在伊朗中部源于第三纪沉积物的土壤上影响坡缕石的发生因素研究

Limited information is available on the distribution and origin of palygorskite in soils developed on Tertiary sediments as the major soil parent materials in central Iran and other Middle Eastern countries. The objectives of this study were to determine the distribution and origin of palygorskite in soils developed on Tertiary sediments, and to identify the major soil properties that influence palygorskite distribution in the soils studied. Sixteen soil profiles developed on Paleocene, Eocene, Oligocene, Oligocene-Miocene, Miocene and Pliocene sediments were studied by X-ray diffraction analysis, transmission electron microscope, and scanning electron microscopy. Physicochemical characteristics of the soils and sediments including particle size distribution, pH, electrical conductivity, organic carbon, gypsum, carbonates, and soluble Si, Ca and Mg were determined. The principal component analysis was used to establish the relationships between palygorskite and the physicochemical characteristics of the soils studied. Results showed that clay fraction of all the soils in the study area was dominated by palygorskite. The highest amount of palygorskite was found in horizons where simultaneous accumulation of both carbonates and gypsum occurred. Limited amount of palygorskite was found in salic and calcic horizons. Palygorskite seemed to be of eolian origin in the surface horizon of all the soils. Using principal component analysis, the soluble Mg/Ca ratio, pH, soluble Si and gypsum contents were identified as the most important factors affecting the distribution and genesis of palygorskite in the soils studied. Results might suggest the neoformation of palygorskite by precipitation from solutions in which evaporation fluxes were very high. However, palygorskite in soils developed on Tertiary sediments in central Iran seems to be of both inherited and pedogenic origins.     

南极Fildes半岛成土过程中主要元素的行为

Nine horizon samples of three soil profiles representative of Dystri-gelic Cambisol, Fibri-gelic Histosol and Relic Ornithosol were taken from Fildes Peninsula of King George Island, South Shetland Islands to quantitatively demonstrate the enrichment, migration and loss of the elements (Si, Al, Fe, Ca, Mg, Mn, K, Na and P) in soil horizons and their behaviour within profiles by application of the enrichment coefficient calculated in terms of the abundance of Ti. Six horizon samples of 4 other profiles randomly taken from the studied area were examined for calculation of the redistributing enrichment coefficient, which was applied for a better understanding of the element redistribution between soil and clay fraction along with soil development. The results showed that the enrichment, migration and redistribution of the elements varied strongly among the investigated soils and horizons, due to the differences of weathering degrees and moisture status, influences of sea bird activities, etc.     

中国福建省土壤的主要粘土矿物

The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evolution.Montmorillonite was found in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit,and some lateritic red soil,red soil and yellow soil with a low weathering degree.Chlorite existed mainly in coastal solonchak and paddy soil developed from marine deposit.1.4nm intergradient mineral appeared frequently in yellow soil,red soil and lateritic red soil.The content of 1.4nm intergradient mineral increased with the decrease of weathering degree from lateritic red soil to red soil to yellow soil.Hydrous micas were more in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit.and puple soil from purple shale than in other soils.Kaolinte was the most important clay mineral in the soils iun this province.The higher the soil weathering degree,the more the kaolinite existed.From yellow soil to red soil to lateritic red soil,kaolinite increased gradually,Kaolinite was the predominant clay mineral accompanied by few other minerals in typical lateritic red soil. Tubular halloysite was a widespread clay mineral in soils of Fujian Province with varying quantities.The soil derived from the paent rocks rich in feldspar contained more tubular halloysite.Spheroidal halloysite was found in a red soil and a paddy soil developed from olivine basalt gibbsite in the soils in this district was largely“primary gibbsite” which formed in the early weathering stage.Gibbsite decreased with the increase of weathering degree from yellow soil to red soil to lateritic red soil.Goethite also decreased in the same sequence while hematite increased.     

类似但成土因素不同的土壤：巴西始成土的趋同演变

Soils result from the interaction of five independent formation factors.If one factor varies,while the others remain constant,different soils can be produced.Herein,we demonstrated an opposing trend,wherein two soils were similar,despite considerable differences in all factors of soil formation.We sampled two Inceptisols (Oxic Dystrudepts) formed on different parent materials (gneiss vs.mica schist),climate (tropical altimontane vs.warmer,drier plateau),topography (1 650 m,45％ slope vs.1000 m,8％ slope),time (rejuvenated vs.old,stable surface),and vegetation (rainforest vs.Cerrado savanna).The two soils had similar chemical properties,whereas the soil on mica schist had finer particle size distribution,lower porosity,and lower saturated hydraulic conductivity.These properties were related to a coarser blocky microstructure compared to the soil on gneiss.Both soils presented active mineral weathering and pronounced pedoplasmation,demonstrated by clay contents ＞ 300 g kg-1,although only the Dystrudept on gneiss possessed coarse rock fragments.The C horizons of both soils presented fragmented clay coatings suggestive of argilluviation,likely relict,because they were not observed in the B horizons.The similarities in many properties of the two Dystrudepts,despite contrasting factors of soil formation,suggest converging evolution and that soil classification at the subgroup level was efficient in grouping similar formative processes in tropical conditions.Moreover,this work revealed that similar pedogenic processes acting on different factors of soil formation can result in similar soil properties,at least for Inceptisols where further soil development is hindered by topographic limitations.     

粘土矿物对土壤腐殖质化学性质的影响

Chemical characteristics of humic substances in soils with different mineralogical characteristics and under different utilization paterns in Zhangpu,Fujian Province,together with two pairs of cultivated soils in North China Plain were studied by chemical analysis,visible and IR spectroscopy and ^13C NMR spectrometry.For soils in Zhanpu the HA/FA ratio and both the aromaticity and the degree of humification of HA were higher in soils with montmorillonite as the predominant clay mineral than in those with kaolinite as the predominant clay mineral,provided these soils were under the same utilization pattern.While for each pair of soils with similar mineralogical characteristics the HA/FA ratio was higher and the C/H ratio and the contnet of carboxyl group of HA were lower in paddy soil than in upland soil.Among the upland soils(or paddy soils)studied the Ha/FA ratio of soil in Zhangpu with kaolinite as the predominant clay mineral was the lowest,and that of soil in Zhangpu with montmorillonite as the predominant clay mineral was the highest .the lowest.and that of soil in Zhangpu with montmorillonite as the predominant clay mineral was the highest It was concluded that the presence of montmorillonite favored the fromation and maturation of humic acid.     

Charge Properties and Clay Mineral Composition of Tianbao Mountains Soils

The clay mineral association,oxides of clay fraction and surface charge properties of 7 soils,which are developed from granite,located at different altitudesof the Tianbao Mountains were studied.Results indicate that with the increase in altitude,1) the weathering process and desilicification of soil clay minerals became weaker,whereas the leaching depotassication and the formation process of hydroxy-aluminum interlayer got stronger;2)the contents of amorphous and complex aluminum and iron,and the activity of aluminum and iron oxides for soil clay fraction increased;and 3) the amount of variable negarive charge,anion exchange capacity and the values of PZC and PZNC also increased.The activity of aluminum and iron oxides,the accumulation of aluminum,and surface charge characteristics and their relation to clay oxides of the vertical zone soils were observed and recorded.     

Air-drying changes the distribution of Hedley phosphorus pools in forest soils

Hedley labile phosphorus(P)pools in soil tend to be several times larger than annual forest requirements,even in highly weathered soils characterized by P limitation.The discrepancy between plant and soil P status could be partly attributable to the frequently adopted air-drying pretreatment that tends to increase soil P solubility.In this study,the effects of air-drying on the distribution of Hedley P fractions were examined using soils collected under 4 forest types at Gongga Mountain,southwestern China.The results showed that the microbial biomass P(Pmic)in the organic horizon decreased markedly after air-drying.The concentrations of Hedley labile P in the air-dried samples were 31%–73%more than those in the field-moist samples.Consequently,the air-drying-induced increments of Hedley labile P pools in the surface soil horizons were 0.8–3.8 times the annual plant P requirements.The organic horizon was more susceptible to the air-drying-induced increases in Hedley labile P than the mineral horizon,probably because of the stronger release of Pmicand disruption of soil organic matter.The quality of P,indexed by the ratio of Hedley labile P to slowly cycling P,shifted in favor of the Hedley labile fractions after air-drying,further revealing that air-drying changed the distribution of Hedley P pools in forest soils.These indicated that the effects of air-drying could not be ignored when interpreting the discrepancy between the P status of plants and the Hedley labile P pools in forest soils.To more efficiently evaluate the P status in forest soils via the Hedley fractionation procedure,the use of field-moist soils is recommended.     

中国土壤分类法中铁铝土的分类

The development of the classification of ferrallitic soils in China is reviewed and the classification of Ferralisols and Ferrisols in Chinese Soil Taxonomy is introduced in order to discuss the correlation between the ferrallitic soil classification in the Chinese Soil Taxonomy and those of the other soil classification systems. In the former soil classification systems of China, the ferrallitic soils were classified into the soil groups of Latosols, Latosolic red soils, Red soils, Yellow soils and Dry red soils, according to the combination of soil-forming conditions, soil-forming processes, soil features and soil properties. In the Chinese Soil Taxonomy, most of ferrallitic soils are classified into the soil orders of Ferralisols and Ferrisols based on the diagnostic horizons and/or diagnostic characteristics with quantitatively defined properties. Ferralisols are the soils that have ferralic horizon, and they are merely subdivided into one suborder and two soil groups. Ferrisols are the soils that have LAC-ferric horizon but do not have ferralic horizon, and they are subdivided into three suborders and eleven soil groups. Ferralisols may correspond to part of Latosols and Latosolic red soils. Ferrisols may either correspond to part of Red soils, Yellow soils and Dry red soils, or correspond to part of Latosols and Latosolic red soils.     

Alberta油砂地区在两种水文流域森林土壤酸化敏感性研究

Input of large amounts of N and S compounds into forest ecosystems through atmospheric deposition is a significant risk for soil acidification in the oil sands region of Alberta. We evaluated the sensitivity of forest soils to acidification in two watersheds （Lake 287 and Lake 185） with contrasting hydrological regimes as a part of a larger project assessing the role of N and S cycling in soil acidification in forest ecosystems. Fifty six forest soil samples were collected from the two watersheds by horizon from 10 monitoring plots dominated by either jack pine （Pinus banksiana） or aspen （Populus tremuloides）. Soils in the two watersheds were extremely to moderately acidic with pH （CaCl2） ranging from 2.83 to 4.91. Soil acid-base chemistry variables such as pH, base saturation, Al saturation, and acid-buffering capacity measured using the acetic acid equilibrium procedure indicated that soils in Lake 287 were more acidified than those in Lake 185. Acid-buffering capacity decreased in the order of forest floor 〉 subsurface mineral soil 〉 surface mineral soil. The most dramatic differences in percent Ca and Al saturations between the two watersheds were found in the surface mineral soil horizon. Percent Ca and Al saturation in the surface mineral soil in Lake 287 were 15% and 70%, respectively; the percent Ca saturation value fell within a critical range proposed in the literature that indicates soil acidification. Our results suggest that the soils in the two watersheds have low acid buffering capacity and would be sensitive to increased acidic deposition in the region.     

Mineral Composition and Weathering of Soils Derived from Xiashu Loess

Mineralogical, physical and chemical analyses of the soils derived from Xiashu loess were carried out. The primary minerals of these soils were found to be mainly composed of light minerals, such as quartz, feldspar and mica, with traces of heavy minerals. Clay minerals, more complicate in composition, were dominated by hydromica, accompanied by smectite, vermiculite, chlorite, kaolinite, 2:1/1:1 randomly interstratified minerals and small amounts of quartz, goethite, lepidocrocite and hematite, Clay minerals were characterized by low crystallinity and fine particle size. In light of the quartz/feldspars ratio of the 0.01-0.05mm silt fraction, and the clay mineral composition, the freeness of iron oxide, and the silica/sesquioxide and silica/alumina ratios in < 0.002mm clay fraction, it is concluded that the weathering intensity of these soils was lower than those of red soil and yellow earth, but higher than that of brown earth, and that the soil allitization, depotassication and hydroxylation of cl     

Stoichiometry of base cations and silicon during weathering of a deep soil profile derived from granite

Evaluation of the stoichiometry of base cations (BCs, including K⁺, Na⁺, Ca²⁺, and Mg²⁺) and silicon (Si) (BCs:Si) during soil mineral weathering is essential to accurately quantify soil acidification rates. The aim of this study was to explore the differences and influencing factors of BCs:Si values of different soil genetic horizons in a deep soil profile derived from granite with different extents of mineral weathering. Soil type was typic acidi-udic Argosol. Soil samples were collected from Guangzhou, China, which is located in a subtropical region. To ensure that the BCs and Si originated from the mineral weathering process, soil exchangeable BCs were washed with an elution treatment. The BCs:Si values during weathering were obtained through a simulated acid rain leaching experiment using the batch method. Results showed that soil physical, chemical, and mineralogical properties varied from the surface horizon to saprolite in the soil profile. The BCs:Si values of soil genetic horizons during weathering were 0.3-3.7. The BCs:Si value was 1.7 in the surface horizon (A), 1.1-3.7 in the argillic horizon (Bt), and 0.3-0.4 in the cambic (Bw) and transition (BC) horizons, as well as in horizon C (saprolite). The general pattern of BCs:Si values in the different horizons was as follows: Bt > A > Bw, BC, and C. Although BCs:Si values were influenced by weathering intensity, they did not correlate with the chemical index of alteration (CIA). The release amounts of Si and BCs are the joined impact of soil mineral composition and physical and chemical properties. A comprehensive analysis showed that the BCs:Si values of the soil derived from granite in this study were a combined result of the following factors: soil clay, feldspar, kaolinite, organic matter, pH, and CIA. The main controlling factors of BCs:Si in soils of different parent material types require extensive research. The wide variance of BCs:Si values in the deep soil profile indicated that H⁺ consumed by soil mineral weathering was very dissimilar in the soils with different weathering intensities derived from the same parent material. Therefore, the estimation of the soil acidification rate based on H⁺ biogeochemistry should consider the specific BCs:Si value.     

福建主要土壤的粘粒云母含量和供钾潜力

利用X射线衍射法估算了福建省221个土壤样品中粘粒云母含量并讨论了与粘粒云母含量变化有关的因素。结果表明母质是影响粘粒云母含量的主要因素。海积物、河积物及页岩上发育的土壤粘粒云母含量一般较高;基性岩上发育的土壤粘粒云母含量一般较低。风化度较高的赤红壤、红壤、黄红壤和黄壤等土类的粘粒云母含量一般较低。风化度较低的C层的粘粒云母含量一般较B层和A层高,但异源母质的堆积可以使A层粘粒云母含量高于B层和C层。     

An experience in using the world reference base for soil resources for the soils of western Georgia

New and previously published data on the soils of western Georgia are generalized, and traditional soil names are correlated with the units of the World Reference Base for Soil Resources. It is argued that krasnozems (red ferrallitic soils) can be attributed to the group of Nitisols (the soils characterized by intense weathering (ferralization) and having shiny ped faces in the nitic horizon); yellow and yellow-brown soils (zheltozems), to the group of Luvisols (the soils with relatively high adsorption capacity in the eluvial horizons and with the horizon of the illuvial accumulation of clay); yellow-podzolic (zheltozem-podzolic) soils, to Alisols (slightly acid soils with the low adsorption capacity, poor aggregation of the upper horizons, low-activity (kaolinite) clay, and with the horizon of clay accumulation (argic horizon)); brown forest soils, to Cambisols (the soils with the cambic horizon characterized by some alteration of the lithogenic texture and structure into the pedogenic texture and structure); and mountainous forest-meadow and meadow soils, to Umbrisols (the soils with the dark-colored unsaturated umbric horizon).     

陕西关中土垫旱耕人为土样区的基层分类研究

选择陕西关中土垫旱耕人为土地区为样区,以该地区代表性土壤土垫旱耕人为土(土)为研究对象,在野外调查、室内分析及查阅大量有关剖面资料的基础上,根据中国土壤系统分类体系,对土垫旱耕人为土(土)的基层分类进行了研究。研究表明,应用土壤颗粒大小级别、矿物学型和土壤温度状况等3项指标对土族进行划分,在0~160cm的控制层段中小于2mm的土壤平均质地,多数剖面为粘壤土,少数为壤土或砂质壤土,矿物学型属伊利石型、伊利石混合型或蛭石型,土壤温度属温性或温热土壤温度状况。土垫旱耕人为土(土)土系的控制层段拟定为从表土层上界向下160cm,对于诊断层的底部在160cm以下的,则从表土层至诊断层的下部边界,特征土层有肥熟表层、土垫表层、暗沃表层、耕作淀积层、粘化层、粘质层、CaCO3高度淀积层、CaCO3中度淀积层、CaCO3低度淀积层、氧化还原层和稚育层。根据样区9个典型剖面,结合关中地区土垫旱耕人为土(土)的有关研究资料,划分了土族和土系,并描述了各土系的典型特征及土系间的变异情况。     

Short‐time clay‐mineral evolution in a soil chronosequence in Oléron Island (France)

Major weathering sequences in soils are well established; however, knowledge on rates of mineral transformations remains unknown, because it is often difficult to date precisely soil processes. This work was carried out on soils developed on recent (< 188 y) sand dunes on the W coast of Oléron Island (France). The coast has been protected against marine and wind erosion by constructing five consecutives barriers close to the coastline since 1820 (1820, 1864, 1876, 1889, 1948) defining the maximum age of the soil parent material, as before the areas between the barriers were under water. Soils on the older dunes have low clay content (> 94% of sand) and exhibit a bleached E horizon that overlies a yellowish brown B horizon. The process responsible for their formation is podzolization promoted by the high permeability of the material and complexing organic matter produced by coniferous vegetation. Initial mineralogy of C horizons is homogenous and constituted of chlorite, illite, illite/smectite mixed‐layer minerals, and kaolinite, quartz, calcite (≈ 8% related to shell fragments), and feldspars. The initial clay‐mineral assemblage of the E horizons is dominated by illite (well‐crystallized WCI and poorly crystallized PCI) and chlorite. With progressive podzolization, poorly crystallized illite is first transformed to illite/smectite mixed‐layer minerals and in a further step into smectite. In addition, transformation of well‐crystallized illite leads to formation of ordered illite/smectite mixed‐layer minerals in the E horizons, which is not commonly described in soils. In the B horizons, illite/smectite mixed‐layer minerals are present with traces of smectite, as well as Al and Fe oxi‐hydroxides as revealed by DCB and oxalate chemical extractions. This chronosequence illustrates that over short distances and short time (< 188 y) intense mineral weathering and soil development occur. Major clay‐mineral changes occur between 132 and 188 y in agreement with development of the pine forest producing acidic litter.     

Dynamics of the dispersity of model soddy-podzolic soils in a long-term lysimetric experiment

Changes in the particle-size composition and specific surface area were considered for soddy-podzolic soils in large lysimeters of the Soil Research Station of Moscow State University, which simulated anthropogenically modified soils with different sequences of genetic horizons in a long-term (1961–2002) experiment. Changes were detected in the degree of dispersion of the soil horizons occurring under conditions inadequate for their genesis: a decrease in the clay content by 7% and in the external specific surface area from 28.9 to 7.4% in the illuvial horizon placed on the surface and the accumulation of colloidal mineral fractions in the Ap horizon buried at a depth of 80–100 cm. The degree of change depended on the occurrence depth of the buried horizons and increased with approaching the surface. The changes in the dispersity of the model soddypodzolic soils in the lysimetric experiment were primarily due to the translocation of the fine fractions with vertical water flows. The long-term experiment carried out under completely controlled conditions showed that, at the initial functioning stages of the soils with anthropogenically modified profiles, this process was well detectable and significant for the monitoring studies.     

海拔与岩性变异对石灰岩发育土壤黏土矿物组成的影响

用X射线衍射法研究了中亚热带区海拔、岩性变异对石灰岩发育土壤黏土矿物组成的影响。结果表明:在海拔约2 000 m的重庆金佛山山顶区,灰黑色钙质页岩石灰岩发育的黑色石灰土,矿物组成复杂,除伊利石为主外,还有少量蛭石、绿泥石、高岭石和蒙脱石,有一定量的母质残留矿物(滑石和滑间皂石);由砂页岩和灰岩互层母质发育的山地黄棕壤,以蛭石为主,伊利石和高岭石其次,有三水铝石和弱结晶针铁矿。在金佛山中下部(600~1 200 m),石灰岩发育的黄色石灰土以蛭石或伊利石为主,有一定量的高岭石,普遍出现针铁矿。湖南怀化盆地海拔200多米,纯灰岩发育的红色石灰土为伊利石、蛭石和高岭石(含埃洛石)组合型,有结晶好的针铁矿和少量赤铁矿。海拔显著影响高岭石含量、针铁矿结晶度,海拔降低时高岭石含量增加,针铁矿结晶度提高。在金佛山山顶区,石灰岩母质岩性和微地形变异对土壤成土过程和黏土矿物组成影响显著。     

Weathering patterns in representative soils of Guanxi Province, south-east China, as indicated by detailed clay mineralogy

The mineralogy of five soils situated on a south-west to north-east transect of Guanxi Province, south-east China was determined by X-ray diffraction (XRD), transmission electron microscopy (TEM), differential thermal analysis (DTA) and chemical composition. One soil had formed on granite under tropical conditions, the others on sedimentary rocks under subtropical conditions. In all soils, kaolinite dominates the clay fractions, and is accompanied by vermiculite or chloritized vermiculite. In the saprolites of the granite-derived and sandstone-derived soils, the kaolinite has a morphology close to that of hydrated halloysite. The formamide and hydrazine/water tests suggested the presence of both poorly-crystalline (dehydrated halloysite) and well-ordered kaolinite. Gibbsite was identified in the saprolites of the granite-derived and sandstone-derived soils but not in the soils themselves. Gibbsite was also identified in the lowermost horizon of a soil derived from Pleistocene sediments. The upper horizon clay of a Rendzina soil formed on Permian limestone contains much more gibbsite and is much more weathered than the corresponding lower horizon clay. Only in the more humid, southernmost soil can the mineral composition be explained by present-day climatic conditions. In the soils from drier areas, the clay mineral composition reflects weathering that had taken place under moister, paleoclimatic conditions. Some of these paleoclimatic conditions had been conducive to lateritic weathering, as is indicated by the presence of goethite-containing pisolitic nodules in one of the soils and in its parent material. Two of the soils appear to be polymorphic, with one part of the soil having weathered more strongly than the other part.     

黄淮海平原晚第四纪古土壤

本文运用孢子花粉,古生物化石和放射性碳断代等手段,从土壤剖面层段的特征,土壤年龄和环境变化方面证明,分布于黄淮海平原的变性土不是现代土壤,而是古土壤,该古土壤自晚新世晚期以来经历了三次沉积－成土作用旋回,其土壤发育程度较弱,且是由钙质结核土层,暗色土层,表土层和（或）淤土层组成的一个叠置型古土壤。