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1.

Purpose

Sediment fingerprinting is a relatively recent research technique, capable of determining the origin of suspended sediment. In this study, we investigated sub-basins within a larger watershed we examined previously. The objectives were to determine if there was spatial variation in the origin of the suspended sediments and to test a streamlined fingerprinting approach which would reduce the cost, thereby paving the way for adoption by government agencies.

Materials and methods

Samples were collected from three tributaries, the outlet of the main stem, and at the middle of the main stem. Two methods to collect suspended sediment samples were compared: a mobile continuous-flow centrifuge and automated samplers. A relatively small initial tracer suite consisting of stable isotopes of nitrogen (N) and carbon (C) (15N and 13C), total N (TN), and total C (TC) was tested. Tracer concentrations were obtained through a single mass spectrometry analysis requiring <1 g of sediment.

Results and discussion

Multivariate discriminant analysis showed that three of the four tracers (δ 15N, δ 13C, and TC) from the initial pool were capable of accurate classification of the source samples. A multivariate mixing model showed that banks contributed the majority of sediment throughout all locations sampled and that in tributaries it was an even more dominant source. Despite variations in land use and stream order, the legacy sediments comprising the banks and floodplains were the main factor in impairment for suspended sediment. We found a small but statistically significant difference in δ 15N and δ 13C concentrations collected using automated samplers vs. the mobile centrifuge, but the effect on analysis of sediment source proportions was minimal.

Conclusions

The results of this study indicate that, at least in the study watershed, the majority of sediment in suspension was of streambank origin. A cost-effective tracer suite was identified as well as an attempt to make a streamlined approach to the technique. The streamlined approach cost much less ($7,550 US) than the conventional approach ($46,600 US) and should be suitable for total maximum daily loads analysis by state government agencies in the Southern Piedmont region of the USA.  相似文献   

2.
Lacustrine sediment cores from depositional areas have frequently been used to estimate pre-industrial rates of atmospheric Hg deposition. However, this approach tends to result in overestimates, partly because of Hg inputs from the catchment, partly because of a horizontal redistribution of sediments within lakes. Peat core studies may suffer from a vertical migration of Hg due to water table fluctuations. A natural Hg deposition rate around 2 μg m?2 y?1 is suggested to be more realistic than values of 3 to 12 μg m?2 y?1 reported from recent studies. The anthropogenic impact on the present Hg deposition may have been underestimated accordingly.  相似文献   

3.
Aerosol and total vapor-phase Hg concentrations in air have been measured at Walker Branch Watershed, Tennessee for ≈ 2 yr. Airborne Hg at this site is dominated by vapor forms which exhibit a strong seasonal cycle, with summer maxima that correspond to elevated air temperature. Concentrations in this forest are near background levels; however, concentrations at a site within 3 km are significantly elevated due to emissions from Hg-contaminated soils. The concentration data have been combined with a recently modified dry deposition model to estimate dry deposition fluxes to the deciduous forest at Walker Branch. Weekly mean modeled Vd values for Hg° ranged from <0.01 (winter) to > 0.1 (summer) cm s1. Weekly dry deposition fluxes ranged from <0.1 μg m−2 during winter to > 1.0 μgg m−2 in the summer. Our dry deposition estimates plus limited measurements of wet deposition in this area indicate that dry deposition may be the dominant input process in this forest, at least during the summer.  相似文献   

4.
To assess the sources, transport and deposition of atmospheric mercury (Hg) in Michigan, a multi-site network was implemented in which Hg concentrations in event precipitation and ambient samples (vapor and participate phases) were determined. Results from the analysis of 2 years of event precipitation samples for Hg are reported here. The volume-weighted average Hg concentration in precipitation was 7.9, 10.8 and 10.2 ng/L for the Pellston, South Haven and Dexter sites, respectively. Yearly wet deposition of Hg for 1992–93 and 1993–94 was 5.8 and 5.5 μg/m2 at Pellston, 9.5 and 12.7 μg/m2 at South Haven and 8.7 and 9.1 μg/m at Dexter. A spatial gradient in both the Hg concentration and wet deposition was observed. Northern Michigan received almost half the deposition of Hg recorded at the southern Michigan sites. The concentration of Hg in precipitation exhibited a strong seasonal behavior with low values of 1.0 to 2.0 ng/L in winter and maximum values greater than 40 ng/L in summer. The spring, summer and autumn precipitation accounted for 89 to 91% of the total yearly Hg deposition. Mixed-layer back trajectories were calculated for each precipitation event to investigate the meteorological history and transport from potential Hg source regions. Elevated Hg concentrations were observed with air mass transport from the west, southwest, south, and southeast. At each of the sites precipitation events for which the Hg concentration was in the 90th and 10th percentile were-analyzed for trace elements by ICP-MS to investigate source impacts.  相似文献   

5.

Purpose

Fine-grained sediment is an important pollutant in streams and estuaries, including the Chesapeake Bay in the USA. The objective of this study was to determine the sources of fine-grained sediment using the sediment fingerprinting approach in the Linganore Creek watershed, a tributary to the Chesapeake Bay.

Materials and methods

The sediment fingerprinting approach was used in the agricultural and forested, 147-km2 Linganore Creek watershed, Maryland from 1 August 2008 to 31 December 2010 to determine the relative percentage contribution from different potential sources of fine-grained sediment. Fine-grained suspended sediment samples (<63 μm) were collected during storm events in Linganore Creek using an automatic sampler and manual isokinetic samplers. Source samples were collected from 40 stream bank sites, 24 agricultural (cropland and pasture) sites, and 19 forested sites. Suspended sediment and source samples were analyzed for elements and stable isotopes.

Results and discussion

Results of sediment fingerprinting for 194 samples collected in 36 separate storm events indicate that stream banks contributed 53% of the annual fine-grained suspended sediment load, agriculture contributed 44%, and forests contributed 3%. Peak flows and sediment loads of the storms correlate to stream bank erosion. The highest peak flows occurred in the winter and, along with freeze–thaw activity, contributed to winter months showing the highest rate of stream bank erosion. Peak flow was negatively correlated to sediment sources from agricultural lands which had the greatest contribution in non-winter months. Caution should be observed when trying to interpret the relation between sediment sources and individual storms using the sediment fingerprinting approach. Because the sediment fingerprinting results from individual storms may not include the temporal aspects of the sourced sediment, sediment that is in storage from previous events, remobilized and sampled during the current event, will reflect previous storm characteristics. Stream bank sediment is delivered directly to the channel during an event, whereas the delivery of upland sediment to the stream is lower due to storage on hillslopes and/or in channels, sediment from stream banks are more likely to be related to the characteristics of the sampled storm event.

Conclusions

Stream banks and agricultural lands are both important sources of fine-grained sediment in the Linganore Creek watershed. Peak flows and sediment loads for the 36 storms show a significant relation to sediment sources from stream bank erosion. Attempting to link upland sediment sources to flow and seasonal characteristics is difficult since much of the upland sediment eroded in an event goes into storage. By averaging sediment sources over several storms, it may be possible to determine not only the sediment sources that are directly contributed during the current event but also sediment from previous events that was in storage and remobilized.  相似文献   

6.
Farmer adoption of practices to build soil health can be enhanced using a knowledge network supported by programs and resources that incorporate technical, social and experiential learning pathways. University Extension plays a critical role in building and supporting the knowledge network by serving as (a) a boundary organization to create space for conversations to occur, (b) network manager to facilitate learning and (c) builder of social capital to encourage trust in the network. The North Dakota State University (NDSU) Soil Health Program was used to illustrate the above approach. Between 2014 and 2016, 32 informal discussion groups, called Soil Health Café Talks, reached 156 individuals. A knowledge network of all participants was developed using NodeXL. The 10 most influential individuals in the network included two scientists, five farmers, one crop consultant and two Extension specialists. All non‐NDSU participants received an evaluation form. Respondents increased their frequency of discussing cover crops with other individuals and increased sharing equipment across farming operations (i.e., vertical tillage implements and no‐till drills). Of the topics discussed, over 25% of respondents adopted practices using cover crops (interseeding and using cover crops for weed control and adjusting rotations to incorporate cover crops) as a result of attending Café Talks. Respondents also increased their use of NDSU Soil Health online resources such as Twitter (22%), YouTube (23%) and the web page (21%) as follow‐up information to Café Talks. Network‐based approaches have proven to be successful in encouraging on‐farm adoption of soil health‐building practices.  相似文献   

7.
The importance of participate mercury (Hg(p)) in the transport, chemistry and deposition of this toxic metal has long been underestimated and largely ignored. While it was once believed to constitute a small percentage of total atmospheric mercury, Hg(p) may contribute a significant portion of the deposition of this metal to adjacent natural waters. Recent measurements of Hg(p) in several urban/industrial areas have documented that Hg can be associated with large particles (>2.5 μm) and in concentrations similar to those of the vapor phase Hg (ng/m3). As part of ongoing effort to diagnose the sources, transport and deposition of Hg to the Great Lakes and other Great Waters, the University of Michigan Air Quality Laboratory (UMAQL) has investigated the physical and chemical properties of particulate-phase Hg in both urban and rural locations. It appears that particulate Hg may be the one of the most difficult of the Hg measurements to perform, and perhaps the one of the most important for deposition and source apportionment studies. Particulate Hg concentrations measured in rural areas of the Great Lakes Region and Vermont ranged from 1 to 86 pg/m3 whereas Hg(p) levels in urban/industrialized areas were in the range 15 pg/m3 to 1.2 ng/m3.  相似文献   

8.
Journal of Soils and Sediments - Sapropel is an organic-rich sediment formed under conditions that can result in sequestration of trace metals. Here, we determined the concentration of total...  相似文献   

9.
10.
Understanding the watershed-scale spatial distribution of soil salinity and its compositions is important for soil management. Here, we present the first study on the Manas River watershed in northwest China. In this study, we took soil samples in upper 20 cm of soil from 186 locations across the watershed and measured total salt concentration (TSC), salt ion composition and soil particle size distribution (PSD). We found that on average topsoil TSC tended to increase, from 3.55 g kg−1 in upstream regions to 19.40 g kg−1 in downstream regions. The stoichiometric analysis showed that the equivalence ratio of soil Cl- to SO42− increased from 0.53 in upstream regions to 2.12 in midstream regions, and further to 3.76 in downstream regions; thus, the soil types were classified into chloride–sulfate, sulfate–chloride and chloride soils types, respectively. Additionally, proportions of small (<2 μm in diameter) and large (>2,000 μm) soil particles increased, while that of medium sizes (2–50 μm) decreased from upstream to downstream, with an increasing coefficient of variance (CV) in PSD. Taken together, watershed-scale topsoil salinity may be horizontally characterized by increased TSC and Na+ & Cl proportions, greater equivalence ratio of Cl vs. SO42− and more balanced distribution of PSD along with surface water flow. Results demonstrated that soil salinity and its ions compositions showed a great variation across the watershed scale, suggesting that soil management may consider the spatial heterogeneity of saline–alkaline soil types, and our results provided scientific guidance for local soil management and restoration.  相似文献   

11.

Purpose

Hydrosedimentological studies conducted in the semiarid Upper Jaguaribe Basin, Brazil, enabled the identification of the key processes controlling sediment connectivity at different spatial scales (100–104 km2).

Materials and methods

Water and sediment fluxes were assessed from discharge, sediment concentrations and reservoir siltation measurements. Additionally, mathematical modelling (WASA-SED model) was used to quantify water and sediment transfer within the watershed.

Results and discussion

Rainfall erosivity in the study area was moderate (4600 MJ mm ha?1 h?1 year?1), whereas runoff depths (16–60 mm year?1), and therefore the sediment transport capacity, were low. Consequently, ~60 % of the eroded sediment was deposited along the landscape, regardless of the spatial scale. The existing high-density reservoir network (contributing area of 6 km2 per reservoir) also limits sediment propagation, retaining up to 47 % of the sediment at the large basin scale. The sediment delivery ratio (SDR) decreased with the spatial scale; on average, 41 % of the eroded sediment was yielded from the hillslopes, while for the whole 24,600-km2 basin, the SDR was reduced to 1 % downstream of a large reservoir (1940-hm3 capacity).

Conclusions

Hydrological behaviour in the Upper Jaguaribe Basin represents a constraint on sediment propagation; low runoff depth is the main feature breaking sediment connectivity, which limits sediment transference from the hillslopes to the drainage system. Surface reservoirs are also important barriers, but their relative importance to sediment retention increases with scale, since larger contributing areas are more suitable for the construction of dams due to higher hydrological potential.  相似文献   

12.
Lead-210 dating of peat cores is one approach that has been used to arrive at historical rates of heavy metal deposition. Despite concerns regarding the validity of210Pb dating due to Pb mobility,210Pb dating can be used if the dates are corroborated with some other independent dating technique. In this study, based on analyses of210Pb dated, pollen corroborated peat cores from two sites in the Czech Republic (Jezerní sla and Bo?í Dar Bog), we illustrate a previously unexplored problem concerning the computation of metal deposition, using Pb as an example. When peat cores are collected, sectioned into depth intervals,210Pb dated and analyzed for metal contents, the210Pb dates most appropriately correspond to the midpoint depth for each interval, whereas the metal contents correspond to the interval between the top and bottom of each section. Thus the210Pb dates and metal content values throughout the core are offset by half the distance of each depth interval. In calculating historical rates of heavy metal deposition two approaches are available for correcting for the depth interval offsets, the traditional approach of date interpolation and our newly proposed metal content interpolation. We see noa priori reason for choosing one approach over the other, and suggest simultaneous use of both date and metal content interpolation. Additionally, acid-insoluble ash (AIA), which has been proposed as a dating technique in and of itself, may be more useful as an interpretive tool which may provide insights into the nature or sources of atmospherically deposited Pb. For example, plots of Pb content per core section versus AIA content per core section for Jezerní slat, located in a relatively pristine area, reveal increased Pb content without increased AIA contents in depths shallower than 6 cm, indicating deposition of gasoline-derived Pb after its introduction in 1922. Similar plots for Bo?í Dar Bog, located in a polluted industrialized region, indicate greater inputs of Pb than would be predicted from AIA, based on the Jezerní sla analyses. We interpret the apparent excess Pb deposition at Bo?í Dar Bog as being contributed by soil-derived dust from local metal mining. Elevated rates in Pb deposition at Bo?í Dar Bog are consistent with the history of local mining known to have occurred in the vicinity. Finally, magnetic susceptibility measurements identify combustion of fossil fuels as a source of atmospheric Pb deposition at Bo?í Dar Bog, but not at Jezerní sla   相似文献   

13.
The Heavy Metal Eulerian Transport (HMET) model has been used to calculate the exchange of As, Cd, Pb and Zn between European countries in 1985. The model was run separately for each emitter country and the computed deposition field was used to calculate the contribution of the emitter to each receptor country. The results of these computations are presented in the form of a country budget matrix for each metal. Accuracy of such computations is dependant on the size and linearity of the numerical method applied to the transport equation. Exchange of heavy metals due to atmospheric transport over Europe is significant. Approximately 30% to 90% of the heavy metals emitted from each country is deposited in other countries. The remaining mass is deposited in European seas, Atlantic Ocean and transported outside the model domain. The largest part of the emission from each country is deposited in the same country. The next largest fraction is transported to the nearest neighbors. The results indicate also a significant long range ransport of heavy metals to the Soviet Union. This is partly justified by the size and location of this receptor country, as well as, the prevailing meteorological conditions in Europe. However, this large transport to USSR is slightly overestimated due to some artificial properties of the numerical method applied to basic model equations. In addition to the country budget, export versus import and emission versus deposition of metals were analyzed for each country. The largest positive difference between export and import was found for Poland, German Federal Republic and Yugoslavia (As, Cd and Zn), and United Kingdom, Italy and Belgium (Pb). The Soviet Union and Czechoslovakia are the countries where import of all metals is significantly larger than export. When emission versus deposition of heavy metals is analyzed, the Soviet Union has much higher emissions than deposition of all metals compared to other European countries.  相似文献   

14.
The AnnAGNPS model, widely utilized as a practical tool for addressing erosion problems and land use planning, was implemented in a small agricultural watershed located in central Belgium, to assess its prediction capacity of runoff, peak flow and sediment yield in humid temperate conditions. Model performance was evaluated at the event scale by using a database reporting hydrological, geomorphologic and land use data collected during a 2‐year period. Seventeen events were modelled and compared with the corresponding observations at the watershed outlet. The model performed well in predicting the largest runoff volumes, as shown by the high values achieved for the coefficients of efficiency (E = 0·89) and determination (r2 = 0·92). However, some events resulted in zero runoff simulation. The prediction capability for peak flow and sediment yield was poor (E = 0·35 and 0·16, respectively). This inaccuracy can have several causes: the internal model deficiencies may be due to the incomplete representation of watershed complex processes, while external problems may be related to the conditions within the modelled watershed and the quality of recorded data. On the whole the AnnAGNPS model may be considered as being suitable to simulate the significant runoff events in the experimental watershed. However, the model may be seen as better suited for comparative assessments of alternative management and policy scenarios and for gross estimation of nutrient loads rather than the precise prediction of a single event, consequently helping in the prediction of land degradation problems in the experimented conditions. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

15.
Water and sediment parameters, with emphasis on S constituents, were compared among lakes (Oneida, South, Deer), seasons, sites and sediment depths. The three lakes differed in size, morphometry, productivity and acid neutralizing capacity and none of the lakes had anoxia in the water column. Redox potentials (Eh) were higher for oligotrophic South and mesotrophic Deer than cutrophic Oneida within the sediment. In the water column, the only S constituent measured was sulfate which was higher in nutrient rich Onieda (110 to 490 μmol I?1) than South (30 to 70 μmol I?1) or Deer (10 to 60 μmol ?1) Total S in sediment was higher for South than for either Deer or Oneida. For Deer and South sediment, total S was greatest in the 5 to 15 cm layer, and this was likely due to historical changes in anthropogenic inputs through atmospheric deposition. The high S concentration in South sediment can be accounted for by particulate deposition of S through the water column. Organic S constituents constituted major forms of S in the sediments of the three lakes. Non-HI reducible S, of which carbon-bonded S was a dominant constituent, comprised a major portion of total S in Oneida, South and Deer. Ester sulfate was the next largest S constituent in South and Deer. As a percent of total S, sulfide (HCL digestion) and sulfate was higher in Oneida than South or Deer. There was an inverse relationship between sediment Eh and sulfide. Pyritic S was measured on bulk samples and constituted 37, 12, and 6% of total S in Oneida, South and Deer. Both inorganic and organic S forms showed seasonal variation and the transformation and translocation of these forms play an important role in the S dynamics of lakes.  相似文献   

16.
Background, aim and scope  Street sediment samples were collected at 50 locations in a mixed land use area of Hamilton, Ontario, Canada, and metal levels were analyzed using a sequential extraction procedure for different particle size classes to provide an estimate of potential toxicity as well as the potential for treatment through best management practices (BMPs). Methodology  The street sediment samples were dry sieved into four different particle size categories and a sequential extraction procedure was done on each size category following the methodology proposed by Tessier et al. 1979 using a Hitachi 180-80 Polarized Zeeman Atomic Absorption Spectrophotometer. Results and discussion  Analysis of variance, post hoc least-significant difference tests, and kriging analysis showed that spatially Mn and Fe levels were associated with a well-defined heavy industrial area that includes large iron- and steel-making operations; Cu and Pb were associated with both the industrial and high-volume traffic areas, while Zn tended to be more associated with high-volume traffic areas. The potential bioavailability of the metals, based on the sum of chemical fractions 1 (exchangeable) and 2 (carbonate-bound), decreased in order: Zn > Cd > Mn > Pb > Cu > Fe. Based on aquatic sediment quality guidelines, there is some concern regarding the potential impact of the street sediment when runoff reaches receiving waters. Conclusions  It is possible that a combination of BMPs, including street sweeping and constructed wetlands, could help to reduce street sediment impact on environmental quality in the Hamilton region. The data presented here would be important in developing and optimizing the design of these BMPs.  相似文献   

17.

Purpose  

The management of natural resources over large spatial scales is inherently complex due to numerous biophysical and socioeconomic factors and the uncertainty associated with environmental systems and human behavior. Numerous approaches have been put forward to facilitate the decision-making process, including adaptive management (AM) which was developed in the 1960s and 1970s as an alternative to more rigid management frameworks. In recent years, it has been utilized for the management of water and river basin resources, particularly in North America. Its use for sediment resources is less well developed. This paper presents a review of the AM approach, including its characteristics, steps, and barriers to implementation. It also gives some recent examples where the AM approach has been used for sediment quantity and quality issues. Finally, it considers the potential of the AM approach for sediment resource management given Water Framework Directive and other legislative requirements.  相似文献   

18.
The southeastern Piedmont of the USA was severely gullied during the early 20th century. A thick canopy established by reforestation in many areas now inhibits the identification or mapping of gullies by aerial photography or other conventional remote sensing methods. An Airborne Laser-Scanning (ALS or LiDAR) mapping mission flown for the U.S. Forest Service in April, 2004 acquired bare-Earth topographic data. This paper tests the ability of the ALS topographic data to identify headwater channels and gullies for two branching gully systems in forested areas and to extract gully morphologic information. Comparisons are made with field traverses using differential GPS and reference cross sections measured by leveling surveys. At the gully network scale, LiDAR data provide accurate maps – the best available – with robust detection of small gullies except where they are narrow or parallel and closely spaced. Errors in mapping channel location and network topological connectivity under forest canopy increase with attempts to identify smaller features such as large rills. The ability of LiDAR data to map gullies and channels in a forested landscape should improve channel-network maps and topological models. At the gully reach scale, attempts to use LiDAR data to extract gully cross-section morphologic information under forest canopy were less successful due to systematic underestimation of gully depths and overestimation of gully top widths. Limited morphologic accuracy of the data set at this scale may be due to low bare-Earth point densities, shadowing of gully bottoms, and filtering of topographic discontinuities during post-processing. The ALS data used in this study are not suitable for detailed morphometric analysis or subtle change detection to monitor gullies or develop sediment budgets. Data collection may be improved by orienting flights over gullies and with increased point densities through improved scanner technology or better filtering and software capabilities to differentiate between vegetation and ground surfaces.  相似文献   

19.
OBJECTIVE: Previous research on the health transition and nutrition security in black South African households revealed the need for further research among farm workers who belong to the poorest population categories. This article gives an overview of the link between nutrition security, livelihoods and HIV/AIDS in South Africa, drawing conclusions for research among farm worker households. DESIGN AND SETTING: A literature review, observations on farms and interviews with farmers and key informants were carried out in 2003 and 2004. Peer examination was done with South African and German researchers from the natural and social sciences. RESULTS: Farm workers face poverty and nutrition insecurity and continue to be a tragically underserved population group, also in terms of research. There is furthermore a lack of in-depth research on underlying causes for nutrition security in South Africa and on the link with livelihoods, poverty and HIV/AIDS. Micro-social qualitative research from the household and gender perspective is required, as valid data on households, their internal dynamics and therefore the reflection of social realities are missing. A multidisciplinary research approach based on a new conceptual framework was developed to address the situation of farm worker households. CONCLUSION: The outlined research contributes to existing programmes on farms in the North West Province, with the findings being valid also for other parts of southern Africa facing poverty, nutrition insecurity and HIV/AIDS.  相似文献   

20.
Li  Tong  Wang  Shuai  Liu  Yanxu  Fu  Bojie  Zhao  Wenwu 《Journal of Soils and Sediments》2020,20(3):1719-1729
Journal of Soils and Sediments - The Mississippi River is the largest river in the USA and one of the most regulated rivers in the world. Understanding fluvial sediment flux changes in the...  相似文献   

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