The efficacy of coconut fibers on the sound-absorbing and thermal-insulating nonwoven composite board

The aim of this study is to examine the efficacy of the coconut fiber on the sound absorption and thermal insulation performance towards the composite nonwoven fabrics. The 2D polyester fiber and 12D fire retardant three-dimensional hollow crimp polyester fiber are individually mixed with 4D low-melting point polyester fiber (4DLMf) to produce 2D polyester nonwoven fabric (2D-PETF) and 12D polyester nonwoven fabric (12D-PETF) respectively. Subsequently, the coconut fiber (CF) is then laminated with the 2D-PETF and 12D-PETF to fabricate two types of PET/CF composite boards through the multiple needle-punching techniques. Accordingly, the sound absorption, thermal insulation, Limiting Oxygen Index and relative mechanical properties of the PET/CF composite boards are evaluated properly. The experimental results reveal that both types of PET/CF composite boards possess excellent thermal insulation performance and fire resistance property. Also, for both types of PET/CF composite boards, the average sound absorption coefficient increases with the increased amount of CF.     

An investigation in structural parameters of needle-punched nonwoven fabrics on their thermal insulation property

The thermal characteristics of hollow polyester fibers were compared with solid polyester fibers in order to study their processing behavior and performance characteristics. The effects of different processing and structural properties including fiber diameter, bulk density of layer, and surface pressure on layers of needle-punched nonwoven fabrics with hollow fibers on thermal resistance properties were also investigated. The results show that hollow fibers have a higher thermal resistance in comparison with solid ones. This is a consequence of air trapping inside the fibers, higher bulkiness, and higher surface area of hollow fibers. Furthermore, thermal resistance of microfibers is better than those of macrofibers in both hollow and solid fibers. The thermal resistance of nonwoven subjected to this study, have an inverted-U-shaped pattern versus the bulk density of the fabric. The results also showed that thermal resistance of needle-punched nonwoven fabrics can be affected by the range of heater temperature during the test, however considerably can be affected by fabric thickness as a main structural property of nonwoven fabrics.     

Synthesis,structure and thermal protective behavior of silica aerogel/PET nonwoven fiber composite

In recent years, flexible, mechanically strong and environmental friendly thermal insulation materials have attracted considerable attention. In this work, silica aerogel/polyethylene terephthalate (PET) nonwoven fiber composite with desirable characteristics was prepared via a two-step sol-gel process followed by an ambient drying method through immersing the PET nonwoven fiber into silica sol. The silica aerogel particles were characterized by FTIR, FE-SEM, TGA and nitrogen adsorption analysis. The morphology and hydrophobic properties of neat PET nonwoven fiber and its silica aerogel composite were also investigated. For studying thermal protective properties, the thermal diffusivity was calculated from temperature distribution curves. The mean pore size of 11 nm, the surface area of 606 m²/g and the total pore volume of 1.77 cm³/g for the silica aerogel particles in the composite are obtained from nitrogen adsorption analysis, indicating the aerogel can maintain its high porosity in the nonwoven composite structure. Silica aerogel particles were efficiently covered the surface of the PET fibers and completely filled the micron size pores of the nonwoven fiber leading to a stronger hydrophobicity and higher thermal insulation performance in the aerogel composite samples compared to the neat PET nonwoven. In this regard, an almost 64 % decrease in the thermal diffusivity was achieved with 66 wt% silica aerogel.     

Effect of the low and radio frequency oxygen plasma treatment of jute fiber on mechanical properties of jute fiber/polyester composite

We investigated the surface modification of jute fiber by oxygen plasma treatments. Jute fibers were treated in different plasma reactors (radio frequency “RF” and low frequency “LF” plasma reactors) using O₂ for different plasma powers to increase the interface adhesion between jute fiber and polyester matrix. The influence of various plasma reactors on mechanical properties of jute fiber-reinforced polyester composites was reported. Tensile, flexure, short beam shear tests were used to determine the mechanical properties of the composites. The interlaminar shear strength increased from 11.5 MPa for the untreated jute fiber/polyester composite to 19.8 and 26.3 MPa for LF and RF oxygen plasma treated jute fiber/polyester composites, respectively. O₂ plasma treatment also improved the tensile and flexural strengths of jute fiber/ polyester composites for both plasma systems. It is clear that O₂ plasma treatment of jute fibers by using RF plasma system instead of using LF plasma system brings about greater improvement on the mechanical properties of jute/polyester composites.     

Properties and performance of polypyrrole (PPy)-coated silk fibers

Different silk substrates in form of spun silk tops, nonwoven web, yarn, and fabric were coated with electrically conducting doped polypyrrole (PPy) by in situ oxidative polymerization from an aqueous solution of pyrrole (Py) at room temperature using FeCl₃ as catalyst. PPy-coated silk materials were characterized by optical (OM) and scanning electron (SEM) microscopy, FT-IR spectroscopy, and thermal analysis (DSC, TG). OM and SEM showed that PPy completely coated the surface of individual silk fibers and that the polymerization process occurred only at the fiber surface and not in the bulk. Dendrite-like aggregates of PPy adhered to the fiber surface, with the exception of the sample first polymerized in the form of tops and then spun into yarn using conventional industrial machines. FT-IR (ATR mode) showed a mixed spectral pattern with bands typical of silk and PPy overlapping over the entire wavenumbers range. DSC and TG showed that PPy-coated silk fibers attained a significantly higher thermal stability owing to the protective effect of the PPy layer against thermal degradation. The mechanical properties of silk fibers remained unchanged upon polymerization of Py. The different PPy-coated silk materials displayed excellent electrical properties. After exposition to atmospheric oxygen for two years a residual conductivity of 10–20 % was recorded. The conductivity decreased sharply under the conditions of domestic washing with water, while it remained essentially unchanged upon dry cleaning. Abrasion tests caused a limited increase of resistance. PPy-coated silk tops were successfully spun into yarn either pure or in blend with untreated silk fibers. The resulting yarns maintained good electrical properties.     

Sound absorption and viscoelastic property of acoustical automotive nonwovens and their plasma treatment

Sound absorption property, viscoelastic property and the effect of plasma treatment of four automotive nonwoven fabrics on these properties are discussed in this research paper. Needle-punched fabrics used for vehicle headliner include 2 polyester fabrics made of hollow polyester fibers or solid polyester fibers, and 2 polypropylene-composite cellulose fabrics made of jute fibers or kenaf fibers, manufactured with the same web structure of apparent fabric density and fabric thickness. Hollow polyester fiber fabric has the highest sound absorption and the highest loss factor, the second highest is jute fiber fabric. The viscoelastic property is found to be related to the sound absorption property of fabric. The plasma treatment on nonwoven fabrics changes their sound absorption and viscoelastic property as well as their fabric weight and pore size. Hollow polyester fabric shows the increased sound absorption and viscoelastic property after the treatment with the increased pore sizes, while regular polyester fabric displays insignificant changes. The cellulose fabrics are more affected by plasma treatment compared to the polyester fabrics in terms of fabric weight loss and pore size, and jute fabric is more affected than kenaf fabric due to fiber weakness. The jute fabric demonstrates the decreased sound absorption and viscoelastic property, while kenaf fabric shows the increased sound absorption with the unchanged viscoelastic property after the treatment.     

Correlation between the Thermo-physical Properties and Core Material Structure of Vacuum Insulation Panel: Role of Fiber Types

Vacuum insulation panel (VIP), which is composed of an evacuated core material encapsulated in an envelope and supplemented with a desiccant, is a high performance thermal insulation material. In this paper, thermos-physical properties of chopped fiber, centrifugal-spinneret-blow (CSB) fiber, flame-spinneret-blow (FSB) fiber and hybrid (CSB: FSB=1:1) fiber as fillers of vacuum insulation panel are explored. The results show that the increase of pore size can improve thermal insulation property; fibers distribute in 2-D structure, which can reduce the heat conduction, leads to reduce the thermal conductivity. VIP with chopped fiber has the best thermal insulation, and thermal conductivity is 1.4 mW/m.K. Due to difference of core materials, thermal insulation characteristics of VIP can be divided into three distinct regions based on the internal pressure range, i.e., (I) ≥12000 Pa region, (II) 80-12000 Pa region, (III) ≤ 80 Pa region. It also finds that service life of VIP can be improved by the reducing the pore size of core materials. VIP with different core materials shows different degradation and the degradation rate of VIP with FSB core material is minimum.     

Comparative study of the mechanical properties of polyester resin with and without reinforcement with fiber-glass and furcraea cabuya fibers

A commercially available polyester resin was reinforced with cabuya fibers. The experimental variables were the fiber loading and the length of the fiber. Tensile strength, flexural strength, and the Izod impact resistance were measured for the samples and compared to the polyester resin performance without reinforcement. Mechanical properties of the cabuya fiber reinforced material were also compared with the same resin but reinforced with glass fibers. An increase in fiber load decreases the tensile strength for the cabuya reinforced composite, where a value of 52.6 MPa corresponded to the tensile stress of the resin without reinforcement and a value of 34.5 MPa for the best reinforcement achieved with cabuya. An increase in both fiber load and length increases the Young’s modulus of the cabuya reinforced material, and a maximum value of 2885 MPa was obtained. The Young’s modulus and impact resistance values for the cabuya composite (2885 MPa and 100.87 J/m, respectively) reached higher values than those obtained for non-reinforced polyester material (2639 MPa and 5.82 J/m, respectively), and lower than the glass fiber composite (5526 MPa and 207.46 J/m, respectively); while the tensile and flexural strength obtained for the cabuya composite (34.5 MPa and 32.6 MPa, respectively) were lower than the unreinforced (52.6 MPa and 62.9 MPa, respectively) and glass fiber reinforced polyester (87.3 MPa and 155 MPa, respectively).     

Kinetics of non-isothermal decomposition and flame retardancy of goatskin fiber treated with melamine-based flame retardant

Fire-retardant fiber was prepared from goatskin fiber by treating with a melamine-based flame retardant. Kissinger and Flynn-Wall-Ozawa methods were used for analyzing the thermo-gravimetric data obtained from the goatskin fiber and the fire-retardant fiber at different heating rates. Kinetic parameters were calculated from the thermo-gravimetric data at different heating rates. Activation energies obtained using the Kissinger and Flynn-Wall-Ozawa methods were 154.57 kJ/mol and 158.45 kJ/mol, respectively, for the goatskin fiber and 210.15 kJ/mol and 212.52 kJ/mol, respectively, for the fireretardant fiber. The oxygen index of the fire-retardant fiber treated with 4 wt% melamine-based flame retardant increased significantly to a value of 31.7 %. The thermal stability and the flame retardant property of the fire-retardant fiber were improved significantly.     

Thermal conductivity and thermal expansion behavior of pseudo-unidirectional and 2-directional quasi-carbon fiber/phenolic composites

In the present paper, a variety of fiber reinforcements, for instance, stabilized OXI-PAN fibers, quasi-carbon fibers, commercial carbon fibers, and their woven fabric forms, have been utilized to fabricate pseudo-unidirectional (pseudo-UD) and 2-directional (2D) phenolic matrix composites using a compression molding method. Prior to fabricating quasi-carbon fiber/phenolic (QC/P) composites, stabilized OXI-PAN fibers and fabrics were heat-treated under low temperature carbonization processes to prepare quasi-carbon fibers and fabrics. The thermal conductivity and thermal expansion/contraction behavior of QC/P composites have been investigated and compared with those of carbon fiber/phenolic (C/P) and stabilized fiber/phenolic composites. Also, the chemical compositions of the fibers used have been characterized. The results suggest that use of proper quasi-carbonization process may control effectively not only the chemical compositions of resulting quasi-carbon fibers but also the thermal conductivity and thermal expansion behavior of quasi-carbon fibers/phenolic composites in the intermediate range between stabilized PAN fiber- and carbon fiber-reinforced phenolic composites.     

Predicting the tensile strength of needle-punched nonwoven mats using X-ray computed tomography and a statistical model

As nonwoven mats are randomly oriented fiber assemblies, the tensile strength of nonwoven mats is determined by their microstructural factors, such as fiber orientation, fiber volume fraction, and fiber-fiber contact level. The complex microstructure of nonwoven mats must be reasonably simplified to properly predict their mechanical properties within affordable efforts. In this study, a new parameter, so called contact efficiency, is defined to describe the fiber-fiber contact level of nonwoven mats. Micro X-ray computer tomography (CT) is employed to characterize the microstructure of needlepunched nonwoven mats made of polypropylene short fibers. The fiber orientation and volume fraction are obtained by analyzing 2D sectional CT image of the nonwoven mat, while the contact efficiency is determined from 3D CT image. A statistical model, developed originally for staple yarns, is modified to predict the tensile strength of the nonwoven mat using the microstructural factors obtained from CT analysis. The prediction is then compared with experiments to validate that the current model incorporating the contact efficiency is highly suitable for predicting the tensile strength of nonwoven mats.     

Green composites. I. physical properties of ramie fibers for environment-friendly green composites

The surface topography, tensile properties, and thermal properties of ramie fibers were investigated as reinforcement for fully biodegradable and environmental-friendly ‘green’ composites. SEM micrographs of a longitudinal and cross-sectional view of a single ramie fiber showed a fibrillar structure and rough surface with irregular cross-section, which is considered to provide good interfacial adhesion with polymer resin in composites. An average tensile strength, Young’s modulus, and fracture strain of ramie fibers were measured to be 627 MPa, 31.8 GPa, and 2.7 %, respectively. The specific tensile properties of the ramie fiber calculated per unit density were found to be comparable to those of E-glass fibers. Ramie fibers exhibited good thermal stability after aging up to 160°C with no decrease in tensile strength or Young’s modulus. However, at temperatures higher than 160°C the tensile strength decreased significantly and its fracture behavior was also affected. The moisture content of the ramie fiber was 9.9%. These properties make ramie fibers suitable as reinforcement for ‘green’ composites. Also, the green composites can be fabricated at temperatures up to 160°C without reducing the fiber properties.     

Study on heat and moisture vapour transmission characteristics through multilayered fabric ensembles

A detailed study on the heat and moisture vapour transmission characteristics of different types of single and multi-layered fabric ensemble by using sweating guarded hot plate (SGHP) has been reported in the present paper. A comparison has been made on thermal and moisture vapour transmission properties of five different insulative fabrics, namely, knitted-raised fabric, needle punched nonwoven, through air bonded nonwoven, spunbonded-through air bonded sandwich nonwoven and warp knitted spacer fabric and three different coated fabrics, namely, plain woven rubber coated, plain woven polyester polymer coated and plain woven polytetrafluoroethylene (PTFE) coated fabric, used for thermal insulation purpose. ANOVA has been conducted to analyse the significance of type of insulative and coated fabrics used. Sandwich nonwoven fabric which has higher thickness and porosity shows higher thermal resistance followed by through air bonded fabric, raised fabric, needle punched fabric and spacer fabric. Spacer fabric shows lesser evaporative resistance due to its lesser thickness and larger aperture size, which increases the diffusion of moisture vapour. Needle punched fabric shows slightly higher evaporative resistance than spacer fabric, followed by raised fabric, through air bonded fabric and sandwich nonwoven fabric. Permeability index of different multilayered fabric ensembles are also compared.     

Mechanical behavior of composites reinforced with fibers caroa

Composites were prepared with 13, 23 30 and 40 % fiber and evaluated the mechanical performance in tensile, flexural and impact. The mechanical properties of these composites were also evaluated function of time at 110 °C thermal exposure. Caroa fibers were characterized by techniques such as thermal gravimetric analysis (TGA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). It was found that the best mechanical properties were achieved for composites containing 23 to 30 % fiber. The incorporation of 23 % fiber caroa increased both the modulus of elasticity in the tensile test as the flexural strength and impact, the composite with 30 % fiber caroa showed higher tensile strength. The results show that the tensile and flexural strength of the composite decreased with time of thermal exposure. The thermal aging at 110 °C caused a decrease in tensile properties of the composites.     

Prediction of the water absorption capacity of VIS/PES needle-punched webs using genetic algorithms

Needle-punched webs for wet cleaning wipes were produced using a dry-laid method of web- forming. Fibrous webs with a different content of hydrophilic viscose and hydrophobic polyester fibers, as well as webs made from 100 % polyester fibers, were utilized during this study. The webs were compared in terms of their water absorption capacity on the basis of their basic construction parameters, such as fiber fineness, raw material (e.g. fiber density), and web density. The higher water absorption capacity of the viscose/polyester-blended needle-punched webs was achieved at higher content of viscose fibers which coincide with the higher fiber density, finer fibers, and lower web density. A prediction model regarding water absorption capacity of viscose/polyester needle-punched webs was developed on the basis of the mentioned construction parameters and a non-deterministic modelling method, e.g. genetic algorithms, and could provide a guideline for the engineering of nonwoven webs in order to fit the desired water absorption capacity.     

Mechanical and physical properties of puncture-resistance plank made of recycled selvages

Glass woven fabric interlayered nonwovens composed of Nylon 6 staple fibers, recycled Kevlar fibers, and low-T_m polyester fibers are prepared into the glass-interlayer plank. Afterwards, their tensile strength, bursting strength, quasistatic and dynamic puncture resistances are evaluated by changing low-T_m polyester and Kevlar fibers mass fractions. The results show that when comprising 30 wt% of low-T_m polyester fibers and 20 wt% of Kevlar fibers, the composite plank yields the maximum tensile strength, bursting strength, quasi-static and dynamic puncture resistances. The double planks arranged in cross direction have higher quasi-static and dynamic puncture resistances than those oriented in parallel direction. According to stereoscope observations, the quasi-static and dynamic puncture resistances of glass-interlayer plank have different fracture mechanism for resisting against spike penetration. In addition, the bursting strength is proportional to quasistatic puncture resistance.     

Manufacturing technique and acoustic evaluation of sandwich laminates reinforced high-resilience inter/intra-ply hybrid composites

This study focused on the fabrication and acoustic property evaluation of sandwich cover-ply-reinforced highresilience thermal-bonding nonwoven hybrid composites. P-phenyleneterephthalamides and bicomponent high-resilience bonding polyester intra-ply hybrid nonwoven fabrics were compounded with glass plain fabric to produce the high strength sandwich structural cover ply by means of needle punching and thermal bonding to reinforce the whole composites and dissipate energy when being impacted. Then, the acoustic absorption properties of the homogenous intra-ply hybrid meshwork layer were investigated before and after being reinforced with the aforementioned cover ply. The influencing factors, including areal density, fiber blending ratio, needle punching depth, and air cavity thickness between back plate of the impedance tube and composites, were comparatively investigated. Results revealed that hybrid composites exhibited exceedingly high acoustic absorption properties. Acoustic absorption coefficients were promoted with increases in areal densities and fiber blending ratio of 3D crimped hollow polyester, particularly at low-mid frequency range. In addition, needle punching depths and back air cavity thicknesses considerably affected the average absorption coefficients. The meshwork center layer reinforced with sandwich structural cover-ply perform high resilience properties.     

The modification of Kevlar fibers in coupling agents by <Emphasis Type="Italic">γ</Emphasis>-ray co-irradiation

Kevlar fibers were treated in three kinds of coupling agents’ solutions by Co⁶⁰ γ-ray co-irradiation. After the treatment, the interlaminar shear strength (ILSS) values of Kevlar fibers/epoxy composites were all improved. Surface elements of the fibers were determined by energy dispersive X-ray microanalysis (EDX). X-ray photoelectron spectroscopy (XPS) indicated that the oxygen/carbon ratio of the treated fibers was increased and Fourier transform infrared (FT-IR) spectrum confirmed the increase in the polar groups at the fiber surface. The tensile strength of the fibers was evaluated by statistical analysis using the Weibull distribution. The wettability of the fiber surface was also enhanced by the treatment. The possible mechanisms of γ-ray co-irradiation treatment are proposed by the radical reactions. The results indicated that γ-ray co-irradiation technique modified the physicochemical properties of Kevlar fibers and improved the interfacial adhesion of its composites.     

Development of thermal insulating and sound absorbing agro-sourced materials from auto linked flax-tows

The aim of this paper is to develop a green composite using only flax fiber material for thermal insulations and sound absorbing using flax-tows and thus enhance the less noble part of the flax plant. The Lin-K process is a simple patented manufacturing process used to develop these self-linked materials. Thermal conductivity, absorbing acoustic coefficient, hydric properties and the effect of several parameters on these performances are reviewed. The use of fine flax-tows leads to extract more organic substances of the inner fibers during the microwave treatment which improves the mechanical performances and reduces the thermal conductivities of these materials. The environment has very significant effects on thermal stability and durability of these materials.     

The optimal continuous manufacturing conditions for oxidized PAN nanofiber nonwovens

In this study, two kinds of polyacrylonitrile (PAN) (carbon fiber grade PAN and oxidized fiber grade PAN) are used as the raw materials for a PAN-based nanofiber nonwoven that is prepared using electrospinning. A high-temperature erect furnace is then used, which uses oxidization processes to prepare oxidized nanofiber nonwovens in a continuous manufacturing process. The parameters used for the oxidation process are oxidation temperatures of 150, 200, 250, 275, 300 and 300 °C, which correspond to a production rate of 3, 5 and 10 cm/min at 5-cN tension. The variation in the yield rate, the breaking strength and the shrinkage of the oxidized PAN based electrospun nonwovens are examined in this study. The results demonstrate that the limit oxygen index (LOI) and aromatization index (AI) increase as the production rate decreases. Under the optimum oxidation conditions, higher quality oxidized electrospun nonwovens are produced using carbon fiber grade PAN with AI of 61 % and LOI of 42 %.