Long-term Continuous Measurements of SO2 Dry Deposition over the Speulder Forest

In 1990 a project to develop a dry deposition monitoring method of SO₂, NH₃ and NO₂ to Speulder forest in the Netherlands began. Detailed annual deposition fluxes for these gases were measured throughout November 1992 to December 1995. This paper describes the measurement set-up and the analysis of the deposition parameters for SO₂. The dry deposition velocity was usually smaller than the maximum V_d, showing a resistance to surface uptake, except for periods when the canopy is wet and surface resistance is negligible. Several methods were tested to estimate annual average fluxes from the gradient measurements. Annual fluxes were estimated by selecting the data for periods fulfilling gradient theory and extending the data by using an inferential method for the other periods. The surface resistance parametrisation used in the inferential method was tested using the selected data and was found to yield systematic larger fluxes of the order of 20%. Annual fluxes were 465 mol ha^-1 a^-1 in 1992/1993, 460 mol ha^-1 a^-1 in 1994 and 330 mol ha^-1 a^-1 in 1995. The uncertainty in the annual flux was estimated to be 25%. The annual average dry deposition velocity was 1.5 cm s^-1. No large differences were found in deposition parameters between each of the three years.     

Critical Loads of SO2 Dry Deposition and Their Exceedance in South China

The critical loads of SO₂ dry deposition in South China,which is transferred from critical level, as well the excess ofcritical loads are computed and mapped. The areas with thelowest critical load and the highest excess are, respectively,identified. The research is complementary to the previousresearches on critical loads for soils, and expected to beintegrated with them to make efficient sulfur emission abatement strategy.     

Fine Particle Dry Deposition onto a Cropland — a Trial to Estimate Deposition Velocity

The dry deposition velocity of fine particles is usually on the order of several tenths of cm s^?1, and accordingly, the concentration gradient of particles above the surface is very small. This makes the application of the gradient method to the determination of the particle deposition velocity very difficult. This study is a trial to find a way around this difficulty. The idea is to evaluate the thickness of the molecular diffusion layer, zb by simultaneously measuring the concentration gradient of gaseous species such as SO₂ ; zb is obtained by combining the turbulent and molecular transport equations for the gas. Then the particle deposition velocity is estimated on the basis of zb and the Brownian diffusion coefficient with an assumption that zb is equal to the thickness of the Brownian diffusion layer. By applying this method to the data collected in a field observation, the velocity of deposition onto a cropland was estimated for submicron particles.     

Simultaneous Determination of Gas and Particle Dry Deposition onto Conditioned Surrogate Surfaces

Aerodynamically designed surrogate surfaces were used to determine the relative importance of gaseous (SO₂, HNO₃, NH₃) and particulate species (SO₄ ^2?, NO₃ ^?, NH₄ ⁺, Ca²⁺) in the dry deposition flux. For 11 sampling periods, we measured the deposition fluxes, ambient gaseous concentrations, size distributions of atmospheric aerosols and some meteorological parameters in Uji. The dry deposition of the gas to a nearly perfect sink was calculated by subtracting the greased surface flux from the total deposition flux to both the greased and reagent impregnated (or water) surface. It was found that the gas phase deposition contributed significantly more (60–93%) than the particulate phase to overall deposition of sulfur and nitrogen compounds. The dry deposition velocities of the species were also calculated using the deposition fluxes and the measured ambient concentrations. Comparisons were made between the measured and modeled particulate deposition flux.     

A Case Study on Estimation of Dry Deposition of Sulfur and Nitrogen Compounds by Inferential Method

In order to estimate dry deposition, deposition velocity calculation and concentration measurement were carried out in Niigata, Japan. Deposition velocities of SO₂ and HNO₃ for some surfaces such as coniferous forest, deciduous forest, agricultural land, and water were calculated taking into account diurnal variations of meteorological elements using routine meteorological data. Deposition velocities of fine and coarse aerosols were also estimated respectively. Concentrations of SO₂, HNO₃, sulfate and nitrate in fine and coarse aerosols respectively were measured from July to December in 1998 using filter pack and denuder methods. The results indicate that HNO₃ dry deposition for the high aerodynamic roughness surfaces such as forests is quite large. It is suggested that sulfate and nitrate aerosols depositions as well as the gases depositions should be taken into account to estimate dry deposition of sulfur and nitrogen compounds. It is also indicated that dry depositions of sulfur and nitrogen compounds are unable to ignore compared with their wet depositions.     

陇东黄土高原塬区冬小麦干物质增长规律分析

用Logistic生长曲线对陇东黄土高原塬区冬小麦干物质积累进行不同气候年型的模拟分析表明：干物质积累在拔节后到乳熟期呈直线递增趋势。增长速率最快时期在抽穗前后．呈单峰型曲线。在不同的气候年型下干物质累积量与降水量、日照时数、≥0℃积温的关系均达极显著水平，而干物质生长率仅在少雨年与气象要素呈显著关系，其它两种气候年型下相关不显著。     

Deposition Patterns of SO4 2−, NO3 − and H+ in the Brazilian Territory

SO₄ ^2?, NO₃ ^? and H⁺ depositions are estimated in the Brazilian territory based on the existing rainfall chemical data and on annual rainfall distribution over the whole territory. Local and regional depositions are estimated. Rainfall chemical data over the Braziliian territory shows that the average pH values are usually low (between 4.0 and 5.5). These values are observed in the tropical Amazon forest as well as in urban areas. However, the rainwater acidity in the tropical forests are due to organic acids naturally produced by the vegetation while in urban areas the acidity is mainly due to acidic anion deposition (NO₃ ^? and SO₄ ^2?). In some Amazonian areas, the average input values through rainfall for NO₃ ^? is about 0.06 keq.ha.yr^?1 and for SO₄ ^2? is between 0.23 and 0.54 keq.ha^?1.yr^?1. On the other hand, in some urban centers, such as São Paulo, values of .072 keq.ha^?1.yr^?1 for NO₃ ^? and 1.16 keq.ha^?1.yr^?1 of SO₄ ^2? are found and in sites where sulfate sources (coal mining) are present, as for the area of Florianópolis, values as high as 5.59 keq.ha^?1.yr^?1 for SO₄ ^2? are found.     

Dry deposition velocity estimates of SO2 from models and measurements over a deciduous forest in winter

Measurements were made of concentrations and vertical flux densities (using the eddy correlation technique) for SO₂ over a deciduous forest during March and April 1990. These were compared with estimates of dry deposition velocities, obtained from resistance analogue models that employ measured meteorological data as input. The models include: (1) the dry deposition module that forms part of a larger Eulerian air quality model, known as ADOM (Acid Deposition and Oxidant Model), (2) a modified version of ADOM and (3) a new parameterization for R _c . The observations yielded V _d values of about 0.5 cm s^?1 for the daytime and 0.1 cm s^?1 at night. ADOM's estimates were much larger, averaging about 3.0 cm s^?1 during the daytime and about 2.0 cm s^?1 at night. When the ADOM canopy resistance was increased by modifying its formulation, the modified dry deposition estimates were slightly larger during the day than at night, averaging about 0.5 cm s^?1. The new parameterization for R _c yielded smaller V _d estimates with no diurnal variation. An attempt is made to relate the observed diurnal cycle of the dry deposition velocity to meteorological parameters.     

Statistical Modeling of Phosphorus Dry Deposition Rates Measured in South Florida

Dry deposition may be a substantial source ofphosphorus (P) to the Florida Everglades. Drydeposition has been measured on a weekly basis in theregion since 1987, but a significant amount of thisdata is missing (about 34%) due to instrumentalfailures and sample contamination. This study developsa statistical model of the P dry depositiontime-series to estimate missing data. The model isbased on a multivariate stochastic time-series theory.Model parameters are calibrated using theexpectation-maximization algorithm which is efficientfor data sets with many gaps. The pooled mean andstandard deviation of the data before estimating themissing values was 88.4±85.7 μg P m^-2d^-1 and after estimating the missing values was87.8±82.4 μg P m^-2 d^-1. Modelverification demonstrates that the calibrated modelsprovide unbiased data estimates while preserving thestatistics of the raw data. For each sampling site themean and standard deviation before and after werequite similar. No trend with time was detected. The Pdeposition fluctuates seasonally (highest in Octoberand lowest in June), but this fluctuation does notfollow the seasonal pattern of Florida's rainfall. Random noise in the data, however, is significant andcauses long-term fluctuations of the data. The datawith gaps filled in are useful for computing theweekly P load distribution.     

Simulation of Dry Deposition Rates of Acidic Pollutants—An Assessment of Deposition Pathways in Hiroshima, Japan

A eulerian grid photochemical transport and dispersion model was used to simulate the dry deposition rates of nitrogen (as HNO₃) and sulfur (as SO₂) in Hiroshima, west Japan. Seasonal patterns of predicted dry deposition fluxes reveal that HNO₃ is most prevalent at more remote locations while SO₂ is deposited near to and slightly downwind from the major emission sources. The predicted dry deposition rates of HNO₃ and SO₂ were compared to the values measured at Mt. Gokurakuji (located in Hatsukaichi) and in Hiroshima City. The simulation results show that the model under-predicted (about 44% and 80%, respectively) both nitrogen and sulfur deposition rates at Mt. Gokurakuji and in Hiroshima City, indicating that the acid deposition in Hiroshima prefecture is possibly affected by long-range transboundary transport of acidic pollutants. Comparison of wet to dry deposition ratios (4.5 and 8.7 for nitrogen and 4.6 and 7.0 for sulfur) from the two observation sites above indicates that wet deposition maybe the most important acid deposition pathway in Hiroshima, Japan.     

黄土高原旱地农业防春旱措施研究初报

针对春旱是影响黄土高原农业生产的主要气象灾害的实际,通过多处理田间试验,研究了主要作物冬麦,玉米防春旱措施。经统计检验,得到在严重干旱年份,防春旱效果好的有效措施,明显提高了降水利用效率。     

Impacts of (NH4)2SO4 Deposition on Norway Spruce (Picea Abies [L.] Karst) Roots

The effects of enhanced (NH₄)₂SO₄ (NS) deposition on Norway spruce (Picea abies [L.] Karst) fine root biomass, vitality and chemistry were investigated using root-free in-growth cores reproducing native organic and mineral soil horizons. The cores were covered and watered every 2 weeks with native throughfall or throughfall supplemented with NS to increase deposition by 75 kg ha^-1 a^-1 NH₄ ⁺-N (86 kg ha^-1 a^-1 SO₄2--S). The in-growth cores were sampled after 19 months and assessed for root biomass, necromass, length, tip number, tip vitality and fine root chemistry. Root biomass and fine root aluminium (Al) concentration were negatively correlated, but NS deposition had no effect on root growth or root tip vitality. NS deposition caused increased fine root nitrogen (N) concentrations in the organic horizon and increased Calcium (Ca) concentrations in the mineral horizon. Fine root biomass was higher in the organic horizon, where fine root Al and potassium (K) concentrations were lower and Ca concentrations higher than in the mineral horizon. Results highlighted the importance of soil stratification on fine root growth and chemical composition.     

Dry Deposition of Sulphur at a High-Altitude Background Station in South Africa

Water, Air, &; Soil Pollution - The inferential method is applied to estimate dry deposition rates of sulphur at a remote rural site on the South African south-eastern escarpment. Two 2-week...     

黄土滑坡研究现状综述

黄土滑坡是我国黄土地区发育的一种斜 (边 )坡表生地质灾害 ,近年来我国科研工作者加强了对该类滑坡的研究。介绍了国内外在滑坡类型划分、形成机理、滑带土及防治措施等方面所取得的研究成果及其进展 ,指出了目前我国在滑坡防治方面存在的问题与不足     

Inhibitory effects of SO2 on biofiltration of aldehydes

Biofiltration is a suitable method for eliminating volatile biodegradable organic chemical from waste gases. However, if substances inhibiting microbiological activity are present in the waste gas, biofiltration efficiencies will be poor. Results are presented on inhibition of biofiltration by SO₂. Inhibition was observed first in a pilot scale experiment on odor abatement in a food processing factory. Then it was shown in laboratory scale experiments that SO₂. concentrations less than 10 ppm have no measurable effect. A concentration of 40 ppm results in 60% inhibition but original efficiency can be restored when the SO₂ supply is shut off. A concentration of 100 PPM of SO₂ results in complete and permanent inhibition.     

黄土颗粒分离方法试验研究

以延安新区I期工程的马兰黄土为研究对象,分别采用筛分法、离心机法和静水沉降法对其进行颗粒分离试验,并利用激光粒度仪对3种分离方法的试验结果进行跟踪对比,以研究最适用于黄土颗粒的分离方法。结果表明:筛分法主要适用于粒径大于0.05mm的黄土颗粒的分离,对粒径小于0.05mm的黄土颗粒分离效果较差,筛分结果的可靠性偏低。离心机法由于自身的局限性且受影响因素较多,试验结果的可靠性较低;静水沉降法主要适用于粒径小于0.05mm的黄土颗粒的分离,颗粒分级效果显著,试验结果的可靠性较高,且试验精度满足要求,但对于粒径小于0.002mm的颗粒分离时间较长。通过3种试验方法的对比可知,在对黄土进行颗粒分离试验时,宜采用筛分—沉降相结合的分离方法,对于大于0.05mm的颗粒宜采用筛分,对于小于0.05mm的颗粒宜采用静水沉降法。     

Fine and Coarse Ionic Aerosol Components in Relation to Wet and Dry Deposition

The distribution of acidic andalkaline constituents (SO₄ ^2-,NO₃ ^-, Cl^-, NH₄ ⁺, Na⁺,K⁺, Ca²⁺) between the fine and coarseparticle range has been examined in an urban locationin Thessaloniki, N. Greece over an 8-month period. The chemistry of wet and dry deposition collected overthe same period was also examined. Statisticalassociations between species within each environmentalphase were investigated using correlation analysis.Use of principal component analysis was made toinvestigate compositional similarities betweenaerosol, deposited dust and rain. It was found thatSO₄ followed by NO₃, NH₄ and Caprevailed in fine aerosol. Sulphates and Ca were alsothe prevailing ions in the coarse particle fraction.Wet deposition was found to be the dominant depositionmechanism for all species. The high dry depositionrates observed for Ca and SO₄ suggest that mostof the dry deposited sulphate is in the form ofCaSO₄. Scavenging ratios of ionic speciesassociated with coarse aerosol were higher than thecorresponding ratios for fine particles. Principalcomponent analysis suggested that variations in ioniccomposition of fine aerosol could be interpretedprimarily by gas-to-particle neutralization reactionsinvolving atmospheric ammonia. In contrast, theinteraction between SO₂ and HNO₃ with Cacompounds seems to be the most likely factor that canexplain variations in wet and dry deposition ioniccontents.     

Dry Deposition of Sulfur Containing Species to the Water Surface Sampler at Two Sites

Sulfate dry deposition increases the deteriorating effects on environment. Sulfate can be deposited from atmosphere to water via both particulate (SO₄ ² :sulfate)and a gas(SO ₂:sulfurdioxide)form.In this research, the fluxes of gaseous(SO ₂)and particulate(SO ₄ ²)species were measured employing a water surface sampler(WSS)and glass fiber filters(GFFs)ontheknife?edge surrogate surface(KSSs)in the campus of Uludag University and the city of Bursa, Turkey.Sampling program was conducte dinter mittently between September2004and March2005.Average to talsulfate fluxes measured with the WS Satthe Uludag University campus and in the city of Bursa were58 ± 41and235 ± 43?mgm ^?2 d ^?1, respectively.The to talsulfate fluxe smeasure dat Bursa were highe rand this was probably due to greater sulfur containing species in it satmosphere.The dry deposition of gas eous SO ² flux was calculated by sub tracting the particulate flux collected with the KSS s from the total flux(particulate sulfate plus SO ₂ flux)obtained by the WSS.Anautomatic SO ₂ analyzer was used concurrently to measure the ambient concentration of gas eous SO ₂. The average SO₂ gas fluxes and ambient SO ₂ concentrations were18 ± 28and54 ± 48?mgm ^?2 day ^?1 and11 ± 7and49 ± 14?μgm ^?3 for the campus and the city, respectively.The measured gaseous SO ₂ fluxes and ambient concentrations were used to calculate the mass transfer coefficient.The calculated MTC values for the campus and the city were0.8 ± 1.0and1.2 ± 1.1?cms ^?1, respectively.The sevalues wereinag reement with previously reported dry deposition velocities for SO ₂.     

Estimation of Dry Deposition by Using a Filter Pack Method at Chunchon, Korea

Atmospheric gases and particulates were collected using four-stage filter-pack in Chunchon from January through December in 1999. Particulate SO₄ ^2? and NO₃ ^?, and gaseous HNO₃, SO₂ and NH₃ were analyzed. Annual average concentration of SO₄ ^2?(S), NO₃ ^?(S), HNO₃ (g), SO₂(g) and NH₃(g) were 5.75µg/m³, 4.98µg/m³, 0.33ppb, 1.52ppb and 7.25ppb, respectively. Annual dry deposition fluxes were estimated using the measured concentration and dry deposition velocity published by other research group. Annual dry deposition of S was 287kg · (km)^?2·y^?1, which accounted for about 30% of total S deposition. For N deposition, dry deposition is predominant; about 70% of total N deposition was through dry process mostly as forms of NH₃ and HNO₃.     

Dependence of SO2 integrated exposure rates on SO2 concentration,wind velocity,temperature, and relative humidity

Integrated exposure rates for SO₂ of a standardized physico-chemical receptor and corresponding SO₂ concentrations and meteorological variables have been measured at various sites in the state of Northrhine Westphalia, Germany from 1982 to 1986. The dependence of exposure rates and deposition velocities of the receptor on SO₂ concentration and meteorological variables has been investigated within the framework of various regression models. A contribution of prime importance to exposure rates of the product of SO₂ concentrations and the square root of wind velocities averaged over exposure time has been established. The model explains 87% of variation. Deposition velocities for this receptor turn out to be of the order of 1 cm s ^?1. A corresponding regression model between deposition velocities and the square root of wind velocities unexpectedly explains only a minor amount of variation of this quantity.