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1.
The purpose of this study was to measure the effect of additives on ammonia loss when used with urea–ammonium nitrate fertilizer (UAN). The fertilizer additives were ammonium thiosulfate (ATS), calcium thiosulfate (CaTS), N-(N-butyl) thiophosphoric triamide (Agrotain, AG), AG + CaTS, or a maleic-itaconic copolymer (Nutrisphere-N, NSN). Four greenhouse studies were conducted, with small fertilizer droplets applied to bare soil, large fertilizer droplets applied to bare soil, small fertilizer droplets applied to soil with 50% straw cover, and large fertilizer droplets applied to soil with 50% straw cover. Ammonia volatilizing from the soil surface was trapped in phosphoric acid and determined by steam distillation. Averaged across all four experiments, the percentage reductions of ammonia loss after 14 days, compared to unamended UAN, were 40% for UAN + ATS, 40% for UAN + CaTS, 51% for UAN + AG, 65% for UAN + AG + CaTS, and 11% for UAN + NSN.  相似文献   

2.
Abstract

The short‐term fate and retention of ammonium (NH4)‐15nitrogen (N) applied to two types of forest soils in east Tennessee was investigated. Four ridgetop forests, predominantly oak (Quercus spp.), were studied. Five applications of NH415N tracer were made to the forest floor at 2‐ to 4‐week intervals over a 14‐week period in 2004. Nitrogen‐15 recovery in the forest floor, fine roots (<2 mm), and the mineral soil (0–20 cm) was calculated at 6, 21, and 42 weeks after the last application. Most of the 15N was retained in the forest floor and the mineral soil, with only small amounts (≤2%) found in roots from both soil layers. Recovery of NH415N was greater in Inceptisols, which had a wider carbon (C)‐to‐N ratio than Ultisols. For both soil types, higher NH415N recoveries and long retention times (half‐lives>100 weeks) indicated the forest floor is an effective filter for atmospheric N inputs.  相似文献   

3.
Tomatoes (Lycopersicon esculentum Mill.) were grown in 9.46‐L plastic pots in a glasshouse for evaluation of their growth and nitrogen (N) losses through leaching. Plants were fertilized with either ammonium nitrate (AN) or one of three slow‐release N fertilizers. The slow‐release N fertilizers were Georgia Pacific liquid 30‐0‐0 (L30), Georgia Pacific granular 42‐0‐0 (N42), and Georgia Pacific granular 24‐0‐0 (N24). Each fertilizer was applied at 112 low N rate (L) and 224 high N rate (H) kg N ha?1. The pots were filled with either a sandy soil from Florida or a loam soil from Georgia. Increasing the N rate did not influence shoot biomass at 19 days after transplanting (DAT) and increased biomass production at 77 DAT. Shoot biomass differed significantly among fertilizer treatments. The accumulation of N in shoots was significantly influenced by fertilizer source, rate, and soil type. The plants grown in the loam soil accumulated significantly more N than those grown in the sandy soil with the same treatment. In the loam soil, the highest and lowest N accumulations occurred in the N42‐H and N24‐L treatments, respectively; and in the sandy soil the corresponding treatments were AN‐H and N24‐L. The amount of N leached varied with the different fertilizers, soils, and time. The net leaching of N ranged from ?0.4% to 6.3% of the fertilizer N applied for the loam soil and 6.5% to 32.9% for the sand soil. The net amount of N leached from the loam soil at both high and low application rates declined in the following order: AN > N24 > N42 > L30; the corresponding order for the sandy soil was AN‐H > N42‐H > L30‐H > N24‐H. L30 had the least leaching potential, and ammonium nitrate had the most. Slow‐release fertilizers had significantly less leaching N than did ammonia nitrate.  相似文献   

4.
Abstract

The determination of soil organic matter by wet digestion techniques is a slow and laborious analysis. Loss‐on‐ignition (LOI) provides a simple alternative technique for the estimation of soil organic carbon in non‐calcareous A horizon soils of the Natal midlands and Zululand forestry regions. Using multiple regressional techniques, the relationships between loss‐on‐ignition, Walkley organic carbon and soil texture for 55 soils were determined over a range of ignition temperatures. The relationships hold best for soil samples with relatively low organic carbon contents (< 5%). The optimum temperature for ignition was found to occur at 450°C and resulted in the relationship: Soil organic carbon = 0.284*LOI percent. No advantage is gained through ignition at higher temperatures due to the loss of clay mineral structural water, even if the soil texture is accurately known.  相似文献   

5.
Nitrification-denitrification losses of 15N-labelled nitrate and ammonium applied to the rhizos phere and nonrhizosphere of flooded rice were evaluated in 2 greenhouse rhizobox experiments.The loss of added N via denitrification was estimated directly by measuring the total fluxes of (N2O N2)12N,It was found that 67% and 51%-56% of 15N-nitrate added to rice rhizosphere were lost as (N2O N2)-15N in the 2 experiments,respectively,which were comparable to that added to norhizosphere soil(70%and 47%,respectively),implying that the denitrifying activity in rice rhizosphere was as high as that in nonrhizosphere soil.However,only trace amounts (0-0\3% of added N)were recovered as (N2O N2)-15N when 15N-ammonium was applied to either rhizosphere or nonrhizosphere,which seems to indicate that the nitrifying activity in the either rhizosphere of nonrhizosphere soils was quite low.The apparent denitrification calculated from 15N balance studies was 10%-47% higher than the total flux of (N2O N2)-15N.Reasons for the large differences can not be explained satisfactorily.Though the denitrifying activity in rhizosphere was high and comparable to that in nonrhizosphere soil.presumably due to the low nitrifying activity and /or the strong competition of N uptake against denitrification.the nitrification-denitrification taking place in rhizosphere could not be an important mechanism of loss of ammonium N in flooded rice-soil system.  相似文献   

6.
The fate of urea-and ammonium bicarbonate(ABC)-nitrogen (N) applied by prevailing traditional techniques to winter wheat (Triticum aestivum L.)or maize (Zea mays L.)grown in the fields of Fluvo-aquic soil was investigated using ^15N tracer-micro-plot technique.Results show that:(1) at maturity of wheat,N recovery in plants and N losses of urea and ABC applied at seeding in autumn were 31-39%,and 34-46%,respextively,while the corresponding figures for side-banding at 10 cm depth in early spring were 51-57%,and 5-12%;surface-broadcast of urea followed by irrigation at early spring was as efficient as the side-banding in improving N recovery in plants and reducing N loss,however,such techuique was found less satisfactory with ABC.(2)At the maturity of maize,N recovery in the plants and N loss of urea and ABC sidebanded at seedling stage or prior to tasseling ranged from 23% to 57%,and 9% to 26%,respectively.(3) Either in Wheat or in maize experiment,the majority of residual fertilizer N in soil profile (0-60cm) was in the form of biologically immobilized organic N,however,the contribution of ammonium fixation by clay minerals increased markedly nwith depth in soil profile.(4) Though the proportion of residual fertilizer N was generally highest in the top 20 cm soil layer,considerable reaidual N (nostly 6-11% of the N applied)was found in 60-100 cm soil layers.  相似文献   

7.
Abstract

Long‐term field experiments are the most suitable tools for determining the optimal nutrient‐supplying technologies that contribute to sustainable agriculture. Under certain environmental conditions (low precipitation, deep groundwater table, negative water balance), part of the applied nitrogen (N) can be found in the soil profile for a longer period and provide N nutrition for crops. A long‐term field experiment has been running at Nagyhörcsök in Hungary since 1973. The nitrogen–phosphorus–potassium (NPK) application rates follow the overall nutrient‐supplying categories (weak, medium, adequate, excessive) by the main nutrients and their combinations. The seasonal dynamics of exchangeable NH4 and NO3 were followed in 1983 and 2003. From certain treatments, two parallel average samples (20–20 subsamples were mixed to get average composite samples by plots) were collected 19 times from March through November from three soil layers. There was no difference in NH4‐N between years, and its seasonal fluctuation was slight in both years, whereas there was an increase in NO3‐N in accordance with the applied N rates. No significant difference occurred in the NO3‐N of the N0P0K0 and the N1P1K1 treatments during both years. A significantly higher NO3‐N content was observed in the higher rate nutrient treatments. Both soil N forms were higher in 1983 than in 2003. Based on the experimental results, the fate and behavior of the surplus N in the soil can be characterized and the residual amount can be taken into account during the calculation of the N‐fertilization demand of arable crops in relation to the N‐fertilizer advisory system.  相似文献   

8.
Abstract

Lead arsenate was extensively used to control insects in apple and plum orchards in the 1900s. Continuous use of lead arsenate resulted in elevated soil levels of lead (Pb) and arsenic (As). There are concerns that As and Pb will become solubilized upon a change in land use. In situ chemical stabilization practices, such as the use of phosphate‐phosphorus (P), have been investigated as a possible method for reducing the solubility, mobility, and potential toxicity of Pb and As in these soils. The objective of this study was to determine the effectiveness of calcium carbonate (lime), P, and iron (Fe) amendments in reducing the solubility of As and Pb in lead‐arsenate‐treated soils over time. Under controlled conditions, two orchard soils, Thurmont loam (Hapludults) and Burch loam (Haploxerolls), were amended with reagent‐grade calcium carbonate (CaCO3), iron hydroxide [Fe(OH)3], and potassium phosphate (KH2PO4) and incubated for 16 weeks at 26°C. The experimental results suggested that the inorganic P increased competitive sorption between H2PO4 ? and dihydrogen arsenate (H2AsO4 ?), resulting in greater desorption of As in both Thurmont and Burch soils. Therefore, addition of lime, potassium phosphate, and Fe to lead‐arsenate‐contaminated soils could increase the risk of loss of soluble As and Pb from surface soil and potentially increase these metal species in runoff and movement to groundwater.  相似文献   

9.
Abstract

A field experiment was conducted at Star City (legal location SW6‐45‐16‐W2); Saskatchewan, Canada from May 2000 to June 2000, to measure nitrogen (N) and phosphorus (P) supply rates from fertilizer bands to the seed‐row of canola crop. Ion exchange resin membrane probes (PRSTM) were used to measure N and P supply rates in four treatments [80 kg N ha?1 of urea as side‐row band, 80 kg N ha?1 of urea as mid‐row band, check/no N (side‐row)/P side‐row, check/no N (mid‐row)/seed placed P]. The treatments were arranged in a randomized complete block design with four replications. Two anion and cation exchange resin probes (PRSTM) were placed in each plot in the seed‐row immediately after seeding and fertilizing. The probes were allowed to remain in the field for 2 days and replaced with another set of probes every 4 days for a total of 14 days until canola emerged. Ammonium‐N, nitrate‐N and P supply rates were calculated based on the ion accumulated on the probes. Urea side‐row band treatments (fertilizer N 2.5 cm to side of every seed‐row) had significantly higher cumulative available N supply rates than mid‐row band placement in which fertilizer N was placed 10 cm from the seed‐row in between every second seed‐row. No significant differences were observed in P supply rates. The higher N rates (120 kg N ha?1) resulted in lower grain yield in side‐row banding than mid‐row banding possibly due to seedling damage. However, the earlier fluxes of N into the seed‐row observed with side‐row banding may be an advantage at lower N rates in N deficient soils.  相似文献   

10.
The measurement of soil carbon dioxide (CO2) respiration is a means to gauge biological soil fertility. Test methods for respiration employed in the laboratory vary somewhat, and to date the equipment and labor required have limited more widespread adoption of such methodologies. A new method to measure soil respiration was tested along with the traditional alkali trap and titration method. The new method involves the Solvita gel system, which was originally designed for CO2 respiration from compost but has been applied in this research to soils with treatments of increasing dairy manure compost. The objectives of this research are to (1) examine the relationship between the CO2 release after 1 day of incubation from soils amended with dairy manure compost that have been dried and rewetted as determined using the titration method and the Solvita gel system, and (2) compare water‐soluble organic nitrogen (N), as well as carbon (C), N, and phosphorus (P) mineralization after 28 days of incubation with 1‐day CO2 release from the titration method and Solvita gel system. One‐day CO2 from both titration and the Solvita gel system were highly correlated with cumulative 28‐day CO2 as well as the basal rate from 7–28 days of incubation. Both methods were also highly correlated with 28‐day N and P mineralization as well as the initial water‐extractable organic N and C concentration.

The data suggest that the Solvita gel system for soil CO2 analysis could be a simple and easily used method to quantify soil microbial activity and possibly provide an estimate of potential mineralizable N and P. Once standardized soil sampling and laboratory analysis protocols are established, the Solvita method could be easily adapted to commercial soil testing laboratories as an index of soil microbial activity.  相似文献   

11.
12.
Abstract

The use and disposal of biosolids, or wastewater treatment sludge, as a fertilizer and soil amendment is becoming increasingly widespread. We evaluated the multiyear use of biosolids in apricot (Prunus armeniaca L.) production, grown on productive agricultural soils. Class A biosolids were initially applied annually at rates of 0, 1.9, 5.8, and 11.7 Mg · ha?1 (dry basis) to a 2‐year‐old apricot orchard on the USDA‐ARS research site on the eastern side of the San Joaquin Valley, CA. These application rates provided estimated rates of 0 (control), 57, 170, and 340 kg total N · ha?1 yr?1, respectively. Compared to the control treatment, the applications of biosolids significantly increased soil salinity (electrical conductivity from 1:1 soil–water extract) and total concentrations of nutrients [e.g., calcium (Ca), magnesium (Mg), sulfur (S), phosphorus (P), zinc (Zn), and copper (Cu)] after 7 years but did not increase the concentrations of selected metals [cadmium (Cd), chromium (Cr), cobalt (Co), nickel (Ni), and lead (Pb)] between 0‐ and 60‐cm soil depths. Mean concentrations of total nitrogen (N) and carbon (C) in soils (0‐ to 15‐cm depth) ranged from a low of 1.3 g kg?1 to a high of 5.2 g · kg?1 and from 14.1 g · kg?1 to 45.7 g · kg?1 for the control and high biosolids treated soils, respectively.

Biosolids applications did not lead to fruit yield reductions, although fruit maturation was generally delayed and more fruits appeared at picking times at the high rate of application. Yellow fruits collected from all biosolids applications were significantly firmer than were fruit collected from control trees, and they had higher concentrations of Ca, potassium (K), S, iron (Fe), and Zn in the fruit. Among the fruit quality parameters tested, the juice pH, total acidity, and fruit skin color were not significantly affected by biosolids applications. Malic acid concentrations decreased most of the time, while citric acid concentrations increased with increasing rates of biosolids applications. Overall, our results suggest that nonindustrial biosolids applied at an annual rate at or less than 11.7 Mg N · ha?1 (340 kg N · ha?1) can be safely used for apricot production on sandy loam soils.  相似文献   

13.
Total nitrogen(N) loss and ammonia volatilization from urea applied to flooded rice grown on a paddy soil in Zhejiang Province were measured by ^15N balance and micro-meteorological methods,respectively.Floodwater properties and ammonia loss from the circular plot were compared with those from the microplots.And the effectiveness of urease inhibitor,NBPT [N-(n-butyl) thiophosphoric triamide],was also tested Results showed that the total losses from urea broadcast and incorporated at transplanting (basal dressing) were similar with those from urea broadcast 12 days after transplanting (top-dressing)(51.5% and 48%,respectively,of applied N),and ammonia losses were low,the corresponding figures were 10.8% and 7.0% of applied N,respectively.Thus,denitrification was a much more important pathway of nitrogen loss than ammonia volatilization under the particular conditions.Addition of NBPT retarded urea hydrolysis,reduced pHs and ammoniacal nitrogen concentrations of floodwater for either the application of urea as basal or as top-dressing,but these effects were not translated into the reduction of total nitrogen loss.Floodwater pHs and ammonia loss in the microplots were apparently lower than those in the circular plot from urea applied as basal dressing;however,such differences were not found when urea was top-dressed.The frequently raining days occurred after top-dressing may be responsible for the insignificant effect of plot size on floodwater pHs and ammonia volatilization.It seems that the effects of phot size on ploodwater properties and ammonia loss mainly depend on weather conditions,in addition to the height and leaf area index of the crop.  相似文献   

14.
Seven short‐fallow plant species were evaluated for their aboveground biomass production, nutrient accumulation, and weed suppression potential in Nkolbisson, Cameroon. The fallow species included Arachis pintoi, Vigna radiata, Desmodium intortum, Centrosema pubescens, Indigofera hirsutus, Indigofera spicata, and Pueraria phaseoloides. The experimental design was a randomized complete block with four replications and seven treatments (fallow species). Twelve months after planting, highly significant differences (p < 0.01) were observed among fallow species for phosphorus (P), potassium (K), calcium (Ca), and magnesium (Mg) concentrations, respectively, in plant tissue. Similarly, highly significant differences (p = 0.0013) occurred among fallow species for aboveground biomass production, which ranged between 3.12 t ha?1 (I. spicata) and 9.16 t ha?1 (A. pintoi). Potassium only showed highly significant differences among plant species for nutrient accumulation (p = 0.0001). However, A. pintoi, C. pubescens, I. hirsutus, and P. phaseoloides yielded substantial amounts of recycled N (>100 kg ha?1 year?1) that can benefit the subsequent crop. For small‐scale producers, these species are likely to supply adequate nitrogen for cereal crops. A total of 26 weed species belonging to 15 botanical families were encountered in the various plots. Weed dry weight differed significantly (p = 0.02) among the fallow plots and ranged from 0.12 t ha?1 (in P. phaseoloides plots) to 2.32 t ha?1 (in A. pintoi plots). Results of this study suggest that there are a wide range of plant species that could be used in improved fallow technologies aimed at improving nutrient‐degraded soils and suppressing weeds.  相似文献   

15.
The suitability of loss‐on‐ignition (LOI) as an alternative to direct measurement of organic carbon (OC) has been debated for decades without resolution. The literature contains an abundance of different linear regression models to describe the LOI–OC relationship, most based on untransformed values of LOI and OC. Such regression is suspect because the variables are unable to occupy Euclidean space. Logratio transformation—based on relative rather than absolute differences—eliminates this constraint. Re‐analysis of the relationship on new and 10 previously published datasets using logratio techniques reveals that the relationship is nonlinear and that the profusion of regression models is in part a function of the range of LOI. Although LOI may offer a crude estimate of OC at high LOI levels, OC/LOI ratios when LOI is less than about 25% are too variable for reliable OC estimation, and interstudy comparisons remain dubious. Direct measurement of OC is recommended.  相似文献   

16.
The Fengqiu long-term field experiment was established to examine effects of organic manure and mineral fertilizers on soil total nitrogen (N) and natural 15N abundance. Fertilizer regimes include organic manure (OM), one-half N from organic manure plus one-half N from mineral N fertilizer (1/2OMN), mineral fertilizers [N–phosphorus (P)–potassium (K), NP, NK, PK], and a control. Organic manure (OM and 1/2OMN) significantly increased soil total N and δ15N, which was expected as a great amount of the N applied remained in soils. Mineral NPK fertilizer and mineral NP fertilizer significantly increased total N and slightly increaed δ15N. Phosphorus-deficient fertilization (NK) and N-deficient fertilization (PK) had no effect on soil total N. Significantly greater δ15N was observed in the NK treatment as compared to the control, suggesting that considerable N was lost by ammonia (NH3) voltalization and denitrification in this P-deficiency fertilization regime.  相似文献   

17.
Abstract

Although nitrogen (N) fertilizer use is essential for economic yields of modern field crops, whether rainfed or irrigated, the underlying concern is to maximize nutrient‐use efficiency and avoid excessive N use that results in deterioration of water quality from the environmental standpoint as well in the interest as human and animal health. Soil testing for N forms and total plant N analysis can contribute to the efficient use of N, but both strategies have limitations. Accordingly, tissue testing of the growing crop has been promoted as an alternative approach. Although such tests have been widely used in the West to monitor the N status of crops, they are rarely used in developing countries. A 2‐year field trial examined the potential of tissue testing of rainfed wheat in a typical Mediterranean environment in the Cukurova region of southern Turkey, because observations from wells in the region had suggested increasing and excessive nitrate levels, most probably from fertilizer N use. The trial, in essence, compared different levels of N fertilizer application based on farmers' traditional application in addition to considering soil mineral N with tissue N based on a color index to refine N application recommendations. The measurements were taken in conjunction with observations on wheat yields. The study showed that using the combined approach of soil and tissue nitrate resulted in lowering the N fertilizer recommendations without any lowering of crop yields, clear evidence that farmers had been using excessive amounts of fertilizer N in the absence of limited or no official guidelines. Thus, such tests should be promoted to replace traditional fertilizer application practices as a simple and easily used tool to improve N‐use efficiency for the farmer, in addition to reducing negative environmental impacts of such use. The quick tests can help promote the awareness of the potential negative effects of overuse of N fertilizer.  相似文献   

18.
In a long‐term maize–wheat rotation at the Punjab Agricultural University, Ludhiana, India (subtropical climate), the effects of nitrogen (N), phosphorus (P), and potassium (K) addition on soil fertility and forms of inorganic P and K in the plow layer of an alkaline sandy loam soil were measured after 11 and 22 years of cropping. The treatments comprised four rates of N (0, 60, 120, and 180 kg N ha?1) as urea, three rates of P (0, 17.5, and 35 kg P ha?1) as single superphosphate, and two rates of K (0 and 33 kg K ha?1) as muriate of potash. The treatments selected for the present study were N0P0K0, N120P0K0, N120P17.5K0, N120P35K0, N120P17.5K33, and N120P35K33. A significant year × treatment interaction in decreasing available N [alkaline potassium permanganate (KMnO4)–oxidizable N) status of soils was found in all the treatments. Available P (Olsen P) in the control plot decreased over time whereas in plots with added P, available P increased significantly after years 11 and 22, with the greatest increase in the N120P17.5Ko treatment. Compared to the initial values, continuous P fertilization resulted in greater total P and chloride P concentrations after 11 and 22 years. Although sodium hydroxide (NaOH) P and sulfuric acid (H2SO4) P increased in P‐treated plots from the start of the trial to year 11, they decreased from year 11 to year 22. Among these inorganic P forms, chloride P was significantly positively correlated with P uptake (r = 0.811*). When only N and P were applied, available K [ammonium acetate (NH4OAc)–extractable K] significantly decreased over time. In plots without K addition, water‐soluble and exchangeable K decreased from their initial status. Compared to year 11, water‐soluble K increased, whereas exchangeable K decreased after year 22 in plots receiving no K fertilizer. Compared with NPK treatments, a significant decrease of total K in NP treatment plots suggests the release and uptake of nonexchangeable K. Water‐soluble K and exchangeable K were not correlated with K uptake. These results suggest that long‐term application of P fertilizers resulted in the accumulation of P in the soil, which could have resulted in saturation of P binding sites. Of the soil inorganic P fractions, only chloride P appears to be a good indicator of plant‐available P. The gradual loss in native soil K and release of nonexchangeable K indicates the need for adding K fertilizer to maintain soil fertility.  相似文献   

19.
A long‐term (61 years) experimental field was used to examine the effect of acidification on the chemical composition of an allophanic Andisol in northeastern Japan. The pH values of the 1:10 water extract of the plow layer soils were 4.1, 4.7, and 6.2 for three fertilizer application treatments: chemical fertilizers only (CF), CF and compost (CFC), and CFC with liming, respectively. Three batch dissolution analyses were conducted to determine water‐soluble and exchangeable (D1), D1 plus, inorganically bound elements to noncrystalline clays and organically bound elements (D2), and total concentration of elements (TCE, 45 elements). The D1 fraction of 20 elements increased, and that of eight decreased with acidification. The D2 fraction of lithium increased, and that of eight elements decreased with acidification. Because the D2 fraction of many other elements and TCE were not strongly altered, present acidification of this soil can be restored with liming and other necessary amendments.  相似文献   

20.
Abstract: Soil quality indicators and nematode abundance were characterized in a loessial soil under long‐term conservation tillage to evaluate the effects of no‐till, double‐disk, chisel, and moldboard plow treatments. Indicators included soil electrical conductivity (EC), soil texture, soil organic matter (SOM), and total particulate organic matter (tPOM). Nematode abundance was positively correlated with EC, silt content, and total POM and negatively correlated with clay content. Clay content was the main source of variation among soil quality indicators and was negatively correlated with nematode abundance and most indicators. The gain in SOM in the no‐till system amounted to 10887 kg over the 24 years or 454 kg ha?1 year?1, about half of this difference (45%) resulting from soil erosion in plowed soils. The balance of gain in SOM with no till (249 kg ha?1 year?1) was due to SOM sequestration with no till. No‐till management reduced soil erosion, increased SOM, and enhanced soil physical characteristics.  相似文献   

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