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1.
Phosphorus (P) in an high-pH soil may not be readily available to a crop, even though soil-testing procedures indicate high levels are present. A 2-year field study was conducted to determine corn yield responses to different rates of P fertilization as a function of soil-test P levels determined using the Mehlich-3 extractant. In 1 of the 2 years of this study, corn yields responded to P application across all soil P levels in a linear plateau fashion, indicating that P availability was limiting regardless of soil P levels. Where soil-test P was less than 40 mg kg?1, corn yields showed a quadratic response to rate of P applied both years, and when soil-test P was between 40 and 60 mg kg?1, corn yields showed a response only in the second year, when better growing conditions occurred. Soil-test P levels based on the Mehlich-3 extractant identified deficiencies in soil P availability to the crop, which could be corrected by P fertilization on a high-pH soil. Uptake efficiency of applied P was low, indicating that much of the P applied was not available to the crop.  相似文献   

2.
Abstract

Highly calcareous soils are abundant in Iran. The calcium carbonate equivalent (CCE) of these soils reach up to 650 g kg?1. Although phosphorus (P) fertilizer is being widely used in these soils, little information, if any, is available about P status in such soils. The objectives of this study were to 1) determine inorganic P forms in 18 surface soils of southern Iran, 2) study P readsorption during different stages of fractionation schemes, 3) assess the ability of NaOH to extract aluminum (Al)‐P, and 4) evaluate the relationships between P availability indices and inorganic P forms. Eighteen soil samples with a wide range of physicochemical properties were selected for this study. Inorganic P forms was determined by sequential extraction with NaHCO3, NH4OAc, NH4F, NaOH, citrate dithionite (CD), and H2SO4, which are referred to as Ca2‐P, Ca8‐P, Al‐P, Fe‐P, occluded P (O‐P), and Ca10‐P. Phosphorus readsorption in different stages was determined by 1 M MgCl2. Furthermore, a fractionation scheme without an NH4F step was used to evaluate the ability of NaOH to extract Al‐P. NaHCO3 (Olsen‐P) and MgCl2‐extractable P (Exch‐P) were regarded as P-availability indices. The abundance of different P forms was in the order Ca2‐P<Fe‐P<Al‐P<O‐P<Ca8‐P<Ca10‐P. Ca2‐P was highly correlated with Olsen‐P and Exch‐P. Ca2‐P, Olsen‐P, and Exch‐P showed a relationship with CCE, citrate–bicarbonate–dithionite extractable Fe (Fed), and Al (Ald). Phosphorus readsorption appeared to be important only in the Ca8‐P step, and the content of readsorbed P was related to Ca8‐P, CCE, and clay content of the soils. In the present study, Al‐P and Fe‐P accounted for 10 and 5% of the sum of the inorganic P fractions, respectively, and Fe‐P showed a strong relationship with Feo, whereas Al‐P showed a significant relationship with oxalate‐extractable Al (Alo) and Ald. It was found that one extraction with NaOH is not a good indicator for Fe‐ and Al‐P, and the ability of NaOH to extract Al‐P was reduced with increase in Al‐P content.  相似文献   

3.
Laboratory experiments were conducted to study the kinetics of phosphorus (P) desorption in different calcareous soils of Hamadan Province of Iran. Soils were fertilized with poultry manure at 50 ton ha–1 and incubated at 25 ± 1 °C at 15% moisture for 6 months. The release rate of P was studied by successive extraction with 0.5 M sodium bicarbonate (NaHCO3) over a period of 1–1752 h. Also, available P was determined. The results showed that available P in fertilized and unfertilized soils ranged from 13.3 to 55.1 and 10.0 to 50.1 mg kg–1, respectively. Phosphorus desorption from the fertilized and unfertilized soils began with a fast initial reaction, followed by a slow secondary reaction. The amount of P released after 1752 h in fertilized and unfertilized soils ranged from 319.2 to 623.9 and 309 to 586.7 mg kg–1, respectively. The amount of P released was significantly correlated with available P. The kinetics of cumulative P release were evaluated using the five kinetic equations. Phosphorus desorption kinetics were best described by the parabolic diffusion law, first order, and power function equations. Rate constants of these equations different in fertilized and unfertilized soils.  相似文献   

4.
《Journal of plant nutrition》2013,36(8):1427-1439
Abstract

Phenolic acids (caffeic, CAF; protocatechuic, PCA; p-coumaric, COU; and vanillic, VAN), catechol (CAT), poly-galacturonic acid (PGA), and citric acid (CIT) were compared for their effectiveness in phosphorus (P) mobilization in three soils differing in chemical properties. The addition of organic ligands at 100 μmol g? 1 soil increased the concentrations of resin P (Pr), water-extractable P (Pw), and bicarbonate-extractable inorganic P (Pbi), thus improving the phosphorus availability. The magnitude of P mobilization in the calcareous soil can be expressed in the following order: CAF > CAT > PCA = CIT > VAN > COU > PGA, which was consistent with the number of phenolic hydroxyl groups they contained and the position of carboxyl on the benzoic ring. In the two acid soils tested, the order of P mobilization was CIT > CAT > PCA > CAF after 24 h incubation, and CIT > PCA > CAF > CAT after a 14 d incubation. The mobilized P originated partly from the organic P fractions, which could be extracted by 0.5 M NaHCO3. In addition, Pr decreased and Pw increased during incubation. The exceptions were that the CAF treatment increased Pr and the CIT treatment did not affect Pw. Calcium extraction from the soils after a 1 d or 14 d incubation could not fully account for the P mobilization. The results suggest that the inorganic P dissolution by the organic ligands was not the only mechanism of P mobilization in the calcareous soil, while in acid soils the chelation of metal cations by organic ligands is likely an important factor in P mobilization.  相似文献   

5.
ABSTRACT

The efficient use of phosphorus (P) fertilizers is very important in South Florida so that the environmental impact is minimal while meeting crop demand. To ensure that this is accomplished, an updated soil test P calibration is needed for sugarcane (Saccharum spp.) grown on Florida mineral soils, which accounts for almost 30% of the total sugarcane planted in the state. An outdoor pot experiment was conducted with the objective of evaluating four soil extractants for potential use in soil test P calibrations. Sugarcane cultivar CL 88–4730 was grown in 26L pots in a randomized complete block design with four replications of four P fertilizer rates (0, 38, 76, and 152 mg P L?1 soil) and four soil series (2 Spodosols, 1 Entisol, and 1 Alfisol). Sugarcane biomass was significantly increased with P fertilizer application and extractable soil P significantly increased with increasing P fertilizer rate. Strongest relationships of extractable soil P with relative fresh weight yield were determined with the water, acetic acid, and ammonium acetate extractants. All extractants tested, including Mehlich 3, had significant relationships with relative yield and leaf P concentration and so all these extractants should be considered in further field calibration studies with sugarcane on Florida mineral soils.

Abbreviations: EAA: Everglades Agricultural Area; EREC: Everglades Research and Education Center; OM: organic matter; TSP: Triple superphosphate  相似文献   

6.
ABSTRACT

Phosphorus (P) deficiency and low P-use efficiency are induced by soil properties, especially in calcareous soils, which are dominant in semi-arid regions of the world such as the Mediterranean region. Alternative approaches to P fertilization involve exploiting plant genetics in order to achieve more efficient use of P by the growing crop. Accordingly, in a greenhouse pot experiment, we evaluated P-efficiency in wheat genotypes grown in typical calcareous soils in southern Turkey. Ten common local genotypes were grown in six soil series for eight weeks using five P application rates (0, 25, 50, 100, and 200 mg P kg?1). Dry matter (DM) yield and P content were significantly increased by increasing P rates, with significant differences between soils. Some genotypes performed better under P stress because of better P utilization efficiency. Shoot DM was the most sensitive indicator of genetic variability under P-deficient conditions. Genotypes classified as efficient-responsive (Adana-99, 1014, Golia, Balatilla) had above average DM yield when P was not added, and responded well to P applications; efficient-non-responsive genotypes (Firat-93, Seri-82, Genc-99, Panda) had below average DM yield, but responded to P applications; inefficient-non-responsive genotypes (Fuat Bey and Ceyhan-99) had below average DM yield; and no genotypes were in the inefficient responsive category. Such P response categorization is needed for better breeding programs for nutrient-use efficiency. The study may aid in selecting P-efficient genotypes in low-P soils, especially where little P is used. The use of P-efficient genotypes should be seen as complement to, rather than a substitute for, chemical P fertilization depending on local conditions.  相似文献   

7.
Developing a fast and reliable soil testing method is critical for improving soil testing efficiency and ensuring reliable fertilizer recommendation. The objectives of this study were to evaluate Mehlich-3 (M-3) as a replacement for ammonium bicarbonate-diethylenetriaminepentaacetic acid (AB-DTPA) to extract phosphorus (P) and potassium (K) and to determinate the relationships between extractable P and K and their uptakes by crop in calcareous soils. M-3 and AB-DTPA were compared by using two approaches. In the first approach, the amounts of extracted P and K were compared by analyzing soil samples collected from agricultural production areas; in the second approach, snap beans (Phaseolus vulgaris) were grown in pot to determine the P and K uptakes by crop. There were significant correlations between M-3 and AB-DTPA for both soil test P and K based on soils collected from the agricultural field and the pot study. Soil test P and K by both extractants were significantly correlated with their uptakes by snap bean. The critical value of M-3-P regarding snap bean uptake was 47 mg kg?1 and was higher than that (18 mg kg?1) for AB-DTPA-P, whereas critical soil test K levels were similar between M-3 and AB-DTPA. M-3 was identified as an alternate improved extraction method instead of AB-DTPA in calcareous soils based on this study. However, more work will be needed to identify the correlation of the two extractants and crop responses under a field condition.  相似文献   

8.
ABSTRACT

Two field experiments were conducted to compare 15 wheat genotypes at two phosphorus (P) levels (zero-P control or low P level—without application of P fertilizer on soil with 8 mg extractable P kg?1, and adequate P level—with P fertilizer applied at 52 kg P ha?1) for yield, P uptake, and P utilization efficiency (P efficiency ratio—PER, P harvest index—PHI, and P physiological efficiency index—PPEI). On the average of two experiments, substantial and significant differences were observed among wheat genotypes for both grain and straw yields at both P levels. Grain yields ranged from 2636 to 4455 kg ha?1 in the zero-P control, and from 2915 to 4753 kg ha?1 at adequate P level. Genotype 5039 produced the maximum grain yield, while 6529-11 had the minimum grain yield at both P levels. Relative reduction in grain yield due to P deficiency stress (PSF) ranged from none to 32%, indicating differential P requirements of genotypes. Genotypes 4943, Pasban 90, Inqlab 91, PB 85, Lu 26s, 4770, Chakwal 86, 4072, 6544-6, and 5039 had little or no response to P application. Phosphorus responsive genotypes included FSD 83, Kohinoor 83, Parvaz-94, Pak 81, and 6529-11. A non-significant correlation (r = ?0.466, P > 0.05) between grain and PSF in zero-P control treatment also indicated the least effect of P deficiency on some wheat genotypes. A wide range of PPEI (270–380 kg grain kg?1 P absorbed in grain + straw at control P level, and 210–330 kg grain kg?1 P absorbed in grain + straw at adequate P level) indicated differential utilization of absorbed P by the genotypes for grain production. This indicated that wheat genotypes differed considerably in their P requirement for growth and responsiveness to P application. The findings also suggested that PPEI was a better parameter for measuring P efficiency than other parameters, and can be used for selecting P efficient genotypes, because it relates to the internal concentration of a nutrient and genetic makeup of plant. It is concluded that genotypes having ability to produce relatively high grain yield, good command to tune P within plant and high PPEI are suited to low P soil conditions. Genotypes 4072, Inqlab 91, 4943, Pak 81 and 5039 were P efficient and had above mentioned abilities, while genotypes FSD 83, 6544-6, and 6529-11 were P inefficient. It should be noted that traits related to P efficiency are inheritable and can be used to improve P use efficiency of a genotype through back cross breeding programs.  相似文献   

9.
This study evaluated the effects of phosphorus (P) fertilizer levels on inorganic P fractions. Wheat cultivars (Azadi and Marvdasht) were grown in the soils amended with the four rates of P fertilizer levels (no fertilizer, 10, 15, and 25 mg available P kg?1 soil). Soils were sampled from rhizosphere and non-rhizosphere areas after 6 weeks. The mean of all P fractions was significantly different in various P fertilizer levels. The smallest and the largest amounts of all P fractions were observed in the soil with no P and in 25 mg kg?1 soil P level, respectively. The Azadi cultivar, as P-efficient, showed the smallest increase in soil P fractions with increasing soil P levels. The means of all P fractions except Al-phosphates (Al-P) were significantly higher in non-rhizosphere soil. There were differences between these cultivars associated with the more inaccessible fractions at the 15 mg P kg?1 soil level.  相似文献   

10.
Rate of zinc (Zn) release from solid to solution phase by organic acids can influence Zn availability in calcareous soils. The objective of the present study was to investigate the effect of different concentrations (1.1, 2.2, and 3.3 mM) of oxalic acid and citric acid on the kinetic release of Zn from two calcareous soils from Eastern Iran. The two organic acids showed significant difference in Zn release from studied soils. Cumulative Zn release during 72 h ranged from 5.85 to 10.4 mg kg?1 in soil 1 and ranged from 8.7 to 16.9 mg kg?1 in soil 2 using different concentrations of oxalic acid. The amount of cumulative Zn release after 72 h in soil 1 ranged from 13.65 to 28.77 mg kg?1 and from 17.63 to 23.13 mg kg?1 when different concentrations of citric acid was used. In general, Citric acid released 38% more Zn from soils than oxalic acid. The release of Zn from soils increased with citric acid concentration but decreased with increasing of oxalic acid concentrations in the solution. The simplified Elovich equation best described Zn release as a function of time (r2 = 0.93 and SE = 0.78). From the present study, Zn release from soils can be limited by the higher concentration of oxalic acid, while citric acid is suitable for enhancing soil lability of Zn.  相似文献   

11.
Abstract

Information on the availability of different soil phosphorus (P) forms is useful for crop production. Phosphorus contents of 12 Iranian calcareous soils from upper‐, mid‐, and lower‐slope positions of two arid and two semiarid toposequences were fractionated to various organic and inorganic pools, and correlations of the P fractions with wheat responses were investigated. Among the inorganic P (IP) fractions, apatite type (Ca10‐P) and dicalcium phosphate equivalents (Ca2‐P) possessed the highest and the lowest amounts of P reserve in the soils, respectively. On average, about 20% of the total P was found in organic form (OP), of which 32% was labile (LOP), 51% was moderately labile (MLOP), and 17% was nonlabile (NLOP). The amounts of the soil P fractions were considerably influenced by the positions of the soils on the landscapes. The maximum contents of soil IP, Ca2‐P, Fe‐P (iron‐bound P), and Ca10‐P were observed in the lower‐slope positions. The amount of soil available [0.5 M sodium bicarbonate (NaHCO3) extractable] P was significantly correlated with Ca2P (r=0.895), Fe‐P (r=0.760), and Occl‐P (iron‐occluded P) (r=0.897). Direct correlation studies, however, showed that wheat shoot dry‐matter yield (DMY) was significantly affected by the amounts of Ca2‐P, Fe‐P, OP, LOP, and MLOP fractions both at early (4 weeks) and late (10 weeks) stages of growth. All organic and inorganic P fractions, except Al‐P (aluminum‐bound P), Ca8‐P (octacalcium phosphate equivalents), and NLOP, also showed significant relations to the amount and/or concentration of P in wheat tissues at 4 and 10 weeks after sowing. Among the measured soil properties, the amount of organic carbon was the most affecting factor on the size of the P fractions.  相似文献   

12.
Incinerating turkey manure is a new option in the USA to generate renewable energy and to eliminate environmental problems associated with manure stockpiling. Incineration produces turkey manure ash (TMA) with a nutrient content of 43 g phosphorus (P) kg?1 and 100 g potassium (K) kg?1. We conducted a greenhouse pot study using a low P (6 mg kg?1) and high K (121 mg kg?1) soil/sand mixture with a 7.0 pH to evaluate early growth response of corn (Zea mays L.) to TMA. A control and five rates based on P (5.6, 10.9, 16.5, 21.9, and 27.2 mg kg?1) and respective K contents in TMA were compared with triple-superphosphate and potassium chloride fertilizer. Plant height and stalk thickness at 24 and 31 days after emergence (DAE) were greatest with the fertilizer, but no differences were detected at the final sampling (52 DAE). Regardless of nutrient source, plant biomass increased with P rate. Because of faster initial plant development, corn dry matter 52 DAE was 15 to 20% greater with fertilizer than with TMA. Corn tissue P concentration was greater with TMA than with fertilizer, but P uptake was similar. Tissue micronutrient concentrations were greatest for the control. Bray 1 P appeared to extract excessive amounts of P in TMA-amended soil, whereas soil P levels with the Olsen extractant provided an estimate of plant-available P that was consistent with plant response. Based on this first approximation, we conclude that TMA is a potential source of P for field crops. Field studies are required to determine recommended application rates.  相似文献   

13.
邱慧珍  张福锁 《土壤通报》2002,33(4):295-299
用土培方法研究了两种磷肥 (枸溶性钙镁磷肥CMP和水溶性磷肥过磷酸钙SSP)和两种非水溶性磷肥活化剂(无机矿物活化剂IA和有机活化剂OA)在石灰性土壤中对不同磷效率小麦苗期生长和基因型差异以及磷效率的影响。结果表明 ,SSP和CMP对不同磷效率基因型小麦生长的影响无显著差异 ,但对植株磷效率的影响效果明显不同。SSP可提高植株的磷吸收效率 ,CMP对提高植株的磷利用效率更有效。不同磷效率小麦生长的基因型差异在所有磷肥处理中均表现 ,但在CMP处理中的差异最大 ,不同溶解性磷肥品种可作为小麦磷效率基因型的鉴定材料。两种非水溶性磷肥活化剂对钙镁磷肥均有效 ,但作用大小和方向因小麦基因型不同而异 ,OA有利于磷高效基因型小麦的生长 ,IA对磷低效基因型小麦的生长则更加有利 ,其效果甚至超过水溶性磷肥。经IA处理的CMP能明显提高小麦植株的磷含量和吸磷量 ,并能显著增加土壤的有效磷含量  相似文献   

14.
Abstract

Kangping soil in northeast China is a sodic soil characterized by a high pH and excessive sodium. The high pH and excessive sodium in sodic soils generally cause loss of soil structure, reduce hydraulic conductivity (HC), increase soil hardness, and make the soil unproductive land. After we mixed organic matter (rice straw) and chemical amendments (H2SO4, CaSO4, and FeSO4), a column experiment was conducted to evaluate the physical and chemical properties of the soil influenced by the changes in HC, penetrability of soil s`urface, pH, electrical conductivity, CO3 2‐, HCO3 ?, Ca2+, Na+, sodium adsorption rate (SAR), available phosphorus (P) and iron (Fe), and leached P.

Organic matter decreased the concentrations of CO3 2‐, HCO3 ?, and Na+ in soil solution and increased the total volume of the leachate. Organic matter also reduced the amount of available Fe and increased the available P. However, organic matter did not affect the penetrability of the soil surface as much as soil hardness, HC, and SAR within the short period of this experiment. Among the chemical amendments, H2SO4 and FeSO4 were more effective than CaSO4 to restore HC, electrical conductivity, Na+, and SAR. The chemical amendments, compared with organic matter, significantly leached P from the soil in this study, but the leaching was independent of the concentration of available P in the soil. The CaSO4 had the strongest effect in increasing leached P from the soil without changing the concentration of available P in the soil. Organic matter with added CaSO4 leached P from the soil more than all other treatments.  相似文献   

15.
长期地膜覆盖与施肥对土壤磷素和玉米吸磷量的影响   总被引:4,自引:1,他引:4  
利用比较法对长期连续覆膜(17年)后土壤磷素的变化以及玉米吸收量的变化进行了研究。结果表明:经过17年的耕作,无论是施有机肥还是磷肥均能显著增加土壤中速效磷以及全磷的含量;覆膜栽培与裸地栽培比较结果,覆膜对于土壤中速效磷以及全磷含量的变化影响不大;对植株的籽粒、轴、叶片、茎的全磷进行了测定后显示:覆膜可以促进籽粒、轴、茎对磷的吸收,抑制了叶片对磷养分的吸收;从成熟期地上部分累积磷的总量来看,覆膜可以明显提高作物对磷的吸收。  相似文献   

16.
External and internal phosphorus (P) requirements of hybrid maize (FHY-396) and indigenous variety (EV-7004) were compared on a Typic Calciargid soil. A sorption isotherm was constructed by equilibrating 2.5 g soil with 25 mL of a 0.01 M calcium chloride (CaCl2) solution containing 2, 3, 6, 12, 25, 50, and 100 mg P L–1. Sorption data were fitted to a modified Freundlich equation [x/m = Kf(EPC)1/n] to compute P rates (0, 30, 60, and 120 mg kg–1 soil) against solution levels (0, 0.09, 0.26, and 0.76 mg P L–1) for a pot study. Applied P significantly increased shoot dry matter, P concentration, and P uptake in both the genotypes. For optimum shoot growth, internal P requirement of hybrid (2.51 mg g–1) was 5% more than variety (2.39 mg g–1). However, external P requirement of hybrid (0.50 mg L–1) was remarkably more than variety (0.19 mg L–1). This strongly advocated greater P rates for the high-yielding hybrid than for the variety.  相似文献   

17.
Evaluation of five soil phosphorus (P) extractants was done on southwestern Nigerian soils from sedimentary and basement complex parent materials to determine the relationship between the extractants and the most appropriate extractant for the soils. The soils differed in properties. Generally, soils from the basement material had less available P compared with sedimentary material. Olsen extracted the greatest P. Bray 1 measured 67% of Olsen P, Hunter measured 52%, Mehlich measured 42%, and Ambic measured 24%. Positive and significant regression (P < 0.001) existed among Bray 1, Olsen, Mehlich, Hunter, and Ambic extractants. The strongest relationship was found among Olsen, Mehlich, and Ambic P. The relationship between maize P uptake and extracted P was quadratic, whereas the relationship with Mehlich was logarithmic. Bray, Mehlich, and Olsen P were the significant contributors to the maize P uptake and dry-matter yield. Extractants in order of P extraction were Olsen > Bray 1 > Hunter > Mehlich > Ambic.  相似文献   

18.
采用室内盆栽试验研究了不同施肥处理下马尾松土壤磷形态,结果表明:施入P肥后土壤中无机磷的含量产生了变化,施入PK后根际土和非根际土土壤中的速效磷含量都有增加;除施入K、PK外,施肥后根际土和非根际土中Al-P的含量都比未施肥的高;施肥后Fe-P的变化比较大,而Fe-P的减少是由于南方土壤中的铁大多是以高价存在,易发生氧化还原反应;O-P是一种无效磷,施肥后土壤中的O-P含量均沉积于土壤而比对照的高;施入N、P、K、PK、NK、NPK后降低了两种土壤中Ca-P的含量。因此,为了促进马尾松的生长发育,可以给马尾松增施NP、PK、NPK肥。  相似文献   

19.
ABSTRACT

Phosphorus (P) fertilization is reported to alleviate the adverse effects of sodicity on survival of the seedlings, growth, and yield of rice. However, it is not known if required levels of Olsen's P to alleviate the adverse sodicity effects varies with increased sodicity stress. The present study, conducted at various pH values (8.0, 9.3, 9.7, and 9.9) with varying levels of P fertilization (P0.0, P0.2, P0.4, P0.6, and P0.8 kg hm? 2), showed that P requirements of rice increased with increases in sodicity stress. At a pH of 8.0, 4.3 mg kg? 1 Olsen's P was sufficient for survival of the seedlings, but not for grain weight (6.3 mg kg? 1). Seedlings required 7.0 and 9.5 mg kg? 1Olsen's P to survive at pH 9.7 and 9.9, respectively. Similarly, high P levels were needed for more total and fertile tillers and spikelets numbers. One thousand (1000) grain weight and grain yield responded to 6.3, 7.7, 8.8, and 10.4 mg kg? 1 Olsen's P at pH values of 8.0, 9.3, 9.7, and 9.9, respectively. Total chlorophyll in the leaves was significant in P fertilized plants. At a pH of 9.7, plants with 7.9 mg kg? 1 Olsen's P had 52% more chlorophyll per 100 ppm sodium (Na) in the leaves compared to those at 6.3 mg kg? 1 Olsen's P. This could possibly be due to improved tissue tolerance to Na in P-fertilized plants. Plants fertilized with P had higher P and potassium (K) concentrations in their shoots. Olsen's P levels of 7.7 mg kg? 1, 7.9 mg kg? 1, and 9.5 mg kg? 1 were effective in restricting increases of Na (a potentially toxic ion) in shoots at pH 9.3, 9.8, and 9.9, respectively, thus helping plants have better yields.  相似文献   

20.
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