Source areas of phosphorus transfer in an agricultural catchment,south-eastern Norway

Abstract

The strategy to mitigate phosphorus (P) losses in areas of arable cropping in Norway has focused on measures to reduce erosion. Risk assessment of erosion has formed the basis for implementation of the measures. The soil P content has increased during recent decades, motivating an evaluation of its effect on P transfer in the landscape. The present study describes the spatial variability of runoff P concentrations from an agricultural dominated catchment (4.5 km²), representative for agriculture in south-eastern Norway. The concentrations of suspended sediments (SS), total P (TP) and dissolved reactive P (DRP) in runoff from 22 subcatchments (0.3–263 ha) during one year (monthly and during runoff-events) were evaluated. Contributions from point sources were 38 kg TP yr^?1 compared to a total P loss of 685 kg yr^?1 from the whole catchment. During low flow, mean diffuse TP concentration in runoff from subcatchments varied from 28 to 382 µg l^?1. The mean low flow TP concentration was 39 µg l^?1 from the housing area (only diffuse runoff) and 33 µg l^?1 from the forested area. During high flow the highest diffuse TP concentration was measured in an area with high erosion risk and high soil P status. At the subcatchment level the transfer of SS varied from 25 to 175% of the whole catchment SS transfer. Correspondingly for TP, the transfer varied from 50 to 260% of the whole catchment TP transfer. For each of five agricultural subcatchments the slope of the relationship between TP and SS concentrations reflected the mean soil P status of the subcatchment. Erosion risk estimates were closely related to the SS concentration (R²=0.83). The study illustrates that soil P status in addition to soil erosion is an important factor for P transfer.     

Sediment and phosphorus transfer in overland flow from a maize field receiving manure

Abstract. The transfer of suspended sediment (SS) and phosphorus (P) in overland flow from 30 m² field plots receiving either nil, surface‐applied or incorporated manure (slurry) were monitored to determine the vulnerability of land cropped to continuous forage maize to diffuse pollutant transfer in winter runoff. In the absence of slurry, P export was dominated by particulate forms, with up to 1 t SS ha^?1 and 0.75 kg total P ha^?1 collected from an individual storm event. Background concentrations of P in soluble (<0.45 μm) form were large (c. 0.5 mg L^?1) by eutrophication standards due to the previous build‐up of soil P, and largely independent of SS concentrations. Largest P exports (representing up to 23% of the slurry P applied) were measured when dairy slurry (3–13% dry solids) was surface‐applied. The P mobilized from the slurry accounted for up to 60% of total plot P export, with the majority occurring in a soluble bioavailable form during the first storm event. Initial P concentrations in runoff were in proportion to the amount of slurry P applied and significantly lower where rainfall was delayed after application. In one year, splitting the slurry application (3 × 10 kg ha^?1) reduced total P export by 25% compared to a single surface application (30 kg P ha^?1). In two years, incorporation of slurry, either by ploughing, or by tine cultivation, reduced the amount of overland flow by 50%, and the amount of P export by up to 60%, compared to the surface‐applied slurry treatments. Timeliness of slurry spreading to avoid periods of wet weather and simple cultivation of maize fields after harvest are practical and effective options to minimize SS and P transfer in land runoff from maize fields. The results also draw attention to the need to grow maize, and apply slurry to fields with a low P loss risk.     

Phosphorus and Suspended Sediment Loads in Base-Flow and Runoff Events: A Case Study of a Small Stream in NW Spain

This study focuses on the role of runoff events in influencing concentrations and export of suspended sediments and phosphorus in a headwater stream draining an agroforestry catchment in northwestern Spain. Large differences exist between suspended sediment and phosphorus (P) concentrations measured during base-flow conditions and runoff events, with a higher delivery during runoff events. Suspended sediment and phosphorus exports were 29.44 and 0.08 kg ha^?1 y^?1 respectively, with more than 50% delivered during runoff events (12% of the year). The relative contributions of phosphorus forms to the total annual export were 75% and 25% as particulate and dissolved phosphorus, respectively. Soil erosion is the main source of suspended sediment and phosphorus in the stream.     

Phosphorus losses from two representative small catchments in the Mediterranean part of Spain

Purpose

Information about phosphorus (P) losses from agricultural catchments in Mediterranean environments is scarce. In this work, P losses in overland flow from two representative small Mediterranean catchments, one dominated by Alfisols and the other by Vertisols, were studied.

Materials and methods

At the lowest level of each catchment, overland flow was measured and several runoff samples taken in each runoff event during two growing seasons (2001–2002 and 2002–2003). After centrifugation, total P in sediments and total and molybdate reactive P in supernatant were determined. Different chemical extraction methods were used to quantify the forms of P in soils and sediments.

Results and discussion

Total P losses in the studied catchments ranged between 0.5 and 3.2 kg ha^?1 year^?1, losses higher than 2 kg P ha^?1 being observed in one event. Phosphorus was mainly lost in the sediments, the ratio of total dissolved P to particulate P being higher in the Alfisol than in the Vertisol catchment. Phosphorus concentration in sediments from the Vertisol catchment was similar to that in the source soils, whereas sediments in the Alfisol catchment had 2.1 times more inorganic P and 9 times more organic P (OP) than the source soils. In the latter catchment, there was an enrichment in the more labile inorganic P forms in the sediments relative to the source soils, which corresponds to a relative enrichment in iron (Fe) oxides by a factor of 2.4. Alfisols had lower TP contents and exhibited lower erosion rates than Vertisols in the studied period but they posed a greater environmental risk than the latter soils because their sediments were richer in P and had a higher proportion of P in forms bound to the Fe oxides compared to the source soils—these P forms can be easily released with the onset of reducing conditions at the bottom of waterbodies.

Conclusions

A study of the P enrichment ratios and the dominant P forms in eroded sediments is therefore necessary to predict the impact of P losses from soils on the ecological quality of waterbodies.     

Nutrient,Sediment, and Bacterial Losses in Overland Flow from Pasture and Cropping Soils Following Cattle Dung Deposition

Abstract

The loss of phosphorus (P), suspended sediment (SS), ammonia (NH₄ ⁺‐N), nitrate (NO₃ ^?‐N), and Escherichia coli in overland flow (OF) from dairy cattle dung can impair surface water quality. However, the risk of P and N loss from grazed pastures varies with time. Current practice in southern New Zealand is to select a field, cultivate, sow in Brassica spp., and graze in winter to save remaining pasture from damage. This deposits dung when soil is wet and OF likely. Hence, we determined P, NH₄ ⁺‐N, NO₃ ^?‐N, and E. coli loss from dung in OF via simulated rainfall from intact grazed pasture and cropland treatments of a soil. Analysis of OF, 0, 1, 4, 11, 24, and 43 days after dung deposition at the upslope end of soil boxes indicated that total P (TP), NH₄ ⁺‐N, and SS concentrations decreased sharply from day zero and leveled out after 11 days. More particulate P and SS were lost from the cultivated than pasture treatment, whereas the reverse occurred for dissolved organic P because of greater sorption of phytase active materials. Escherichia coli losses were high (1×10⁵ 100 mL^?1) in both treatments throughout. Using the equations of fit in an example field site indicated that management of dung deposition could affect up to 25–33% of TP lost in OF.     

Surface and Subsurface Phosphorus Losses from Sugarcane Fields with Different Management Practices

Phosphorus losses in runoff from sugarcane fields can contribute to non-point source pollution of surface and subsurface waters. The objective of this study was to evaluate the effects of three different management practices on P losses in surface runoff and subsurface leaching from sugarcane (Saccharum officinarum L.) fields. Field experiments with treatments including conventional burning (CB), compost application with burning (COMB), and remaining green cane trash blanketing (GCTB) treatments were carried out to assess these management practice effects on P losses from sugarcane fields. In the CB treatment, sugarcane residue was burned after harvest. The COMB treatment consisted of compost applied at ??off bar?? with sugarcane residue burned immediately after harvest. Compost was applied in the amount of 13.4 Mg ha^?1 annually, 8 weeks before planting. In the GCTB treatment, sugarcane residue was raked off from the row tops and remained in the wheel furrow after harvest. Surface runoff was collected with automatic refrigerated samplers, and subsurface leachate was collected with pan lysimeters over a period of 3 years. Measured concentrations of total P (TP), dissolved reactive P (DRP), and particulate P (PP) in surface runoff from the COMB treatment were significantly higher than concentrations from the CB and GCTB treatments. The mean losses of P (TP and DRP) after burning (postharvest, years 2 and 3) were significantly greater than the no-burn treatment (preharvest, year 1) in the CB, COMB, and CB/COMB/GCTB combined options. Additionally, the mean losses of total suspended solid and total combustible solids in residue burning were, on average, 2.7 and 2.2 times higher than the no-burn practices, respectively (preharvest and GCTB treatment). Annual P losses from surface runoff in the third year of study were 12.90%, 6.86%, and 10.23% of applied P in CB, COMB, and GCTB treatments, respectively. However, the percent of annual DRP losses from applied P in COMB and GCTB treatments was similar magnitude, and their values were less than 50% compared to the value from CB treatment. In the leaching study, percent of monthly mean TP and DRP losses in the COMB and GCTB treatments were greatly reduced. Based on these results, the COMB and GCTB procedures were equally recommended as sugarcane management practices that improve water quality in both surface runoff and subsurface leachate.     

绍兴平原水稻田表层及次表层的排水中磷的浓度及形态

Phosphorus (P) is the limiting factor for eutrophication in most freshwater ecosystems. In China, Ptransported from intensively cultivated land has been reported as an important source of P in surface waters.In this study, we investigated P concentration and forms in surface and subsurface drainage from wetland ricefields in the Shaoxing plain, Zhejiang Province, China. From selected rice fields, surface drainage sampleswere collected at rice-growing, non-growing and fertilization periods, and subsurface drainage samples atdrought and rewetting (irrigation or precipitation after 5～10 d drought period in the surface soils) and wet(drainage under long-term wet soil condition) periods. Water samples were characterized for their totalreactive P (TRP), dissolved reactive P (DRP) and particulate reactive P (PRP). Concentrations of the TRPand DRP in the surface drainage ranged from 0.08 to 1.50 and 0.06 to 1.27 mg L-1, respectively. The TRPand DRP were dependent on field operation activities, and decreased in the order of fertilization period ＞rice-growing period ＞ non-growing period. Phosphorus concentration of runoff receiving P fertilizer can bean environmental concern. The PRP concentration in the surface drainage, ranging from 0.01 to 0.57 mgL-1, accounted for 8%～78% of the TRP. Concentration of the TRP in the subsurface drainage was from0.026 to 0.090 mg L-1, consisting of 29%～90 % of the DRP and 10%～71% of the PRP. In the droughtand rewetting period, the PRP accounted for, on average, 63% of the TRP, much higher than in the wetperiod (23%), suggesting that there was transport of P in preferential flow during drainage events after ashort-term drought period in the surface soils. Therefore, P losses in particulate form may be importantin the subsurface drainage from rice fields when surface soils form cracks and favor rapid flow downwardthrough the soil profiles, suggesting the important role of water-dispersible colloid particles in mediating andco-transporting P in the subsurface drainage of rice fields.     

Management options to decrease phosphorus and sediment losses from irrigated cropland grazed by cattle and sheep

In southern New Zealand, grazing of forage crops is common practice to satisfy feed requirements of animals in winter when pasture growth is limited. This practice has been shown to cause soil physical damage and increased loss of surface water contaminants sediment and phosphorus (P) to water bodies. Strategies to mitigate the loss of sediment and P were trialled on a Pallic soil type (Aeric Fragiaquept) in the North Otago Rolling Downlands of New Zealand. All sites were irrigated and measurements were made of losses in overland and sub‐surface flow from intensive cattle or sheep grazed, winter forage crops, and sheep grazed pasture. Two mitigations (restricted grazing of crop to three hours and the application of aluminium sulphate) were assessed for their potential to decrease contaminant loss from cropland. Volumes of surface runoff and loss of total P, filterable reactive P and sediment showed significant differences (P < 0.05) between the control treatments (i.e. no mitigation) with cattle crop (88 mm surface runoff) > sheep crop (67 mm) > sheep pasture (33 mm). The contribution of irrigation water to overland flow water, as a result of saturation‐excess conditions, varied between treatments with more loss under cattle crop (20% of total) compared with sheep crop (15%) and sheep pasture (11%). These differences are probably an effect of soil physical condition and highlight the importance of accurate irrigation scheduling to keep soil moisture below field capacity. Restricted winter grazing and alum application after grazing significantly (P < 0.05) decreased P losses in surface runoff under cattle (from 1.4 to 0.9 kg P/ha) and sheep (from 1.0 to 0.7 kg/P/ha) grazed crop plots by about 30%. In cattle grazed plots, restricted grazing also decreased suspended sediments (SS) by 60%. The use of restricted grazing is suggested as a means of decreasing P and SS loss from grazed winter forage crops. The use of alum shows some promise for decreasing P losses, but requires further work to determine its long‐term effectiveness and use in other soils and management regimes.     

Enhancing the P trapping of pasture filter strips: successes and pitfalls in the use of water supply residue and polyacrylamide

In intensive pastoral systems the landscape at ground level is clad in dense, filtering vegetation – yet phosphorus losses in overland flow do occur, and pollution of surface waters is a serious consequence. The use of pre‐applied polyacrylamide (PAM) or chitosan to trap particulate phosphorus (PP) and P‐sorbing potable water treatment alum residue (PWTR) to enhance vegetative filtering effects is examined here using field and laboratory overland flow simulation (flows from 0.43 to 0.34 litres s^?1 (m width)^?1) and analysis. Fitted equations suggest that up to 40% of dissolved reactive P applied (0.75 mg P litre^?1) in overland flow could be captured in a flow length of 2.1 m (1 kg PWTR m^?2). Unfortunately, drying decreased PWTR effectiveness, though little of the P captured was readily desorbed. This effect did not appear to be the result of gibbsite formation. Compared with the other treatments, there was a strong treatment effect of pre‐applied PAM on the change in PP losses (P < 0.001) over time, though evidence suggests the PAM effect declined during a 44 minute flow period. We showed that the investigated two‐pronged approach to the enhancement of the effectiveness of P trapping by pasture had limitations. Laboratory sheet‐flow simulations suggest that a field‐stable P sorber with sorption characteristics similar to those of the un‐dried PWTR could be an effective retention enhancer for dissolved P. Pre‐applied PAM can have an effect on particulate‐P trapping but was rapidly dissolved and removed by flow.     

Relationships between Phosphorus and Suspended Sediment Concentrations in a Stream Draining a Rural Area in NW Spain

This study assesses the possible use of suspended sediment as an indirect measurement of phosphorus (P) concentrations in a rural headwater catchment located in NW Spain. Particulate P accounted for about 70 percent of the P export, indicating that P transport is linked to sediment in this catchment. The relationship between P and suspended sediment concentrations showed that particulate P was strongly dependent on suspended sediment, although the relationship is not consistent throughout seasons. The particulate P–suspended sediment relationship behaved differently at low flow and runoff events; the relationship was only significant during runoff events. This is because low flow is dominated by dissolved P and by pathways that do not mobilize or transport sediment. The particulate P–suspended sediment ratio was lower during runoff events than during low flow, which is consistent with enrichment ratio effects.     

Evaluation of chemical amendments to control phosphorus losses from dairy slurry

Land application of dairy slurry can result in incidental losses of phosphorus (P) to runoff in addition to increased loss of P from soil as a result of a buildup in soil test P (STP). An agitator test was used to identify the most effective amendments to reduce dissolved reactive phosphorus (DRP) loss from the soil surface after land application of chemically amended dairy cattle slurry. This test involved adding slurry mixed with various amendments (mixed in a beaker using a jar test flocculator at 100 rpm), to intact soil samples at approximate field capacity. Slurry/amended slurry was applied with a spatula, submerged with overlying water and then mixed to simulate overland flow. In order of effectiveness, at optimum application rates, ferric chloride (FeCl₂) reduced the DRP in overlying water by 88%, aluminium chloride (AlCl₂) by 87%, alum (Al₂(SO₄)₃·nH₂O) by 83%, lime by 81%, aluminium water treatment residuals (Al‐WTR; sieved to <2 mm) by 77%, flyash by 72%, flue gas desulphurization by‐product by 72% and Al‐WTR sludge by 71%. Ferric chloride (€4.82/m³ treated slurry) was the most cost‐effective chemical amendment. However, Al compounds are preferred owing to stability of Al–P compared with Fe–P bonds. Alum is less expensive than AlCl₂ (€6.67/m³), but the risk of effervescence needs further investigation at field‐scale. Phosphorus sorbing materials (PSM) were not as efficient as chemicals in reducing DRP in overlying water. The amendments all reduced P loss from dairy slurry, but the feasibility of these amendments may be limited because of the cost of treatment.     

Transport and Retention of Phosphorus Pollutants in the Landscape with a Traditional,Multipond System

The landscape structure of a multipond system, runoff type andP-pollutant transport in an experimental watershed was studiedduring 1995 and 1998. A multipond system is a wetland system composed with many tiny ponds and ditches. In this watershed, it was found that such a system effectively controls the hydrological process through its huge storage capacity. The multipond system has a high interaction of land/water ecotones,which decreases the flow velocity systematically and results ina high sedimentation of the particulate matters.The multipond system intercepts runoff and creates either continuous or discontinuous flow. The retention efficiency of the system was very high in both cases but differed in nature. During continuous runoff on 1 May 1998, in a subwatershed Baojiatang, the retention rates of water, total phosphorus (TP),dissolved phosphorus (DP) and suspended solids (SS) by the multipond system were 83.0, 93.9, 90.9 and 94.9%, respectively.During discontinuous runoff on 29 June 1998, runoff volume generated from all lands was 1841 m³, but no surface waterwas exported and the system retention rates of TP, DP and SS were nearly complete. The removal of particulate phosphorus bythe system was more effective than removal of DP and thus DP wasthe main form of phosphorus exported from the watershed duringcontinuous flow. Because of such control, the export amount ofphosphorus was greatly reduced. The output of TP and DP was 0.013 and 0.012 kg ha^-1, respectively, from Liuchahe watershed in 1995, and they were 0.037 and 0.030 kg ha^-1 in 1998 correspondingly.     

Measuring Water-Extractable Phosphorus in Manures to Predict Phosphorus Concentrations in Runoff

Water-extractable phosphorus (WEP) in manures can influence the risk of phosphorus (P) losses in runoff when manures are land applied. We evaluated several manure handling and extraction variables to develop an extraction procedure for WEP that will minimize pre-analysis manure-sample-handling effects on WEP measurements. We also related manure WEP determinations to runoff dissolved reactive phosphorus (DRP) concentrations found in previously conducted field simulated rainfall experiments using the same manures to evaluate WEP as a predictor of P runoff losses. Dairy and poultry manure WEP concentrations increased with manure-to-water extraction ratio and shaking time. Relative to fresh manures, drying and grinding dairy manures before analysis usually decreased WEP concentrations, while WEP in poultry manures was often increased. Pre-analysis handling effects on WEP were minimized at the 1:1000 extraction ratio with a 1-h shaking time. Relationships between manure WEP and runoff DRP concentrations were strongly influenced by season of year and WEP extraction procedure. The best prediction of DRP concentration in spring runoff experiments was with manure WEP concentration at the 1:1000 extraction ratio. With fall runoff studies, DRP concentrations were best predicted with WEP application rate rather than concentration. These seasonal differences can be explained by the greater percentage of rainfall that ran off in the fall compared to the spring. For all studies, runoff DRP concentrations were strongly related (r² = 0.82) to the ratio of runoff to rainfall volumes, confirming that models need to take runoff hydrology into account as well as manure WEP in P-loss risk assessments.     

Potential phosphorus leaching from sandy topsoils with different fertilizer histories before and after application of pig slurry

This study investigated the effects of historical long‐term and recent single applications of pig slurry on phosphorus (P) leaching from intact columns of two sandy topsoils (Mellby and Böslid). The soils had similar physical properties, but different soil P status (ammonium lactate‐extractable P; P‐AL) and degree of P saturation (DPS‐AL). Mellby had P‐AL of 220–280 mg/kg and DPS‐AL of 32–42%, which was higher than for Böslid (P‐AL 140 mg/kg and DPS 21%). The study investigated the effects since 1983 of four treatments with different fertilizer histories, in summary high (HighSlurryMellby) and low (LowSlurryMellby) rates of pig slurry and mineral P (MinMellby) applications at Mellby and mineral P application at Böslid (MinBöslid). The columns were irrigated in the laboratory five times before and five times after a single application of pig slurry (22 kg P/ha). Concentrations of dissolved reactive P (DRP), dissolved organic P and total‐P (TP) in leachate and loads were significantly higher (P < 0.005) from the treatments at Mellby than those at Böslid. TP concentrations followed the trend: HighSlurryMellby (0.57–0.59 mg/L) > MinMellby (0.41–0.49 mg/L) > LowSlurryMellby (0.31–0.36 mg/L) > MinBöslid (0.14–0.15 mg/L), both before and after the single slurry application. DRP concentrations in leachate were positively correlated with DPS‐AL values in the topsoil (R² = 0.95, P < 0.0001) and increased with greater DPS‐AL values after the single slurry application (R² = 0.79, P < 0.0001). Thus, DPS‐AL can be an appropriate indicator of P leaching risk from sandy soils. Moreover, the build‐up of soil P because of long‐term repeated manure applications seems to be more important for potential P losses than a single manure application.     

Oscillation of Three Phosphorus Forms and Suspended Solids Content from 1999 to 2007 in a Spanish Agroforestry Catchment under Atlantic Climate

Phosphorus (P) transfers may accelerate water eutrophication to waters. Increasing awareness of the role of diffuse P sources motivates land managers in different regions of Europe to undertake conservation programs that place emphasis not only on soil conservation but also on water quality and eutrophication risk. Fertilizer applications and wastes are the main sources of dissolved P in Galicia and in the Atlantic regions of Spain. The aim of this study was to assess the temporal changes in concentration of total P (TP), sedimentary P (SP), and total dissolved P (TDP) and suspended solids at the outlet of an agroforestry catchment located in northwestern Spain. The study datasets range from January 1999 to December 2007, with 992 water samples collected. The water-collection strategy was a stratified point sampling involving more frequent collections when flow was high. Phosphorus contents were assessed by inductively coupled plasma (ICP)–mass spectroscopy (MS), and suspended solids were measured by filtration. The content ranges of the different studied P forms and suspended solids were as follows: TDP between 1 and 672 mg L^?1, SP between 1 and 1064 mg L^?1, TP between 1 and 1111 mg L^?1, and suspended solids between 1 and 1044 mg L^?1. A few events of intense precipitation with peaks of TP greater than 200 mg L^?1 and in some cases even more than 1000 mg L^?1 were responsible for most of the P losses in the catchment studied. TP and SP, TP and suspended solids, and SP and suspended solids showed highly significant correlations during the entire study period, evidencing the erosive origin of P in this catchment.     

Predicting environmental soil phosphorus limits for dissolved reactive phosphorus loss

The dependence of runoff dissolved reactive phosphorus (DRP) loss on soil test P or rapid estimations of degree of P saturation (DPS) often varies with soil types. It is not clear whether the soil‐specific nature of runoff DRP versus DPS is due to the different sorption characteristics of individual soils or the inability of these rapid DPS estimates to accurately reflect the actual soil P saturation status. This study aimed to assess environmental measures of soil P that could serve as reliable predictors of runoff DRP concentration by using soils collected from Ontario, Canada, that cover a range of chemical and physical properties. A P sorption study was conducted using the Langmuir equation  to describe amount of P sorbed or desorbed by the soil (Q_s, mg/kg) versus equilibrium P concentration (C, mg/L) in solution, where Q_max is P sorption maximum (mg/kg), k represents P sorption strength (L/mg), and Q₀ (mg/kg) is the P sorbed to soil prior to analysis. Runoff DRP concentration increased linearly with increasing DPS_sorp (i.e. the ratio of (Q₀ + Q_D)/Q_max) following a common slope value amongst soil types, while the P buffering capacity (PBC₀) at C = C₀ yielded a common change point, below which runoff DRP concentration decreased greatly with increasing PBC₀ compared to that above the change point, where C₀ and Q_D represent the equilibrium P concentration and amount of P desorbed, respectively. Both DPS_sorp and PBC₀ showed great promises as indicators of runoff DRP concentration.     

The effect of soil phosphorus on particulate phosphorus in land runoff

Accumulation of surplus phosphorus (P) in the soil and the resulting increased transport of P in land runoff contribute to freshwater eutrophication. The effects of increasing soil P (19–194 mg Olsen‐P (OP) kg⁻¹) on the concentrations of particulate P (PP), and sorption properties (Q_max, k and EPCo) of suspended solids (SS) in overland flow from 15 unreplicated field plots established on a dispersive arable soil were measured over three monitoring periods under natural rainfall. Concentrations of PP in plot runoff increased linearly at a rate of 2.6 μg litre⁻¹ per mg OP kg⁻¹ of soil, but this rate was approximately 50% of the rate of increase in dissolved P (< 0.45 μm). Concentrations of SS in runoff were similar across all plots and contained a greater P sorption capacity (mean + 57%) than the soil because of enrichment with fine silt and clay (0.45–20 μm). As soil P increased, the P enrichment ratio of the SS declined exponentially, and the values of P saturation (P_sat; 15–42%) and equilibrium P concentration (EPCo; 0.7–5.5 mg litre⁻¹) in the SS fell within narrower ranges compared with the soils (6–74% and 0.1–10 mg litre⁻¹, respectively). When OP was < 100 mg kg⁻¹, P_sat and EPCo values in the SS were smaller than those in the soil and vice‐versa, suggesting that eroding particles from soils with both average and high P fertility would release P on entering the local (Rosemaund) stream. Increasing soil OP from average to high P fertility increased the P content of the SS by approximately 10%, but had no significant (P > 0.05) effect on the P_sat, or EPCo, of the SS. Management options to reduce soil P status as a means of reducing P losses in land runoff and minimizing eutrophication risk may therefore have more limited effect than is currently assumed in catchment management.     

Effects of shelter belts on fence-line pacing of deer and associated impacts on water and soil quality

Sustainable land use for deer farming requires the maintenance of good soil and water quality, which can be adversely affected by fence‐line pacing. This study tested the hypothesis that the absence or presence of shelter belts (one or two) in paddocks decreases fence‐line pacing and associated soil and water quality impacts. Soils near the fence line and in the rest of the paddock, in paddocks containing zero, one or two shelter belts, were sampled for bulk density and macroporosity (pores >30 μm diameter). Large intact samples (1 × 0.2 × 0.1 m³) were used to generate overland flow via rainfall simulation. The flow was tested for nutrients [phosphorus (P) and nitrogen (N) fractions], suspended sediment (SS), and the faecal indicator bacteria, Escherichia coli. Results showed that bulk density, void volume, SS, particulate P and total P were affected by location (fence line or rest of paddock) but, along with all other measurements except E. coli, were not affected by the number of shelter belts. Thus, the inclusion of shelter had no effect on the concentration of contaminant lost in overland flow or any soil physical or hydrological parameter, but decreased the run‐off of E. coli. The lack of contrast between the location of soils can be partly attributed to the soil type (Brown, NZ soil classification, USDA Taxonomy: Typic Fragiudalf), which when compared with past studies was less erosive and lost less P into solution. Other factors may have been different management or the lesser impact of weaners compared with older hinds and stags on soil properties. Although only E. coli concentrations were decreased by the inclusion of shelter, factors such as improved production and animal welfare weigh heavily in favour of installing and maintaining shelter on deer farms. However, the environmental benefit of shelter should be tested in other farms where factors such as slope, soil, climate and farm management may increase the contrast with no shelter.     

Effectiveness of Grass Filters in Reducing Phosphorus and Sediment Runoff

Surface water contamination can often be reduced by passing runoff water through perennial grass filters. Research was conducted in 2006 to 2008 to evaluate the size of cool season grass filters consisting primarily of tall fescue (Festuca arundinacea Schreb) with some orchard grass (Dactylis glomerata L.) relative to drainage area size in reducing runoff sediment and phosphorus (P). The soil was Pohocco silt loam Typic Eutrochrepts with a median slope of 5.5?%. The grass filters occupying 1.1 and 4.3?% of the plot area were compared with no filter with four replications. The filters were planted in the V-shaped plot outlets which were 3.7?×?11.0?m in size. The filter effect on sediment and P concentration was determined from four natural runoff events when nearly all plots had runoff. Filter effect on runoff volume and contaminant load was determined using total runoff and composites of samples collected from 12 runoff events. Sediment concentration was reduced by 25?% with filters compared with no filter (from 1.10 to 1.47?g?L^?1), but P concentration was not affected. The 1.1 and 4.3?% filters, respectively, compared with having no grass filter, reduced: runoff volume by 54 and 79?%; sediment load by 67 and 84?% (357 to 58?kg?ha^?1); total P load by 68 and 76?% (0.58 to 0.14?kg?ha^?1); particulate P (PP) load by 66 and 82?% (0.39 to 0.07?kg?ha^?1); and dissolved reactive P (DRP) load by 73 and 66?% (0.2 to 0.07?kg?ha^?1), respectfully. A snowmelt runoff event had 56?% greater DRP concentration compared with rainfall-induced runoff events. Grass filters reduced sediment and P load largely by reducing runoff volume rather than reducing concentration. Well-designed and well-placed grass filters that occupy 1.0 to 1.5?% of the drainage area and intercept a uniform flow of runoff from a drainage area can reduce sediment and nutrient loss in runoff by greater than 50?%.