The xenon record of extinct radioactivities in the Earth

Analyses of xenon from well gas rich in carbon dioxide reveal a large excess of radiogenic xenon-129 from the decay of extinct iodine-129. Smaller excesses observed in the heavy xenon isotopes are from fission. These results place narrow limits on any age difference between the earth and the oldest meteorites. The occurrence of excess radiogenic xenon-129 in well gas also suggests that any quantitative degassing of existing solid materials to form the atmosphere must have been limited to a very early period of the earth's history, approximately the first 10(8) years. Alternatively, this observation is consistent with a model of the earth's continuous, but still incomplete, degassing since its time of formation.     

Plutonium-fission xenon found in Earth's mantle

Data from mid-ocean ridge basalt glasses indicate that the short-lived radionuclide plutonium-244 that was present during an early stage of the development of the solar system is responsible for roughly 30 percent of the fissiogenic xenon excesses in the interior of Earth today. The rest of the fissiogenic xenon can be ascribed to the spontaneous fission of still live uranium-238. This result, in combination with the refined determination of xenon-129 excesses from extinct iodine-129, implies that the accretion of Earth was finished roughly 50 million to 70 million years after solar system formation and that the atmosphere was formed by mantle degassing.     

Isotopic composition of rare gases in lunar samples

Data from total melt and step-by-step heating experiments on the Apollo 11 lunar samples suggest a close affinity between lunar and meteoritic rare gases. Trapped neon-20/neon-22 ratios range from 11.5 to approximately 15, resembling those for the gas-rich meteorites. Trapped krypton and xenon in the lunar fines and in the carbonaceous chondrites are similar except for an interesting underabundance of the heavy isotopes in both lunar gases which suggests that the fission component found in carbonaceous chondrites is depleted in lunar material. Spallation gases are in most cases quite close to meteoritic spallation gases in isotopic composition.     

Plutonium-244: confirmation as an extinct radioactivity

The mass spectrum of xenon from spontaneous fission in a laboratory sample of plutonium-244 is precisely what meteoriticists predicted it would be; this discovery completes a web of proof that this nuclide is a bona fide extinct radioactivity of galactic origin, that r-process nucleosynthesis was ongoing in the galaxy at the time of the birth of the sun, and that the early meteoritic abundances of plutonium-244, heretofore tentative, can be utilized with confidence in models for the chronology of galactic nucleosynthesis. The search for an explanation for anomalous fission-like xenon in carbonaceous chondrites can now be narrowed.     

The atmosphere of Mars: detection of krypton and xenon

Krypton and xenon have been discovered in the martian atmosphere with the mass spectrometer on the second Viking lander. Krypton is more abundant than xenon. The relative abundances of the krypton isotopes appear normal, but the ratio of xenon-129 to xenon-132 is enhanced on Mars relative to the terrestrial value for this ratio. Some possible implications of these findings are discussed.     

Martian gases in an antarctic meteorite?

Significant abundances of trapped argon, krypton, and xenon have been measured in shock-altered phases of the achondritic meteorite Elephant Moraine 79001 from Antarctica. The relative elemental abundances, the high ratios of argon-40 to argon-36 (>/= 2000), and the high ratios of xenon-129 to xenon-132 (>/= 2.0) of the trapped gas more closely resemble Viking data for the martian atmosphere than data for noble gas components typically found in meteorites. These findings support earlier suggestions, made on the basis of geochemical evidence, that shergottites and related rare meteorites may have originated from the planet Mars.     

Airborne short-lived radionuclides of unknown origin in sweden in 1976

On five occasions during the first half of 1976 traces of neptunium-239 and molybdenum-99 were detected in southern Sweden. These activities were accompanied by small amounts of fission products such as iodine-131 and barium-140. One of the events was coincident in time with large peaks in the atmospheric tritium gas concentration.     

Ages, irradiation history, and chemical composition of lunar rocks from the sea of tranquillity

The (87)Rb-(87)Sr internal isochrons for five rocks yield an age of 3.65 +/-0.05 x 10(9) years which presumably dates the formation of the Sea of Tranquillity. Potassium-argon ages are consistent with this result. The soil has a model age of 4.5 x10(9) years, which is best regarded as the time of initial differentiation of the lunar crust. A peculiar rock fragment from the soil gave a model age of 4.44 x 10(9) years. Relative abundances of alkalis do not suggest differential volatilization. The irradiation history of lunar rocks is inferred from isotopic measurements of gadolinium, vanadium, and cosmogenic rare gases. Spallation xenon spectra exhibit a high and variable (131)Xe/(126)Xe ratio. No evidence for (129)I was found. The isotopic composition of solar-wind xenon is distinct from that of the atmosphere and of the average for carbonaceous chondrites, but the krypton composition appears similar to average carbonaceous chondrite krypton.     

Noble gases in stratospheric dust particles: confirmation of extraterrestrial origin

Noble gas elemental and isotopic ratios were measured in a group of 13 "chondritic" stratospheric dust particles. Neon and argon are present in "solar" proportions; xenon appears to be dominated by contributions from "planetary" sources. The apparent xenon concentration is higher than that measured in any bulk meteorite, approaching the concentration found in the noble gas-rich, acid-insoluble residues from carbonaceous chondrites.     

Neutron-induced fission of uranium: a dating method for lunar surface material

Volcanic glasses collected on the rim of Shorty Crater in the Apollo 17 area were formed 3.63 x 10(9) years ago. The amounts of xenon-136 produced by neutron-induced fission of uranium-235 indicate that the glasses resided on the lunar surface for about 38 million years before they were deeply buried. The glass spherules were reexcavated by the impact that formed Shorty Crater 17 million years ago, and remained undisturbed until they were collected.     

Noble Gases in the Murchison Meteorite: Possible Relics of s-Process Nucleosynthesis

The Murchison carbonaceous chondrite contains a new type of xenon component, enriched by up to 50 percent in five of the nine stable xenon isotopes, mass numbers 128 to 132. This component, comprising 5 x 10(-5) of the total xenon in the meteorite, is released at 1200 degrees to 1600 degrees C from a severely etched mineral fraction, and probably resides in some refractory mineral. Krypton shows a similar but smaller enrichment in the isotopes 80 and 82. Neon and helium released in the same interval also are quite anomalous, being highly enriched in the isotopes 22 and 3. These patterns are strongly suggestive of three nuclear processes believed to take place in red giants: the s process (neutron capture on a slow time scale), helium burning, and hydrogen shell burning. If this interpretation is correct, then primitive meteorites contain yet another kind of alien, presolar material: dust grains ejected from red giants.     

Iodine-129 in terrestrial ores

Xenon extracted from natural iodyrite (silver iodide) from Broken Hill, New South Wales, Australia, contains excess xenon-129 from the in situ decay of naturally occurring iodine-129 and excess xenon-128 from neutron capture on iodine-127. On the basis of the amount of radiogenic xenon-129, it is estimated that, prior to the nuclear age, terrestrial iodine contained an equilibrium ratio of iodine-129 to iodine-127 of between 3.3 x 10(-15) and 2.2 x 10(-15).     

Elements 112 to 119: were they present in meteorites?

Chondrites contain a small fission xenon component of unexplained origin. Evidence on the geochemical behavior of this component suggests that it was not derived from an actinide element (Z = 89 to 103), or from a transition metal between Z = 104 and 111, but from a more volatile progenitor. The most likely candidates are the superheavy elements between Z = 112 and 119, whose lighter congeners (mercury, tellurium, lead, and the like) are known to be strongly fractionated in meteorites.     

Spontaneous fission-neutron fission xenon: a new technique for dating geological events

A method for dating geological samples which uses fission product xenon in a manner similar to the use of radiogenic argon in the 40Ar-39Ar technique has been developed. The results of stepwise heating experiments for a zircon from the Ahaggar region in the Sahara are compared to the geochronology determined by the rubidiumstrontium, uranium-thorium-lead, and potassium-argon dating methods.     

Fallout from the Chinese nuclear explosion of 17 June 1967

Low-level activities of iodine-131, barium-140, and strontium-89 were found in a series of rain samples collected at Fayetteville, Arkansas, during the period from late June through August 1967. The ratios of these short-lived isotopes to strontium-90 were determined as accurately as possible. The data indicate that the debris from the Chinese nuclear explosion was injected primarily into the stratosphere.     

Xenon-133: ambient activity from nuclear power stations

The average activity of xenon-133 within and at approximately 100 kilometers from Albany, New York, from April to July 1975 was 2.6 picocuries per cubic meter of air. The source was gaseous effluents from boiling water reactors located in the northeastern United States. Its 5.29-day half-life makes xenon-133 an appropriate isotope to observe for the study of regional and hemispheric dispersion of pollutants.     

Exinct superheavy element in meteorites: attempted characterization

If the unexplained fission xenon component in meteorites is due to a volatile superheavy element, this element must have had a heat of vaporization of 54 +/- 3 kilocalories per mole and a normal boiling point of 2500 degrees +/- 400 degrees K. The prime candidates are elements 111 and 115, followed by 113, 114, 112, and 116. Elements 105 to 110 are not volatile enough and can therefore be excluded.     

Interhemispheric transport of atmospheric fission debris from French nuclear tests

Radioactive iodine-131 (half-life, 8.06 days) and barium-140 (half-life, 12.8 days), released into the atmosphere (21 degrees S, 137 degrees W) by the French nuclear tests conducted during the period 24 August to 8 September 1968, have been observed in rainfall at Arkadelphia, Arkansas (34 degrees N, 94 degrees W). The maximum time required for the transport of the debris from a mid-southern to a mid-northern latitude appears to be about 3 weeks.     

甲壳素包裹型缓释肥料养分释放特性研究

[目的]研究甲壳素包裹型缓释肥料(CCF)的养分释放特性。[方法]通过对CCF在30℃水中的进行释放试验,来描述其养分释放特性。[结果]结果表明,可将CCF的释放过程分为稳定阶段和衰退阶段;CCF在水中的溶出曲线为L型,且观察不到明显的滞后阶段;在稳定阶段,释放速率dMt/dt为一定值;在衰退阶段,释放速率随时间的延长而下降,且下降趋势逐渐缓慢,可以描述为dMt/dt=29.337t-1。[结论]CCF具有长效,缓释的作用,能够促进农作物的稳定生长,而实现作物的增产。     

不同氮肥类型对玉米产量和经济效益及氮肥利用率的影响

在大田试验条件下,采用随机区组设计了5个施氮水平,研究了不同类型尿素及用量对玉米干物质量、叶面积指数、籽粒产量、经济效益及氮肥利用率的影响。结果表明：包膜复合肥处理的开花前玉米的地上部干重、叶面积指数与常规尿素处理差异较小,开花后显著高于常规尿素处理,收获时其籽粒产量显著高于常规尿素处理。施包膜复合肥能显著提高玉米的籽粒产量、经济效益及氮肥利用率。