IONIC DISPLACEMENT AND RECLAMATION OF SALINE‐SODIC SOILS USING CHEMICAL AMENDMENTS AND CROP ROTATION

Biological, chemical and bio‐chemical strategies have been tested in the past for reclamation of saline‐sodic and sodic soils. The efficiency of two crop rotations (rice‐wheat and Sesbania‐wheat) alone or in combination with either gypsum (CaSO₄.2H₂O) or sulfuric acid (H₂SO₄) was tested for ionic displacement from four saline‐sodic soils. Pure gypsum was applied at 50 per cent of soil gypsum requirement at the time of planting rice and Sesbania, whereas 95 per cent pure sulfuric acid was added at 50 per cent soil gypsum requirement as one‐third applications by mixing with the first three irrigations. The rice crop biomass decreased at a soil saturation extract electrical conductivity (EC_e) of 8 dS m⁻¹, whereas wheat and Sesbania were influenced at a sodium adsorption ratio (SAR) of ≥40. Gypsum treatment helped the crops flourish well at these EC_e and SAR levels. The infiltrated volume of water dropped with decrease in EC_e : SAR ratio of soils and increase in crop biomass production. Crops rotation treatments alone helped leach sodium (Na⁺) and other ions successfully at SAR ≤ 21 but were less effective at SAR ≥ 40 at which point plants growth was also curtailed. Gypsum and H₂SO₄ treatments significantly aided leaching of Na⁺ and other ions with water at SAR ≥ 40 under both the crop rotations. Hence, crops effectively reclaimed soil at low sodicity level, whereas at high SAR, chemical amendments are obligatory in order to reclaim soils. This study also suggests that the required dose of H₂SO₄ should be applied with pre‐planting irrigation for better yield of the first crop. Copyright © 2011 John Wiley & Sons, Ltd.     

Reclamation and salt leaching efficiency for tile drained saline‐sodic soil using marginal quality water for irrigating rice and wheat crops

Due to increased population and urbanization, freshwater demand for domestic purposes has increased resulting in a smaller proportion for irrigation of crops. We carried out a 3‐year field experiment in the Indus Plains of Pakistan on salt‐affected soil (EC_e 15·67–23·96 dS m⁻¹, pH_s 8·35–8·93, SAR 70–120, infiltration rate 0·72–0·78 cm h⁻¹, ρ _b 1·70–1·80 Mg m⁻³) having tile drainage in place. The 3‐year cropping sequence consisted of rice (Oryza sativa L.) and wheat (Triticum aestivum L.) crops in rotation. These crops were irrigated with groundwater having electrical conductivity (EC) 2·7 dS m⁻¹, sodium adsorption ratio (SAR) 8·0 (mmol L⁻¹)^1/2 and residual sodium carbonate (RSC) 1·3 mmol_c L⁻¹. Treatments were: (1) irrigation with brackish water without amendment (control); (2) Sesbania (Sesbania aculeata) green manure each year before rice (SM); (3) applied gypsum at 100 per cent soil gypsum requirement (SGR) and (4) applied gypsum as in treatment 3 plus sesbania green manure each year (GSM). A decrease in soil salinity and sodicity and favourable infiltration rate and bulk density over pre‐experiment levels are recorded. GSM resulted in the largest decrease in soil salinity and sodicity. There was a positive relationship between crop yield and economic benefits and improvement in soil physical and chemical properties. On the basis of six crops, the greatest net benefit was obtained from GSM. Based on this long‐term study, combined use of gypsum at 100 per cent soil gypsum requirement along with sesbania each year is recommended for soil amelioration and crop production. Copyright © 2010 John Wiley & Sons, Ltd.     

Sodium removal from a calcareous saline–sodic soil through leaching and plant uptake during phytoremediation

Saline–sodic and sodic soils are characterized by the occurrence of sodium (Na⁺) to levels that can adversely affect several soil properties and growth of most crops. As a potential substitute of cost‐intensive chemical amelioration, phytoremediation of such soils has emerged as an efficient and low‐cost strategy. This plant‐assisted amelioration involves cultivation of certain plant species that can withstand ambient soil salinity and sodicity levels. It relies on enhanced dissolution of native calcite within the root zone to provide adequate Ca²⁺ for the Na⁺ Ca²⁺ exchange at the cation exchange sites. There is a lack of information for the Na⁺ balance in terms of removal from saline–sodic soils through plant uptake and leaching during the phytoremediation process. We carried out a lysimeter experiment on a calcareous saline–sodic soil [pH of saturated soil paste (pH_s) = 7.2, electrical conductivity of the saturated paste extract (EC_e) = 4.9 dS m⁻¹, sodium adsorption ratio (SAR) = 15.9, CaCO₃ = 50 g kg⁻¹]. There were three treatments: (1) control (without application of a chemical amendment or crop cultivation), (2) soil application of gypsum according to the gypsum requirement of the soil and (3) planting of alfalfa (Medicago sativa L.) as a phytoremediation crop. The efficiency of treatments for soluble salt and Na⁺ removal from the soil was in the order: gypsum ≈ alfalfa > control. In the phytoremediation treatment, the amount of Na⁺ removed from the soil through leaching was found to be the principal cause of reduction in salinity and sodicity. Copyright © 2003 John Wiley & Sons, Ltd.     

The influence of blue-green algae on the biological amelioration of alkali soils

Summary Virgin alkali (sodic) soils have a high pH and high exchangeable Na and are often barren. Blue-green algae, however, tolerate excess Na and grow extensively on the soil surface in wet seasons. Experiments using a highly degraded alkali soil (silt loam, pH 10.3, electrical conductivity 3.5 dS m^-1, 90% exchangeable Na) were conducted in soil columns, with or without gypsum, in order to study the influence of waterlogging on the growth of indigenous and inoculated blue-green algae and hence, soil reclamation. The growth of indigenous blue-green algae was initially slow in alkali soil, due to the high pH and exchangeable Na, and depressed in gypsum-amended soil, due to excess Ca. Inoculation hastened the establishment of blue-green algae in both the unamended alkali soil and the gypsum-amended soil, overcoming the adverse influence of excess Na in the former and excess Ca in the latter. Gypsum was effective in amelioration (pH 9.05, electrical conductivity 1.2 dS m^-1, 41% exchangeable Na after 11 weeks) but blue-green algae were ineffective even after 17 weeks. In combination with gypsum, blue-green algae had no additional effect, and the C and N increases due to the growth of indigenous or inoculated blue-green algae were insignificant.Alkali soil reclamation by biological methods requires mobilization of Ca from native soil calcite and the exchange of Ca for Na in the exchange complex. The ineffectiveness of blue-green algae was ascribed to their inability to mobilize Ca. It is argued that current theories favouring blue-green algae as a biological amendment to bring about alkali soil reclamation are untenable and are not comparable with an effective chemical amendment such as gypsum.     

Potential of Carbon Dioxide Biosequestration of Saline–Sodic Soils during Amelioration under Rice–Wheat Land Use

Potential for carbon dioxide (CO₂) biosequestration was determined during the reclamation of highly saline–sodic soils (Aridisols) after rice (2003) and wheat (2003–2004) crops at two sites in District Faisalabad, Pakistan. Two treatments were assessed: T₁, tube-well brackish water only; and T₂, soil-applied gypsum at 25% soil gypsum requirement?+?tube-well brackish water. The irrigation water used at both sites had different levels of salinity (EC 3.9–4.5 dS m^?1), sodicity (SAR 21.7–28.8), and residual sodium carbonate (14.9 mmol_c L^?1). Composite soil samples were collected from soil depths of 0–15 and 15–30 cm at presowing and postharvest stages and analyzed for pH, EC_e, and sodium adsorption ratio (SAR). After rice harvest, there was no significant effect of gypsum application on EC_e, pH, and SAR at both sites, except pH at 0–15 cm depth decreased significantly with gypsum at site 1. After wheat harvest, EC_e, pH, and SAR decreased significantly with gypsum at site 1, whereas the effect of gypsum on these parameters was not significant at site 2. Compared to initial soil, EC_e and SAR in soil decreased considerably after rice or wheat cultivation, particularly at site 1, whereas pH increased slightly due to cultivation of these crops. For rice, the total CO₂ sequestration was significantly increased with gypsum application at both sites and ranged from 1499 to 2801 kg ha^?1. The total sequestration of CO₂ was also significantly increased with gypsum application in wheat at both sites and ranged from 2230 to 3646 kg ha^?1. The amounts of CO₂ sequestered by crops due to gypsum application were related to seed and straw yield responses of rice and wheat to gypsum, which were greater at site 1 than site 2. Also, the yield response to applied gypsum was greater for rice than wheat at site 1, whereas the opposite was true at site 2. Overall, the combined application of gypsum with brackish water reduced soil EC_e and SAR compared to brackish water alone, particularly at site 1. Our findings also suggest that the reclamation strategies should be site specific, depending on soil type and quality of brackish water used for irrigation of crops. In conclusion, the use of gypsum is recommended on brackish water–irrigated salt-prone soils to improve their quality, and for enhancing C biosequestration and crop production for efficient resource management.     

Salt-tolerant forage cultivation on a saline-sodic field for biomass production and soil reclamation

Chemical reclamation of sodic and saline-sodic soils has become cost-intensive. Cultivation of plants tolerant of salinity and sodicity may mobilize the CaCO₃ present in saline-sodic soils instead of using a chemical approach. Four forage plant species, sesbania (Sesbania aculeata), kallar grass (Leptochloa fusca), millet rice (Echinochloa colona) and finger millet (Eleusine coracana), were planted in a calcareous saline-sodic field (EC_e = 9·6–11·0 dS m⁻¹, SAR = 59·4–72·4). Other treatments included gypsum (equivalent to 100 per cent of the gypsum requirement of the 15 cm soil layer) and a control (no gypsum or crop). The crops were grown for 5 months. The performance of the treatments in terms of soil amelioration was in the order: Sesbania aculeata ≅ gypsum > Leptochloa fusca > Echinochloa colona > Elusine coracana > control. Biomass production by the plant species was found to be directly proportional to their reclamation efficiency. Sesbania aculeata produced 32·3 Mg forage ha⁻¹, followed by Leptochloa fusca (24·6 Mg ha⁻¹), Echinochloa colona (22·6 Mg ha⁻¹) and Eleusine coracana (5·4 Mg ha⁻¹). Sesbania aculeata emerged as the most suitable biotic material for cultivation on salt-affected soils to produce good-quality forage, and to reduce soil salination and sodication processes.     

Implication of Gypsum Rates to Optimize Hydraulic Conductivity for Variable‐Texture Saline–Sodic Soils Reclamation

Sodium (Na⁺) dominated soils reduce saturated hydraulic conductivity (K_s) by clay dispersion and plugging pores, while gypsum (CaSO₄•2H₂O) application counters these properties. However, variable retrieval of texturally different saline–sodic soils with gypsum at soil gypsum requirement (SGR) devised to define its quantity best suited to improve K_s, leach Na⁺ and salts. This study comprised loamy‐sand (LS), sandy loam (SL), and clay loam (CL) soils with electrical conductivity of saturation extract (EC_e) of ~8 dS m⁻¹, sodium adsorption ratio (SAR) of ~44 (mmol L⁻¹)^1/2 and exchangeable sodium of ~41%, receiving no gypsum (G₀), gypsum at 25% (G₂₅), 50% (G₅₀) and 75% (G₇₅) of SGR. Soils packed in lysimeters were leached with low‐carbonate water [EC at 0·39 dS m⁻¹, SAR at 0·56 (mmol L⁻¹)^1/2 and residual sodium carbonate at 0·15 mmol_c L⁻¹]. It proved that a rise in gypsum rate amplified K_s of LS ≫ SL > CL. However, K_s of LS soil at G₂₅ and others at G₇₅ remained efficient for salts and Na⁺ removal. Retention of calcium with magnesium (Ca²⁺ + Mg²⁺) by LS and SL soils increased by G₅₀ and decreased in G₇₅, while in CL, it also increased with G₇₅. The enhanced Na⁺ leaching efficiency in LS soil with G₂₅ was envisaged by water stay for sufficient time to dissolve gypsum and exchange and leach out Na⁺. Overall, the superiority of gypsum for LS at G₂₅, SL at G₅₀ and CL at G₇₅ predicted cost‐effective soil reclamation with a decrease in EC_e and SAR below 0·97 dS m⁻¹ and 5·92 (mmol L⁻¹)^1/2, respectively. Copyright © 2015 John Wiley & Sons, Ltd.     

Amelioration of saline–sodic soil with gypsum can increase yield and nitrogen use efficiency in rice–wheat cropping system

A 2-year field experiment was conducted to determine crop yield and N use efficiency (NUE) from a saline–sodic soil (clay loam) with and without application of gypsum. Treatments included two N application rates (15% and 30%) higher than the recommended one to the normal soil, and gypsum added at 50% and 100% of soil gypsum requirement (SGR) to the saline–sodic soil, both cultivated with rice and wheat during 2011–2013. Results revealed a decrease in pH of saturated soil paste (pH_s), electrical conductivity of saturation extract (EC_e), sodium adsorption ratio (SAR) and exchangeable sodium percentage with N fertilizer along with gypsum application in saline–sodic soil. However, the effect was most prominent when gypsum was added at 50% of SGR. Crop yield and NUE remained significantly lower (p < 0.05) in saline–sodic-soils as compared to normal soil. However, gypsum application reduced this difference from 47% to 17% since both yield and NUE increased considerably. Crop yield and NUE remained higher for wheat than for rice. During first year, higher doses of N with gypsum application at 50% SGR proved most effective, whereas, in subsequent year, recommended N along with gypsum at 50% SGR became more profitable. All these results lead us to conclude that gypsum application can ameliorate saline–sodic soil thereby increasing crop yield and NUE.     

Sodic Soil Reclamation Potential of Gypsum and Biocharadditions: Influence on Physicochemical Properties and Soil Respiration

Reclamation of sodic soils is proving increasingly vital as greater land area becomes salt-affected in the northern Great Plains of the United States. Flue gas desulfurization gypsum (FGDG) can be an agriculturally important resource for increasing land productivity through the amelioration of sodic soils. Biochar is also considered as an aid in reclaiming degraded soils. In this incubation study, two rates of FGDG (33.6 Mg ha^?1 and 66.2 Mg ha^?1), two rates of biochar made from sugar beet (Beta vulgaris L.) pulp (16.8 Mg ha^?1), and one rate of FGDG combined with one rate of biochar (33.6 Mg ha^?1 ea.) were applied to a sodic soil. Soil physicochemical properties, including cationic exchange, pH, electrical conductivity (EC_e), sodium adsorption ratio (SAR_e), total organic carbon (TOC), water retention, and soil respiration rate, were assessed during and at the end of the incubation period. Addition of FGDG to sodic soil increased EC_e from 3.5 to 8.4 dS m^?1 and decreased SAR_e from 16 to 9. Biochar addition to sodic soil increased TOC from 62.2 to 99.5 μg g^?1 and increased soil respiration rate (mg C kg^?1 soil day^?1) on every measurement period. When FGDG and biochar were both added to the sodic soil, TOC did not significantly improve; however, EC_e increased from 3.5 to 7.7 dS m^?1, SAR_e decreased from 16 to 9, and soil respiration rate increased for all measurements. The results confirm there is potential for FGDG and biochar to reclaim sodic soils alone, and applied in combination.     

Amelioration of a calcareous saline-sodic soil by gypsum and forage plants

A field experiment was carried out at the University of Agriculture, Faisalabad (Pakistan) during 1988–90 to evaluate the comparative efficiency of chemical and biological methods for the reclamation of a calcareous saline-sodic soil (pHs

1 pHs = pH of saturated soil paste

= 8.2–8.6; ECe

2 ECe = Electrical conductivity of the saturation extract

= 7.4–9.0 dS m⁻¹; SAR

3 SAR = Sodium adsorption ratio

= 55.6–73.0 for upper 30 cm layer). Five treatments were assessed, three involved cropping: sesbania (Sesbania aculeata), sordan (Sorghum bicolor x Sorghum sudanese), and kallar grass (Leptochola fusca) and two were non-cropped (control and gypsum at 100.0 per cent GR-15·0 cm) were employed. Water of low electrolyte concentration (EC = 0.27 dS m⁻¹) was used for irrigation and leaching. Sesbania and kallar grass were found to be effective biotic materials for soil reclamation. These plant species produced substantial biomass and also improved the soil environment by lowering the EC and SAR of the soil. Sordan was relatively less-effective due to its sensitivity to high temperature and sodicity during germination and early seedling stages. After two cropping seasons, wheat (cultivar LU 26S) was sown as a test crop. Efficiency of treatments as indicated by wheat grain yield was in the order: sesbania = gypsum > kallar grass > sordan > control.     

Amelioration of sodic soils by trees for wheat and oat production

Prolonged occupation of sodic soils by trees results in the latters' amelioration in terms of decreased pH and electrical conductivity and improved organic matter and fertility status. To assess whether sodic soils reclaimed by tree plantations can be used for growing agricultural crops, a greenhouse pot trial was conducted during winter of 1994–95 (November–April) at the Central Soil Salinity Research Institute, Karnal, India. Wheat (Triticum aestivum, L; cultivar HD 2329) and oat (Avena sativa, L. cultivar local) plants were grown in topsoils (30 cm) collected from 24-year-old plantations of Prosopis juliflora, Acacia nilotica, Eucalpytus tereticornis, Terminalia arjuna and Albizia lebbek that had been established in 1970 on a highly sodic soil (pH₂ 10·2–10·5), and a reclaimed sodic soil from a farm field adjacent to the plantations. The organic carbon content and nutrient status of the soil under the 24-year-old plantations was much higher than that of a reference farm soil reclaimed through gypsum in 1974. Soil amelioration was highest under Prosopis canopies (pH 7·4 and organic carbon 0·89 per cent) in topsoil and minimum in Eucalpytus canopies (pH 8·6 and organic carbon 0·56 per cent). Reduced sodicity and improved fertility resulted in much better growth reference and productivity of the wheat and oat test crops grown on the five plantation soils, than in the reference farm soil. Grain and straw yields of wheat and oats were maximum in Prosopis soil (wheat 61·7 g grains and 87·5 g straw and oats 87·9 g grains and 111·1 g straw per pot) and minimum in Eucalpytus soil (32·3 and 25·3 g, and 42·7 and 58·5 g per pot). Grain yields of both wheat and oats obtained in the Prosopis soil were 4·5 and 3·5 times more, respectively, than obtained in the reference farm soil. The phosphorus concentration in whole plant tissues of wheat and oats was highest in Prosopis soils reflecting the prevailing phosphorus status and better restoration processes of the soils. Potassium concentration was little affected due to different soil treatments. The study clearly indicated that prolonged afforestation of sodic soils by tree plantations, particularly by Prosopis and Acacia trees, may restore the productivity of abandoned soils to much above the present agricultural production levels. The results further suggest that 24 years' occupation of sodic soils by trees, such as Prosopis, Acacia, Eucalyptus, Terminalia and Albizia, did not result in a build-up or accumulation of toxic allelochemicals which could be injurious to wheat and oats cultivation on such soils. © 1998 John Wiley & Sons, Ltd.     

Effect of freezing and thawing processes on some physical properties of saline–sodic soils mixed with sewage sludge or fly ash

Dispersion of saline–sodic soils was rather difficult to leach. Therefore, negative effects of freeze–thaw on soil physical properties should be reduced by inexpensive and practical methods. This study investigates the effect of freeze–thaw cycles (3, 6, and 9) on wet aggregate stability, bulk density, and permeability coefficient in three soils with different electrical conductivity and exchangeable sodium percentage levels (soil I: 5.30 dS m⁻¹, 47.51%; soil II: 42.80 dS m⁻¹, 55.45%; soil III: 36.30 dS m⁻¹, 59.34%) which consist of different proportions of sewage sludge and fly ash by volume (10%, 20%, and 30%). The experiment was conducted under laboratory conditions using disturbed and non-cropped soil samples mixed with sewage sludge and fly ash. Soils mixed with sewage sludge produced higher aggregate stability and permeability coefficients and lower bulk density values as compared to the soils mixed with fly ash. Sewage sludge added with a rate of 30% eliminated the negative effects of freeze–thaw processes on wet aggregate stability. Freeze–thaw processes did not affect the bulk density of the soils II and III, which were mixed with sewage sludge. However, fly ash addition decreased the bulk density of these soils very significantly after nine freeze–thaw cycles. Addition of sewage sludge or fly ash with rates of 20% and 30% significantly increased the permeability coefficients in soil I after nine freeze–thaw cycles. Results indicated that addition of sewage sludge and/or fly ash to saline–sodic soils could be alternative way for reducing negative effects of freezing–thawing on soil wet aggregate stability, bulk density, and permeability coefficient.     

施加脱硫石膏对盐碱土固碳的影响

增加陆地生态系统碳固定能力能有效缓解大气CO 2升高引起的温室效应。以干旱区典型盐土和碱土为研究对象,通过室内土柱模拟试验,研究不同施用量脱硫石膏(0,10,20,21.78,30,40 t/hm²)对盐土和碱土生态系统碳储量(包括土壤碳储量和生物量碳储量)的影响。结果表明:与对照相比,施加脱硫石膏盐土总碳储量(C)降低8.78%~15.72%,其中以土壤有机碳储量降低为主;碱土总碳储量(C)增加5.00%~23.94%,其中以土壤无机碳增加为主。脱硫石膏施加后盐土总生物量碳储量(C)较对照平均降低23.14%,碱土总生物量碳储量(C)较对照平均增加30.44%。施用脱硫石膏碱土生态系统碳储量(C)较对照增加0.09~0.42 kg/m²,而盐土生态系统碳储量(C)较对照降低0.33~0.56 kg/m²。相关分析结果表明,脱硫石膏施加量、土壤电导率以及由脱硫石膏施加引起的土壤含水量变化是影响盐碱土生态系统固碳的主要因素。总体上,施加脱硫石膏后,盐土生态系统碳储量显著降低,碱土生态系统碳储量显著增加,其中施加量30,40 t/hm²处理对盐碱土生态系统碳储量影响效果最大。研究结果可为增加干旱区生态系统碳固定提供科学参考。     

Characteristics of synthetic soil aggregates produced by mixing acidic “Kunigami Mahji” soil with coal fly ash and their utilization as a medium for crop growth

Abstract

This study was carried out to examine the characteristics and potential utilization of synthetic soil aggregates (SSA) produced by mixing acidic “Kunigami Mahji” soil in Okinawa, Japan, with waste materials, such as coal fly ash, used paper and starch, as media for crop growth. A series of different SSA were produced by incorporating various percentages (i.e. 0, 20, 40, 60, 80 and 100%) of coal fly ash into the “Kunigami Mahji” soil with used paper and starch. The particle density and bulk density of the original “Kunigami Mahji” soil were 2.67 and 1.23 g cm^?3, respectively. The increased percentages of added coal fly ash, used paper and starch significantly decreased the particle and bulk densities of SSA compared with the original “Kunigami Mahji” soil because of the low particle and bulk densities of the coal fly ash (2.10 and 0.96 g cm^?3, respectively). The SSA particle density varied between 2.39 and 2.14 g cm^?3, and bulk density varied between 0.72 and 0.81 g cm^?3, depending on the additional percentages of coal ash from 20–100%. Maximum water-holding capacity and saturated hydraulic conductivity were increased with the formation of SSA with coal fly ash, used paper and starch binder compared with the original “Kunigami Mahji” soil. The saturated hydraulic conductivity values of the SSA increased because of their low bulk density compared with the original soil. The addition of coal fly ash, used paper and starch to the acidic (pH = 4.62) “Kunigami Mahji” soil to form SSA increased the pH (6.70–9.96), electrical conductivity, exchangeable cation concentration and cation exchange capacity. The addition of coal fly ash up to 60% increased the aggregate strength. The growth and yield of komatsuna and soybean crops with SSA as a crop growth medium was assessed. Both crops showed the highest growth and yield when grown with SSA containing 20% of coal fly ash. Synthetic soil aggregates containing more than 20% of coal fly ash reduced plant growth and yield. Therefore, SSA produced from “Kunigami Mahji” soil with 20% of coal fly ash, used paper and starch can be successfully used as a medium for crop growth.     

Effect of Primary Biomethanated Spentwash on Soil Properties,Nutrient Uptake,and Yield of Wheat on Sodic Soil

The experiment on the effect of primary biomethanated spentwash (PBSW) on soil properties, nutrient uptake and yield of wheat on sodic soil was carried out at a research farm of Post Graduate Institute, Mahatma Phule Krishi Vidyapeeth, Rahuri, Maharashtra state, India, during the post-monsoon season. The experimental soil was sodic calcareous having Sawargaon series of isohyperthermic family of Vertic Haplustepts. The experiment was laid out in a randomized block design with nine treatments and three replications. The treatments consisted of varying doses of PBSW (100, 200, 300, 400 and 500 m³ ha^?1), absolute control, farmyard manure (FYM) 5 t ha^?1 + RDF-AST (recommended dose of fertilizer as per soil test), FYM 5 t ha^?1 + 50% GR (gypsum requirement) + RDF-AST and FYM 5 t ha^?1 + 100% GR + RDF-AST. The results revealed that the physical properties, namely bulk density and hydraulic conductivity, were improved in sodic soil due to the application of increased doses of PBSW. A significant reduction in pH, calcium carbonate and exchangeable sodium percentage (ESP) and an increase in organic carbon, cation-exchange capacity (CEC) and electrical conductivity (EC) were observed in the soil, due to the addition of PBSW. The available soil nitrogen (N), phosphorus (P), potassium (K) and micronutrient iron, manganese, copper and zinc (Fe, Mn, Cu and Zn) content after the harvest of wheat was the highest in the 500 m³ ha^?1 treatment compared with all the other treatments. The exchangeable calcium (Ca²⁺), magnesium (Mg²⁺) increased significantly and exchangeable Sodium (Na⁺) reduced significantly with increased doses of PBSW. The saturation paste extract analysis also showed the same trend. A significant increase in the EC of the saturation paste of extract of the soil was observed in all PBSW treatments and it was the highest (4.75 dS m^?1) in PBSW application @ 500 m³ ha^?1. The application of PBSW @ 500, 400, 300 and 200 m³ ha^?1 resembled the treatments of FYM + gypsum @ 100 GR + RDF-AST, FYM + gypsum @ 50 GR + RDF-AST and FYM + RDF-AST, respectively, regarding the biological properties of sodic soil. The PBSW application @ 500 m³ ha^?1 had recorded the highest grain (47.33 q ha^?1) and straw (72.72 q ha^?1) yield and the maximum total uptake of N, P, K, Fe, Mn, Cu, and Zn by wheat, which was at par with the treatment of FYM (5 t ha^?1) + gypsum @ 100% GR + RDF-AST.     

Does Biochar Improve Establishment of Tree Seedlings in Saline Sodic Soils?

Reforestation of saline sodic soil is increasingly undertaken as a means of reclaiming otherwise unproductive agricultural land. Currently, restoration of degraded land is limited to species with high tolerances of salinity. Biochar application has the potential to improve physical, biological and chemical properties of these soils to allow establishment of a wider range of plants. In a glasshouse trial, we applied biochar made from Acacia pycnantha (5 Mg ha⁻¹) or no biochar to either a low (EC_e 4·75 dS m⁻¹, ESP 6·9), a moderate (EC_e 27·6 dS m⁻¹, ESP 29·3) or a high (EC_e 49·4 dS m⁻¹, ESP 45·1) saline sodic soil. The regional common reforestation species Eucalyptus viminalis and Acacia mearnsii were planted as tubestock in to the soils. Early establishment indicators, including growth, plant condition and nutrition, were assessed at the end of a simulated growing season, 108 days after biochar application. Application of biochar increased height, and decreased root : shoot and the concentration of Mn, N and S in plants of E. viminalis when grown in the highly saline sodic soil. Biochar application increased the concentration of B in leaves of E. viminalis and increased the concentration of P, K and S in leaves of A. mearnsii when grown in the low saline sodic soil. The results confirm that there is potential for biochar to assist in reforestation of saline sodic soils. Copyright © 2015 John Wiley & Sons, Ltd.     

CaSO4改良苏打碱土的离子吸附交换过程分析与数值模拟

分析CaSO4改良苏打碱土的机理可以为其替代品(脱硫石膏、粉煤灰和磷石膏等)的田间应用提供理论依据。本文通过土柱试验构建了综合考虑离子吸附交换以及土壤水力传导度动态变化的多离子溶质运移方程,并利用UNSATCHEM软件进行了数值模拟。结果表明:CaSO4改良碱化土壤是一个伴随着离子吸附交换反应的复杂过程,同时受到土壤理化特性动态变化的影响,利用UNSATCHEM多离子溶质运移模型能够准确地模拟土壤溶液中Ca2 和Na 的迁移转化、土壤胶体Na 和土壤溶液中Ca2 的吸附交换过程,且其精度较高。同时,CaSO4改良苏打碱土并不是一个短期过程,要想使其彻底改良,一是需要不断淋洗,二是通过分次施加CaSO4,使碱化土壤在长期的一段时间内都保持一定的Ca2 源,以增加CaSO4的持续改良效果。     

Soil quality indices for evaluation of long‐term land use and soil management practices in semi‐arid sub‐tropical India

Land use changes and soil management can potentially alter soil quality. A study was conducted to assess the long‐term (>20 years) effects of perennial trees (PT), vegetable crops (VC), rice–wheat (RW) system, sewage‐irrigated fields (SF), maize–wheat (MW) system and uncultivated soils (US) on soil quality. Soil physical quality parameters were significantly affected only in the SF system when compared with the US soil, particularly for bulk density (BD 1·51 Mg m⁻³ in SF vs. 1·34 in US). Among chemical parameters, electrical conductivity was high in SF, and soil nutrients (N, P, K, S, Zn, Fe, Cu and Mn) were well above the critical limits of deficiency in all the systems. Soil parameters were integrated into soil quality indices (SQIs) by unscreened transformation and principal component analysis (PCA). SQI observed under each system were compared with the US to assess the degree of degradation. Mean SQI differences showed that PT (+16·02 per cent), VC (+4·80 per cent), RW (+10·04 per cent), and MW (+11·30 per cent) are aggrading, whereas SF (−2·06 per cent) is degrading with respect to the reference soil (US). Adoption of MW system proved to be better than traditional RW; and in general agricultural crops have a significant advantage than VC, in terms of maintaining soil quality. Sewage irrigation is not a sustainable practice and long‐term use may degrade the soil. Among the SQIs, PCA with nonlinear scoring function (NLSF) based SQI was effective in judging land degradation due to soil quality changes as affected by long‐term land use and soil management practices. Copyright © 2008 John Wiley & Sons, Ltd.     

Efficiency of Phosphogypsum and Mined Gypsum in Reclamation and Productivity of Rice–Wheat Cropping System in Sodic Soil

In this study, efficacies of mined gypsum and phosphogypsum (PG), when applied at equivalent doses, were compared for sodic soil reclamation and productivity of rice–wheat system. Application of PG, followed by karnal grass as first crop, resulted in the greatest reduction of soil pH and exchangeable sodium percentage (ESP) followed by PG applied at 10 Mg ha^?1 alone. Application of PG at 10 Mg ha^?1 resulted in greater yields of both rice and wheat than other treatments. Ditheylenetriaminepentaacetic acid (DTPA)–extractable micronutrients of PG-treated soil were greater than in mined gypsum–treated soil. A greater portion of applied P entered the calcium (Ca)–phosphorus (P) fraction in PG-treated soil, which also resulted in more soluble P than the mined gypsum–treated soil. Phosphogypsum effected greater increase in aggregation, soil organic carbon, microbial biomass carbon, and aggregate associated carbon and decrease in zeta potential, leading to increased hydraulic conductivity and moisture retention capacity in soil over mined gypsum–treated soil.     

Leaching and reclamation of calcareous saline‐sodic soil by moderately saline and moderate‐SAR water using gypsum and calcium chloride

Lysimeter experiments were conducted with sandy‐clay‐loam soil to study the efficiency of two amendments in reclaiming saline‐sodic soil using moderately saline and SAR (sodium‐adsorption ratio) irrigation water. Gypsum obtained from industrial phosphate by‐products and reagent grade Ca chloride were applied to packed soil columns and irrigated with moderately saline (ECe = 2.16 dS m^–1), moderate‐SAR water (SAR = 4.8). Gypsum was mixed with soil prior to irrigation at application rates of 5, 10, 15, 20, 25, and 32 Mg ha^–1, and Ca chloride was dissolved directly in leaching water at application rates of 4.25, 8.5, 12.75, 17.0, and 21.25 Mg ha^–1, respectively. The highest application rate in both amendments resulted in 96% reduction of total Na in soil. The hydraulic conductivity (HC) of soils receiving gypsum increased in all treatments. The highest HC value of 6.8 mm h^–1 was obtained in the highest application rate (32 Mg ha^–1), whereas the lowest value of 5.2 mm h^–1 was observed with the control treatment. Both amendments were efficient in reducing soil salinity and sodicity (exchangeable‐sodium percentage, ESP); however, Ca chloride was more effective than gypsum as a reclaiming material. Exchangeable Na and soluble salts were reduced with gypsum application by 82% and 96%, and by 86% and 93% with Ca chloride application, respectively. Exchangeable Ca increased with increasing amendment rate. Results of this study revealed that sodium was removed during cation‐exchange reactions mostly when the SAR of effluent water was at maximum with subsequent passage of 3 to 4 pore volumes. Gypsum efficiently reduced soil ESP, soil EC, leaching water, and costs, therefore, an application rate of 20 Mg ha^–1 of gypsum with 3 to 4 pore volumes of leaching water is recommended for reclaiming the studied soil.