Estimation of soil weathering stage and acid neutralizing capacity in a toposequence Luvisol–Cambisol on loess under deciduous forest in Belgium

Soils derived from loess are extensive in Europe and are well suited for forestry. They are suspected to be poor acid buffers, however. We have estimated the weathering stage and acid neutralizing capacity of acid soils under forest in a toposequence on loess in the Belgian silt belt. The soils vary distinctly in morphology and physico‐chemical properties according to their topographic position. Dystric Cambisols have developed in colluvial deposits in the dry valley floors, whereas Dystric Luvisols have formed on the slopes in a rejuvenated material. The Cambisols are more acid and less saturated in bases than are Luvisols. They are strongly depleted of clay and contain less weatherable minerals. Easily weatherable minerals are concentrated mainly in the clay fraction of both soil types. Clay minerals of size < 2 μm therefore act as major sinks for protons in these soils. A simplified expression taking into account the total reserve in bases, total aluminium and iron occluded in silicates is used to estimate acid neutralizing capacity. Our estimates confirm that these acid loessic soils are indeed poor acid buffers. They show that the Dystric Cambisols depleted of clay are sensitive to potential acidification, whether natural or man‐made.     

Morphogenetic features of soils in the Cat Tien National Park,southern Vietnam

Morphogenetic features of soils on the selected plots in the Cat Tien National Park in southern Vietnam have been studied with the use of a set of morphological, analytical, and instrumental methods. The lithological factor and topographic position play the leading role in the development of the particular genetic soil features. The soils can be subdivided into four groups according to these factors. The soils developing from volcanic deposits with a predominance of tephra can be classified as thin clayey brown tropical soils (Dystric Skeletic Rhodic Cambisols (Clayic)), and the soils developed from less weathered colluvial derivatives of basalts with some admixture of tephra can be classified as dark-humus clayey tropical soils (Skeletic Greyzemic Umbrisols (Clayic)). Very poor soils developed from the eluvium of argillites are classified as thin weakly developed clayey tropical soils (Dystric Regosols (Clayic)). The soils forming from the alluvial sediments of different textures are classified as alluvial loamy sandy soils (Dystric Fluvisols (Arenic, Drainic)) and as alluvial clay loamy soils (Eutric Fluvisols (Episiltic, Endoclayic)).     

Vertical Distributions of Trace Metals in Natural Soil Horizons from Japan. Part 1. Effect of Soil Types

To predict the long-term behavior of trace metals in a soilprofile, we studied the vertical distributions of barium, zinc,copper, chromium, nickel, cobalt, lead, and the principalmetals, aluminum, iron and manganese, in three soils withdeveloped horizons obtained from rural areas in Japan. Totalelement analysis and selective extraction tests with variousreagents were conducted to clarify the extractability of themetals at each sampling depth.Soil-b (Dystric Cambisols) had the highest extractability ofelements although the vertical distributions of its traceelements were similar to those of soil-d (Umbric Andosols),which had to lowest metal extractability of the three soils.Soil-KUR (Orthic Acrisols or Dystric Cambisols) was the oldest of the three soils and showed downward movement of some tracemetals (chromium and nickel) and principal elements (Fe and Mn)that was probably induced by long-term weathering.The extractability of manganese, zinc and barium with water washigher than other metals examined in all three soils. Lead andcobalt in soil-b and soil-KUR also were considered to have highextractability under long-term weathering processes. Zinc andlead accumulated near soil surface showed higher extractabilitywith every reagent used than those in deep layers of the three soils.     

Cation exchange resin and test vermiculite to study soil processes in situ in a toposequence of Luvisol and Cambisol on loess

Both the ion accumulation on cation exchange resin and the transformation of test vermiculite in situ have been used to identify current processes in acid forest soils. We used such test materials to study weathering in a toposequence Dystric Luvisol–Spodo‐Dystric Cambisol on loess under deciduous forest in Belgium. The resin and a trioctahedral vermiculite were inserted for 2 years in the major horizons, down to a depth of 60 cm. The cation accumulation on the resin revealed that four main acid‐consuming systems are currently active in the toposequence. With decreasing acid neutralizing capacity, these systems are in the Luvisols: (i) the pool of exchangeable bases, (ii) the Al‐bearing minerals controlling the Al concentration in the liquid phase; and in the podzolized Cambisols: (iii) the less weatherable K‐bearing minerals, (iv) the Mg‐bearing phyllosilicates made free of Al interlayers in complexing conditions. The loss of cation exchange capacity in the test vermiculite is related to Al interlayering. However, this process masks a significant interlayer accumulation of magnesium, which is generated by the weathering of the test mineral itself. The largest interlayer accumulation of Mg occurs in the podzolized Cambisol, suggesting more intense weathering of the test vermiculite in this soil.     

Steepland resources: characteristics, stability and micromorphology

Steeplands of Central America are a major land resource, but due to population pressures they are rapidly being deforested leading to landscape instability. Microwatersheds of Southern Honduras were examined to correlate soil type, landform, slope gradient and slump potential. Soils most susceptible to slumping were moderately deep (0.5–1 m) Haplustalfs and Haplustepts. These soils occupy about 25% of the landscape, and have slope gradients of 45–90%. Soils are developed on plagioclase-rich andesitic parent material, are loam to clay loam in texture and have high base status. However, due to weathering of parent material, sand and silt fractions are dominated by quartz with smaller amounts of plagioclase, vermiculite and kaolinite. The A and B horizons have an open porphyric related distribution with plagioclase as the coarse fraction in a fine-grained groundmass. The andesitic parent rock contains abundant hydrothermally altered plagioclase phenocrysts in a single-spaced porphyric-related (c/f_5μm ratio of 4:1) distribution. Some feldspars are partially to completely altered to clay pseudomorphs, probably vermiculite. Microfabric analysis of soil and pararock did not show any striated b-fabric indicative of shear failure. However, microfabrics do confirm translocated clay into the subsoil as typic pore coatings indicating long-term landscape stability prior to deforestation.     

The influence of parent material on soil fertility degradation in the coastal plain of Tanzania

Differences in the vulnerability of soils to fertility degradation are compared for two major soil groups located in the coastal plain of Tanzania and cropped with sisal (Agave sisalana). Ferralsols derived from intermediate gneiss of Precambrian age and Cambisols developed in Jurassic and Neogene limestones partly covered with Quaternary deposits were selected for comparison. A clear influence of parent material was apparent when soils were continuously cropped with sisal and no fertilizers were applied. Serious soil fertility decline occurs in Ferralsols, but Cambisols are resilient to chemical degradation and the fertility decline in these soils was very limited. The differences in degradation rates are explained by the lower initial fertility and low nutrient reserve of Ferralsols, while the Cambisols had higher initial fertility levels and nutrients removed by the sisal crop are replenished by the weathering of the underlying parent material. Sustainable soil fertility management of Cambisols includes only NPK fertilization, but heavy dressings of lime, organic manures and/or chemical fertilizers are required to improve the fertility status of the Ferralsols and to produce crops in a sustainable manner.     

Soil–landscape variability: mapping and building detail information for soil management

The study of soil–landscape relationships at a detailed scale (1:10 000) and its use for soil management was less common in developing countries. The study was conducted in western Ethiopia with the aim to explain the soil variability across landscapes, classify soils into mapping units and produce a map of these soils. This study was performed based on a discrete model of spatial variation. Five soil reference groups: Vertisols, Cambisols, Fluvisols, Luvisols and Leptosols were identified in the study site. Distribution of the soil reference groups was determined by landscape position. Variation in soil texture, colour, pH , exchangeable acidity, organic carbon, total nitrogen, available phosphorus (av. P), carbon to nitrogen ratio (C/N), exchangeable potassium (K), calcium (Ca), magnesium (Mg), sodium (Na) and cation exchange capacity (CEC ) was observed within and among soil mapping units (SMU s). Variability was considerably high for exchangeable Ca and CEC . Factor analysis result indicated that variation in soil properties within land unit was comparatively highest in Leptosols of SMU 9 (88.87%) and lowest in Vertisols of SMU 1 (60.82%). Moderate‐to‐fine scale mapping of soil properties helps to build detail information for soil management. Grouping fields into mapping units that require more or less similar management measure would be an important soil–landscape concept. As a result, mapping units could be used as cost‐effective means of treating variable field so as to optimize the forecasted benefits.     

Soils of the Main Ethiopian Rift Valley escarpment: A transect study

The mountainous environment of the Ethiopian highlands has a great variety of ecotopes and thus demands great flexibility in land management. Different climatic conditions and landscape positions induce different soil forming processes, leading to various soil types with specific risks and potentials. The present study portrays a soil sequence of the central section of the Main Ethiopian Rift Valley, from the footslopes of the eastern escarpment to the marginal volcano structures. Six profiles under natural vegetation are described for classification according to the USDA Soil Taxonomy and World Reference Base for Soil Resources classification systems, and special site characteristics are discussed. The Acacia savannah of the footslopes (1900 m a. s. l.) is characterized by Vertisols (Mazic Vertisols/Aridic Haplusterts), with often pronounced effects of seasonal waterlogging. All other soils are well-drained and reflect the general increase in rainfall with elevation and slope, causing a decline in topsoil pH and a change from cation-rich clay soils of the Podocarpus-dominated forest at 2300 m a. s. l. (Mollic Nitisols/Typic Palehumults) to strongly-leached Humic Umbrisols/Humic Dystrudepts of the Hagenia-dominated forest around 2600 m a. s. l. The highland savannah plain (2700 m a. s. l.) with a drier and cooler environment has typically Mollic Cambisols/Dystric Haplustepts, which are less leached and have a rather brownish colour. At 2900 m a. s. l., Niti-umbric Alisols/Andic Hapludalfs are found in the Hypericum forest at the midslopes of the marginal volcanoes receiving high rainfall, whereas soil development is at a more initial state in the Erica-dominated forest at 3200 m a. s. l. (Umbric Andosols/Alic Hapludands). Clay mineral composition is kaolinite-dominated for the upper five profiles, with a high proportion of poorly crystalline components in the upper savannah and the volcano upslopes. The lowermost profile probably has a polygenetic origin indicated by an abrupt change from a smectitic to a kaolinitic composition in the subsoil. Soil development on quite homogeneous bedrock appears essentially controlled by relief and climate, underlining the suitability of the region as a model area for in-depth gradient studies on ecosystem processes and land use.     

Soil and erosion features of the central plateau region of Tigrai,Ethiopia

The results of reconnaissance soil surveys covering 6,000 km² are used to describe the Central Plateau region, which lies at elevations of 2,000 to 2,800 m in northern Ethiopia. Landform and soil sequences on calcareous shales, dolerites and sandstones are described, in which the principal soil units are Lithosols, Luvisols, Cambisols, Arenosols and Vertisols. Detailed morphological and analytical data are presented for a profile representative of arable soils in each sequence.Small-scale subsistence cultivation of cereals is the dominant land use; all land which is physically cultivable is at present cultivated. Settlement patterns are closely related to soil type, nucleated settlement occurring on fine textured soils but dispersed settlement on coarser textured and more freely draining soils.Erosion and soil moisture features of the three landforms described were investigated and compared. Empirical methods and suspended sediment measurements indicate high rates of regional soil loss (17–33 t ha^?1 yr^?1), accounted for by seasonally high rates of rainfall erosivity, steep terrain and poor land use. The recent development of gully erosion is seen to be linked to the disintegration of waterfall tufas. Application of the universal soil loss equation to arable lands indicates potential annual soil losses in the range of 400 t ha^?1 on Vertisols to 200 t ha^?1 on Cambisols: differences in rates are ascribed principally to differences in crop planting dates, which affect the degree of vegetative protection during periods of high rainfall erosivity.Soil moisture is shown to be in the available range for less than three months in the year. The time at which moisture in the profile enters the available range differed between the three soils monitored and was found to be closely related to the crop planting date, thus indirectly affecting the erosion hazard.     

An experience in using the world reference base for soil resources for the soils of western Georgia

New and previously published data on the soils of western Georgia are generalized, and traditional soil names are correlated with the units of the World Reference Base for Soil Resources. It is argued that krasnozems (red ferrallitic soils) can be attributed to the group of Nitisols (the soils characterized by intense weathering (ferralization) and having shiny ped faces in the nitic horizon); yellow and yellow-brown soils (zheltozems), to the group of Luvisols (the soils with relatively high adsorption capacity in the eluvial horizons and with the horizon of the illuvial accumulation of clay); yellow-podzolic (zheltozem-podzolic) soils, to Alisols (slightly acid soils with the low adsorption capacity, poor aggregation of the upper horizons, low-activity (kaolinite) clay, and with the horizon of clay accumulation (argic horizon)); brown forest soils, to Cambisols (the soils with the cambic horizon characterized by some alteration of the lithogenic texture and structure into the pedogenic texture and structure); and mountainous forest-meadow and meadow soils, to Umbrisols (the soils with the dark-colored unsaturated umbric horizon).     

Clay Dispersion of Hardsetting Inceptisols in Southeastern Nigeria as Influenced by Soil Components

Abstract

Hardsetting soil properties are undesirable in agricultural soils because they hamper moisture movement and soil aeration. The soils of the floodplain of Niger River in eastern Nigeria hardsets upon drying, following dispersion, puddling, and slaking during the waterlogged period. Ten soil samples collected from a depth of 0–20 cm were analyzed for their properties. The soils are classified as Fluvaquentic Eutropepts or Dystric Gleysol (FAO). The objective was to investigate the influence of some soil properties on water‐dispersible clay (WDC) of the soils, which is the precursor of the hardsetting process. The total clay content (TC) correlated significantly with WDC (r=0.94??), whereas the water‐dispersible silt (WDSi) was higher than its corresponding total silt content. The WDC showed a positive correlation with dithionite extractable Fe (Fed), Al (Ald), and oxalate extractable Fe (Feo) (r=0.75?, 0.89??, and 0.76? respectively). Exchangeable Mg²⁺ correlated significantly with WDSi (r=0.70). Principal component analysis of the soil variables indicates that 15 soil components, which influence WDC as hardsetting properties, were reduced to 5 orthogonal components. The parameters that influence hardsetting properties are exchangeable Na⁺, K⁺, Ca²⁺, Mg²⁺, Fed, Alo, and Feo. Other soil properties are kaolinite, smectite, illite, and WDC, including soil organic carbon (OC), electrical conductivity (EC), and ESP. Therefore, those soil properties, which explain hardsetting characteristics most, are exchangeable Na⁺, Fed, OC, Mg²⁺, and Alo. There are negative consequences on the erodibility, runoff, infiltration and tillage of the soils at both submerged and dry conditions due to clay dispersion, low OC, and hardsetting behavior of the soil.     

Schwefelformen in Waldböden SO2-belasteter Standorte des Fichtelgebirges

Sulfur fractions in forest soils of the SO₂-polluted Fichtelgebirge The sulfur status of a soil sequence (two Dystric Cambisols, Haplic Podzol, Eutric Cambisol) in SO₂-polluted coniferous and hardwood forests of the Fichtelgebirge (North-East Bavaria) is investigated. In the mineral soil layers S_t fluctuates between 37 to 943 ppm; 11–84% of S_t is S_p. Layers rich in clay contain up to 79%-S_E, whereas in sandy to silty substrates organic bound C?S-S dominates. The organic surface layers show 1.0–2.9‰ S_t, maximum in the Oh. 69–90% of S_t are C?S-S. S_p is low with a maximum in the L-horizons (9–19% of S_t). S_E is vice versa, because values increase from L (0–8% of S_t) to Oh (7–22% of S_t). The characterization of the sulfur status in a forest ecosystem by investigation of organic layers presumably is more reliable than the results of needle and mineral soil analyses.     

Base cation,aluminum, and phosphorus release potential in Danish forest soils

Long‐term nutrient supply in forest ecosystems is due to the dissolution of primary and secondary minerals in soils. The potential of nutrient release in 19 forest soils in a cool humid climate was examined. The soil profiles are classified as Alfisols (10), Spodosols (2), Entisols (4), Ultisols (1), and Mollisols (2), thus covering a gradient in soil fertility. Short‐term and long‐term release of calcium, magnesium, potassium, phosphorus, and aluminum was evaluated by a batch extraction using dilute nitric acid (0.1 M) for 2 hours, followed by 2 days (48 h), and 7 days (168 h). The solution was renewed after 2 and 50 hours extraction time. Nutrient pools expressed as g m^–2 to soil depth 100 cm, and a base index (Ca²⁺+ Mg²⁺+ K⁺ (mol_c m^–2) : Ca²⁺ + Mg²⁺ + K⁺ + Al³⁺ (mol_c m^–2)) were interpreted in relation to soil texture classes. Subsoil texture classes: Coarse: < 5 % clay; medium 5–10 % clay or (> 5 % silt or > 50 % fine sand), or fine > 10 % clay were evaluated as an indicator of forest soil quality. Base cation and phosphorus release decreased in the order fine > medium > coarse. Texture classes explained base cation release by about 80 % of total variation, and phosphorus release by 40–50 %. The base index generally increased by extraction time for sandy soils and decreased for loamy soils. This indicated that sandy soils released accumulated reactive aluminum in the 0–2 hour extraction. Subsoil texture class is suggested as a pedotransfer function for long‐term nutrient release potential in Danish forest soils.     

秦岭北坡土壤发生特性与系统分类

根据野外调查资料和典型土壤剖面理化性质 ,包括室内化验数据综合分析表明 :秦岭北坡土壤的主要发生特性随海拔高度呈有规律的变化 ,依照《中国土壤系统分类 (修订方案 )》检索 ,土壤垂直带谱结构为 :土垫旱耕人为土—简育干润淋溶土—简育湿润淋溶土—酸性湿润雏形土—暗沃寒冻雏形土—暗瘠寒冻雏形土     

Effects of cattle manure on selected soil physical properties of smallholder farms on two soils of Murewa,Zimbabwe

The effects of cattle manure and inorganic N‐fertilizer application on soil organic carbon (SOC), bulk density, macro‐aggregate stability and aggregate protected carbon were determined on clay and sandy soils of the Murewa smallholder farming area, Zimbabwe. Maize was grown in four fields termed homefields (HFs) and outfields (OFs) because of spatial variability induced by management practices and with the following fertility treatments: control (no fertility amelioration), 5, 15 and 25 t/ha cattle manure + 100 kg/ha N applied annually for seven consecutive years. The addition of cattle manure resulted in significant (P < 0.01) increases in SOC, macro‐aggregate stability and aggregate protected carbon in clay soils from at least the 5 t/ha cattle manure rate and was comparable between HFs and OFs on clay soils. Aggregate protected carbon in clay soils was significantly higher from the 15 and 25 t/ha cattle manure rates compared to the 5 t/ha cattle manure treatment. In contrast, only SOC was significantly (P < 0.05) increased with the addition of cattle manure on the sandy soils, while bulk density, macro‐aggregate stability and aggregate protected carbon were not significantly changed. Bulk density was also not significantly (P > 0.05) different on the clay soils. A significant and positive linear relationship (r² = 0.85) was found between SOC and macro‐aggregate stability, while an r² value of 0.82 was obtained between SOC and aggregate protected carbon on the clay soils. However, no regressions were performed on data from the sandy soils because of the lack of significant changes in soil physical properties. Application of cattle manure and inorganic N‐fertilizer significantly increased (P < 0.05) maize grain yield on both soil types. Results show that inorganic N‐fertilizer combined with cattle manure at 5–15 t/ha per yr is necessary to increase maize yields and SOC on sandy soils in Murewa, while at least 15 t/ha per yr cattle manure is required on the clay soils to improve physical properties in addition to maize yields and SOC.     

Effect of soil properties and environmental factors on chemical compositions of forest soils in the Russian Far East

Purpose

Forest ecosystem acts as a significant sink and source of elements; however, the dynamics of trace elements (TEs) in soils of boreal zone are still poorly characterized. Data on relationships of TEs, major elements (MEs), soil properties, and parent rock geochemistry in boreal forest of Northeast Asia are scarce. Therefore, the objectives of this study were to evaluate the origination of TEs in forest soils and identify soil properties and ecosystem processes controlling accumulation and profile distribution of TEs.

Materials and methods

Dystric Cambisols and underlying parent rocks have been sampled within hilly landscape covered by Gmelin larch (Larix gmelinii (Rupr.) Rupr.) forests in Amur region (Russia). This paper considers 10-selected soil characteristics, total concentrations of 19 TEs, and 10 MEs measured by ICP-MS and RFA analysis. Factor analysis has been employed to highlight underlying relationships hidden in a complex data of element concentration and soil characteristics. Origination of TEs was assessed by using an enrichment factor (EF) considering concentration of TEs in soil in comparison to underlying parent rocks using Ti as a reference element.

Results and discussion

A group of biophile Zn, Mo, Sn, and Pb were enriched in the upper soil horizon, and depleted in mineral compared to parent rocks. Beryllium, Sc, Cr, Cu, Ga, Ge, Ta, Th, and U were depleted in both horizons. Ni and Cs show highest enrichment in both studied soil horizons. Frequently occurring forest fires affect soil characteristics and TEs dynamic only in the upper part of soil profile. Factor analysis revealed potential effect of exchangeable Na and soil pH on accumulation of the elements in the upper horizon, as a result of ash deposition by fire.

Conclusions

The studied TEs primarily originate from underlying parent rocks. Accumulation versus leaching of TEs in Dystric Cambisols might be element specific and affected by fire-derived ash. Our work shows that the upper horizon of forest soils could act as a significant sink of group of TEs. Therefore, long-term observations of TEs dynamic in soil profiles are needed to elucidate biogeochemical cycles in frequently burned forests of Northeast Asia. The present study for the first time has established an important wide data set of TEs concentration in Dystric Cambisols of natural boreal forests in the Russian Far East.

     

Assay of chitinase and N-acetylglucosaminidase activity in forest soils with 4-methylumbelliferyl derivatives

Chitinase and N-acetylglucosaminidase activities in forest soils were examined by a highly sensitive method using 4-methylumbelliferyl (4MU) derivatives of N-acetyl-D-glucosamine oligomers as substrates. The method involves the fluorometric estimation of the 4-MU released through the activity of the soil enzymes when a soil sample and the substrate are incubated in a buffer. The activities of both enzymes decreased markedly with depth in the 4 forest soil profiles studied (i.e. Andosol, Podzol, 2 Cambisols). The activities of these soil enzymes were highly correlated with the carbon and nitrogen content of the soils.     

Reisböden aus Kolluvium basaltischen Ursprungs im Hochland von Madagaskar

Paddy soils from basaltic colluvium in the Highland of Madagascar Three soils under lowland rice cultivation, found on the Highland of Madagascar, in the Vakinankaratra region, were investigated, in order to help understanding their ecology and to assess their fertility. The parent material of the three soils consists of basaltic colluvium. According to the FAO-UNESCO (1988), these soils have been classified as Ferralic Cambisol (D2) and Dystric Gleysol (D3 et D4). They are very poor in alkali cations, and rich in aluminium, iron and clay. The clay is mainly composed of gibbsite, kaolinite as well as of little amounts of goethite and quartz. This composition underlines the high degree of intensive soil weathering. The low fertility of the investigated soils is due to very low contents of available P, Ca, Mg, K and N, as well as to the high content of iron and manganese, which are toxic for rice plants under the anaerobic conditions of the soils during flooding. We therefore recommend to add to the soil beside NPK fertilizers, limestone powder in order to obtain a pH-value between 6 and 7. This will lead to an increase of Ca, Mg, and K as well as to a better plant availability of phosphorus and a decrease of the toxic effects of iron and manganese.     

The importance of andic soils in mountain ecosystems: a pedological investigation in Italy

Andic soils have unique morphological, physical and chemical properties that induce both considerable soil fertility and great vulnerability to land degradation. In recent years there have been many reports of soils with andic properties in Non‐Volcanic Mountain Ecosystems (NVME) in different parts of the world. This paper attempts to assess the importance of andic soils in mountain ecosystems of Italy. We used the criteria of altitude (> 700 m above sea level), slope (< 12°) and active green biomass (maximum Normalized Difference Vegetation Index (NVDI) value > 0.5) for identifying sites where andic soil processes may occur in the NVME of Italy. We characterized in detail 42 soils in the areas thus identified. According to WRB (2006) the main soils are Andosols, Cambisols, Phaeozems, Umbrisols and Podzols. Despite the taxonomic diversity, the morphological, micromorphological and chemical properties indicate considerable pedological homogeneity in these soils. The most striking features are the large values of Al_o + 0.5Fe_o (as %), which is a standard index for andic soil properties ( USDA, 2006; WRB, 2006 ), but it occurs at the wrong depths for many of our soils to qualify as true Andosol/Andisols and there is little evidence of podzolization. We therefore suggest that (i) andic soils must be recognized more clearly in soil classification, particularly with respect to the depths at which andic properties are developed, and (ii) the importance of andic soils in Italian NVMEs (and possibly elsewhere in the world) has been underestimated. These soils warrant further investigation because of their agricultural potential and ecological importance.     

Conditions related to solubility of rare and minor elements in forest soils

Soil solutions expelled by high‐speed centrifugation (13900 g) of intact soil sample cores at field moisture from 30 forest topsoils (A horizons of mainly Dystric and Eutric Cambisols, according to the FAO‐Unesco system) low in clay were subjected to analysis of 60 elements, using ICP‐MS and ICP‐AES. Concentrations measured were related to soil and soil solution properties assumed to be important for the solubility of elements, using stepwise regression analysis. On an average two thirds of the variability in soil solution concentration of elements were accounted for by, in particular, organic C concentrations, pH and/or nitrate concentrations of the solutions, varying among elements from 19 to 90 %. Concentrations of elements strongly positively related to soil solution acidity were Al, Be, Ge, Li, Ni, Pb, and Zn, strongly negatively related to acidity were Ca, Mo, and W. Most positively related to nitrate concentrations in soil solutions were B, Ba, Cd, Mg, Mn, and Sr; negatively were Nb, Ta, and Ti. Concentrations of organic C in the soil solutions correlated positively, often quite closely, with most of the other elements studied, including La, all the lanthanides, and with Ag, Br, Cr, Fe, Ga, Hf, Hg, In, P, Th, U, Y, and Zr. Soluble organic compounds were apparently ’︁carriers’ of these elements in the soil solution. The concentrations of elements in HNO₃ digests of the soils usually accounted for just little or no statistical variability of their soil solution concentrations.