Prediction of Soil Cation Exchange Capacity Using Different Soil Parameters by Intelligent Models

ABSTRACT

The traditional methods for the measurement of soil cation exchange capacity (CEC) are time-consuming and laborious. It is also difficult to maintain stability for long-term experiments and projects. Therefore, it is necessary to develop an indirect approach such as pedotransfer functions (PTFs) to estimate this property from more easily available soil data. The aim of this study was to compare multiple linear and nonlinear regression, classification and regression trees (C&RT), artificial neural network (ANN) model included multiple layer perceptron (MLP) and k-nearest neighbors (k-NN) to develop PTFs for predicting soil CEC. Soil samples, 929, were used into two subsets for training and testing of the models. Sensitivity and statistical analyzes were conducted to determine the most and the least influential variables affecting soil CEC. The prediction capability of models was assessed by statistical indicators included the normalized root-mean-square error (NRMSE) and the coefficient of determination (R²). Results of the present investigation showed that the k-NN and ANN models had the ability to estimate soil CEC by computing easily measurable variables with a guarantee of authenticity, reliability, and reproducibility. Therefore, the results of this study provide a superior basis for predicting soil CEC and could be applied to other parts of the world with similar challenges.     

Alternative methods in the development of pedotransfer functions for soil hydraulic characteristics

Soil hydraulic properties are needed in the modeling of water flow and solute movement in the vadose zone. Pedotransfer functions (PTFs) have received the attention of many researchers for indirect determination of hydraulic properties from basic soil properties as an alternative to direct measurement. The objective of this study was to compare the performance of cascade forward network (CFN), multiple-linear regression (MLR), and seemingly unrelated regression (SUR) methods using prediction capabilities of point and parametric PTFs developed by these methods. The point PTFs estimated field capacity (FC), permanent wilting point (PWP), available water capacity (AWC), and saturated hydraulic conductivity (Ks) and the parametric PTFs estimated the van Genuchten retention parameters. A total of 180 soil samples was extracted from the UNSODA database and divided into two groups as 135 for the development and 45 for the validation of the PTFs. The model performances were evaluated with three statistical tools: the maximum error (ME), the model efficiency (EF), and the D index (D) using the observed and predicted values of a given parameter. Despite the fact that the differences among the three methods in prediction accuracies of the point and parametric PTFs were not statistically significant (p > 0.05) except θ_r and α (p < 0.05) based on the ANOVA test, overall MLR and SUR were somewhat better than CFN in prediction of the point PTFs, whereas CFN performed better than the other two methods in prediction of the parametric PTFs. The F.F values of FC and θ_r for CFN, MLR, and SUR methods were 0.705. 0.805, 0.795 and 0.356, −0.290, −0.290, respectively, which refer to the best and worst predictions. Properties (Ks, θ_r, α) having some difficulty in prediction were better predicted by CFN and SUR methods, where these methods predict all hydraulic properties from basic soil properties simultaneously rather than individually as in MLR. This suggests that multivariate analysis using such functional relationships between hydraulic properties and basic soil properties can be utilized in developing more accurate point and parametric PTFs with less time and effort.     

青海三江源地区土壤容重转换函数的建立与比较

Bulk density (BD) is an important soil physical property and has significant effect on soil water conservation function. Indirect methods, which are called pedotransfer functions (PTFs), have replaced direct measurement and can acquire the missing data of BD during routine soil surveys. In this study, multiple linear regression (MLR) and artificial neuron network (ANN) methods were used to develop PTFs for predicting BD from soil organic carbon (OC), texture and depth in the Three-River Headwater region of Qinghai Province, China. The performances of the developed PTFs were compared with 14 published PTFs using four indexes, the mean error (ME), standard deviation error (SDE), root mean squared error (RMSE) and coefficient of determination (R²). Results showed that the performances of published PTFs developed using exponential regression were better than those developed using linear regression from OC. Alexander (1980)-B, Alexander (1980)-A and Manrique and Jones (1991)-B PTFs, which had good predictions, could be applied for the soils in the study area. The PTFs developed using MLR (MLR-PTFs) and ANN (ANN-PTFs) had better soil BD predictions than most of published PTFs. The ANN-PTFs had better performances than the MLR-PTFs and their performances could be improved when soil texture and depth were added as predictor variables. The idea of developing PTFs or predicting soil BD in the study area could provide reference for other areas and the results could lay foundation for the estimation of soil water retention and carbon pool.     

Predicting Cationic Exchange Capacity in Calcareous Soils of East-Azerbaijan Province,Northwest Iran

The aim of this research is to study the efficiency of pedotransfer functions (PTFs) and artificial neural networks (ANNs) for cationic exchange capacity (CEC) prediction using readily available soil properties. Here, 417 soil samples were collected from the calcareous soils located in East-Azerbaijan province, northwest Iran and readily available soil properties, such as particle size distribution (PSD), organic matter (OM) and calcium carbonate equivalent (CCE), were measured. The entire 417 soil samples were divided into two groups, a training data set (83 soil samples) and test data set (334 soil samples). The performances of several published and derived PTFs and developed neural network algorithms using multilayer perceptron were compared, using a test data set. Results showed that, based on statistics of RMSE and R², PTFs and ANNs had a similar performance, and there was no significant difference in the accuracy of the model results. The result of the sensitivity analysis showed that the ANN models were very sensitive to the clay variable (due to the high variability of the clay). Finally, the models tested in this study could account for 85% of the variations in cationic exchange capacity (CEC) of soils in the studied area.

Abbreviations: ANN: arti?cial neural networks; MLP: multilayer perceptron; MLR: multiple linear regression; PTFs: Pedotransfer Functions; RBF: Radial Basis Function; MAE: mean absolute error; MSE: mean square error; CEC: cationic exchange capacity     

Simple methods for estimating field capacity using Mamdani inference system and regression tree

Using easily measurable soil properties could save time and cost for field capacity (FC) prediction. The objective of this study was to compare Mamdani fuzzy inference system (MFIS) and regression tree (RT) for FC predicting using such properties. One hundred and sixty-five soil samples from Unsaturated Soil hydraulic database data-set and 45 from Hydraulic Properties of European Soils data-set were used for the development and validation of MFIS and RT, respectively. Fuzzy rules and tree diagram based on the relationships between these predictor variables and the response variable FC were defined and 48 rules were written. Results showed a positive linear relevancy in terms of standardized independent variable weight, W*, between clay content and FC and negative linear relevancy between geometric mean particular size diameter (d_g) and FC. Among predictor variables, d_g (W* = 0.81) and bulk density (BD) (W* = 0.49) had the highest and lowest influence on FC, respectively. A tree diagram is presented for the prediction of FC using clay content, dg, and BD. Overall, based on statistical parameters, RT method (R² = 0.78, geometric mean error (GME) = 1.02, mean error (ME) = 0.01 cm³ cm^?3, and root mean square error (RMSE) = 0.04 cm³ cm^?3) showed a higher performance than MFIS method (R² = 0.72, GME = 1.16, ME = 0.08 cm³ cm^?3, and RMSE = 0.06 cm³ cm^?3) to predict FC.     

Soil erodibility and its prediction in semi-arid regions

ABSTRACT

Pedotransfer functions (PTFs) have been used to save time and cost in predicting certain soil properties, such as soil erodibility (K-factor). The main objectives of this study were to develop appropriate PTFs to predict the K-factor, and then compare new PTFs with Universal Soil Loss Equation (USLE) and the Revised Universal Soil Loss Equation (RUSLE) K-factor models. The K-factor was measured using 40 erosion plots under natural rainfall in Simakan Watershed, an area of 350 km² in central of Iran. The Regression Tree (RT) and Multiple Linear Regression (MLR) were used to develop PTFs for predicting the K-factor. The result showed that the mean of measured K was 0.01 t h MJ^?1 mm^?1. The mean K value predicted by USLE and RUSLE was 2.08 and 2.84 times more than the measured K, respectively. Although calcium carbonate was not considered in the original USLE and RUSLE K-factors, it appeared in the advanced PTFs due to its strong positive significant impact on aggregate stability and soil infiltration rate, resulting in decreased K-factor. The results also showed that the RT with R² = 0.84 had higher performance than developed MLR, USLE and RUSLE for the K estimation.     

Selection of a Suitable Soft Computing Model for Estimation of Soil Cation Exchange Capacity

ABSTRACT

Measuring of soil cation exchange capacity (CEC) is difficult and time-consuming. Therefore, it is essential to develop an indirect approach such as pedotransfer functions (PTFs) to predict this property from more readily available soil data. The aim of this study was to compare multiple linear and nonlinear regression, adaptive neurofuzzy inference system, and an artificial neural network (ANN) model to develop PTFs for predicting soil CEC. One hundred and seventy-one soil samples were used into two subsets for training and testing of the models. The model's prediction capability was evaluated by statistical indicators that include RMSE, R², MBE, and RI. Results showed that the ANN model had the most reliable prediction when compared with other models. This study provides a strong basis for predicting soil CEC and identifying the most determinant properties influencing soil CEC in the north regions of Iran. Analytical framework results could be applied to other parts of the world with similar challenges.

Abbreviations: ANFIS: Adaptive Neuro-Fuzzy Inference System; ANN: Artificial Neural Network; CEC: Cation Exchange Capacity; CV: Coefficient of Variation; FFBP: Feed-Forward Back-Propagation; FIS: Fuzzy Inference System; MBE: Mean Bias Error; MF: Membership Function; MLR: Multiple Linear Regressions; MNLR: Multiple Non-Linear Regressions; MLP: Multi-layer Perceptron; OC: Organic Carbon; PTFs: Pedotransfer Functions; R²: Determination Coefficient; RI: Relative Improvement; RMSE: Root Mean Square Error; SD: Standard Deviation     

Using support vector machines to predict cation exchange capacity of different soil horizons in Qingdao City,China

Agricultural, environmental and ecological modeling requires soil cation exchange capacity (CEC) that is difficult to measure. Pedotransfer functions (PTFs) are thus routinely applied to predict CEC from easily measured physicochemical properties (e.g., texture, soil organic matter, pH). This study developed the support vector machines (SVM)‐based PTFs to predict soil CEC based on 208 soil samples collected from A and B horizons in Qingdao City, Shandong Province, China. The database was randomly split into calibration and validation datasets in proportions of 3:1 using the bootstrap method. The optimal SVM parameters were searched by applying the genetic algorithm (GA). The performance of SVM models was compared to those of multiple stepwise regression (MSR) and artificial neural network (ANN) models. Results show that the accuracy of CEC predicted by SVM improves considerably over those predicted by MSR and ANN. The performance of SVM for B horizon (R² = 0.85) is slightly better than that for A horizon (R² = 0.81). The SVM is a powerful approach in the simulation of nonlinear relationship between CEC and physicochemical properties of widely distributed samples from different soil horizons. Sensitivity analysis was also conducted to explore the influence of each input parameter on the CEC predictions by SVM. The clay content is the most sensitive parameter, followed by soil organic matter and pH, while sand content has the weakest influence. This suggests that clay is the most important predictor for predicting CEC of both soil horizons.     

利用土壤传递函数估算土壤水力学特性研究进展

Characterization of soil hydraulic properties is important to environment management; however, it is well recognized that it is laborious, time-consuming and expensive to directly measure soil hydraulic properties. This paper reviews the development of pedotransfer functions (PTFs) used as an alternative tool to estimate soil hydraulic properties during the last two decades. Modern soil survey techniques like satellite imagery/remote sensing has been used in developing PTFs. Compared to mechanistic approaches, empirical relationships between physical properties and hydraulic properties have received wide preference for predicting soil hydraulic properties. Many PTFs based on different parametric functions can be found in the literature. A number of researchers have pursued a universal function that can describe water retention characteristics of all types of soils, but no single function can be termed generic though van Genuchten (VG) function has been the most widely adopted. Most of the reported parametric PTFs focus on estimation of VG parameters to obtain water retention curve (WRC). A number of physical, morphological and chemical properties have been used as predictor variables in PTFs. Conventionally, regression algorithms/techniques (statistical/neural regression) have been used for calibrating PTFs. However, there are reports of utilizing data mining techniques, e.g., pattern recognition and genetic algorithm. It is inferred that it is critical to refine the data used for calibration to improve the accuracy and reliability of the PTFs. Many statistical indices, including root mean square error (RMSE), index of agreement (d), maximum absolute error (ME), mean absolute error (MAE), coefficient of determination (r²) and correlation coefficient (r), have been used by different researchers to evaluate and validate PTFs. It is argued that being location specific, research interest in PTFs will continue till generic PTFs are developed and validated. In future studies, improved methods will be required to extract information from the existing database.     

Estimating the bulk density in 0– 20 cm of tilled soils in China’s Loess Plateau using support vector machine modeling

ABSTRACT

Pedotransfer functions (PTFs), as an indirect forecasting method, offer an alternative for labor-intensive bulk density (BD) measurements. In order to improve the forecasting accuracies, support vector machine (SVM) method was first used to develop PTFs for predicting BD. Cross-validation and grid-search methods were used to automatically determine the SVM parameters in the forecasting process. Soil texture and organic matter content were selected as input variables based on results of predecessors, coupled with gray correlation theory. And additional properties were added as inputs for improving PTF's accuracy and reliability. The performance of the PTF established by SVM method was compared with artificial neural network (ANN) method and published PTFs using two indexes: root-mean-square error (RMSE) and coefficient of determination(R²). Results showed that the average RMSE of published PTFs was 0.1053, and the R² was 0.4558. The RMSE of ANN–PTF was 0.0638, and the R² was 0.7235. The RMSE of SVM–PTF was 0.0558, and the R² was 0.7658. Apparently, the SVM–PTF had better performance, followed by ANN–PTF. Additionally, performances could be improved when accumulated receiving water was added as predictor variable. Therefore, the first application of SVM data mining techniques in the prediction of soil BD was successful, improved the accuracy of predictions, and enhanced the function of soil PTFs. The idea of developing PTFs using SVM method for predicting soil BD in the study area could provide a reference for other areas.     

Charge characteristics and exchangeable cation status of Korean Ultisols and Alfisols and Thai Ultisols and Oxisols

The charge characteristics of A₁ or Ap and B₂ horizon samples of total 23 Ultisols, Alfisols and Oxisols in Korea and Thailand were studied by measuring the retention of NH₄⁺ and NO₃^? at different pH values (4–8) and NH₄NO₃ concentrations (0.1–0.005 m ). The magnitude of their negative charge (σ^?; meq/100g) was dependent on pH and NH₄NO₃ concentration (C; m ) as represented by a regression equation: log σ^?=apH +blogC +c. The values of the coefficient a (0.04–0.226), b (0.03–0.264) and c (–0.676–1.262) were correlated with the kinds of the soil and horizon and with the region where the soil exists. The retention of NO₃^? was less than 1 and 2–3 meq/100 g for the A₁ or Ap and B₂ horizon samples, respectively. The sum of exchangeable base and Al (‘effective’ CEC) was close to and higher than the magnitude of permanent charge (=σ^? measured at pH = 4.3 and at C = 0.005 m ) for one-third and two-thirds of samples, respectively. A σ^? value of 16 meq/100 g clay at pH = 7 and C = 0.01 m was found appropriate to separate the B₂ horizons of Thai Ultisols and Oxisols from those of Korean Ultisols and Alfisols. Korean Alfisols and Ultisols and Thai Ultisols were distinguished from each other on the status of exchangeable base and Al     

Development of ensemble pedotransfer functions for cation exchange capacity of soils of Qingdao in China

Soil cation exchange capacity (CEC), which is considered to be an indicator of buffering capacity, is an important soil attribute that influences soil fertility but is costly, time‐consuming and labour‐intensive to measure. Pedotransfer functions (PTFs) have routinely been used to predict soil CEC from easily measured soil properties, such as soil pH, texture and organic matter content. However, uncertainty in which one to select can be substantial as different PTFs do not necessarily produce the same result. In this study, a total of 100 soil samples were collected from surface horizons (0–20 cm) in different regions of Qingdao City, China. Three ensemble PTFs (ePTFs), including simple ensemble mean (SEM), individually bias‐removed ensemble mean (IBREM) and collective bias‐removed ensemble mean (CBREM), were developed to reduce the uncertainty in CEC prediction based on 12 published regression‐based PTFs. In addition, a local PTF (LPTF) for CEC was also developed using multiple stepwise regression and basic soil properties. The performances of the three ePTFs were compared with those of the published PTFs and LPTF. Results show that the differences between the performances of the published PTFs were substantial. When the systematic bias of each published PTF was removed separately, the prediction capability of the PTFs was increased. The performance of LPTF was significantly better than that of SEM, but slightly worse than IBREM. It is noted that CBREM had higher accuracy than all of the other methods. Overall, CBREM is a promising approach for estimating soil CEC in the study area.     

Neural network models to predict cation exchange capacity in arid regions of Iran

Design and analysis of land‐use management scenarios requires detailed soil data. When such data are needed on a large scale, pedotransfer functions (PTFs) could be used to estimate different soil properties. Because existing regression‐based PTFs for estimating cation exchange capacity (CEC) do not, in general, apply well to arid areas, this study was conducted (i) to evaluate the existing models and (ii) to develop neural network‐based PTFs for predicting CEC in Aridisols of Isfahan in central Iran. As most researches have found a significant correlation between CEC and soil organic matter content (OM) and clay content, we also used these two variables for modelling of CEC. We tested several published PTFs and developed two neural network algorithms using multilayer perceptron and general regression neural networks based on a set of 170 soil samples. The data set was divided into two subsets for calibration and testing of the models. In general, the neural network‐based models provided more reliable predictions than the regression‐based PTFs.     

不同施肥措施对洞庭湖区旱地肥力及作物产量的影响

应用长期定位试验方法,研究了洞庭湖区非粮食作物棉花-油菜轮作下,农民习惯施肥(TF)、配方施肥(NPK)及有机肥和化肥不同配比模式[有机肥来源氮占配方肥总氮量的50%(50%OM)、30%(30%OM)和10%(10%OM)]的作物产量和土壤养分的变化,以期为相应作物种植制度下的合理施肥提供参考。研究结果表明:在本试验施肥量及有机无机肥配比下,有机肥和化肥配施显著提高了棉花和油菜的产量,且以50%OM处理产量最高,各处理产量的顺序为50%OM30%OM10%OMNPKTFCK(不施肥对照);当有机氮施用量占总氮量的50%时(50%OM处理),棉花和油菜产量分别比NPK处理高24.52%、29.57%,比习惯施肥(TF)处理分别高46.03%和49.07%。同时,施用有机肥各处理作物产量的年际变化均不到20%,明显小于NPK、TF和CK处理,即施用有机肥不仅能促进旱地作物高产,同时也能保证其稳产。有机肥与化肥配施能增加土壤有机质、全氮、碱解氮和速效钾含量,且以50%OM处理效果最好,与试验前比较的增加幅度分别达57.5%、38.2%、65.1%和48.1%;土壤有效磷含量有随施入磷素量的增加而增加趋势;而CK处理土壤有机质和养分含量则均呈逐年下降的趋势。各处理土壤有机质和养分含量(Y)随试验年限(X)的变化均可用方程式Y=a X+b来表示。在洞庭湖区肥力较高的旱地土壤中,合理的有机肥和化肥施用比例对保障非粮作物高产稳产和耕地地力提升尤为重要,且本试验条件下当有机肥来源氮占总施氮量的50%时能获得最佳效果。     

Pedo-transfer functions for estimating the hydraulic properties of paddy soils in subtropical central China

Pedo-transfer functions (PTFs) have been widely used to estimate soil hydraulic properties in the simulation of catchment eco-hydrological processes. However, the accuracy of existing PTFs is usually inadequate for use. To develop PTFs for local use, soil columns were collected from a double rice-cropped agricultural catchment in subtropical central China. The PTFs for saturated soil hydraulic conductivity (K_s) and parameters (θ_s, α, and n) of the van Genuchten model for the soil water retention curve (SWRC) were obtained based on soil’s basic properties, and compared with models developed by Li et al. in 2007 and Wösten et al. in 1999, respectively. Our results indicated that K_s in the range of 0.04–1087 cm d^?1 and θ_s in the range of 0.34–0.51 cm³ cm^?3 were both well estimated with the R²_adj of 0.72 and 0.87, respectively, but α (0.04–0.65 cm^?1) and n (1.05–1.21) were relatively poorly predicted with the respective R²_adj of 0.38 and 0.55, despite the use of more input parameters. Our local derived PTFs outperformed the other two existing models. However, if the local PTFs for paddy soils are not available, the Wösten et al. 1999 model can be proposed as a useful alternative. Therefore, this study can improve our understanding of the development and application of PTFs for predicting paddy soil hydraulic properties in China.     

ELECTRIC CHARGE CHARACTERISTICS OF ANDO A, AND BURIED A, HORIZON SOILS

The electric charge characteristics of four Ando soils (A₁ and μA₁) and a Chernozemic soil (Ap) were studied by measuring retention of NH₄⁺ and Cl^– at different pH values and NH₄Cl concentrations. No positive charge appeared in the Ando soils at pH values 5 to 8.5 except for one containing allophane and imogolite. The magnitude of their negative charge (CEC; meq/l00g soil) was dependent on pH and NH₄Cl concentration (C; N) as represented by a regression equation: log CEC =a pH +b log C +c, where the values of a and b were 0.113–0.342 and 0.101–0.315, respectively. Unlike the Chernozemic soil, Ando soils containing allophane, imogolite, and/or 2:1–2:1:1 layer silicate intergrades and humus showed a marked reduction of cation retention as pH decreased from 7 to 5. This was attributed to the charge characteristics of the clay minerals and to the carboxyl groups in humus being blocked by Al and Fe.     

Pedotransfer functions for estimating plant available water and bulk density in Swedish agricultural soils

Abstract

Pedotransfer functions (PTFs) to estimate plant available water were developed from a database of arable soils in Sweden. The PTFs were developed to fulfil the minimum requirements of any agro-hydrological application, i.e., soil water content at wilting point (θ _wp ) and field capacity (θ _fc ), from information that frequently is available from soil surveys such as texture and soil organic carbon content (SOC). From the same variables we also estimated bulk density (ρ) and porosity (ε), which seldom are included in surveys, but are needed for calculating element mass balances. The seven particle-size classes given in the data set were aggregated in different ways to match information commonly gained from surveys. Analysis of covariance and stepwise multiple linear regression were used for quantifying the influence of depth, particle size class, textural class and soil organic carbon on the characteristic variables. PTFs developed from other data sets were also tested and their goodness-of-fit and bias was evaluated. These functions and those developed for the Swedish database were also tested on an independent data set and finally ranked according to their goodness of fit. Among single independent variables, clay was the best predictor for θ _wp , sand (or the sum of clay and silt) for θ _fc and SOC for ρ and ε. A large fraction of the variation in θ _wp and θ _fc is explained by soil texture and SOC (up to 90%) and root mean square errors (RMSEs) were as small as 0.03 m³ water m^?3 soil in the best models. For the prediction of ρ and ε in the test data set, the best PTF could only explain 40–43% of the total variance with corresponding RMSEs of 0.14 g cm^?3 and 5.3% by volume, respectively. Recently presented PTFs derived from a North American database performed very well for estimating θ _wp (low error and bias) and could be recommended for Swedish soils if measurements of clay, sand and SOC were available. Although somewhat less accurately, also θ _fc could be estimated satisfactorily. This indicates that the determination of plant available water by texture and SOC is rather independent of soil genesis and that certain PTFs are transferable between continents.     

Enhancing pedotransfer functions with environmental data for estimating bulk density and effective cation exchange capacity in a data‐sparse situation

Soil bulk density (BD) and effective cation exchange capacity (ECEC) are among the most important soil properties required for crop growth and environmental management. This study aimed to explore the combination of soil and environmental data in developing pedotransfer functions (PTFs) for BD and ECEC. Multiple linear regression (MLR) and random forest model (RFM) were employed in developing PTFs using three different data sets: soil data (PTF‐1), environmental data (PTF‐2) and the combination of soil and environmental data (PTF‐3). In developing the PTFs, three depth increments were also considered: all depth, topsoil (<0.40 m) and subsoil (>0.40 m). Results showed that PTF‐3 (R²; 0.29–0.69) outperformed both PTF‐1 (R²; 0.11–0.18) and PTF‐2 (R²; 0.22–0.59) in BD estimation. However, for ECEC estimation, PTF‐3 (R²; 0.61–0.86) performed comparably as PTF‐1 (R²; 0.58–0.76) with both PTFs out‐performing PTF‐2 (R²; 0.30–0.71). Also, grouping of data into different soil depth increments improves the estimation of BD with PTFs (especially PTF‐2 and PTF‐3) performing better at subsoils than topsoils. Generally, the most important predictors of BD are sand, silt, elevation, rainfall, temperature for estimation at topsoil while EVI, elevation, temperature and clay are the most important BD predictors in the subsoil. Also, clay, sand, pH, rainfall and SOC are the most important predictors of ECEC in the topsoil while pH, sand, clay, temperature and rainfall are the most important predictors of ECEC in the subsoil. Findings are important for overcoming the challenges of building national soil databases for large‐scale modelling in most data‐sparse countries, especially in the sub‐Saharan Africa (SSA).