Bauxite residue fines as an amendment to residue sands to enhance plant growth potential—a glasshouse study

Purpose  

This glasshouse study was conducted to determine if amending bauxite residue sand with residue fines would improve its suitability as a growth medium. Alcoa’s West Australian operations mechanically separate residue into two size fractions: residue fines (which are dominated by particles <150 μm) and residue sands (>150 μm). Residue sand represents the primary material used as a growth medium for rehabilitation, and prior to amendments, it exhibits many characteristics unfavourable for plant growth.     

Biochar amendment changes temperature sensitivity of soil respiration and composition of microbial communities 3 years after incorporation in an organic carbon-poor dry cropland soil

Topsoil samples were collected from plots in a dry cropland in the North China Plain 3 years after a single incorporation of biochar at 20 and 40 t ha^?1 and analyzed for abundances and composition of microbial community and for respiration under controlled laboratory conditions at 15, 20, and 25 °C. The addition of biochar generally reduced soil respirations at the three temperatures and the temperature sensitivity (Q₁₀) at 15–20 °C. Biochar amendment significantly increased bacterial 16S rRNA gene abundances and fungal ITS gene diversity and induced clear changes in their community compositions due to improvements in soil chemical properties such as soil organic C (SOC) and available N contents and pH. Illumina Miseq sequencing showed that the relative abundances of Actinobacteria, Gammaproteobacteria, Firmicutes, and Alternaria within Ascomycota, capable of decomposing SOC, were significantly decreased under biochar at 40 t ha^?1. The Q₁₀ values at 15–20 °C were significantly correlated with fungal diversity and dehydrogenase activity. Our results suggest that after 3 years a single biochar amendment could induce a shift in microbial community composition and functioning towards a slower organic C turnover and stability to warming, which may potentially reduce soil C loss in dryland under climate warming in the future.     

Application of soil amendments to contaminated soils for heavy metal immobilization and improved soil quality—a critical review

ABSTRACT

Today, soil metal pollution has become a significant environmental issue of great public concern. This is because soil is both a major sink for heavy metal(loid)s (HMs) released into the environment, by both pedogenic and anthropogenic activities; and also a major source of food chain contamination mainly through plant uptake and animal transfer. In addition, HM contamination of soil leads to negative impacts on soil characteristics and function by disturbing both soil biological and physiochemical properties (e.g. extreme soil pH, poor soil structure and soil fertility and lack of soil microbial activity). This eventually leads to decreased crop production. Various soil remediation techniques have been successfully employed to reduce the risks associated with HMs efflux into soil. Among these, the use of low-cost and environmentally safe inorganic and organic amendments for the in-situ immobilization of HMs has become increasingly popular. Immobilization agents have successfully reduced the availability of metal ions through a variety of adsorption, complexation, precipitation, and redox reactions. Soil amendments can also be a source of nutrients and thus can also act as a soil conditioner, improving the soil’s physiochemical properties and fertility, resulting in enhanced plant establishment in metal contaminated soils. This article critically reviews the use of immobilizing agents in HM contaminated agricultural and mining soils paying particular attention to metal immobilization chemistry and the effects of soil amendments on common soil quality parameters.     

Humic acid composition and soil fertility of soils near an ancient charcoal kiln: are they similar to Terra Preta de Índios soils?

Journal of Soils and Sediments - Charcoal production during the nineteenth century transformed landscapes in the Brazilian Atlantic Forests in Rio de Janeiro city. These paleo-territories were...     

Organic waste amendment effects on soil microbial activity in a corn–rye rotation: Application of a new approach to community-level physiological profiling

The role of phosphorus (P) application and arbuscular mycorrhizal fungi (AMF) on growth, arsenic (As) and P accumulation in lettuce plants growing in an As-polluted soil (total As 250 mg kg⁻¹), was investigated. In particular, it was tested whether application of a commercial inoculum (CI), with (+P at 90 kg P ha⁻¹) and without (−P at 0 kg P ha⁻¹) P fertilizer, supported greater plant growth and provided more P, enhancing As tolerance, than indigenous fungi alone. The influence of these treatments on As and P availability in the rhizosphere and bulk soils was also investigated. Greenhouse pot experiments were established where plants were grown with and without commercial inoculum (+CI, −CI) in unsterilized conditions. Inoculation with commercial inoculum and P application together considerably increased plant biomass, by enhancing host plant P nutrition and lowering shoot and root As concentrations compared to plants inoculated only with native AMF. In the rhizosphere of +CI+P plants there was P soil depletion compared to −CI+P. The results evidenced that, with P addition, inoculation with commercial inoculum alleviated the toxicity of excessive As by improving P nutrition without increasing As concentrations in the plant, emphasizing the role of beneficial microbes and P fertilizer to improve soil fertility in As-contaminated soil.     

Clay amendment to sandy soil—effect of clay concentration and ped size on nutrient dynamics after residue addition

Purpose

Crop growth on sandy soils can be increased by claying. In modified sandy soils, the added clay is in the form of peds ranging in size from millimetres to centimetres creating a highly non-uniform matrix where ped size could influence nutrient availability and organic C binding. The aim of the study was to determine the effect of clay addition rate and ped size in residue amended sandy soil on soil respiration, nutrient availability and organic C retention.

Materials and methods

In this study, clay peds of 1, 2 or 3 mm size derived from a clay-rich Vertosol (73 % clay) were added to a sandy soil (3 % clay) at clay addition rates of 10 and 20 % w/w. After the addition of ground faba bean residue (C/N 37) at 10 g kg^?1, the soils were incubated for 45 days at 80 % of water-holding capacity.

Results and discussion

Clay addition had no consistent effect on cumulative respiration, but reduced NH₄ ⁺ availability with a greater reduction at 20 % compared to 10 % clay and with 1 and 2 mm compared to 3 mm peds. Sandy soil with clay peds had a greater maximum NH₄ ⁺ and P sorption capacity than sandy soil alone, and sorption capacity was higher at 20 % compared to 10 % clay addition and greater with 1 mm compared to 3 mm peds. Retrieval of clay peds at the end of the experiment showed ped breakdown during the experiment but also the formation of larger peds. Compared to the <53 μm fraction added at the start of the experiment, the total organic carbon (TOC) content of the <53 μm fraction was increased up to nearly two fold, particularly in the smaller peds (1 and 2 mm).

Conclusions

When sandy soils are amended with clay, N availability and organic C binding depend on both clay addition rate and ped size.

     

Studies on the survival of algae added to chemically treated soils—1. methodology

A modification of the method of Tchan (1952) for the direct enumeration of soil algae was evaluated with a view to determining effects of pesticides and herbicides upon soil algae. Modifications to Tchan's technique were the use of a Hg vapour u.v., light source for microscopy and a specially designed haemocytmeter slide. These modifications increased the intensity of fluorescence of algal cells, facilitated accurate estimation of numbers in soil as shown by high percentage recoveries of known numbers of algal cells added to sterile soil, and enabled transmitted or incident light systems to be used equally successfully.Using direct microscopy, various algal cells in culture were examined for fluorescence. Fluorescence during different stages of growth of two species of unicellular green algae was determined. Viable cells at all stages of growth were found to fluoresce. Newly killed cells, inactivated by heat, acid and herbicide treatment were found not to fluoresce. Twenty seven species of algae, selected for their wide range of structure and for their common occurrence in British soils were all found to fluoresce either in culture or when incubated in sterile soil.Four different (agronomic) soil types were examined for indigenous algae. To overcome seasonal variations that occur in numbers of algae, the effect of seeding soils with a mixed inoculum of algal cells was determined.The effects of shaking and ultra-sonicating soil suspensions before examination were compared in order to recover efficiently a known number of cells added to different soils. Survival of added algae in four soils of pH 5.8–7.8, and in one soil maintained at moisture contents ranging from 20–100% of the moisture holding capacity was determined. Growth of algae in soil at two different light intensities was also examined.     

Loss‐on‐ignition as an estimator of soil organic carbon in a‐horizon forestry soils

Abstract

The determination of soil organic matter by wet digestion techniques is a slow and laborious analysis. Loss‐on‐ignition (LOI) provides a simple alternative technique for the estimation of soil organic carbon in non‐calcareous A horizon soils of the Natal midlands and Zululand forestry regions. Using multiple regressional techniques, the relationships between loss‐on‐ignition, Walkley organic carbon and soil texture for 55 soils were determined over a range of ignition temperatures. The relationships hold best for soil samples with relatively low organic carbon contents (< 5%). The optimum temperature for ignition was found to occur at 450°C and resulted in the relationship: Soil organic carbon = 0.284*LOI percent. No advantage is gained through ignition at higher temperatures due to the loss of clay mineral structural water, even if the soil texture is accurately known.     

Contribution of Subcommission a (salt affected soils) to the achievements in the investigation and management of saline and Alkali soils 1964–2001

This paper was written by M. Redly soon before her death in September 2010. It summarizes the work of a big team of soil scientists studying the genesis, geography, and method of reclamation of salt-affected soils in the second half of the 20th century. It is also a tribute to I. Szabolcs, the organizer and the first chairman of the Subcommision on Salt-Affected Soils at the ISSS. The work of this subcommision can be considered an inspiring example of international cooperation in solving topical problems of soil science.     

Inoculation of pines with mycorrhizal fungi in natural soils—I.: Effects of density and time of application of inoculum and phosphorus amendment on mycorrhizal infection

On two soils lacking fungi capable of forming mycorrhizas with Pinus, the addition of superphosphate at 40 kgP/ha greatly increased mycorrhiza formation in Pinus radiata D. Don and P. elliottii Little and Dorman. Phosphorus could be partially replaced by increasing inoculum density or avoiding delay in inoculation after sowing. Chlamydospores were less effective than basidiospores as inoculum except at the highest density and in the presence of added P. At low available P concn such as are common in Australian soils, the normal pattern of infection of new short roots is interrupted and re-infection from the soil is of greater importance. Survival of mycorrhizal fungi in the soil in the absence of the host may therefore be a critical factor in inoculation programs.     

Inoculation of pines with mycorrhizal fungi in natural soils—II.: Effects of density and time of application of inoculum and phosphorus amendment on seedling yield

Addition of superphosphate at 40 kgP/ha greatly increased yield in seedlings of Pinus radiata D. Don, and P. elliottii Little and Dorman on two soils lacking fungi capable of forming mycorrhizas with Pinus. P could be partially replaced by increasing inoculum density or avoiding delay in inoculation. Chlamydospores were less effective than basidiospores as inoculum, and there were highly significant differences in yield produced by different fungal species at high inoculum densities and in the presence of added P. These effects are discussed with respect to the intensity of mycorrhizal infection and postulated differences in sensitivity to microbial competition and antagonism.     

More evidence that anaerobic oxidation of methane is prevalent in soils: Is it time to upgrade our biogeochemical models?

Estimating future fluxes of CH₄ between land and atmosphere requires well-conceived process-based biogeochemical models. Current models do not represent the anaerobic oxidation of methane (AOM) in land surface soils, in spite of increasing evidence that this process is widespread. Our objective was to determine whether AOM, or potential AOM, commonly occurs in 20 hydromorphic soils spanning a wide range of chemical properties. Bulk soil samples were collected under shallow water near the shoreline of 15 recently drained fish ponds in southern Bohemia (Czech Republic), as well as from below the water table at 3 peatland locations in northeast Scotland and 2 acid sulfate soils on the southern coast of Finland. Each soil slurry was incubated under both oxic and anoxic conditions, with or without the addition of alternative electron acceptors (SO₄²⁻ and NO₃⁻) or H₂PO₄⁻. Here, “oxic” and “anoxic” conditions refer to anoxic soil respectively incubated in a headspace containing air or argon. Using the isotope dilution method, we determined the gross production and oxidation rates of CH₄ after 2 days incubation under oxic headspace conditions, and after 2, 21 and 60 days incubation under anoxic conditions. Large differences in net CH₄ fluxes were observed between soil types and between incubation conditions. AOM was detected in each of the 20 bulk soil samples, which spanned >6 pH units and 2 orders of magnitude in organic C content. Significant positive relationships were found between AOM and gross CH₄ production rates under anoxic conditions, resulting in AOM rates that were sometimes higher than CH₄ oxidation rates under oxic headspace conditions. There was no relationship between net and gross CH₄ production rates, such that 2 soil types could display similar low net rates, yet conceal very large differences in gross rates. The effects of alternative electron acceptors on AOM were idiosyncratic and resulted in no net trend. We did find, however, a negative effect of SO₄²⁻ and H₂PO₄⁻ on gross CH₄ production rates under anoxic and oxic conditions respectively. Under oxic headspace conditions, CH₄ oxidation was related to soil organic C content. Taken collectively, our results suggest that AOM, or potential AOM, is prevalent over a wide range of soil types, that AOM may contribute substantially to CH₄ oxidation in soils, and that AOM in soils should be integrated to current process-based CH₄ cycling models.     

Analysis of cinnamaldehyde and diallyl disulfide as eco-pesticides in soils of different textures—a laboratory-scale mobility study

Journal of Soils and Sediments - This work presents for the first time the development of a method for the analysis of cinnamaldehyde and diallyl disulfide in soil by ultrasound assisted extraction...     

Properties and classification of selected volcanic ash soils from Abashiri,Northern Japan—transition of Andisols to Mollisols

Abstract

Properties and classification of four selected volcanic ash soils from Abashiri, Hokkaido were studied and the transition of Andisols to Mollisols was discussed. Two of the four pedons (Brown Andosol and Cumulic Andosol)¹ showed morphological, clay mineralogical, physical, and chemical properties common to most Andisols in Japan. However, the properties of the other two pedons (Acid Brown Forest soil and Brown Forest soil)¹ were considerably different from those of common Andisols in Japan. It was found that the changes in the andic soil properties or transition of Andisols to Mollisols was closely related to the progression of clay weathering, mainly the transformation of noncrystalline clay materials to halloysite. One of the four pedons (Brown Forest soil)¹had the clay fraction dominated by halloysite from the uppermost horizon down to the bottom of the profile and satisfied both andic and mollic requirements. Thus we concluded that the pedon is a transitional soil between Andisols and Mollisols and that the transition is closely related to the duration of surface weathering under relatively weak leaching conditions. The four pedons were classified according to the Andisol Proposal (Leamy et al. 1988, New Zealand Soil Bureau) as follows:

Pedon 1: Medial, amorphic (allophane/imogolite), frigid Typic Hapludand (Brown Andosol).¹ Pedon 2: Medial, amorphic (allophane/imogolite), frigid Typic Melanudand (Cumulic Andosol).¹ Pedon 3: Medial, amorphic (allophane/ imogolite), over kandic, frigid Typic Melanudand (Acid Brown Forest soil).¹ Pedon 4: Medial, kandic, frigid Typic Hapludand (Brown Forest soil).¹     

Economic benefits of large-scale remediation of contaminated marine sediments—a literature review and an application to the Grenland fjords in Norway

Purpose  

As input to a cost-benefit analysis of large-scale remediation measures of contaminated sediments in the Grenland fjords in Norway, we conducted a contingent valuation (CV) survey of a representative sample of households from municipalities adjacent to these fjords.     

Inorganic and organic carbon dynamics in forested soils developed on contrasting geology in Slovenia—a stable isotope approach

Purpose

Soil carbon dynamics were studied at four different forest stands developed on bedrocks with contrasting geology in Slovenia: one plot on magmatic granodiorite bedrock (IG), two plots on carbonate bedrock in the karstic-dinaric area (CC and CD), and one situated on Pleistocene coalluvial terraces (FGS).

Materials and methods

Throughfall (TF) and soil water were collected monthly at each location from June to November during 2005–2007. In soil water, the following parameters were determined: T, pH, total alkalinity, concentrations of Ca²⁺ and Mg²⁺, dissolved organic carbon (DOC), and Cl^? as well as δ¹³C_DIC. On the other hand, in TF, only the Cl^? content was measured. Soil and plant samples were also collected at forest stands, and stable isotope measurements were performed in soil and plant organic carbon and total nitrogen and in carbonate rocks. The obtained data were used to calculate the dissolved inorganic carbon (DIC) and DOC fluxes. Statistic analyses were carried out to compare sites of different lithologies, at different spatial and temporal scales.

Results and discussion

Decomposition of soil organic matter (SOM) controlled by the climate can explain the ¹³C and ¹⁵?N enrichment in SOM at CC, CD, and FGS, while the soil microbial biomass makes an important contribution to the SOM at IG. The loss of DOC at a soil depth of 5 cm was estimated at 1 mol m^?2 year^?1 and shows no significant differences among the study sites. The DOC fluxes were mainly controlled by physical factors, most notably sorption dynamics, and microbial–DOC relationships. The pH and pCO₂ of the soil solution controlled the DIC fluxes according to carbonate equilibrium reactions. An increased exchange between DIC and atmospheric air was observed for samples from non-carbonate subsoils (IG and FGS). In addition, higher δ¹³C_DIC values up to ?19.4?‰ in the shallow soil water were recorded during the summer as a consequence of isotopic fractionation induced by molecular diffusion of soil CO₂. The δ¹³C_DIC values also suggest that half of the DIC derives from soil CO₂ indicating that 2 to 5 mol m^?2 year^?1 of carbon is lost in the form of dissolved inorganic carbon at CC and CD after carbonate dissolution.

Conclusions

Major difference in soil carbon dynamics between the four forest ecosystems is a result of the combined influence of bedrock geology, soil texture, and the sources of SOM. Water flux was a critical parameter in quantifying carbon depletion rates in dissolved organic and inorganic carbon forms.

     

Sediment as a dynamic natural resource—from catchment to open sea

Journal of Soils and Sediments -     

Vineyard soils under organic and conventional management—microbial biomass and activity indices and their relation to soil chemical properties

Eight vineyards in Pfaffenheim (P) and Turckheim (T) close to Colmar, France, forming four pairs of organic and conventional vineyards, were analyzed for microbial biomass and activity indices in relation to important soil chemical properties (carbon, nutrient elements, heavy metals) and also to differences between the bottom and top positions on the vineyard slope. The question was whether the vineyard management affects especially the soil microbiological indices. Three locations were on limestone (P-I, P-II, T-II), one on granite (T-I). The gravel content (>2 mm) ranged from 9 to 47%. The management systems had no significant main effect on the contents of organic C, total N, P, and S. The mean total contents of man-derived heavy metals decreased in the order Cu (164 μg g⁻¹ soil) > Zn (100 μg g⁻¹ soil) > Pb (32 μg g⁻¹ soil). The contents of microbial biomass C varied between 320 and 1,000 μg g⁻¹ soil. The significantly highest content was found at location P-II, the significantly lowest at the moderately acidic location T-I. The contents of microbial biomass N and adenosine triphosphate showed a similar trend. At location T-I, the fungal ergosterol-to-microbial biomass C ratio and the metabolic quotient qCO₂ were significantly highest, whereas the percentage of soil organic C present as microbial biomass C was lowest. Highest percentages of soil organic C present as microbial biomass C and lowest qCO₂ values were found in the organic in comparison with the conventional vineyards. None of the soil microbiological indices was significantly affected by the position on the slope, but all were significantly affected by the management system. This was mainly due to the highest index levels in the organic vineyard location P-II with the longest history in organic management.     

Optical sensing and chemometric analysis of soil organic carbon – a cost effective alternative to conventional laboratory methods?

Soil organic carbon (SOC) is frequently determined by the Walkley‐Black (WB) method. A limitation of the test is incomplete oxidation of the carbon fraction and underestimation of SOC. Automated dry combustion methods are expensive and slow. Optical sensing and chemometric analysis offer the potential of an economical method capable of quantifying SOC fractions. The aim of this study was to identify the best SOC analysis method to facilitate maximum sampling resolution based on the cost per sample, analytical accuracy and time. A comparative evaluation was made of five techniques; (1) the WB method, (2) total combustion by total organic C analyser, (3) infrared (IR) diffuse reflectance spectroscopy, (4) a portable spectroradiometer and (5) laboratory hyperspectral imaging. This involved assessing equipment costs, consumables and time to derive total analytical cost. The benefits were sample throughput and analytical accuracy. Instrumentation represented the largest input to analytical cost and for optical methods was governed by the spectral range. In contrast to dry combustion, this cost is offset by high sample throughput and minimal consumable requirements for IR spectroscopy and hyperspectral imaging. Hyperspectral imaging is identified as the most rapid technique with potential to scan about 720 samples per day at 90% less cost than the WB method. The opportunity cost of hyperspectral imaging is to forfeit some analytical accuracy associated with the dry combustion method. Dry combustion, despite its high cost per sample, incurs no further costs associated with updating prediction models or developing site or soil specific correction factors.     

Magnesium fixation—a possible cause of negative yield responses to lime applications

Abstract

Negative yield responses are common when highly leached soils are limed to neutrality. A number of explanations have been proposed, but very few have been experimentally verified or are entirely acceptable. In this paper the problem is re‐examined and a new possible causal mechanism is proposed.

Data assembled from the literature are used to demonstrate that a consistently observed reduction in Mg uptake by plants when soils are limed to neutrality is often accompanied by a generally ignored reduction in exchangeable soil Mg. Using data for soils of North American and African origin, it is demonstrated that when the soils were limed with pure Ca sources, the level of exchangeable soil Mg was reduced between 36 and 93%. Furthermore, after treatment with a Mg containing liming material, initial increases in the level of exchangeable Mg were followed by similarly large decreases when the soil pH approaches neutrality.

The applicability of known Mg fixation mechanisms is briefly discussed and the suggestion is made that Mg fixation may offer an acceptable explanation for some of the yield depressions observed on liming to neutrality. Research is currently in progress to gather sufficient data to answer the many questions raised.