Analysis of Soil Chemical Properties of Sand-Based Turfgrass Rootzone using Fourier Transform–Infrared Spectroscopy

To evaluate diffuse reflectance Fourier transform–infrared (DRIFT) in near-infrared (NIR) and mid-infrared (MIR) regions in conjunction with partial least square regression analysis for sand-based turfgrass soils, soil samples were collected from greens 6 to 9 years old, composed of two rootzone mixtures and from two establishment fertilization regimes, at different depths (surface to 7.6 cm in 12 layers). Mid-infrared and NIR spectroscopy resulted in similar calibration accuracy for total organic carbon, total nitrogen, cation exchange capacity, electric conductivity, and pH with R ² > 0.80. The modeling process for MIR spectrum was repeated on sample subsets, which were grouped from the original samples based on rootzone mixtures, putting green age, and depth to test the robustness of prediction models. Results of this study suggested that DRIFT-NIR and DRIFT-MIR could be used to predict these properties of sand-based turfgrass soils providing the soil samples are from similar depths.     

Trace Analysis of N-Nitrosamines in Water Using Solid-Phase Microextraction Coupled with Gas Chromatograph–Tandem Mass Spectrometry

A method that utilizes solid-phase microextraction (SPME) coupled with gas chromatography (GC) and chemical ionization tandem mass spectrometry (MS/MS) was developed for analyzing a group of emerging pollutants, N-nitrosamines, in water. The developed analytical method requires a water sample of less than 5 ml and only 1.5 h for complete analysis. The method detection limits for N-nitrosodimethylamine (NDMA), N-nitrosodiethylamine, and N-nitrosodi-n-propylamine were in the range of 3.2 to 3.5 ng/l; for N-nitrosomorpholine, it was 15.2 ng/l. The method was successfully employed to measure the N-nitrosamine concentration at trace levels of nanogram per liter in four water treatment plants (WTPs) and one water distribution system. In the WTPs, only NDMA was detected in the treatment processes. Within the treatment train, NDMA was observed after chlorination. The level of NDMA significantly declined after slow sand filtration due presumably to microbial degradation. The NDMA concentration collected from consumer tap water was about 40% higher on average than that in the finished water. The excellent performance of the SPME/GC/MS/MS method in various water matrices as well as the shorter analysis time and smaller sample volume compared to currently used extraction techniques makes it an alternative means for the analysis of N-nitrosamine in drinking water, wastewater, and laboratory research with small reactors.     

Evaluating Methods of In‐Field Soil Organic Matter Analysis

Abstract

The actual content of the soil organic carbon (SOC) has to be periodically measured for soil classification and nutrient management purposes. Traditional SOC tests are relatively time consuming and costly. A rapid field test would be valuable to delineate soil map units with similar SOC to simplify the process of land evaluation while increasing precision. The objectives of this study were to develop and evaluate a new field measurement technique for the quick assessment of SOC. The new method measures the emitted CO₂ concentration 3 min after treatment of the soil sample with acidic potassium (K) permanganate solution. The inorganic carbonate content of the soil is measured separately with the addition of sulphuric acid only. Carbon dioxide concentration from both procedures is measured with a portable infrared gas analyzer. The difference between the concentrations measured after the two separate reactions provide an estimate of SOC. Samples from brown forest soils (ca Hapludalf) (0.19–5.53% SOC) were used for the method development. The correlation coefficient between the SOC determined by the new method and laboratory wet combustion method content was 0.76 for the full range of SOC and 0.81 for the soil samples with less than 20% carbonate.     

Root Growth and Soil Water Dynamics in Relation to Inorganic and Organic Fertilization in Maize–Wheat

Agricultural productivity is increasingly becoming dependent upon soil fertility, which is generally thought to be supplemented through the application of nutrients mainly through inorganic fertilizers. The present study aims to characterize the soil physical environment in relation to long-term application of farmyard manure (FYM) and inorganic fertilizers in a maize–wheat cropping system. The treatments in both the maize and wheat systems included a control (without any fertilizer or FYM), FYM (farmyard manure at 20 t ha^?1), N₁₀₀ (nitrogen at 100 kg ha^?1), N₁₀₀P₅₀ (nitrogen and phosphorus at 100 and 50 kg ha^?1), and N₁₀₀P₅₀K₅₀ (nitrogen, phosphorus, and potash at 100, 50, and 50 kg ha^?1). The treatments were replicated four times in a randomized complete block design in sandy loam soil. The root mass density in surface layers of both the crops was lower in FYM and higher in inorganic fertilizer plots. The root length density was found to be highest in FYM-treated plots and lowest in control plots. The periodic soil matric suction during wheat following maize remained highest in FYM plots followed by that in N₁₀₀ plots in all the layers. The soil water storage of wheat at harvest (rice–wheat) was highest (21.1 cm) in control and lowest (17.8 cm) in FYM-treated plots. The soil water status, root growth, and crop performance improved with balanced fertilization.     

Acid–Base Characteristics and Clay Mineralogy in the Rhizospheres of Norway Maple and Common Spruce and in the Bulk Mass of Podzolic Soil

Eurasian Soil Science - Acid–base characteristics and composition of clay minerals were estimated in the rhizospheres of Norway maple (Acer platanoides) and common spruce (Picea abies) and in...     

Availability of Lead and Cadmium in Farmland Soil and Its Distribution in Individual Plants of Dry‐Seeded Rice

Abstract

Availability of lead (Pb) and cadmium (Cd) in farmland soils and its distribution in individual plants of dry‐seeded rice were investigated utilizing graphite furnace atomic absorption spectrometry (GFAAS) with a matrix modification technique. Five extractants were compared, and the operating conditions for GFAAS were optimized. The detection limits were 4.2 ng for Pb with the precision of 1.54% and 0.1 ng for Cd with the precision of 2.38%. The contents of the extractable Pb and Cd in soils were determined with the five extractants, and availability of Pb and Cd in farmland soil was discussed. The contents of Pb and Cd in different parts of dry‐seeded rice were lower than those in dry‐seeded rice soil. The contents of Pb and Cd in rice were lower than in other parts. The end top leaves accumulated the highest amounts of Pb and Cd.     

Soil Total Nitrogen and Natural 15Nitrogen in Response to Long-Term Fertilizer Management of a Maize–Wheat Cropping System in Northern China

The Fengqiu long-term field experiment was established to examine effects of organic manure and mineral fertilizers on soil total nitrogen (N) and natural ¹⁵N abundance. Fertilizer regimes include organic manure (OM), one-half N from organic manure plus one-half N from mineral N fertilizer (1/2OMN), mineral fertilizers [N–phosphorus (P)–potassium (K), NP, NK, PK], and a control. Organic manure (OM and 1/2OMN) significantly increased soil total N and δ¹⁵N, which was expected as a great amount of the N applied remained in soils. Mineral NPK fertilizer and mineral NP fertilizer significantly increased total N and slightly increaed δ¹⁵N. Phosphorus-deficient fertilization (NK) and N-deficient fertilization (PK) had no effect on soil total N. Significantly greater δ¹⁵N was observed in the NK treatment as compared to the control, suggesting that considerable N was lost by ammonia (NH₃) voltalization and denitrification in this P-deficiency fertilization regime.     

Fractions of Iron in Soil under a Long-Term Experiment and Their Contribution to Iron Availability and Uptake by Maize–Wheat Cropping Sequence

Soil and plant samples were collected from an ongoing long-term experiment (LTE) at the Indian Agricultural Research Institute farm, New Delhi, to study the distribution of various fractions of iron (Fe) and their contribution to availability and plant uptake in a maize–wheat sequence. The optimum dose-based treatments adopted for the study were nitrogen (N), nitrogen–phosphorus (NP), nitrogen–phosphorus–potassium (NPK), NPK + farmyard manure (FYM), NPK+ zinc (Zn), and control (no fertilizer or manure). Different fractions of Fe in the soil were sequentially extracted using different extractants. Diethylenetriaminepentaacetic acid (DTPA)–extractable Fe did not differ significantly among the treatments as a result of continuous cropping for more than three decades. The overall mean total iron (Fe) content varied from 2.36 to 2.61% under different treatments. Residual Fe constitutes a major portion of total Fe in all four layers of soil. The Fe associated with easily reducible Mn and organic matter contributed directly to DTPA-extractable Fe both in pre-maize and post-wheat soil. Residual Fe contributed directly to uptake Fe by maize and wheat crops.     

Distribution and Accumulation of Copper and Cadmium in Soil–Rice System as Affected by Soil Amendments

The effects of seven amendments on the distribution and accumulation of copper and cadmium in a soil–rice system were investigated using a pot experiment. Results showed that application of limestone, calcium magnesium phosphate (Ca–Mg–P fertilizer), calcium silicate (silicon fertilizer), Chinese milk vetch, pig manure, and peat significantly decreased the concentrations of Cu and Cd in rice roots by 24.8–75.3% and 9.7–49.9%, respectively. However, no significant difference was observed between zinc sulfate (zinc fertilizer) and the control treatment. The concentrations of Cu and Cd in different parts of rice followed the order: root > straw > grain, and all amendments restrained the transfer of Cu and Cd from rice root to stem. Copper and Cd concentrations in rice stems at the tillering stage were the highest, and then decreased from the tillering stage to the heading stage. However, they increased again at the ripening stage. The results also showed that application of amendments changed Cu and Cd solubility in soil and decreased their bioavailability, which resulted in the reduction of Cu and Cd uptake by rice. Significant correlations between the concentrations of Cu and Cd in soil solutions and in rice stems were found. The result demonstrated that limestone has the best efficiency among all the amendments used in reducing Cu and Cd contamination to rice production.     

Genotypic Differences in Concentration and Bioavailability of Kernel‐Iron in Tropical Maize Varieties Grown Under Field Conditions

Abstract

Iron deficiency is estimated to affect over one‐half the world population. Improving the nutritional quality of staple food crops through breeding for high bioavailable iron represents a sustainable and cost effective approach to alleviating iron malnutrition. Forty‐nine late maturing tropical elite maize varieties were grown in a lattice design with two replications in three locations representing three agroecologies in West and Central Africa to identify varieties with high levels of kernel‐Fe. Bioavailable iron was assessed for some varieties selected for high Fe concentration in kernel and improved agronomic traits using an in vitro digestion/Caco‐2 cell model. Significant differences in kernel‐Fe and ‐zinc concentration were observed among varieties (P < 0.001). Kernel‐Fe levels ranged from 16.8 to 24.4 mg kg^?1, while kernel‐Zn levels ranged from 16.5 to 24.6 mg kg^?1. Environment did not have a significant effect on kernel‐iron and ‐zinc levels, but genotype by environment (G × E) interaction was highly significant. The genetic component accounted for 12% of the total variation in kernel‐Fe and 29% for kernel‐Zn levels. Kernel‐Fe was positively correlated with kernel‐Zn (R ² = 0.51, P < 0.0001). Significant differences in iron bioavailability were detected among selected Fe‐rich varieties grown at one location. Mean bioavailable Fe ranged between 30% below to 88% above the reference control variety. The results indicate that genetic differences exist in kernel‐Fe and ‐Zn concentrations and Fe bioavailability. These differences may be useful in biofortification intervention programs, but additional research is needed to determine the efficacy of iron‐rich maize varieties in alleviating iron deficiency in humans.     

Bioresource Nutrient Recycling and Its Relationship with Biofertility Indicators of Soil Health and Nutrient Dynamics in Rice–Wheat Cropping System

A field experiment was conducted for 3 years during 2006–2009 in India to study the effects of plant nutrient recycling through crop residue management, green manuring, and fertility levels on yield attributes, crop productivity, nutrient uptake, and biofertility indicators of soil health in a rice–wheat cropping system. The study revealed that soil microbial biomass carbon (SMBC) and carbon dioxide (CO₂) evolution were significantly greatest under crop residue incorporation (CRI) + Sesbania green manuring (SGM) treatment and were found at levels of 364 μg g^?1 soil and 1.75 μg g^?1 soil h^?1, respectively; these were increased significantly by recycling of organic residues. Activities of dehydrogenase and phosphatase enzymes increased significantly after 3 years, with maximum activity under CRI + SGM treatment. The CRI with or without SGM significantly influenced the plant height, number of tillers m^?2, number of grains panicle^?1 or ear^?1, and 1000-grain weight. Mean yield data of rice and wheat revealed that CRI or crop residue burning (CRB) resulted in slightly greater yield over crop residue removal (CRR) treatment. The CRI + SGM treatment again observed significantly greatest grain yields of 7.54 and 5.84 t ha^?1 and straw yields of 8.42 and 6.36 t ha^?1 in rice and wheat, respectively, over other crop residue management treatments. Total nitrogen (N), phosphorus (P) and potassium (K) uptake in rice–wheat system was greatest with amounts of 206.7, 37.2, and 205.6 kg ha^?1, respectively, in CRI + SGM treatment. Fertility levels significantly influenced the rice and wheat yield with greatest grain yields of 6.66 and 5.68 t ha^?1 and straw yields of 7.94 and 5.89 t ha^?1 in rice and wheat, respectively, with the application of 150% of recommended NPK. Total NPK uptake in rice–wheat system also increased significantly with increase in fertility levels with greatest magnitude by supplying 150% of recommended NPK. Overall, nutrient recycling through incorporation of crop residues and Sesbania green manuring along with inorganics greatly improved the crop productivity, nutrient uptake, and biofertility indicators of soil health with substantial influence on SMBC, CO₂ evolution, and dehydrogenase and phosphatase enzyme activities. This indicates that crop residue management along with Sesbania green manuring practice could be a better option for nutrient recycling to sustain the crop productivity and soil health in intensive rice–wheat cropping system in India as well as in similar global agroecological situations, especially in China, Pakistan, and Bangladesh.     

Effect of Incorporation of Crop Residues on a Maize–Groundnut Sequence in the Humid Tropics. II. Soil Physical and Chemical Properties

Abstract

A two‐year study (1997–1999) was conducted on a sandy clay loam (Typic Paleudult) at the experimental farm of the Universiti Putra to determine the effects of application of crop residues on changes of some soil properties in a maize (Zea mays L.)–groundnut (Arachis hypogaea) crop rotation system. Five crops of a rotation of sweet corn–groundnut–sweet corn–groundnut–sweet corn were sown with three treatments: recommended inorganic fertilizer [nitrogen (N), phosphorus (P), and potassium (K)] with crop residue (T1), recommended inorganic fertilizer without crop residues (T2) or one‐half of the recommended inorganic fertilizer with crop residues combined with 10 t ha^?1 of chicken manure (T3). Soil organic carbon (OC), soil water content and soil bulk density were not significantly changed. Application of crop residues for two years increased cation exchange capacity (CEC) whereas supplementing crop residues with CM had significantly increased soil pH of the topsoil. Phosphorous in manure treatment had moved down the soil profile, which might cause eutriphication of under ground water, particularly during the rainy season. Based on this work, incorporation of crop residues could be a beneficial practice for improving the fertility of acid soils.     

Investigation of Nitrate–Nitrogen (NO3–N) Mass Balance Between Effluent and Soil Under the Effect of Raw Pistachio Residues and its Biochar Application

Disruption in the nitrogen (N) cycle balance has a negative impact on the overall trend of sustainable development, and using soil amendments is necessary to reduce these hazards. This study was carried out as a factorial experiment in a completely randomized design. The treatments consisted of three levels of amendments (0, 7.5 g/kg of pistachio residues, and 7.5 g/kg of biochar) and four levels of irrigation water salinity including 0.5 (urban water), 5.5, 8, and 10.5 dS/m and in three replications. Two pistachio seedlings were transferred to all columns and then in three steps, and in each step, 25 mg N/kg of potassium nitrate was added. The results indicated that pistachio residuals and its biochar increased nitrate outflow from effluent by 9% and 52%, respectively. The effects of amendment treatment and irrigation water salinity on all three characteristics of output nitrate, soil nitrate, and absorbed plant nitrate were significant at 1% level.     

Effects of Continuous Use of Chemical Fertilizers and Manure on Soil Fertility and Productivity of Maize–Wheat under Rainfed Conditions of the Western Himalayas

Long-term effects of continuous use of chemical fertilizers and manure on soil fertility and productivity of a maize–wheat system were investigated in the ongoing long-term fertilizer experiment, during rabi (2007–2008) and kharif (2008) seasons at the research farm of Chaudhary Sarwan Kumar Himachal Pradesh Agricultural University–Hill Agricultural Research and Extension Centre, Dhaulakuan. After 16 cropping cycles, bulk density decreased in plots where farmyard manure (FYM) was applied, whereas pH decreased in all the treatments. The organic carbon content of the soil increased in all the treatments except 100% nitrogen (N). Cation exchange capacity (CEC) increased in all the treatments over the initial status of the soil. Available N showed buildup over the initial status in most of the treatments. Available phosphorus (P) declined from initial status in treatments where only N was applied alone or with FYM. There was reduction in available potassium (K) status in all the treatments except 100% NPK. Continuous addition of FYM with balanced application of inorganic fertilizers improved content of exchangeable calcium (Ca) and magnesium (Mg) over initial status compared to imbalanced application of fertilizers. Continuous use of imbalanced inorganic fertilizers resulted in lesser crop yields and nutrient uptake compared to that with the application of balanced dose of inorganic fertilizers with FYM.     

Application of Soil and Plant Analysis for Applied Research and Development in West Asia–North Africa: An International Center's Perspective

Abstract

The networks of 15 international research centers around the globe that are sponsored by the Consultative Group for International Agricultural Research (CGIAR) seeks to alleviate poverty in the developing world through enhanced production, while maintaining biodiversity and the sustainability of natural resources. The mandate of the International Center for Agricultural Research in the Dry Areas (ICARDA) is to focus on improving semi‐arid cropping systems in the drought‐prone West Asia and North Africa region. Since its inception in 1997, ICARDA's soil laboratory played a pivotal role in backstopping the institution's on‐station and on‐farm research in Syria and its collaborative research with the region's national programs. This article gives an overview of the evolution of soil and plant analysis in serving the center's mission. A major effort was the regional soil test calibration program, which set the basis for rational use of fertilizers and the identification of related nutrient constraints. Such analyses were extensively employed in all the long‐term dryland cropping system trials and later in irrigated agriculture and the interface between plant nutrition and crop breeding. Major emphasis was given to improving and upgrading analytical services in the region's laboratories. Despite advances made in analytical methodology, the challenge is to apply to solving real problems in the service of humanity.     

Differences in Root Exudation Among Phosphorus‐Starved Genotypes of Maize and Green Gram and Its Relationship with Phosphorus Uptake

Abstract

Availability of phosphorus (P) in soil and its acquisition by plants is affected by the release of high and low molecular weight root exudates. A study was carried out to ascertain the qualitative and quantitative differences in root exudation among the genotypes of maize (Zea mays L.) and green gram (Vigna radiata L.) under P‐stress. Results showed that both inter‐ and intra‐species differences do exist among maize and green gram in terms of root exudation, P uptake, and shoot and root P content. In general, green gram, a legume crop, had greater root exudation compared to maize. However, the amino acid content of the total root exudates in maize was two‐fold as compared to green gram. The maize and green gram genotypes possessed genetic variability in root exudation. Irrespective of the species or genotypes, a positive relationship was found among P uptake rates, total root exudation, and shoot and root ³²P content. The amount of sugars and amino acid present in the root exudates of P‐starved seedlings also add to the variation in P uptake efficiency of genotypes.     

Efficiency of Phosphogypsum and Mined Gypsum in Reclamation and Productivity of Rice–Wheat Cropping System in Sodic Soil

In this study, efficacies of mined gypsum and phosphogypsum (PG), when applied at equivalent doses, were compared for sodic soil reclamation and productivity of rice–wheat system. Application of PG, followed by karnal grass as first crop, resulted in the greatest reduction of soil pH and exchangeable sodium percentage (ESP) followed by PG applied at 10 Mg ha^?1 alone. Application of PG at 10 Mg ha^?1 resulted in greater yields of both rice and wheat than other treatments. Ditheylenetriaminepentaacetic acid (DTPA)–extractable micronutrients of PG-treated soil were greater than in mined gypsum–treated soil. A greater portion of applied P entered the calcium (Ca)–phosphorus (P) fraction in PG-treated soil, which also resulted in more soluble P than the mined gypsum–treated soil. Phosphogypsum effected greater increase in aggregation, soil organic carbon, microbial biomass carbon, and aggregate associated carbon and decrease in zeta potential, leading to increased hydraulic conductivity and moisture retention capacity in soil over mined gypsum–treated soil.     

Simultaneous Determination of Aniline,Benzidine, Microcystins,and Carbaryl in Water Using Ultra-Performance Liquid Chromatography–Electrospray Ionization Tandem Mass Spectrometry

A method for simultaneously determining the levels of aniline, benzidine, microcystin variants (microcystin-LR, RR, and YR) and carbaryl in water was developed based on ultra-performance liquid chromatography–electrospray ionization tandem mass spectrometry (UPLC-MS/MS). The chromatographic conditions were optimized for the trace determination. Without sample enrichment, the method detection limit for all test compounds ranged from 0.040 to 0.155 μg/L; meanwhile, the recoveries for all test compounds were 83.1–114%. Precision, indicated by the relative standard deviation, was <12.9%. The results meet the requirements for the determination of these compounds. Without the need to clean up the samples, the results of the analysis of samples from wastewater and surface water demonstrated that the UPLC-MS/MS method has the capability to analyze complex matrices in the trace-level monitoring of wastewater samples.     

Evaluation of Agronomic and Environmental Soil P Test Methods in a Network of Hungarian Long‐Term Field Trials

Abstract

Winter wheat shoot weight and phosphorus (P) concentrations, corn leaf weight and P concentrations, and soil AL, Olsen, H₂O, Bray 1, Pi (Fe-oxide impregnated paper strip) and AERM (anion exchange resin membrane) contents were determined in a network of uniform Hungarian national long‐term field trials. P application had a significant effect on soil P test values at different P levels and sites. The relationship between the different soil P test methods was studied separately for different soil groups (all, acid, and calcareous soils). Corn leaf weight was influenced by the sites much more than by soil P supply level, whereas corn leaf P percentage was influenced by both sites and P levels. For winter wheat, both sites and soil P levels had a positive effect on wheat shoot weight. Wheat shoot P percentage was influenced by the soil P supply much more than by the sites. Correlation between corn leaf P percentage and the Pi or AERM extractable P and between wheat shoot P percentage and the Pi and AERM P values was logarithmic.     

Kinetics of K Desorption from Soils in a Constant Electric Field (Electro-Ultrafiltration) and Its Application

Kdesorption from soils in a constant electric field (field strength:44.5Vcm^-1) by means of electro-ultrafil-tration (EUF) followed second-order kinetics and could be described by the equation dd/dt=k(D-d)2. From theequation, such kinetic parameters relating to K desorption from soils as the maximum desorbable quantity D, quantity of K desorbed within 40 minutes d40, initial desorption rate Vo, desorption rate constant k and half-time t1/2 could be calculated. An expression which describes the relationships between the kinetic parameters on the one hand and the responses of barley to fertilizer-K in the field experiments in different sites and the potassium-supplying power of soils on the other was established. Vo, D and d40 were significantly correlated with barley relative yield, K uptake by barley and the content of soil available potassium. The rate constants of K desorption varied between 4.42×10^-4-1.80×10^-3kg mg^-1 min^-1 and highly correlated with the relative yield of barley.