Use of reflectometry for determination of nitrate‐nitrogen in well water

Recurrent monitoring of water wells is necessary to ensure that nitrate‐nitrogen (NO3‐N) concentrations in groundwater do not exceed 10 mg/L, the maximum contaminant level set by the U.S. Environmental Protection Agency. Continuous chemical analysis is often a time consuming and expensive process. A recently developed ‘Reflectoquant Analysis System’, which employs reflectometry techniques, may offer a simple and accurate method for NO3‐N analysis. The objective of this study was to evaluate the ‘Reflectoquant Analysis System’ as an alternative method for determination of NO3‐N in well water. Water samples were collected from 42 wells in Oklahoma. The samples were analyzed using the ‘Reflectoquant Analysis System’, automated cadmium reduction (Griess‐Ilosvay), ion chromatography, and phenoldisulfonic acid procedures. The linear range of the ‘Reflectoquant Analysis System’ is 1.1 to 50.6 mg/L NO3‐N. Samples exceeding this range must be diluted before analysis is performed. Excluding two wells where NO3‐N was >50.6 mg/L, simple correlation was high (r > 0.91) among the four procedures evaluated. In addition, slopes and intercepts from linear regression of NO3‐N among procedures were not significantly different. Population means obtained using the four methods were very similar. For this sample of wells, the ‘Reflectoquant Analysis System’ was precise and provided NO3‐N analysis of water samples equivalent to standard methods. Other advantages of the ‘Reflectoquant Analysis System’ are short analytical times, reduced operator training period, and competitive costs compared to standard methods.     

Response of summer‐planted potatoes to level of applied nitrogen and water

The irrigation and nitrogen (N) requirements of potatoes (cv. Delaware) were determined using sprinklers in a line‐source design on a Spearwood sand. Irrigation water was applied at 73 to 244% of the daily pan evaporation (Epan) and N at 0 to 800 kg N ha^‐1 (total applied) as NH₄NO₃ in 10 applications post‐planting. There was a significant yield (total and marketable) response to irrigation, at all levels of applied N, and N at all levels of applied water (P<0.001). The interaction between irrigation and N was also significant (P<0.001). There was no significant yield response to irrigation from 149% Epan (i.e., W3 treatment) to 244% Epan (i.e., W6 treatment). Irrigation at 125 and 150% of Epan was required for 95 and 99% of maximum yield, respectively, as determined from fitted Mitscherlich relationships. Critical levels of N required for 95 (417 kg ha^‐1) and 99% (703 kg ha^‐1) of maximum yield were also determined from a Mitschlerlich relationship fitted to the average of the W3 to W6 treatments. The percent total N and nitrate‐N in petioles of youngest fully expanded leaves required for 95 and 99% of maximum yield was 1.78 and 2.11, respectively, at the 10 mm tuber stage, and 0.25 and 0.80% at the 10mm plus 14 day stage (from quadratic regressions). There was a significant (P≤0.001) increase in N uptake by tubers with level of applied N from 57 kg ha^‐1 at 0 kg applied N ha^‐1 to 190 kg ha^‐1 at 800 kg applied N ha^‐1 (from a Mitscherlich relationship fitted to the average of W3 to W6 treatments). After accounting for N uptake from soil reserves (57 kg N ha^‐1), apparent recovery efficiency (RE) of fertilizer N by tubers [RE=(Up‐Uo/Np) where Up=uptake of N by the crop, Uo=uptake in absence of applied N and Np is the level of applied N, expressed as a fraction] declined from 0.28 at 100 kg applied N ha^‐1 to 0.17 at 800 kg applied N ha^‐1. There was a linear increase in ‘after cooking darkening’ (i.e., greying) of tubers with increasing level of applied N. Conversely, ‘sloughing’ (i.e., disintegration) of tubers decreased (inverse polynomial) with increasing level of applied N. Rate of irrigation had no effect on these cooking qualities. Reducing applied irrigation and N from levels required for 99% of maximum yield to levels required for 95% of maximum yield would not lead to a significant reduction in profit. This would increase apparent recovery efficiency of applied N by plants, maintain tuber quality, and reduce the impact of potato production on the water systems of the Swan coastal plain.     

Does oxidation affect the water functionality of myofibrillar proteins?

Water-binding properties of myofibrils extracted from porcine muscle, and added hemoglobin with and without exposure to H2O2, were characterized using low-field proton NMR T2 relaxometry. The effects of pH and ionic strength in the samples were investigated as pH was adjusted to 5.4, 6.2, and 7.0 and ionic strength was adjusted to 0.29, 0.46, and 0.71 M, respectively. The formation of dityrosine as a measure of oxidative protein cross-linking revealed a significant increase in dityrosine concentrations upon H2O2 activation. The formation of dityrosine was strongly pH-dependent and increased with decreasing pH. In addition, increased levels of thiobarbituric acid reactive substances were observed upon addition of H2O2, implying that lipid oxidation was enhanced, however, with a different oxidation pattern as compared to the myofibrillar proteins. Low-field NMR relaxation measurements revealed reduced T2 relaxation times upon H2O2 activation, which corresponds to reduced water-holding capacity upon oxidation. However, a direct relationship between degree of oxidation and T2 relaxation time was not observed with various pH values and ionic strengths, and further studies are needed for a complete understanding of the effect of oxidation on myofibrillar functionality.     

Effects of a bentonite–water mixture on soil-saturated hydraulic conductivity

To reduce water loss in light-textured soils, hydraulic conductivity should be reduced by mixing the soils with some soil conditioners, e.g. sodium-bentonite. The objectives of this study were to investigate the effects of irrigation water with different bentonite concentrations (0, 0.05, 0.1, 0.15 and 0.2%) on hydraulic gradient (i) and relative saturated hydraulic conductivity (K _rs) in a laboratory soil column with a loamy sand soil. Addition of sodium-bentonite to the soil increased i throughout each experiment. Furthermore, addition of bentonite reduced K _rs, and a 0.2% bentonite–water concentration after infiltration of 48 mm of bentonite–water mixture (BWM), reduced the K _rs value to 56% of K _s. K _rs was reduced as the concentrations of bentonite increased and its value reached ～0.5 to 0.6 as the infiltration of BWM increased. The lowest value of K _rs and the greatest reduction rate occurred at a bentonite concentration of 0.2%. It is concluded that BWM can be used as a channel liner. Using a 0.2% bentonite concentration resulted in a reduction in the seepage ratio from 1.0 to 0.08.     

Effects of vesicular‐arbuscular mycorrhizas and phosphorus on water status and growth of apple

Apple (Malus hupehensis Rehd) seedlings were grown in sterilized and non‐sterilized soil with or without phosphorus (P) added and inoculated by VA mycorrhizal (VAM) fungi (Glomus versifome Daniels et Tappe and Glomus macrocarpum Tul et Tul). In sterilized soil, the VAM infection increased the transpiration rate (Tr.) of the leaves, reduced the stomatal resistance (Sr.) and the permanent wilting percentage (PWP) and enhanced the rate of recovery of the plant from the water stress and the plant growth (e.g. leaf number, stem diameter and dry weight). It also increased absorption of most minerals, especially Zn and Cu by the roots and weakened the P‐Cu and P‐Zn interactions. Phosphorus fertilization had some positive effects on the water status, P nutrition and growth, but it reduced the Cu concentration. VAM improved the water status and enhanced drought tolerance of the trees by enhancing absorption and translocation of water by the external hyphae. The efficiency of inoculation in nonsterile soil was not obvious.     

A simulation study on effect of surface film-forming material on water evaporation

A greenhouse experiment was conducted to investigate the effect of surface film-forming material (SFFM), a mixture of 16~18-octadecanols by emulsification, on water evaporation. Air-dried soil with distilled water was incubated firstly for 7 days to reestablish soil biological activity and then for another 7 days after treated with SFFM at rates of 0, 1, 2, 4, 6 and 8 g m^-2, respectively. Everyday during the 7-day incubation after addition of SFFM, water losses due to evaporation were measured by an electronic balance. The rate of water evaporation with the addition of SFFM was reduced significantly compared with the control treatment and the effectiveness of SFFM on water evaporation reduced with time. According to the equation expressions of the effect of SFFM on water evaporation, the half-life of effectiveness of SFFM on water evaporation was introduced and calculated to analyze quantitative relationship between the effectiveness of SFFM on water evaporation and the addition rate of SFFM. The calculated half-life increased with the addition rate of SFFM and the confidence of the calculated values of the half-life was high, suggesting that the half-life of effectiveness of SFFM on water evaporation could be described quantitatively and may be helpful for ameliorating application method of SFFM and screening surface-film forming materials in order to improve nitrogen fertilizer use efficiency in flooded rice fields.     

Microbial reduction of dinitrotoluene sulfonates in TNT red water–contaminated soil

Journal of Soils and Sediments - Large quantities of TNT red water which contained mainly dinitrotoluene sulfonates (DNTS) were produced during the production of TNT, threatening the surrounding...     

Morphology and water barrier properties of nanobiocomposites of κ/ι-hybrid carrageenan and cellulose nanowhiskers

The current study presents the development and characterization of novel carrageenan nanobiocomposites showing enhanced water barrier due to incorporation of cellulose nanowhiskers (CNW). CNW, prepared by acid hydrolysis of highly purified α cellulose microfibers, were seen to have a length of around 25-50 nm and a cross section of ca. 5 nm when dispersed in the matrix. The nanobiocomposites were prepared by incorporating 1, 3, and 5 wt % of the CNW into a carrageenan matrix using a solution casting method. Morphological data (TEM and optical microscopy) of the nanocomposites containing CNW were compared with the morphology of the corresponding biocomposites containing the original cellulose microfibers and the differences discussed. Thermal stability by TGA, water vapor permeability, and percent water uptake were also determined. The main conclusion arising from the analysis of the results is that the nanobiocomposites containing 3 wt % of CNW exhibited the lowest reduction in water vapor permeability, that is, ca. 71%, and that this reduction was largely attributed to a filler-induced water solubility reduction. This fully biobased nanoreinforced carrageenan can open new opportunities for the application of this biopolymer in food-packaging and -coating applications.     

Ecotoxicological assessment of nickel pollution of soil and water environments adjacent to soddy–podzolic soil

The indicators of functioning of soil microorganisms in soddy–podzolic soil contaminated with Ni compounds show different ranges of soil ecotoxicity. A halving of soil microorganisms' nitrogen-fixing activity has been shown in slightly acidic soddy–podzolic cultivated soil with a Ni concentration of 150 mg/kg and for noncultivated acidic soils with a Ni concentration 100 mg/kg. The reduction of denitrification activity in cultivated soil has been observed with a Ni concentration of 500 mg/kg, and in uncultivated soil it has been observed at a Ni dose of 100 mg/kg. The inhibition of soil respiration in slightly acidic soil occurred only at the highest dose of Ni, 1000 mg/kg, while in the acidic soil it took place at 300 mg/kg. Biotesting based on bacterial luminescence can be used for determination of soil pollution with heavy metals such as Ni, as well as for the assessment of the toxicity of aqueous environments in contact with contaminated soils.     

Phytoindication of the water status and nutrient supply of oil-polluted soils in the middle reaches of the Ob’ River

The method of phytoindication of the soil water status and nutrient supply was applied to natural and oil-contaminated soils in the middle reaches of the Ob’ River. These soil characteristics were indirectly assessed using the ecological scales developed by L. G. Ramenskii. On this basis, changes in the soil water status and nutrient supply under the impact of soil contamination with oil and oil products were estimated for the particular soil and landscape conditions     

Greenhouse gas diffusive fluxes at the sediment–water interface of sewage-draining rivers

Purpose

The purposes of this study were to analyse the spatiotemporal variations in greenhouse gas diffusive fluxes at the sediment–water interface of sewage-draining rivers and natural rivers, and investigate the factors responsible for the changes in greenhouse gas diffusive fluxes.

Materials and methods

Greenhouse gas diffusive fluxes at the sediment–water interface of rivers in Tianjin city (Haihe watershed) were investigated during July and October 2014, and January and April 2015 by laboratory incubation experiments. The influence of environmental variables on greenhouse gas diffusive fluxes was evaluated by Spearman’s correlation analysis and a multiple stepwise regression analysis.

Results and discussion

Sewage-draining rivers were more seriously polluted by human sewage discharge than natural rivers. The greenhouse gas diffusive fluxes at the sediment–water interface exhibited obvious spatiotemporal variations. The mean absolute value of the CO₂ diffusive fluxes was seasonally variable with spring>winter>fall>summer, while the mean absolute values of the CH₄ and N₂O diffusive fluxes were both higher in summer and winter, and lower in fall and spring. The annual mean values of the CO₂, CH₄ and N₂O diffusive fluxes at the sewage-draining river sediment–water interface were ??123.26?±?233.78 μmol m^?2 h^?1, 1.88?±?6.89 μmol m^?2 h^?1 and 1505.03?±?2388.46 nmol m^?2 h^?1, respectively, which were 1.22, 4.37 and 134.50 times those at the natural river sediment–water interface, respectively. The spatial variation of the N₂O diffusive fluxes in the sewage-draining rivers and the natural rivers was the most significant. As a general rule, the more serious the river pollution was, the greater the diffusive fluxes of the greenhouse gases were. On average for the whole year, the river sediment was the sink of CO₂ and the source of CH₄ and N₂O. There were positive correlations among the CO₂, CH₄ and N₂O diffusive fluxes. The main influencing factor for CO₂ and N₂O diffusive fluxes was the water temperature of the overlying water; however, the key factors for CH₄ diffusive fluxes were the Eh of the sediment and the NH₄⁺-N of the overlying water.

Conclusions

River sediment can be either a sink or a source of greenhouse gases, which varies in different levels of pollution and different seasons. Human sewage discharge has greatly affected the carbon and nitrogen cycling of urban rivers.

     

Improved soil–plant water dynamics and economic water use efficiency in a maize field under locally water stress

Soil–plant water dynamics is a major driving factor on crop yield which could be improved under optimal irrigation strategy. The soil water dynamics under partial root-zone drying (PRD) and its consequent effects on maize economics returns were investigated in a two-year field study in the research field of Sari Agricultural Sciences and Natural Resources University. Irrigation treatments included full irrigation (FI) and two PRD treatments including PRD₁ and PRD₂, receiving 100%, 75% and 55% of crop water demand at each irrigation event, respectively. TDRs were used for measuring soil water contents on a daily basis. Economic analysis was done based on net present value (NPV), benefit-to-cost ratio (B/C) and internal rate of return (INRR) indices. Applying PRD₁ treatment increased soil wetting front advance by 110–330% compared those for other treatments which caused 50% increase in root water uptake. Improved soil water dynamics under PRD1 prevented a significant reduction in maize grain yield, leading to 37.7%, 6.14% and 192% increase in NPV, B/C and INRR, respectively, under PRD₁ than those for FI treatment. Thus, PRD₁ was the most economic water-saving irrigation strategy under which 25% of irrigation water would be saved due to a better utilization of soil water supply.     

Calibration of the time‐domain reflectometer and determination of the volumetric water content of the soil profile in an ultisol of Costa Rica

Abstract

An experiment was conducted to determine if time‐domain reflectometry (TDR) could be used to measure the water content at different depths in the O‐to‐75 cm soil layer. Probes of three wires (1/8 inch diameter and 30 cm exposed length) were installed in field plots differing in current crop‐fertilization history. Measurements of volumetric water content using bulk density and gravimetric water content were made to calibrate the TDR method. Comparison of water contents determined by TDR with those from gravimetric samples showed that there is a linear relationship (small offset but same slope) of water content with depth, indicating that there is little difference in volumetric water content from the 0 to 75 depth. However, the TDR method gives consistently lower water content values as compared with values obtained by gravimetric determination. Continuous measurements of profile soil water content with TDR in wet and dry periods during the year indicated that the mayor differences in volumetric water content correspond to the first 30 cm depth.     

Organogel-emulsions with mixtures of β-sitosterol and γ-oryzanol: influence of water activity and type of oil phase on gelling capability

In this study, water-in-oil emulsions were prepared from water containing different salt concentrations dispersed in an oil phase containing a mixture of β-sitosterol and γ-oryzanol. In pure oil, the β-sitosterol and γ-oryzanol molecules self-assemble into tubular microstructures to produce a firm organogel. However, in the emulsion, the water molecules bind to the β-sitosterol molecules, forming monohydrate crystals that hinder the formation of the tubules and resulting in a weaker emulsion-gel. Addition of salt to the water phase decreases the water activity, thereby suppressing the formation of sitosterol monohydrate crystals even after prolonged storage times (～1 year). When the emulsions were prepared with less polar oils, the tubular microstructure was promoted, which significantly increased the firmness of the emulsion-gel. The main conclusion of this study is that the formation of oryzanol and sitosterol tubular microstructure in the emulsion can be promoted by reducing the water activity and/or by using oils of low polarity.     

Incorporation of metal bioavailability into regulatory frameworks—metal exposure in water and sediment

Background, aim, and scope  

The cause for this position paper is the impression that risk assessors consider primarily the concentration of free metal ions dissolved in solution controlling metal bioavailability in aquatic systems. Aiming at a more realistic risk assessment of metals, bioavailability has to be discussed under the scope of main uptake routes of metals to organisms.     

Variability of soil water content controlled by evapotranspiration and groundwater–root zone interaction

The central moments of soil water content (SWC) variability at the field scale are determined by soil texture, considering both smooth topography and groundwater table position. The characteristics of variability are governed by other soil factors like soil structure, micro relief, preferred water flow paths, root system characteristics, rock content, etc. This paper shows the integral effect of all these hardly quantifiable factors on SWC variability simulated by the processes of evapotranspiration and groundwater–root zone interaction using the HYDRUS ET model. SWC and soil hydraulic characteristics were spatially determined over a 4.5 ha field during two sampling campaigns under different atmospheric and groundwater conditions, and data distributions were compared to SWC distributions provided by mathematical modeling. The entire spring–summer period of 2003 was then examined for changes of SWC spatial variability. It was found that evapotranspiration influences SWC spatial variability only if SWC is under the critical value when wetter parts of the field evaporate more water than drier parts, resulting in smoothed SWC variability. Under wet conditions the spatial variability of SWC increases by drainage, as those parts of the soil with coarser texture drain faster than finer-textured parts.     

Contact angles at the water–air interface of hydrocarbon-contaminated soils and clay minerals

Contact angles at the water–air interface have been measured for triturated preparations of clays and soils in order to assess changes in their hydrophobic properties under the effect of oil hydrocarbons. Tasks have been to determine the dynamics of contact angle under soil wetting conditions and to reveal the effect of chemical removal of organic matter from soils on the hydrophilicity of preparations. The potentialities of static and dynamic drop tests for assessing the hydrophilic–hydrophobic properties of soils have been estimated. Clays (kaolinite, gumbrine, and argillite) have been investigated, as well as plow horizons of soils from the Republic of Tatarstan: heavy loamy leached chernozem, medium loamy dark gray forest soil, and light loamy soddy-calcareous soil. The soils have been contaminated with raw oil and kerosene at rates of 0.1–3 wt %. In the uncontaminated and contaminated chernozem, capillary water capacity has been maintained for 250 days. The contact angles have been found to depend on the degree of dispersion of powdered preparation, the main type of clay minerals in the soil, the presence and amount of oxidation-resistant soil organic matter, and the soil–water contact time. Characteristic parameters of mathematical models for drop behavior on triturated preparations have been calculated. Contamination with hydrocarbons has resulted in a reliable increase in the contact angles of soil preparations. The hydrophobization of soil surface in chernozem is more active than in soils poorer in organic matter. The complete restoration of the hydrophilic properties of soils after hydrocarbon contamination is due to the oxidation of easily oxidizable organic matter at the low content of humus, or to wetting during several months in the absence of the mazut fraction.     

Can the increase of irrigation frequency improve the rate of water and salt migration in biochar-amended saline soil?

Journal of Soils and Sediments - It is difficult to leach salt into the deep layers of saline or sodic soils due to their poor permeability. The frequency of irrigation is a major factor affecting...     

Performance of a non‐nuclear resonant frequency capacitance probe. II. Measurement of dryland crop water use

Abstract

Resonant frequency capacitance techniques have been recently developed as a safe and reliable method for measuring water content of various materials. A previous study with a commercial capacitance probe (Troxler Sentry 200‐AP) showed it to be a safe, reliable, and a rapid method of in situ measurement of soil water content in the field provided it is calibrated for individual soils. Further testing of this resonant frequency capacitance probe was done to evaluate the performance of the probe by comparing results of field measured crop water use to those reported in similar studies using other methods of determining in situ soil water content in the field. These tests were done in two field experiments which were conducted during the summer of 1994 using corn and sorghum as the indicator crops. The experimental field was the same used to calibrate the capacitance probe in the previous study. Treatments consisted of three plant populations of corn and four plant populations in two cultivars of grain sorghum. The crop water use for corn and sorghum averaged over all treatments were 452 and 424 mm, respectively. The measured crop water use values for corn and sorghum were comparable to the crop water use values reported in several similar previous studies using different in situ soil water measuring instruments.