Phosphorus Extraction Methods for Water Treatment Residual–Amended Soils

Abstract

Water treatment residuals (WTR) can adsorb tremendous amounts of phosphorus (P). A soil that had biosolids applied eight times over 16 years at a rate of 6.7 Mg ha^?1 y^?1 contained 28 mg kg^?1 ammonium–bicarbonate diethylenetriaminepentaacetic acid (AB‐DTPA), 57 mg kg^?1 Olsen, 95 mg kg^?1 Bray‐1, and 53 mg kg^?1 Mehlich‐III extractable P. To 10 g of soil, WTRs were added at rates of 0, 0.1, 1, 2, 4, 6, 8, and 10 g, then 20 mL of distilled deionized H₂0 (DI) were added and the mixtures were shaken for 1 week, filtered, and analyzed for soluble (ortho‐P) and total soluble P. The soil–WTR mixtures were dried and P extracted using DI, AB‐DTPA, Olsen, Bray‐1, and Mehlich‐III. Results indicated that all methods except AB‐DTPA showed reduced extractable‐P concentrations with increasing WTR. The AB‐DTPA extractable P increased with increasing WTR rate. The water‐extractable method predicted P reduction best, followed by Bray‐1 and Mehlich‐III, and finally Olsen.     

Soil‐Test Methods for Florida Sands Treated with an Aluminum–Water Treatment Residual and Various Phosphorus Sources

Use of aluminum (Al)–rich water treatment residuals (Al‐WTR) has been suggested as a practice to immobilize excessive phosphorus (P) in Florida soils that could represent an environmental hazard. Fertilizer P requirements can differ in WTR‐amended and unamended soil, so careful selection of soil‐testing methodology is necessary. Acidic extractants can dissolve WTR sorbed P and overestimate plant‐available P. We evaluated the suitability of the Mehlich 1 P (M‐1P) and other agronomic soil‐test procedures in an Al‐WTR‐treated Florida soil. Bahiagrass (paspalum notatum Fluggae), ryegrass (Lolium perenne L.), and a second bahiagrass crop were grown in succession in a Florida topsoil amended with four sources of P at 44 kg P ha^?1 (P‐based rates) and 179 kg PAN ha^?1 [nitrogen (N)–based rates] and three WTR rates (0, 10, and 25 g kg^?1 oven‐dry basis). Both water‐extractable P (WEP) and iron (Fe) strip P (ISP), but not M‐1P, values of soil sampled at planting of each grass were greater in the absence than in the presence of WTR. Total plant P uptake correlated with WEP (r² = 0.82^***) and ISP (r² = 0.75^***), but not M‐1P (r² = 0.34^***). Correlations of the dry‐matter yield, P concentration, and P uptake of the first bahiagrass were also better with WEP and ISP than with M‐1P values. However, regression of plant responses with M‐1P improved after the first crop of bahiagrass. Both WEP and ISP values were better predictors of available soil P than M‐1P in a field study with same four P sources surface applied to established bahiagrass at the same two P rates, with and without WTR. Both WEP and ISP are recommended as predictors of P adequacy in soils treated with WTR, especially for soils recently (< 5 months) treated with Al‐WTR.     

Correlation of Mehlich 3, bray 1, and ammonium acetate extractable P,K, Ca,and Mg for Alaska agricultural soils

Abstract

Soil test recommendations currently used in Alaska are based on a limited amount of in‐state data along with consideration of data from other states. Recently, Mehlich 3 extractable P has been found to be highly correlated to yield on representative agricultural soils in Alaska. To fully use its multi‐element capability, a study was conducted to correlate Mehlich 3 extractable P and cations (K, Ca, and Mg) with the P and cations extracted by the Bray 1 and ammonium acetate methods respectively.

When Mehlich 3 extractable K and Mg were regressed with ammonium acetate extractable K and Mg respectively, the relationship was essentially one‐to‐one and the relationship held across all soils tested. Significant variation was observed among soils in the extraction of Mehlich 3‐P and Ca relative to Bray 1‐P and ammonium acetate‐Ca. Individual soil character appeared to affect the regressions for extractable P and Ca, even though the R² values were generally high. The regression slopes for Mehlich 3‐P versus Bray 1‐P ranged from 1.01 to 1.88 with Mehlich 3 extracting an average of 66% more P than Bray 1 in the volcanic ash soils, and 12% more in the loess soils. The regression slopes for Mehlich 3‐Ca versus ammonium acetate‐Ca ranged from 0.95 to 1.33, and the former extracted an average of 17% more Ca than the latter. It is suggested that the regression data of P and Ca can be extrapolated to other soils based on soil classification; to extend the soil test data over a geographic base.     

Development of a New Soil Extractant for Simultaneous Phosphorus,Ammonium, and Nitrate Analysis

Abstract

A new soil extractant (H³A) with the ability to extract NH₄, NO₃, and P from soil was developed and tested against 32 soils, which varied greatly in clay content, organic carbon (C), and soil pH. The extractant (H³A) eliminates the need for separate phosphorus (P) extractants for acid and calcareous soils and maintains the extract pH, on average, within one unit of the soil pH. The extractant is composed of organic root exudates, lithium citrate, and two synthetic chelators (DTPA, EDTA). The new soil extractant was tested against Mehlich 3, Olsen, and water for extractable P, and 1 M KCl and water‐extractable NH₄ and NO₂/NO₃. The pH of the extractant after adding soil, shaking, and filtration was measured for each soil sample (5 extractants×2 reps×32 soils=320 samples) and was shown to be highly influential on extractable P but has no effect on extractable NH₄ or NO₂/NO₃. H³A was highly correlated with soil‐extractable inorganic N (NH₄, NO₂/NO₃) from both water (r=0.98) and 1 M KCl (r=0.97), as well as being significantly correlated with water (r=0.71), Mehlich 3 (r=0.83), and Olsen (r=0.84) for extractable P.     

Integration of Soil pH with Soil‐Test Values of Zinc for Prediction of Yield Response in Rice Grown in Mollisols

Seventeen Mollisols having pH_(1:2) in the range of 6.00 to 8.42 were analyzed with five extractants, and the extractable zinc (Zn) ranges were 0.84 to 2.75 mg Zn kg^?1 soil for diethylenetriaminepentaacetic acid (DTPA) (pH 7.3), 0.91 to 2.72 mg Zn kg^?1 soil for DTPA + ammonium bicarbonate (pH 7.6), 1.82 to 7.18 mg Zn kg^?1 soil for Mehlich 3, 1.22 to 3.83 mg Zn kg^?1 soil for ethylenediaminetetraacetic acid (EDTA) + ammonium carbonate, and 0.88 to 1.18 mg Zn kg^?1 soil for 1 mol L^?1 magnesium chloride (MgCl₂) (pH 6.0). Zinc extracted by DTPA (pH 7.3) and Mehlich 3 showed significant positive correlation with sand content, whereas only Mehlich 3 showed negative correlation with soil pH. All extractants showed significant positive correlation with each other except for 1 mol L^?1 MgCl₂‐extractable Zn, which had significant positive correlation with only Mehlich 3– and EDTA + ammonium carbonate–extractable Zn. A greenhouse experiment showed that Bray's percentage yield of rice was poorly correlated to extractable soil Zn but had a significant and negative linear correlation with soil pH (r = ?0.662, significant at p = 0.01). Total Zn uptake by rice had a significant positive correlation with 1 mol L^?1 MgCl₂– and Mehlich 3–extractable Zn. A proposed parameter (p extractable Zn + p OH^?) involving both soil extractable Zn and pH terms together showed significant and positive correlation with Bray's percentage yield and total Zn uptake of rice. The calculated values of critical limits of soil Zn in terms of the proposed parameter were 14.1699 for DTPA (pH 7.3), 13.9587 for DTPA + ammonium bicarbonate, 13.7016 for Mehlich 3, 13.9402 for EDTA + ammonium carbonate, and 14.1810 for 1 mol L^?1 MgCl₂ (pH 6.0). The critical limits of Zn in rice grain and straw were 17.32 and 22.95 mg Zn kg^?1 plant tissue, respectively.     

Lowland Rice Response to Thermophosphate Fertilization

Abstract

Use of adequate rates of phosphorus (P) in crop production on high‐P‐fixing acid soils is essential because of high crop response to P fertilization and the high cost of P fertilizers. Information on lowland rice response to thermophosphate fertilization grown on Inceptisols is limited, and data are also lacking for soil‐test‐based P fertilization recommendations for this crop. The objective of this study was to evaluate response of lowland rice to added thermophosphate and to calibrate P soil testing for making P fertilizer recommendations. A field experiment was conducted for two consecutive years in central Brazil on a Haplaquept Inceptisol. The broadcast P rates used were 0, 131, 262, 393, 524, and 655 kg P ha^?1, applied as thermophosphate Yoorin. Rice yield and yield components were significantly increased with the application of P fertilizer. Average maximum grain yield was obtained with the application of 509 kg P ha^?1. Uptake of macro‐ and micronutrients had significant quadratic responses with increasing P rates. Application of thermophosphate significantly decreased soil acidity and created favorable macro‐ and micronutrient environment for lowland rice growth. Across 2 years, soil‐test levels of Mehlich 1–extractable P were categorized, based on relative grain yield, as very low (0–17 mg P kg^?1 soil), low (17–32 mg P kg^?1 soil), medium (32–45 mg P kg^?1 soil), or high (>45 mg P kg^?1 soil). Similarly, soil‐test levels of Bray 1–extractable P across 2 years were very low (0–17 mg P kg^?1 soil), low (17–28 mg P kg^?1 soil), medium (28–35 mg P kg^?1 soil), or high (>35 mg P kg^?1 soil). Soil P availability indices for Mehlich 1 extractant were slightly higher at higher P rates. However, both the extracting solutions had highly significant association with grain yield.     

Appraisal of Some Soil Tests for Zinc Availability to Late‐Sown Wheat Grown in Mollisols

Abstract

Five soil extractants, namely, 0.005 M diethylene triamine pentaacetic acid (DTPA) (pH 7.3), 0.005 M DTPA+1 M ammonium bicarbonate (pH 7.6), Mehlich 3, 0.01 M ethylene diamine tetraacetic acid (EDTA)+0.05 M ammonium carbonate (pH 8.6), and 1 M magnesium chloride (MgCl₂) (pH 6.0), were evaluated to predict the response of wheat to zinc (Zn) application in Mollisols. These extractants could be arranged in the following decreasing order of their Zn extracting power: Mehlich 3>0.005 M DTPA+1 M ammonium bicarbonate>0.01 M EDTA+0.05 M ammonium carbonate>0.005 M DTPA>1 M MgCl₂. The critical limits of Zn in soil, below which the yield response to late sown wheat (var. UP‐2338) to Zn application could be expected, were 0.57 mg 0.005 M DTPA (pH 7.3) extractable and 1.72 mg Mehlich 3–extractable Zn kg^?1 soil. The critical limit of Zn in whole shoot at 60 days after emergence was found to be 26.1 mg Zn kg^?1 plant tissue. The DTPA and Mehlich 3–extractable soil Zn also correlated significantly and positively with Zn concentration in whole shoot at 60 days after emergence and total Zn uptake by wheat at harvest.     

Divergent Relationships of Phosphorus Soil Tests in Temperate Grassland Soils

Abstract

Various soil tests are used to estimate phosphorus (P) availability for both crop uptake and potential loss to water. Conversion equations may provide a basis for comparison between different tests and regions, although the extent to which information can be interchanged is uncertain. The objective was to determine and quantify relationships between specific soil test extractants for samples taken annually in October and February over 4 years from four sites in each of eight soil series under grassland. The extractants comprised Mehlich‐3, Morgan, Olsen, Bray‐1, lactate–acetate, CaCl₂ (1∶2 and 1∶10 soil–solution ratios), and resin. The results showed distinct relationships for each soil series, for which individual lines regression models (different intercepts and slopes) were superior to a single conversion equation across all soils. The ensuing difference between soils was large and ranged from 1.9 to 8.0 and 9.2 to 15.6 mg kg^?1 P for Morgan and Olsen, respectively, at 20 mg kg^?1 Mehlich‐3 P. Generally, the environmentally oriented tests CaCl₂ and resin correlated best with Morgan. Some soil‐specific limitations were also observed. CaCl₂ was less efficient than Morgan, and Morgan less efficient than Mehlich‐3 on a high Fe–P soil derived from Ordovician‐shale diamicton, compared with the general trend for other soils. This finding suggests that further disparity may arise where evaluation of critical, or other, limits across regions involves even a limited sequence of tests.     

Bioavailability of Inorganic Phosphorus Fractions in Calcareous Soils Estimated by Neubauer Technique,Iron‐Impregnated Filter Paper,and Chemical Tests

Abstract

Plants commonly suffer from phosphorus (P) deficiency in calcareous soils. Plant responses to P application on such soils mostly show poor correlation with their soil test P values. Experiments were conducted on 24 different soil samples under laboratory and greenhouse conditions to illustrate the relationship of various inorganic P fractions in different calcareous soils with P uptake by plants, P extraction by iron‐impregnated filter paper, and P soil test values estimated by 0.5M NaHCO₃ and ammonium bicarbonate diethylene triamine penta‐acetic acid. Total P in the 24 soils ranged from 652 to 1245 mgkg^?1 with a mean of 922 mgkg^?1. A major proportion (98%) of inorganic P was in HCl‐P (Ca‐bound) form. The HCl‐P (Ca‐bound) ranged from 296 to 729 with a mean of 480 mgkg^?1. The iron (Fe) and aluminum (Al)‐P (NaOH‐P) ranged from 0.92 to 12 mgkg^?1 with a mean of 1.57 mgkg^?1. The Fe‐P (citrate‐dithionite bicarbonate) ranged from 0.22 to 4.40 mgkg^?1 with a mean of 5.99 mgkg^?1. Data regarding P release from the soil matrix obtained by desorption with iron‐impregnated filter paper was best described by the Elovich equation. Range of slope and intercept values were found to be 5.48 to 17.3 and 17.23 to 56.27 mgkg^?1, respectively. Intercept values calculated for the Elovich equation may be related to labile P initially available for plant uptake in soils. Intercept values calculated for the Elovich equation correlated (r=0.77) significantly (p<0.01) with NaHCO₃ extractable (Olsen‐P)P. Significant correlation (p<0.05) of intercept with CDB‐P (r=0.44) and of slope with HCl‐P (0.43) suggested that the initially available P, regulated through CDB‐P, is replenished by HCl‐P [calcium (Ca) bound].     

Correlation of Soil pH and Mehlich‐3 Phosphorus with Postflood Rice Phosphorus Concentrations in Arkansas

Abstract

Plant‐available phosphorus (P) measured by routine soil‐test methods is poorly correlated with rice grain yield in Arkansas. Our objective was to determine whether soil water pH (pH_w) and Mehlich‐3 P were correlated with growth and yield of rice grown on silt loam soils. Data from 35 field studies were used to correlate Mehlich‐3 P and pH_w with relative yield, dry matter accumulation, and P concentration at the midtillering stage. Significant linear or nonlinear relationships between pH_w or Mehlich‐3 P with rice growth parameters were delineated but explained less than 27% of the variability in dry matter and P concentrations at the midtillering stage and grain yield at maturity. Mehlich‐3 P and pH_w together explained 61% of the variability in midtillering P concentrations. Midtillering whole‐plant P concentrations were positively related to relative grain yield and dry matter production and will be used to identify soils with limited P availability for rice in Arkansas.     

Changes in Soil Test Phosphorus from Broiler Litter Additions

Abstract

Nutrient surpluses on the Delmarva Peninsula have led to a continual accumulation of soil test phosphorus (STP), a potential source for transport of phosphorus (P) to surface waters. This article examines the effects of initial soil test P concentrations and broiler litter additions on STP accumulation. Broiler litter (BL) was applied at rates of 0, 2.5, 5, 7.5, and 10 g kg^?1 (dry weight) to three soils: an Evesboro sandy loam (Mesic, coated Typic Quartzipsamments), a Pocomoke sandy loam (coarse‐loamy, siliceous, thermic typic Umbraquults), and a Matapeake silt loam (fine‐silty, mixed, semiactive, mesic Typic Hapludults). Soils and BL were incubated for 16 weeks with subsamples analyzed after 4 and 16 weeks. There was a linear increase in STP (Mehlich‐3), water‐soluble P (WS‐P), iron‐oxide strip‐extractable P (FeO‐P), and Mehlich‐3 phosphorus saturation ratio (M3‐PSR) with broiler litter additions. Regression analysis indicated few significant differences in STP response to added BL between soils within the same soil group having different initial STP levels. Correlation analysis and stepwise regression indicated that increases in WS‐P and FeO‐P from added BL were more closely related to the degree of P saturation of the soil rather than traditional STP measurements. Therefore, decisions regarding manure placement within a watershed should be based on the potential P sorption capacity of the soil as well as potential P transport pathways when the goal is the reduction of P transfer to waterbodies.     

Comparison of Iron Oxide–Impregnated Paper Strips with Other Extractants in Determining Available Soil Phosphorus

Abstract

Iron oxide–coated strips (P_i) can serve as a sink to continuously remove phosphorus (P) from solution. In this way, P extraction is analogous to the P absorption by plant roots. The objective of this study was to compare the iron oxide–coated paper strips with other chemical extraction methods to estimate the plant P availability for corn (Zea mays) growing in the greenhouse in some soils of Hamadan province of Iran. Sixteen soil samples with different physicochemical properties were analyzed for available P using Olsen, Colwell, Mehlich‐1, 0.01 M CaCl₂, AB‐DTPA, and 0.1 M HCl methods and p_i. Furthermore, the effects of two P levels (0 and 200 mg P kg^?1) on the plant indices (P uptake, relative yield, and plant responses) were studied in a greenhouse experiment using 10 soil samples. The results showed that the amount of extractable P decreased in the order of 0.01 M CaCl₂<AB‐DTPA<p_i<Olsen<Colwell<Mehlich‐1<0.1 M HCl. The amount of P extracted by the p_i method was significantly correlated with other extractants. The amounts of P extracted by all chemical methods were significantly correlated. The results of a pot experiment showed that the amount of P extracted by the p_i method was significantly correlated with the plant P uptake. However, the other methods were not significantly correlated with P uptake. The results of this experiment showed that p_i method was able to predict the plant availability of soil P.     

Relationship between Soil Phosphorus Availability and Phosphorus Loss Potential in Runoff and Drainage

Abstract

Elevated soil phosphorus (P) content is common in the central coastal valleys of California, the result of decades of the intensive vegetable production. Undesirably high P concentration in surface water in this region stimulated interest in evaluating techniques to rank the potential for soil P loss to the environment. Phosphorus availability of 25 representative soils from fields in vegetable rotations were evaluated by the following techniques: bicarbonate‐extractable P (P_bc)–calcium chloride, extractable P (P_cc), P extractable by iron‐impregnated paper (P_Fe), P extractable by anion exchange resin (P_ae), and the degree of P saturation (P_sat). A column study was conducted in which these soils were evaluated for soluble P concentration in runoff and leachate from two simulated irrigation events. There were strong correlations among all measures of soil P availability (r=0.66–0.90). Runoff soluble P was most strongly correlated with P_cc, P_ae, and P_bc (r=0.98, 0.93, and 0.91, or 0.98, 0.90, and 0.85 in the first and second irrigation, respectively). The relationship of runoff soluble P to P_bc, P_ae, and P_cc was characterized by a change point; runoff soluble P from soils <50 mg kg^?1 P_bc was minimal, whereas at higher P_bc runoff P reached levels of environmental concern. Leachate soluble P was also correlated with P_cc, P_ae, and P_bc (r=0.84–0.99). Across soils, leachate soluble P averaged 1.4 mg L^?1, compared to 0.11 mg L^?1 for runoff P. We conclude that P_cc, P_ae, and P_bc are useful tests to rank the potential for P loss in irrigation runoff or drainage. Given the relative complexity of the P_ae technique, P_bc and P_cc appear to be the most practical soil tests for this purpose.     

Comparison of mehlich 3, mehlich 1, ammonium bicarbonate‐DTPA, 1.0M ammonium acetate,and 0.2M ammonium chloride for extraction of calcium,magnesium, phosphorus,and potassium for a wide range of soils

Abstract

Extractants employed for routine soil analysis vary from one laboratory to another. Lack of a universal soil extractant is a serious limitation for interpretation of analytical results from various laboratories on nutritional status of a given soil. This limitation can be overcome by developing functional relationships for concentrations of a given nutrient extractable by various extradants. In this study, extractability of Ca, Mg, P, and K in a wide range of soils (0–15 cm) from citrus groves in Florida representing 21 soil series, with varying cultural operations, were compared using Mehlich 3 (M3), Mehlich 1 (M1), ammonium acetate (NH₄AOc), pH = 7.0 (AA), 0.2M ammonium chloride (NH₄Cl), and ammonium bicarbonate‐DTPA (AB‐DTPA) extractants. Soil pH (0.01M CaCl₂) varied from 3.57 to 7.28. The concentrations of Ca or Mg extractable by M3, M1, AA, and NH₄Cl were strongly correlated with soil pH (r² = 0.381–0.482). Weak but significant correlations were also found between AB‐DTPA extractable Ca or Mg and soil pH (r² = 0.235–0.278). Soil pH relationships with extractable K were rather weak (r² = < 0.131) for M1 and NH₄Cl but non‐significant for M3, AB‐DTPA, and AA. Concentrations of Ca, Mg, and K extractable by M3 were significantly correlated with those by either M1, AA, or NH₄Cl extractants. Mehlich 3‐P was significantly correlated with P extractable by M1 extractant only. Mehlich 3 versus AB‐DTPA relationship was strong for K (r² = 0.964), weaker for Mg and P (r² = 0.180–0.319), and non‐significant for Ca. With the increasing emphasis on possible use of M3 as an universal soil extractant, data from this study support the hypothesis that M3 can be adapted as a suitable extractant for routine soil analysis.     

Predicting Maize Yield,Nutrient Concentration,and Uptake in Phosphorus- and Potassium-Fertilized Soils: Pressurized Hot Water and Other Alternatives to Mehlich I Extraction in Guatemala Soils

Abstract

Poor accessibility and cost of soil testing reduce effectiveness of fertilizer use on small‐scale subsistence farms, and inadequate funding promotes adoption of soil tests in developing countries with minimal validation. For example, Mehlich I extraction of phosphorus (P) currently used extensively in Guatemala may not be suitable for Guatemala's broad range of soils. At least four alternatives are available but relatively untested [Bray 1, Mehlich III, Olsen, and pressurized hot water (PHW)]. Pressurized hot water is relatively simple and inexpensive but is not yet tested against other extraction methods under variable P or potassium (K) fertilization levels. To determine whether PHW‐extracted nutrients could be used to predict maize yield and nutrient concentration and uptake, soil, plant tissue and grain samples were obtained from a multiple‐site field study, and calibration studies were conducted using five rates of P and three rates of K on soils incubated without plants or cropped with maize in greenhouse and field conditions. In the multiple‐site field study, maize yield related significantly to PHW‐extractable P (r²=0.36) and to leaf P concentration (r²=0.23), but Mehlich I–extractable P did not. In the two soils used in the greenhouse study, maize yield, vegetative P concentration, and total P uptake by maize were predicted by PHW‐extractable P (R²=0.72, 0.75, and 0.90, respectively). In the field experiment, grain yield was not improved by P or K application, but P concentration of maize leaf tissue did relate significantly with PHW‐extracted P (R²=0.40). Mehlich I did not. There were no yield responses to K application in any experiment, but relationships defined between extractable K for all five K‐extraction procedures and soil‐applied K were similarly significant. In comparison, PHW was as good as or better than Olsen whereas Bray 1 and Mehlich III were less consistent. Mehlich I was overall the poorest P extractant. Mehlich I extraction of P should be replaced by one of the four alternatives tested. PHW is the least expensive and, therefore, most viable for use in Guatemala soils.     

Predicting Plant Phosphorus Requirements for Hawaii Soils using a Combination of Phosphorus Sorption Isotherms and Chemical Extraction Methods

Phosphorus (P) is an essential nutrient for plant growth and reproduction. One of the tasks of soil testing is to identify whether the soil P level is sufficient to meet crop requirements, and if not, to provide an estimate of the quantity of P that must be added for good growth of a given crop. Data for 12 soils (11 series) from Hawaii were used to develop correlations between critical P concentrations in soil solution derived from P sorption isotherms with P extracted with Mehlich 3, Olsen, or modified Truog solutions. Extractable P, in turn, was correlated with P fertilizer requirements. Critical P levels in soil solution reported in the literature for various crops ranged from 0.005 mg L^?1 for cassava (Manihot esculenta) to 0.30 for lettuce (Lactuca sativa) and to 1.6 for nonmycorrhizal onions (Allium cepa). The P buffer coefficient, defined as the ratio of fertilizer P added to extractable P, averaged 2.2, 4.2, and 8.6 for the modified Truog, Olsen, and Mehlich 3, respectively. Phosphorus requirements for certain crops could be estimated by the following steps: (i) obtaining (possibly one time only) soil solution P levels via P sorption isotherm for a given soil (series or family), (ii) identifying the critical soil solution P for a given crop from the literature, (iii) regressing soil solution P against extractable P, and (iv) establishing relationships between extractable P and fertilizer P.     

Effect of Application of Chromium Feedstock Compost on the Growth and Bioavailability of Some Trace Elements in Lettuce

A pot experiment was conducted to investigate the effect of chromium compost (0, 10, 30, and 50%) on the growth and the concentrations of some trace elements in lettuce (Lactuca sativa L.) and in the amended soils. Compost addition to the soil (up to 30%) increased dry matter yield (DMY); more than 30% decreased DMY slightly. The application of compost increased soil pH; nitric acid (HNO₃)–extractable copper (Cu), chromium (Cr), lead (Pb), and zinc (Zn); and diethylenetriaminepentaacetic acid (DTPA)–, Mehlich 3 (M3)–, and ammonium acetate (AAc)–extractable soil Cr and Zn. The addition of Cr compost to the soil increased tissue Cr and Zn but did not alter tissue cadmium (Cd), Cu, iron (Fe), manganese (Mn), nickel (Ni), and Pb. The Cr content in the lettuce tissue reached 5.6 mg kg^?1 in the 50% compost (326 mg kg^?1) treatment, which is less than the toxic level in plants. Our results imply that compost with high Cr could be used safely as a soil conditioner to agricultural crops.     

Use of NH4 HCO3‐DTPA soil test to assess availability and toxicity of selenium to alfalfa plants

Abstract

This study was carried out to determine if ammonium bicarbonate‐DTPA soil test (AB‐DTPA) of Soltanpour and Schwab for simultaneous extraction of P, K, Zn, Fe, Cu and Mn can be used to determine the availability index for Se. Five Mollisols from North Dakota were treated with sodium selenate and were subjected to several wetting and drying cycles. These soils were extracted with hot water and with ammonium bicarbonate‐DTPA (AB‐DTPA) solution for Se analysis. Alfalfa plants were grown in these soils in a growth chamber to determine plant uptake of Se. In addition to the above experiment, coal mine soil and overburden materials from Western Colorado were extracted and analyzed as mentioned above.

It was found that hot water and AB‐DTPA extracted approximately equal amounts of Se from Mollisols. A high degree of correlation (r =0.96) was found between Se uptake by plants and AB‐DTPA extractable Se. Extractable level of Se in treated soils was decreased with time due to change of selenate to less soluble Se forms and plant uptake of Se. An AB‐DTPA extractable Se level of over 100 ppb produced alfalfa plants containing 5 ppm or higher levels of Se that can be considered toxic to animals. Soils with about 2000 ppb of extractable Se were highly toxic to alfalfa plants and resulted in plant concentrations of over 1000 ppm of Se. The high rate of selenate (4ppm Se) was less toxic to alfalfa plants in soils of high organic matter content. This lower toxicity was accompanied with lower extractable levels of Se.

The AB‐DTPA solution extracted on the average about 31% more Se than hot water from the mine and overburden samples and was highly correlated with the latter (r =0.92). The results indicated the presence of bicarbonate‐exchangeable Se in these materials.     

Effect of Grinding on Soil Extraction by Aqua Regia, 2 M Nitric Acid,and Mehlich 3

Abstract

The effect of grinding on soil extraction was determined for two soil fractions and three extractants. Arsenic (As), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), vanadium (V), and zinc (Zn) were extracted by aqua regia and 2 M nitric acid. Mehlich 3 extractant was used for determination of potassium (K), magnesium (Mg), calcium (Ca), phosphorus (P), iron (Fe), and aluminum (Al). One hundred forty‐seven agricultural soil samples representing all major soil types, climatic regions, and proportions of agronomic cultures in the Czech Republic were collected for the study. Particle size fractions smaller than 2 mm and smaller than 0.150 mm were chosen for investigation. Extraction of elements by aqua regia was similar for both size fractions of soil. Cold 2 M nitric acid is a weaker extractant than aqua regia, and a statistically significant increase in extractable Be (5%), Cd (6%), Co (11%), Cu (5%), Ni (5%), and V (2%) was measured with the finely ground soils. An increase for the finer fraction for K (10%) and Mn (25%) was found for Mehlich 3. A more complex nonlinear relationship was found for Mehlich 3 extractable Al and Fe. This was probably caused by a more intensive re‐adsorption of Fe and Al to the finely ground soils.     

Comparison of Multi-element to Single‐Element Extractants for Macro‐ and Micronutrients in Acid Soils from Spain

Abstract

Different chemical reagents are used to assess plant‐available nutrients from soils with similar properties. The use of different extractants is a serious limitation when comparing results between different soil‐testing laboratories, often leading to large differences in fertilizer recommendations for similar crops.

In this study, 80 samples from acid soils from Galicia (Spain) were used to compare several soil nutrient extractants. Traditional and tested extractants for acid soil such as Bray 2 and ammonium acetate were used to evaluate multielement extractants such as ethylenediaminetetraacetic acid–ammonium acetate (EDTA‐aa), ammonium bicarbonate–diethylenetriaminepentaacetic acid (AB‐DTPA), and Mehlich 3.

Linear regression analyses were performed to relate the amount of each nutrient obtained by traditional soil extractants to the amount obtained by multielement extractants. Strong correlation was found between extractable Bray 2 P and Mehlich 3 P (r²=0.97, slope=0.87, and intercept=?0.48). The slope of the regression line between EDTA‐aa‐extractable calcium (Ca) and that from ammonium acetate (Aa) approached 1∶1 (r²=0.86). Similar results were obtained for magnesium (Mg) (r²=0.99). Soil zinc (Zn) concentrations extracted by Mehlich 3 and EDTA‐aa were similar; slope of the regression line was 0.95 (r²=0.88). With regard to copper (Cu), Mehlich 3 extracted approximately 20% more Cu than EDTA‐aa.

The results showed that Mehlich 3 and EDTA‐aa are suitable for assessment of plant available phosphorus (P), potassium (K), Ca, Mg, Cu, Zn, and iron (Fe) in acid soils.