Release Rates of Ammonium‐Nitrogen,Nitrate‐Nitrogen,Phosphorus, Potassium,Magnesium, Iron,and Manganese from Seven Controlled‐Release Fertilizers

Abstract

Samples of seven controlled‐release fertilizers, Nutricote Total 13–13–13, Nutricote Total 18–6–8, Osmocote Plus 15–9–12, Osmocote 13–13–13, Polyon 18–6–12, Polyon 14–14–14, and Plantacote 14–8–15, were placed in leaching columns containing acid‐washed sand. Samples of all leachates were analyzed weekly to determine release rates of ammonium‐nitrogen (N), nitrate‐N, phosphorus (P), potassium (K), magnesium (Mg), manganese (Mn), and iron (Fe). Release rates for P from all products were slower than those for NH₄‐N, NO₃‐N, and K. Release of Mg, Mn, and Fe was very poor, with less than 50% of the total amount of each of these elements ever being released from the prills for some products. Nutricote products released Fe and Mn more effectively than did Osmocote or Plantacote.     

Evaluation of Nutrient Release in Salt‐Saturated Soils

Abstract

The effects of irrigating with saline water on native soil fertility and nutrient relationships are not well understood. In a laboratory experiment, we determined the extent of indigenous nutrient [calcium (Ca), magnesium (Mg), potassium (K), manganese (Mn), and zinc (Zn)] release in salt-saturated soils. Soils were saturated with 0, 75, and 150 mmolc L^?1 sodium chloride (NaCl) solution and incubated for 1, 5, 10, and 15 days. The saturation extracts were analyzed for pH, ECe, and water‐soluble Ca, Mg, K, Mn, and Zn, and the remainder soil samples were analyzed for exchangeable forms of these elements. In a subexperiment, three soil types (masa, red‐yellow, and andosol) were saturated individually either with 100 mmolc L^?1 of NaCl, sodium nitrate (NaNO₃), or sodium sulfate (Na₂SO₄) salt. These salts were also compared for nutrient release. Soils treated with NaCl released higher amounts of water‐soluble than exchangeable nutrients. Except for Zn, the average concentrations of these nutrients in the soil solution increased significantly with time of incubation, but concentrations of the exchangeable forms varied inversely with time of incubation. The masa soil exhibited the highest concentrations of Ca and Mg, whereas K was highest in andosol. The extract from soils treated with NaCl contained greater amounts of soluble cations, whereas soils treated with Na₂SO₄ produced the lowest concentration of these elements irrespective of the type of soil used.     

Effects of Slow‐Release Fertilizers on Tomato Growth and Nitrogen Leaching

Tomatoes (Lycopersicon esculentum Mill.) were grown in 9.46‐L plastic pots in a glasshouse for evaluation of their growth and nitrogen (N) losses through leaching. Plants were fertilized with either ammonium nitrate (AN) or one of three slow‐release N fertilizers. The slow‐release N fertilizers were Georgia Pacific liquid 30‐0‐0 (L30), Georgia Pacific granular 42‐0‐0 (N42), and Georgia Pacific granular 24‐0‐0 (N24). Each fertilizer was applied at 112 low N rate (L) and 224 high N rate (H) kg N ha^?1. The pots were filled with either a sandy soil from Florida or a loam soil from Georgia. Increasing the N rate did not influence shoot biomass at 19 days after transplanting (DAT) and increased biomass production at 77 DAT. Shoot biomass differed significantly among fertilizer treatments. The accumulation of N in shoots was significantly influenced by fertilizer source, rate, and soil type. The plants grown in the loam soil accumulated significantly more N than those grown in the sandy soil with the same treatment. In the loam soil, the highest and lowest N accumulations occurred in the N42‐H and N24‐L treatments, respectively; and in the sandy soil the corresponding treatments were AN‐H and N24‐L. The amount of N leached varied with the different fertilizers, soils, and time. The net leaching of N ranged from ?0.4% to 6.3% of the fertilizer N applied for the loam soil and 6.5% to 32.9% for the sand soil. The net amount of N leached from the loam soil at both high and low application rates declined in the following order: AN > N24 > N42 > L30; the corresponding order for the sandy soil was AN‐H > N42‐H > L30‐H > N24‐H. L30 had the least leaching potential, and ammonium nitrate had the most. Slow‐release fertilizers had significantly less leaching N than did ammonia nitrate.     

Decomposition and Nutrient Release from Litter Fall in the Semi‐arid Tropics of Sudan

In Sudan, tree plantations remain the first choice and are widely used in protecting arable lands from sand movement. Decomposition and nutrient changes from leaves of some agroforestry trees (Eucalyptus microtheca, Ficus spp., and Leucaena leucocephala) and litter fall from guava (Psidium guajava) and mango (Magnifera indica) were monitored (in a 12‐week litter‐bag experiment). Rate of dry‐matter weight loss from guava (0.098 wk^?1) was significantly (P < 0.01) faster than from mango residues (0.04 wk^?1). Corresponding values for Leucaena, Eucalyptus, and Ficus were 0.0533, 0.0524, and 0.0438 wk^?1, respectively. In general, micronutrients tend to accummulate during a decomposition period. Potassium (K) was the only element found to be consistently lost by leaching very rapidly from all litters. Nitrogen (N) was released at a significantly (P < 0.03) higher rate from Leucaena (0.0558 wk^?1) compared to Ficus (0.0399 wk^?1) and Eucalyptus (0.0301 wk^?1). Mobility of nutrients from the litters was in the order of K > phosphorus (P) = N > calcium (Ca) > magnesium (Mg). It is concluded that ficus and mango leaves are suitable for improving quality of arid soils through buildup of soil organic matter and supplying easily released organic sulfur (S) (environmentally sound management practice) whereas litter from guava is suitable for temporary nutrient correction. Mixing of guava and mango residues may slow fast decomposition of the former.     

Batch‐Determined Elements Release from Wood Ash Mixed with an Acidic Forest Soil Sample

Abstract

A serial batch leaching experiment was carried out to evaluate the release of elements from wood ash mixed with a strongly acidic forest soil sample. Wood ash application resulted in increased leachate pH, dissolved organic carbon (DOC), and electrical conductivity (EC). Increasing application of wood ash increased cumulative release of inorganic carbon (IC), chloride (Cl), nitrate (NO₃), sulfate (SO₄), potassium (K), sodium (Na), calcium (Ca), magnesium (Mg), manganese (Mn), phosphorus (P), and copper (Cu). Release of NO₃, P, iron (Fe), aluminum (Al), Cu, and lead (Pb) continued. Large amounts of DOC, K, Ca, and SO₄ were mobilized. Inorganic C, Fe, and Mg were released in moderate quantities. Manganese, Na, Al, Cl, and NO₃ were released in limited amounts. Amounts of leached P, Pb, and Cu were lower. The mixed order equation adequately described the release of elements in the soil‐ash mixture. Accumulation of elevated amounts of trace elements does not appear to be a problem when higher wood ash rates are avoided. Wood ash should be applied in split application to avoid short‐term concentrated alkaline and salty conditions that could interfere with plant growth.     

Potassium Release in an Aeric Haplaquept as Influenced by Long-Term Rice–Rice Cropping with Different Rates of Fertilizers and Manuring

Different fractions of potassium (K) and the kinetics of K release as influenced by 21 cycles of rice–rice cropping with different rates of fertilizers and manuring were investigated on an Aeric Haplaquept (kaolinitic Inceptisol) soil profile from Bhubaneswar, India. The neutral 1 N ammonium acetate–extractable K in the surface soil layer (0–15 cm) increased from its initial value of 11.2 mg K kg^?1 to 14.8, 14.2, and 17.5 mg K kg^?1 soil in different treatments. However, the nonexchangeable K content in the surface soil layer dropped considerably to a level of 4.8–20.0 mg K kg^?1 soil. Cumulative nonexchangeable K release after 121 h of extraction with 0.01 M calcium chloride (CaCl₂) was <14 mg K kg^?1. The first-order kinetic model best described the nonexchangeable K release. The decrease in pH and increase in iron (Fe) content indicated the possibilities of K supply to plants through the dissolution of soil minerals.     

Tree Diversity,Carbon Storage,and Soil Nutrient in an Old‐Growth Forest at Changbai Mountain,Northeast China

Abstract

The study of plant diversity and its role in ecosystem functioning is becoming a central issue in ecology. The relationships between carbon storage and tree diversity of natural forest at small scale are still unclear. This research investigated these relationships in an old‐growth forest at Changbai Mountain, Northeast China. It was found that at small scale, tree carbon storage generally increases with increasing tree species richness, but for stands with same species richness, tree carbon storage varies dramatically. At the small scale, tree species evenness has a significantly linear relationship with nature logarithm of total tree carbon storage. The stand carbon storage of trees is mainly controlled by stand tree composition. Fraxinus mandshurica, Pinus koraiensis, Quercus mongolica, Tilia amurensis, and Acer mono contribute more than 85% of stand carbon storage of trees. Stands with similar tree composition at small scale have different soil organic carbon storage and nutrient contents. Tree species evenness has great impact on soil N content at the soil horizon less than 30 cm deep, but its impacts on C/N, P, K, and S contents are small. Tree density has a negative linear relationship with soil organic C and C∶N ratio at the soil horizon is less than 30 cm deep. The implication of our findings here for carbon sequestration in the Kyoto Protocol is also discussed.     

Leaching and Transformation of Nitrogen Fertilizers in Soil After Application of N with Irrigation： A Soil Column Method

A soil column method was used to compare the effect of drip fertigation （the application of fertilizer through drip irrigation systems, DFI） on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation （SFI）, and to study the leaching loss and transformation of three kinds of nitrogen fertilizers （nitrate fertilizer, ammonium fertilizer, and urea fertilizer） in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N （NH4^＋-N ＋ NO3^--N） in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control （without urea addition）, on the first day when soils were fertigated with urea, there were increases in NH4^＋-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4^＋-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4^＋-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4^＋-N fixation or volatilization in the soil during the fertigation process.     

Bioavailability of Heavy Metals in Biosolids‐Amended Soil

Abstract

A single biosolids application was made to 1.5×2.3 m confined plots of a Davidson clay loam (Rhodic Kandiudult) in 1984 at 0, 42, 84, 126, 168, and 210 Mg ha^?1. The highest biosolids application supplied 750 and 600 kg ha^?1 of Cu and Zn, respectively. Corn (Zea mays L.), from 1984 to 2000, and radish (Raphanus sativus L.) and romaine lettuce (Lactuca sativa var. longifolia), from 2001 to 2004, were grown at the site to assess heavy‐metal bioavailability. Extractable (0.005 diethylenetriamine (DTPA) and Mehlich 1) Cu and Zn were determined on 0 to 15‐cm depth samples from each plot. Corn yield increased with biosolids rate each year until 1993 to 1997, when yield decreased with biosolids rate because of phytotoxicity induced by low (<5.0) soil pH. The corn yield reduction was reversed between 1998 and 2000 upon raising the soil pH to approximately 6.0 by limestone addition following the 1997 season. Between 2001 and 2004, radish and lettuce yields were either not affected or slightly increased with biosolids rate, even as soil pH declined to below 5.5. Plant‐tissue metal concentrations increased with biosolids rate and as pH declined but were always within the normal range of these crops. Mehlich 1 and DTPA extractable metals increased linearly with biosolids rate. Extractability of Cu and Zn decreased approximately 50% over the past 20 years despite a decrease in soil organic matter concentration and greater than 95% conservation of the metals.     

Gaseous Loss of Nitrogen from Fertilizers Applied to a Paddy Soil in Southeastern China

Total nitrogen(N) loss and ammonia volatilization from urea applied to flooded rice grown on a paddy soil in Zhejiang Province were measured by ^15N balance and micro-meteorological methods,respectively.Floodwater properties and ammonia loss from the circular plot were compared with those from the microplots.And the effectiveness of urease inhibitor,NBPT [N-(n-butyl) thiophosphoric triamide],was also tested Results showed that the total losses from urea broadcast and incorporated at transplanting (basal dressing) were similar with those from urea broadcast 12 days after transplanting (top-dressing)(51.5% and 48%,respectively,of applied N),and ammonia losses were low,the corresponding figures were 10.8% and 7.0% of applied N,respectively.Thus,denitrification was a much more important pathway of nitrogen loss than ammonia volatilization under the particular conditions.Addition of NBPT retarded urea hydrolysis,reduced pHs and ammoniacal nitrogen concentrations of floodwater for either the application of urea as basal or as top-dressing,but these effects were not translated into the reduction of total nitrogen loss.Floodwater pHs and ammonia loss in the microplots were apparently lower than those in the circular plot from urea applied as basal dressing;however,such differences were not found when urea was top-dressed.The frequently raining days occurred after top-dressing may be responsible for the insignificant effect of plot size on floodwater pHs and ammonia volatilization.It seems that the effects of phot size on ploodwater properties and ammonia loss mainly depend on weather conditions,in addition to the height and leaf area index of the crop.     

Phosphorus Fertilizer Requirements and Nutrient Uptake of Irrigated Dry‐Season Cotton Grown on Virgin Soil in Tropical Australia

Considerable amounts of phosphorus (P) fertilizer will be required on soils in the proposed Ord Stage II area of northwestern Australia if a sustainable dry‐season cotton production system is to be established, because in their virgin state the soils are known to be inherently low in P. This study aimed to determine P fertilizer requirements on these soils to optimize cotton yield as well as nutrient uptake. Five rates of P fertilizer were applied to soil recently cleared of trees and prepared for irrigation. In the second year, these same rates were imposed over the trial. We conclude that the application of 60 kg ha^?1 of P was sufficient to allow maximum yield and quality for dry‐season cotton grown in the first season on virgin soils in the Ord River Irrigation Area, whereas a total of 80 kg ha^?1 of P was required when cotton was grown over two seasons.     

Influence of Long‐Term Application of Organic and Inorganic Fertilizer to Build Up Soil Fertility and Nutrient Uptake in Mint‐Mustard Cropping Sequence

Abstract

Field experiment was conducted for 7 years continuously to evaluate the influence of combined application of organic and inorganic fertilizer on soil fertility buildup and nutrient uptake in mint (Mentha arvensis) and mustard (Brassica juncea) cropping sequence. Maximum organic carbon was observed under full supply of organic manure (T₂; FYM at 20 t ha^?1) averaged across all the Stages of cropping sequence. It was increased by 38, 50, and 51% in T₂ in Stages I (after mint harvest/presowing of dhaincha), II (after incorporation of dhaincha (Sesbania aculeata)/presowing of mustard), and III (after harvest of mustard/preplanting of mint), respectively, over their respective controls. In general, magnitude of organic carbon was recorded higher in Stage II after green manuring of Sesbania compared with Stages I and III. Nitrogen availability in treated plots was increased by 26.0–89.9, 15.2–64.5, and 4.9–52.0% in Stages I (after mint harvest/presowing of Sesbania), II (after incorporation of dhaincha/presowing of mustard), and III (after harvest of mustard/preplanting of mint), respectively, over their respective control. Average across all the three Stages showed a positive balance of nitrogen (N), phosphorus (P), and potassium (K) in soil under different treatments. Mean of the three Stages indicated that maximum available N, P, and K were increased by 36.1, 129.0, and 65.20% in T₄ (N:P:K: 133:40:40 and FYM at 6.7 t ha^?1), T₄ (N:P:K::133:40:40 and FYM at 6.7 t ha^?1), and T₃ (N:P:K::100:30:30 and FYM at 10 t ha^?1), respectively, over their initial status. Supply of organic and inorganic fertilizer (T₄; N:P:K::133:40:40 and FYM at 6.7 t ha^?1) was found most suitable combination with respect to N, P availability in soil, and productivity of mint and mustard crop.     

Change of Organic Carbon Content and Its Fractions in Black Soil under Long‐Term Application of Chemical Fertilizers and Recycled Organic Manure

Abstract

Soil organic matter (SOM) is an important indicator for soil quality and sustainable agriculture, and agricultural practices may strongly affect SOM content and chemistry. Thus, a long‐term experiment was conducted in northeast China to study the effect of chemical fertilizers and recycled organic manure on the contents of SOM along its fractions of black soil (0–20‐cm depth). Eight treatments were used: 1) control, 2) recycled organic manure (ROM), 3) nitrogen (N) alone, 4) N+ROM, 5) N+phosphorous (P), 6) N+P+ROM, 7) N+P+potassium (K), and 8) N+P+K+ROM. The results showed that from 1985 to 2002; soil total organic carbon (TOC) decreased by 6.5% over the 18 years in control (33.25 g/kg in 1985), 5.6% in ROM treatment, and 5.1% in N‐alone treatment, and 1.5% in the N+P treatment but increased by 0.3% in the N+P+K treatment. In the three treatments of chemical fertilizers together with ROM (i.e., N+ROM, N+P+ROM, and N+P+K+ROM), soil TOC content in 2002 increased by 0.3%, 1.3%, and 2.8%, respectively, when compared with control in 1985. Compared with control in 2002, light fraction organic carbon (LFOC) content increased by 23% in N+ROM treatment, 24% in N+P+ROM, and 28% in N+P+K+ROM, and readily oxidized carbon (ROC) content increased by 24% 31%, and 39%, respectively, in these three treatments. The ROC was well correlated with soil TOC. Compared with the data from 18 years ago, in all eight treatments organic carbon of soil in the humic acid fraction decreased by 5.0–13% and in fulvic acid decreased by 1.4–14%; however, with chemical fertilizers and ROM applied together, the rate of decrease was reduced. Overall, ROM is effective for increasing the content of soil TOC and thus, its different active carbon fractions in black soil would help to maintain or increase soil productivity.     

Release of Soil Nonexchangeable K by Organic Acids

The amounts of soil nonexchangeable K extracted with 0.01mL/L oxalic acid and citric acid solutions and that with boiling 1mL/L HNO3 for ten minutes were remarkably significantly correlated with each other,and the amount extracted with the oxalic acid solution was higher than that with the citric acid solution.The soil nonexchangeable K release was comprised of two first-order kinetic processes.The faster one was ascribed to the interlayer K in outer sphere,while the slower one to that in inner sphere.The rate constants of the soil nonexchageable K were significantly correlated with the amounts of nonexchangeable K ex tracted with boiling 1mL/L HNO3 for ten minutes.Study on the fitness of different kinetic equations indicated that the first-order,parabolic diffusion and zero-order equations could all describe the release of soil nonexchangeable K well,but Elovich equation was not suitable to describe it.     

Phosphorus Fertilizer Requirements and Nutrient Uptake of Irrigated Dry‐Season Cotton Grown on Virgin Soil in Tropical Australia

Abstract

Considerable amounts of phosphorus (P) fertilizer will be required on soils in the proposed Ord Stage II area of northwestern Australia if a sustainable dry‐season, cotton‐production system is to be established, because in their virgin state, the soils are known to be inherently low in P. This study aimed to determine P‐fertilizer requirements on these soils to optimize cotton yield as well as nutrient uptake. Five rates of P fertilizer were applied to soil recently cleared of trees and prepared for irrigation. In the second year, these same rates were imposed over the trial. It was concluded that the application of 60 kg ha^?1 of P was sufficient to allow maximum yield and quality for dry‐season cotton grown in the first season on virgin soils in the Ord River Irrigation Area (ORIA), and a total of 80 kg ha^?1 of P was required when cotton was grown over two seasons.     

Heavy‐Metal Contamination of Soil and Vegetables in Wastewater‐Irrigated Agricultural Soil in a Suburban Area of Hanoi,Vietnam

The To Lich and Kim Nguu Rivers, laden with untreated waste from industrial sources, serve as sources of water for irrigating vegetable farms. The purposes of this study were to identify the impact of wastewater irrigation on the level of heavy metals in the soils and vegetables and to predict their potential mobility and bioavailability. Soil samples were collected from different distances from the canal. The average concentrations of the heavy metals in the soil were in the order zinc (Zn; 204 mg kg^?1) > copper (Cu; 196 mg kg^?1) > chromium (Cr; 175 mg kg^?1) > lead (Pb; 131 mg kg^?1) > nickel (Ni; 60 mg kg^?1) > cadmium (Cd; 4 mg kg^?1). The concentrations of all heavy metals in the study site were much greater than the background level in that area and exceeded the permissible levels of the Vietnamese standards for Cd, Cu, and Pb. The concentrations of Zn, Ni, and Pb in the surface soil decreased with distance from the canal. The results of selective sequential extraction indicated that dominant fractions were oxide, organic, and residual for Ni, Pb, and Zn; organic and oxide for Cr; oxide for Cd; and organic for Cu. Leaching tests for water and acid indicated that the ratio of leached metal concentration to total metal concentration in the soil decreased in the order of Cd > Ni > Cr > Pb > Cu > Zn and in the order of Cd > Ni > Cr > Zn > Cu > Pb for the ethylenediaminetetraaceitc acid (EDTA) treatment. The EDTA treatment gave greater leachability than other treatments for most metal types. By leaching with water and acid, all heavy metals were fully released from the exchangeable fraction, and some heavy metals were fully released from carbonate and oxide fractions. The concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the vegetables exceeded the Vietnamese standards. The transfer coefficients for the metals were in the order of Zn > Ni > Cu > Cd = Cr > Pb.     

Soil Potassium‐Release Characteristics and the Correlation of its Parameters with Garlic Plant Indices

Abstract

Potassium (K)‐release characteristics (PRC) of soil play a significant role in supplying available K. Information about PRC in the Hamadan soils is limited. The objective of this research was to study the PRC in nine soils from the Hamadan province by successive extraction with 0.01 M CaCl₂ over a period of 2000 h. The correlation of kinetic equation rate constants with soil properties and garlic indices was also studied. The release of K was initially rapid. More than 60% of the total K released during the first 168 h. The amount of K released after 168 h varied among soils and ranged from 292.8 to 736.8 mg kg^?1. The amount of K released after 2000 h was significantly correlated with K extracted by 1 M HNO₃, 0.01 M CaCl₂, and 0.1 M BaCl₂, whereas it was not significantly correlated with other soil properties. Potassium‐release characteristics were evaluated using five kinetic equations. Statistical analysis showed that the Elovich equation described the K‐release kinetics. A plot of other equations shows a discontinuity in slope at 168 h. Thus, two equations were applied to segments of the total reaction time (2 to 168 and 168 to 2000 h). The release‐rate constants (slope) in segment 1 are higher than in segment 2. The release‐rate constant of the Elovich equation and the zero‐order equation in two segments were significantly correlated with 1 M HNO₃, 0.01 M CaCl₂, and 0.1 M BaCl₂. Rate constants of the other equations were not significantly correlated with soil properties. The release‐rate constants of the Elovich equation and release‐rate constants of the zero‐order equation in two segments were significantly correlated with garlic indices. Rate constants of other equations were not significantly correlated with garlic indices. The results of this research showed that the Elovich and zero‐order equations can be used to describe K‐release characteristics.     

Integration of Soil pH with Soil‐Test Values of Zinc for Prediction of Yield Response in Rice Grown in Mollisols

Seventeen Mollisols having pH_(1:2) in the range of 6.00 to 8.42 were analyzed with five extractants, and the extractable zinc (Zn) ranges were 0.84 to 2.75 mg Zn kg^?1 soil for diethylenetriaminepentaacetic acid (DTPA) (pH 7.3), 0.91 to 2.72 mg Zn kg^?1 soil for DTPA + ammonium bicarbonate (pH 7.6), 1.82 to 7.18 mg Zn kg^?1 soil for Mehlich 3, 1.22 to 3.83 mg Zn kg^?1 soil for ethylenediaminetetraacetic acid (EDTA) + ammonium carbonate, and 0.88 to 1.18 mg Zn kg^?1 soil for 1 mol L^?1 magnesium chloride (MgCl₂) (pH 6.0). Zinc extracted by DTPA (pH 7.3) and Mehlich 3 showed significant positive correlation with sand content, whereas only Mehlich 3 showed negative correlation with soil pH. All extractants showed significant positive correlation with each other except for 1 mol L^?1 MgCl₂‐extractable Zn, which had significant positive correlation with only Mehlich 3– and EDTA + ammonium carbonate–extractable Zn. A greenhouse experiment showed that Bray's percentage yield of rice was poorly correlated to extractable soil Zn but had a significant and negative linear correlation with soil pH (r = ?0.662, significant at p = 0.01). Total Zn uptake by rice had a significant positive correlation with 1 mol L^?1 MgCl₂– and Mehlich 3–extractable Zn. A proposed parameter (p extractable Zn + p OH^?) involving both soil extractable Zn and pH terms together showed significant and positive correlation with Bray's percentage yield and total Zn uptake of rice. The calculated values of critical limits of soil Zn in terms of the proposed parameter were 14.1699 for DTPA (pH 7.3), 13.9587 for DTPA + ammonium bicarbonate, 13.7016 for Mehlich 3, 13.9402 for EDTA + ammonium carbonate, and 14.1810 for 1 mol L^?1 MgCl₂ (pH 6.0). The critical limits of Zn in rice grain and straw were 17.32 and 22.95 mg Zn kg^?1 plant tissue, respectively.     

Stretching Soil Sampling to Watershed: Evaluation of Soil‐Test Parameters in a Semi‐arid Tropical Watershed

Soil sampling is an integral component of fertility evaluation and nutrient recommendation for efficient use of nutrients in crop production. Little attention has been devoted to evaluating methodology for sampling watersheds under dryland agriculture. A stratified random sampling methodology for sampling the Appayapally watershed in Mahabubnagar district of Andhra Pradesh state in the semi‐arid tropical region of India was adopted and evaluated. The watershed has an area of about 500 ha, with gentle sloping lands (<1% slope), and 217 farmers own land in the watershed. The soils are Alfisols. A total of 114 soil samples were collected from the top 15‐cm layer to represent the entire watershed. Each sample was a composite of 7–8 cores, randomly collected from the area represented by a crop and group of farmers. The soil samples were air dried, ground, and analyzed for pH, electrical conductivity (EC), organic carbon (C), total nitrogen (N), and extractable phosphorus (P), potassium (K), calcium (Ca), magnesium (Mg), sodium (Na), sulfur (S), zinc (Zn), manganese (Mn), iron (Fe), copper (Cu), and boron (B). Statistical analysis of the results on soil fertility parameters showed that the mean‐ or median‐based results of soil tests performed in the study did not differ significantly when the sample set size varied from 5 to 114 (100% of the population). Our results indicate that farmers' fields in the Appayapally watershed are uniform in the chemical fertility parameters studied, and even a small sample set size can represent the whole population. However, such a sampling strategy may be applicable only to watersheds that are very gently sloping and where fertilizer use is very low, resulting in an overall low fertility in the whole watershed.     

Use of Chromameter‐Measured Color Parameters in Estimating Color‐Related Soil Variables

Abstract

Soil color is a soil property that may be used as an interpreting index in estimating processes and properties. Quantifying color allows one to obtain information for rapidly estimating the related processes in soils. CIELAB color parameters L*, a*, and b* of ground (air‐dried and sieved) soil samples and aggregate surfaces of four soil profiles formed in calcareous colluviums in northern Turkey were analyzed. Values of color parameters measured in ground and intact soils were compared and related to soil properties by the regression technique. Results revealed that the L* value obtained with a ground soil sample was a significant predictor of organic matter in A horizons (p < 0.001). Although calcic horizons yielded the highest L* values, no significant relationship was obtained between calcium carbonate contents and lightness of soils in any of horizons studied. The parameters of b* could adequately be used to quantify dithionite‐extractable iron oxide contents in soils studied. The results further showed that the CIELAB color parameters obtained with ground samples were more informative than that of aggrevated samples in relating color parameters to soil properties.