly respired, but since C_org was the second largest pool of the overall balances, they were also stabilized in the soils at least in the short term. It is suggested that the increased SOM mineralization observed in this study (positive priming effects) was probably induced by C exchange processes between the soil matrix and soluble rhizodeposits. Moreover, soluble rhizodeposit-C was detected in MB-C and CO₂-C evolved outside the direct root zone, showing the availability of these C-components in the bulk soil.     

The molecular composition of soil organic matter as determined by 13C NMR and elemental analyses and correlation with pesticide sorption

Although the chemical composition of soil organic matter (SOM) is known to significantly influence sorption of pesticides and other pollutants, it has been difficult to determine the molecular nature of SOM in situ. Here, using ¹³C nuclear magnetic resonance (NMR) data and elemental composition in a molecular mixing model, we estimated the molecular components of SOM in 24 soils from various agro‐ecological regions. Substantial variations were revealed in the molecular nature of SOM. As a proportion of soil carbon the proportion of the carbonyl component ranged from 0.006 to 0.05, charcoal from 0 to 0.15, protein from 0.09 to 0.29, aliphatic from 0.14 to 0.30, carbohydrate from 0.21 to 0.31, and lignin from 0.05 to 0.42. The relationships between K_oc (sorption per unit mass of organic carbon) of carbaryl (1‐naphthyl methylcarbamate) and phosalone (S‐6‐chloro‐2,3‐dihydro‐2‐oxobenzoxazol‐3‐ylmethyl O,O‐diethyl phosphorodithioate) and the molecular nature of organic matter in the soils were significant. Of the molecular components estimated, lignin and charcoal contents correlated best with sorption of carbaryl and phosalone. Aliphatic, carbohydrate and protein contents were found to be negatively correlated with the K_oc of both pesticides. The study highlights the importance of the molecular nature of SOM in determining sorption affinities of non‐ionic pesticides and presents an indirect method for sorption estimation of pesticides.     

Interactive effects of substrates and ectomycorrhizal colonization on growth of a poplar clone

A balsam poplar clone (Populus trichocarpa cv. Weser 6) was inoculated by two ectomycorrhizal strains (Laccaria bicolor MW 158 and Paxillus involutus 1444) in Kick‐Brauckmann‐pots. The substrates were two arable sandy soils (Cambisols) with different organic matter content and nutrient supply. One soil (WIL) was rich in organic matter (C_org = 1.6%) and total nitrogen (N_t = 0.14%), whereas the other soil (RIE) had low contents of C_org (0.8%) and N_t (0.08%). Leaf nutrient concentrations, shoot lengths, root and shoot biomass production and nitrogen accumulation in the biomass were determined to discover possible inoculation effects. Mycorrhization indices (% colonized fine roots) of 36% with Laccaria bicolor and 40% with Paxillus involutus were observed on the C_org rich soil (WIL) in contrast to 16% and 14% on the C_org poor soil (RIE), respectively. Inoculation of poplar on the soil WIL increased shoot length, biomass production, shoot:root ratio and total N uptake of the cuttings, whereas on the soil RIE only the shoot:root ratio increased and the N nutrition was improved. We conclude that interactions between soil and fungus should be tested when choosing ectomycorrhizal strains for inoculation.     

A rapid microwave digestion method for colorimetric measurement of soil organic carbon

Abstract

Soil organic matter is an active component of agroecosystems. Rapid and precise measurement of organic carbon (C_org) is essential to monitor changes in organic matter and soil quality. A new semi‐micro wet digestion method for the determination of C_org was developed using rapid microwave energy applied at 500 J mL^‐1 digestion mixture to enhance oxidation of C_org by K₂Cr₂O₇and conc. H₂SO₄. This proposed method and three existing methods of soil C determination were compared with the LECO dry combustion carbon analyzer. The r² value for the proposed microwave method regressed against LECO C was 0.9913. The recovery of C_org by the rapid microwave digestion method for spectrophotometric measurement was 91.7±1.2% (conversion factor 1.09) of C measured by the LECO dry combustion method. Compared to the traditional Walkley‐Black's method, the proposed spectrophotometric with microwave digestion method was rapid and more precise, used smaller reagent volumes, and produced less waste.     

Soil fertility in a long‐term fertilizer trial with different tillage systems

The presented results originate from a field experiment established in 1972 on an Eutric cambisol with two main factors: soil tillage (conventional‐, reduced‐, and no‐tillage) and NPK fertilization. The test plants were maize and winter wheat in two years rotation.

The long‐term soil fertility without and with optimum fertilization, the influence of fertilization, tillage and crop sequence on grain yields, the organic carbon content (C_org) and the nitrate infiltration are discussed.

In the course of years without any NPK fertilization grain yields of maize and winter wheat decreased significantly and reached a minimum level which was modified however by the actual climatic conditions. The analogous yield level of optimum NPK fertilization at maize showed a growing tendence while at wheat it remained mostly constant.

The method of soil tillage influenced grain yield of winter wheat to a lesser extent than the yield of maize. Grain yields of maize and winter wheat were consistently lower with no‐till as compared to reduced or conventional tillage, however the differences with w. wheat were much smaller. The effect of tillage was especially high at N₀ P₀ K₀. Crop rotation had a positive effect on the yields of maize. For winter wheat at N₀ P₀ K₀ oneself was the better forecrop, while at optimum N and PK maize performed a little better. C_orgcontent of soil slightly increased in the course of 25 years not only on the fertilized plots but on the nil plots too. Increasing N‐doses showed only a little effect on the C_org. There was a little positive effect of no‐till on C_org content of soil as well as compared fall ploughing. Soil tillage did not much influence the total amount of nitrate in the soil profile. The distribution of nitrate‐N in the soil profile was more affected by the actual climatical circumstances than by the system of tillage. However big nitrate accumulations were found in the subsoil according to different soil tillage systems at some other times, as well as lack of it, which suppose the possibility of a relative quick nitrate infiltration.     

Soil development on loess substrate in central Germany — results of a long‐term trial on soil formation§

In 1948, a model soil formation trial was started in Halle/Saale by Schmalfuß. Loess nearly free of soil organic matter (SOM) was used as substrate and the soil formation has been studied in dependence on the level of mineral P and N fertilization. The trial consists of 48 glazed clay cylinders (∅︁ 40 cm × 100 cm), which are open at the bottom. The cylinders are embedded in the ground and stand on a layer of gravel. The trial is divided in a section with constant P and graduated N application and a section with constant N and graduated P application respectively. In the first 30 years, yields increased strongest in the highest NP fertilizer treatment compared with the no‐N or no‐P fertilizer treatment. Afterwards yields in the different fertilization treatments remained nearly constant on the reached levels. Actually the mean shoot dry matter per year is 2.5 times higher in the highest fertilizer treatment as compared to the no‐N fertilizer treatment. The C_org content in the topsoil increased over 49 years in the highest fertilized treatment from 0.18% at the beginning of the trial to 1.94%. Compared to the treatments without N or P fertilization this corresponded, however, only to a 1.2 fold increase. With higher levels of fertilizer application, humus accumulation and biological activity increased relatively faster than the C_org content in the topsoil. Soil organic matter improved the nutrient availability (increase of cation exchange capacity, mobile P fractions). It is assumed that decalcification and the decrease in the C/N ratio will continue. The lower C_org and N_org contents and the lower cation exchange capacity in comparison with soils developed in‐situ near to the parent loess material suggest a still ongoing soil formation process in the trial.     

Diversity of humus stocks in the arable soils of the Late Pleistocene ground morains in Mecklenburg,West Pomerania,Germany

Abstract

Local humus stocks (= contents of soil organic matter, SOM in kg · m^?2) of arable soils were investigated in several regions of the seemingly uniform ground moraine-landscape. Depending on relief position, quantifiable effects of humus removal or enrichment are evident, caused by denudation or colluviation. The depth (thickness) of the investigated humus-bearing topsoil horizons varies between 15 and 150 cm overall and amounts on average to 67 cm. Extreme values of SOM (resp. C_org) stocks are 2.73 (1.58) and 137.41 (79.70) kg · m^?2. The average values of all found SOM (resp. C_org) stocks in the investigated arable soils amount to 10.78 (6.25) kg · m^?2. Humus stocks are not only of importance for the agricultural yield potential but also because of their function as a sink for, or a source of, atmospheric CO₂, which is of special current interest due to its influence on menacing climate change. The total carbon content of the corresponding column of atmosphere, 1.60 kg · m^?2, amounts to only one quarter of the average in our arable soils.     

Relation between soil organic matter and yield levels of nonlegume crops in organic and conventional farming systems

The aim of this study was to evaluate the interaction between yield levels of nonleguminous crops and soil organic matter (SOM) under the specific conditions of organic and conventional farming, respectively, and to identify implications for SOM management in arable farming considering the farming system (organic vs. conventional). For that purpose, correlations between yield levels of nonlegume crops and actual SOM level (C_org, N_t, C_hwe, N_hwe) as well as SOM‐level development were examined including primary data from selected treatments of seven long‐term field experiments in Germany and Switzerland. Yield levels of nonlegume crops were positively correlated with SOM levels, but the correlation was significant only under conditions of organic farming, and not with conventional farming treatments. While absolute SOM levels had a positive impact on yield levels of nonlegumes, the yield levels of nonlegumes and SOM‐level development over time correlated negatively. Due to an increased demand of N from SOM mineralization, higher yield levels of nonlegumes obviously indicate an increased demand for OM supply to maintain SOM levels. Since this observation is highly significant for farming without mineral‐N fertilization but not for farming with such fertilization, we conclude that the demand of SOM‐level maintenance or enhancement and thus adequate SOM management is highly relevant for crop production in organic farming both from an agronomical and ecological point of view. Under conventional management, the agronomic relevance of SOM with regard to nutrient supply is much lower than under organic management. However, it has to be considered that we excluded other possible benefits of SOM in our survey that may be highly relevant for conventional farming as well.     

Contribution of Soil Components on the Sorption of Chlorpyrifos

It is generally assumed that the sorption of a nonionic pesticide on soil depends mainly on the content of soil organic matter (SOM); however, there are other factors that can contribute to this process. The possible causes of variation in the carbon-normalized partition coefficient (K _OC) for chlorpyrifos (CPF) for a diverse set of ten soils have been investigated. On the one hand, the analysis of the chemical composition of the SOM was analyzed, and on the other hand, the likely interactions between the organic matter and the mineral phase were assessed. Sorption experiments of CPF were performed on whole soil, on soils treated with 2% hydrofluoric acid (HF), and onto calcined soil at 550 °C. Organic matter chemistry of soil was determined by ¹³C CP/MAS NMR spectroscopy; K _OC values were positively correlated with aryl C relative proportion and negatively correlated with alkyl C and O-aryl C proportions and prediction equation of K _OC was found (R ²?=?0.82, p?<?0.001). To evaluate possible organo-mineral interactions, a mathematical model was proposed which calculates the concentration of CPF at equilibrium (C _cal) considering adsorption coefficients for the organic (K _DHF) and inorganic (K _D550 °C) soil constituents, separately. The comparison between C _cal and the equilibrium concentration obtained from experimental data (C _exp) onto whole soil allowed us to confirm that interactions between the OM and clay affect the adsorption of CPF in whole soil. Such findings should be taken into account in the development of predictive models for the evaluation of the fate and transport of this pesticide in soil.     

Organic C levels of Ap horizons in North German Pleistocene sands as influenced by climate,texture, and history of land‐use

We evaluated the contents of organic carbon (C_org) of Ap horizons from 11 North German study areas along a Southeast to Northwest precipitation gradient with respect to their general levels and as related to C : N ratio, soil texture (clay content), bulk soil density, climate, and historical land‐use since 1780. The focus was on sandy soils, with the largest group of samples originating from 308 km² of the Fuhrberg catchment north of Hannover/Lower Saxony. Data from loess areas were used for comparisons. Major aims were (1) to quantify current C_org stocks, (2) to provide data on site‐specific, steady‐state C_org levels in old arable soils, and (3) to identify the main controls of C_org levels in the studied sands. The mean C_org content in sandy, well‐drained, old Ap horizons (uplands, > 200 years under cultivation, near steady‐state) increased with precipitation from < 8 g kg^—1 in the dry eastern parts of the study area (530 mm year^—1, 8.3°C) to 25 g kg^—1 in the moist Northwest (825 mm year^—1, 8.4°C). The C_org levels in lowlands which have been drained for more than 40 years were approximately 3 g kg^—1 higher than those of uplands under a similar climate. The factor clay content had no predictive value because low contents were associated with high C_org levels. Large proportions of refractory organic matter in sands resulting from specific features of historical land‐use and soil development (calluna heathland, heath plaggen fertilization, podzolization) appeared to be the most probable reason for such high C_org levels. However, the high C_org levels of these old arable sites were still exceeded by those of younger arable areas formerly under continuos grassland. A chrono‐sequence suggested that a period of about 100 years is necessary until a new steady‐state C_org level is established after conversion of grassland into arable land. Elevated C_org levels in current Ap horizons were also found for former woodland and heathland soils. The main conclusion is that sands can contain a lot of stable organic matter, sometimes more than finer textured soils.     

Silicon fractions in Histosols and Gleysols of a temperate grassland site

The importance of silicon (Si) in nutrition is currently being recognized by its beneficial effects on many crops. Therefore, it is important to determine the soil Si status and to examine different extractants for testing plant‐available Si. Little information is available about the Si status of Histosols and C_org‐rich Gleysols in temperate climate. This study was undertaken (1) to characterize different Si pools in C_org‐rich groundwater soils of an experimental site and (2) to study the influences of small‐scale variability on element distribution. At the experimental site, the thickness of the C_org‐rich layer ranges between 4 and 5 dm overlying fine‐sandy fluvial sediments. Four extractants were evaluated: 0.01 M CaCl₂, 0.5 M acetic acid, 0.1 M sodium pyrophosphate, and 0.1 M Tiron (C₆H₄Na₂O₈S₂ · H₂O). Further, total element content was determined following HNO₃/HF digestion. Calcium chloride–soluble Si shows no significant relations to other parameters analyzed. On the basis of published data, the soils investigated could be classified as Si‐deficient. The Si fraction extracted with acetic acid displays relations to C_org content of the soil and a weak correlation to CaCl₂‐soluble Si, indicating that both solutions extract overlapping but not the same fractions. Sodium pyrophosphate extracts mainly organo‐mineral Fe and Al complexes in the soils studied, which is reflected in a highly positive correlation to C_org. Pyrophosphate‐soluble Si showed a negative relationship to C_org, which means a closer relation of this Si fraction to mineral matter than to C_org. The Tiron solution extracted most Si of all extractants, but this amounts only 1% of the total Si content. Taking into account the element‐specific relationship between pyrophosphate and Tiron‐extractable Fe, Al, and Si, it can be concluded that Tiron dissolves mainly the opaline silica present in Histosols and C_org‐rich Gleysols. The distribution of C_org and ash content shows clear spatial trend at the experimental site, which is correlated to pyrophosphate‐extractable as well as total Si. This small‐scale variability of soil parameters itself is related to a distinct microrelief.     

Biological activity and organic matter mineralization of soils amended with biowaste composts

This study aims to elucidate the significance of compost and soil characteristics for the biological activity of compost‐amended soils. Two agricultural soils (Ap horizon, loamy arable Orthic Luvisol and Ah horizon, sandy meadow Dystric Cambisol) and a humus‐free sandy mineral substrate were amended with two biowaste composts of different maturity in a controlled microcosm system for 18 months at 5 °C and 14 °C, respectively. Compost application increased the organic matter mineralization, the C_mic : C_org ratio, and the metabolic quotients significantly in all treatments. The total amount of C_org mineralized ranged from < 1 % (control plots) to 20 % (compost amended Dystric Cambisol). Incubation at 14 °C resulted in 2.7‐ to 4‐fold higher cumulative C_org mineralization compared to 5 °C. The C_mic : C_org ratios of the compost‐amended plots declined rapidly during the first 6 months and reached a similar range as the control plots at the end of the experiment. This effect may identify the compost‐derived microbial biomass as an easily degradable C source. Decreasing mineralization rates and metabolic quotients indicated a shift from a compost‐derived to a soil‐adapted microbial community. The C_org mineralization of the compost amended soils was mainly regulated by the compost maturity and the soil texture (higher activity in the sandy textured soils). The pattern of biological activity in the compost‐amended mineral substrate did not differ markedly from that of the compost‐amended agricultural soils, showing that the turnover of compost‐derived organic matter dominated the overall decay process in each soil. However, a priming effect occurring for the Dystric Cambisol indicated, that the effect of compost application may be soil specific.     

Specific features of the ecological functioning of urban soils in Moscow and Moscow oblast

Urban soils (constructozems) were studied in Moscow and several cities (Dubna, Pushchino, and Serebryanye Prudy) of Moscow oblast. The soil sampling from the upper 10-cm-thick layer was performed in the industrial, residential, and recreational functional zones of these cities. The biological (the carbon of the microbial biomass carbon, C_mic and the microbial (basal) respiration, BR) and chemical (pH_water and the contents of C_org, heavy metals, and NPK) indices were determined in the samples. The ratios of BR to C_mic (the microbial respiration quotient, qCO₂) and of C_mic to C_org were calculated. The C_mic varied from 120 to 738 μg C/g soil; the BR, from 0.39 to 1.94 μg CO₂-C/g soil per hour; the C_org, from 2.52 to 5.67%; the qCO₂, from 1.24 to 5.28 μg CO₂-C/mg C_mic/g soil per h; and the C_mic/C_org, from 0.40 to 1.55%. Reliable positive correlations were found between the C_mic and BR, the C_mic and C_mic/C_org, and the C_mic and C_org values (r = 0.75, 0.95, and 0.61, respectively), as well as between the BR and C_mic/C_org values (r = 0.68). The correlation between the C_mic/C_org and qCO₂ values was negative (r = −0.70). The values of C_mic, BR, C_org, and C_mic/C_org were found to correlate with the ammonium nitrogen content. No correlative relationships were revealed between the determined indices and the climatic characteristics. The principal component analysis described 86% of the variances for all the experimental data and clearly subdivided the locations of the studied soil objects. The ANOVA showed that the variances of C_mic, C_org, and BR are controlled by the site location factor by 66, 63, and 35%, respectively. The specificity of the functioning of the anthropogenic soils as compared with their natural analogues was clearly demonstrated. As shown in this study, measurable biological indices might be applied to characterize the ecological, environmental-regulating, and productive functions of soils, including urban soils.     

Activity,Adsorption, and Lixiviation of Acetochlor in Soil under No Tillage and Conventional Tillage: Influence of Straw Coverage

Abstract

The activity of residual herbicides employed for weed control varies with adsorption, lixiviation, degradation, and biological transformation of these compounds in the soil. The purpose of this study was to evaluate the activity of the herbicide acetochlor (2‐chloro‐N‐ethoxymethyl‐6′‐ethylacet‐o‐toluidine) in Typic Paleodult under no tillage and conventional tillage. Field and laboratory experiments were carried out at the Universidade Federal do Rio Grande do Sul. Weed control with and without straw coverage, and adsorption and lixiviation of acetochlor, in soil with both tillage systems were evaluated. Adsorption and lixiviation processes were determined by high‐performance liquid chromatography (HPLC) with UV detector. The coefficients K _d and K _oc were higher in no‐tillage soil, indicating a more effective acetochlor adsorption. The maximum concentration of acetochlor was found in a depth of 15–20 cm, indicating a higher lixiviation in this soil. The acetochlor was more effective in weed control using conventional tillage when compared to no tillage. The straw coverage reduced the control efficiency of the herbicide.     

Influence of deer exclusion on soil nutrients in oak forests of a central European low mountain range

High densities of red deer can have severe impacts on soil nutrient status by removing the ground vegetation and enhancing erosion of the fertile soil layers. We compared four fenced deer exclosures with adjacent unfenced sites to evaluate the effect of deer grazing and trampling on the soil nutrient status (C_org, N_t, PO₄³⁻, Ca²⁺, Mg²⁺, K⁺) in sloping oak forests of a central European low mountain range. The investigation was set up as a three‐factor randomized complete block design (RCBD) with the factors: ‘fencing’ (fenced/unfenced), ‘gradient’ (gentle/steep) and ‘aspect’ (windward/leeward). We hypothesized that exclusion of red deer by fencing would increase soil nutrient contents independent of slope gradient and aspect. Fencing increased the contents of C_org, N_t, Ca²⁺ and PO₄³⁻, but only at the windward sites. This effect was less pronounced at the gently sloping site than at the steep site, which exhibited the lowest contents of C_org, N_t and PO₄³⁻ of all sites. We did not find increased soil nutrients in the fenced exclosures at the leeward sites, neither at the steep nor at the gently sloping site. At both slope aspects nutrient contents (C_org, N_t, PO₄³⁻, K⁺) tended to be higher on the gentle than at the corresponding steep slopes. Our results suggest that red deer trampling and grazing enhance the loss of soil nutrients at predisposed sites such as windward locations with a high slope gradient. Only at such sites did the exclusion of red deer increase several soil nutrients. Copyright © 2005 John Wiley & Sons, Ltd.     

Soil organic carbon as affected by direct drilling and mulching in sugar beet – wheat rotations

The effect of conventional ploughing, mulching, and direct drilling on the soil organic C (soil C_org) contents through the soil profile and on total soil C_org stocks (0–45 cm) was investigated at five different German sites. All sites showed similar results: after 10–13 years, soil C_org contents in the surface soil (0–10 cm) were 15–71% and 33–42% higher under direct drilling and mulching, respectively, than under ploughing (8–18 g kg^?1). Under ploughing, the soil C_org contents were distributed homogenously through the soil profile. Either mulching or direct drilling resulted in 3–28% higher soil C_org stocks than ploughing (49–116 t ha^?1). However, the tillage management was no significant factor since the sites showed the effects to different extents but were the mathematical replications. Five to six years later, trends and values were similar. We concluded that the main effect of mulching or direct drilling was the stratification with higher soil C_org contents in the surface soil. Since this is a positive means for soil protection, we suggested that the use of mulching or direct drilling can contribute to a sustainable soil management in crop rotations with sugar beet which are characterized by a strong physical impact on the soil during harvest.