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1.
Initial marsh soil development from brackish sediments The initial marsh soil development from brackish sediments was investigated in a transect from the tidal flat to the dike in the southeast Dollart (Lower Saxony, Germany). Oxidized morphological features increased from the tidal flat to the dike. Simultaneously the bulk density increased from 0.57 g cm—3 to 1.12 g cm—3 and the water content decreased from 78.8 % to 54.9 %. The soils closest to the tidal flat were massive, those closest to the dike had a crumble structure. The clay/carbonate ratio increased slightly from 3.3 to 4.8 in the same succession as well as the C/N ratio from 13.9 to 15.6. Likewise the salinity decreased from 7.8 ‰ to 1.5 ‰ and the dominance of Na was replaced by Ca within the pool of exchangeable and soluble cations. The data indicate initial processes of marsh soil development: structure forming, settlement, aeration, salt and lime loss, decomposition and changing ratios of adsorbed cations. Similar to marine developments the soils will enter the terrestrial phase as carbonate containing soils not characterized by the brackish sedimentation conditions. For the initial development of today old marshland soils (”︁Kleimarshes”) from brackish sediments, in contrast, it is likely, that they were already free of carbonate when entering the terrestrial phase. This is explained by long‐term reduction and oxidation of sulfur and low sedimentation rates.  相似文献   

2.
On the genesis of tidal marsh soils I. The influence of sediment- and soil-structure The significance of sediment structure for soil structure has often been disregarded when discussing the properties and genesis of tidal marsh soils. After defening several terms that are often misinterpreted, three types of tidal-marsh-soils with different structure are described: 1 . the typical clayey tidal-marsh-soils with very various aggregate structures: The well aired and permeable “SEEMARSCH” (marine-tidal-marsh-soil) with polyhedral and prismatic structure, which is formed from the flaky “card-house” structure of marine sediments rich on salt; the densely paked “BRACKMARSCH” (brackish-tidal-marsh-soil), whose moisture is due to perched water, which coarse prismatic to columnar structure, which is formed from the mainly horizontally orientet structure of brackish sediments due to dispersion; the moderately permeable “FLUSSMARSCH” (tidal-river-marsh-soil), whose wetness is often due to groundwater, with medium to coarse prismatic structure, which is formed from the finely aggregated structure of perimarine tidal-river sediments; 2 . the tidal marsh soils poor in clay, rich in silt and very fine sand with coherent structure and low air porosity, due to a strong tendency towards puddling of the top soil by raindrops, causes the formation of “HAFTNÄSSEMARSCH” (marsh soil whose moisture is due to capillar water); 3 . the tidal-marsh-soils rich in plant remains, clay and with a high level of groundwater often extremly acid, with coherent structure, which formed the generally highly permeable “ORGANOMARSCH”. The conditions of formation of these soils and the soil parameters are discussed also.  相似文献   

3.
On the genesis of tidal marsh soils II. Carbonate sedimentation, decalcification A central problem of the tidal-marsh soils is the calcareous deposit of the parent material. On the basis of small-scale, systematic investigations it has been demonstrated in two “key areas” in the Weser tidal flats, that fluviatile and brackish soils are descended from calcareous or not-calcareous sediments. Soils buildet from calcareous sediments shows a low depth and a low rate of decalcification because of a high content of clay and bases as well a permanent high level of groundwater during the development of the soils.  相似文献   

4.
微咸水灌溉对斥水土壤水盐运移的影响   总被引:10,自引:4,他引:6  
土壤斥水性影响着作物的产量,为了研究微咸水灌溉对斥水土壤水盐运移的影响,进行了室内土柱微咸水入渗试验。对比了不同矿化度和斥水程度对两种土质水盐运移的影响,探讨了微咸水入渗后土壤斥水性的变化特征。结果表明,不斥水土壤的入渗能力随矿化度的增加而增加。亲水和斥水土壤的入渗率均可采用Kostiakov公式简单模拟。斥水土壤入渗能力在矿化度为1?g/L时达到最大,超过1?g/L后则随矿化度的增大而减小。微咸水入渗的累积入渗量与湿润锋推进距离呈良好的线性关系,斥水性土壤中的相同剖面水盐的含量比不斥水的减小。微咸水入渗后土壤产生了一定的斥水性。该研究表明微咸水灌溉对盐渍化土壤的水盐分布和斥水性均有一定程度的影响。  相似文献   

5.
Cesium and Strontium Exchange Properties of Marsh Soils The cesium and strontium exchange properties of some typical marsh soils of the estuary and lower river Weser region were described. Soil samples were taken according to the existing soil maps 1:25000 of Lower Saxony e.g. a “sea marsh soil”. a “brackish marsh soil”, and a “river marsh soil”. The exchange properties were determined by Cs/Ca and Sr/Ca exchange curves (Q/I relations) as generally used in soil potassium research. In addition to the Q/I relations the following investigations were carried out: - Cs and Sr desorption experiments (one time equilibration with Ca++ solutions) - Cs and Sr reexchange experiments (eight times equilibration with water, Ca++, Ba++, and K+ solutions) - the naturally-occuring Cs and Sr contents of the soils including amounts caused by imissions or fallout, respectively - clay mineral composition and swelling of layer silicates due to saturation with Ca++, Sr++, Cs+, and K+ ions. Q/I relations as well as desorption and reexchange experiments indicated strong cesium and low strontium fixation by the soils investigated. This was considered the reason for the stronger transfer of Sr from soil to plants as compared with Cs. Furthermore, the reexchange experiment revealed nearly complete reversibility of the Sr sorption reactions by equilibration with the divalent cations Ca++ and Ba++ and some Sr fixation after treatment with K+ solutions. However, cesium was much better reexchanged by K+ than by Ca++ and Ba++ ions. This led to the conclusion that Cs fixed in interlayer positions of clay minerals could be remobilized by potassium and ammonium fertilization. The naturally-occuring Cs contents of the soils were found to be below the detection limit of the analytical methods used. The contents of naturally-occuring exchangeable Sr, however, was in agreement with the amounts of “labile Sr” as derived from the Sr/Ca exchange curves. Concerning the cesium exchange properties a clear distinction between “sea and river marsh soils” on the one hand and “brackish marsh soils” on the other hand was established due to differences in clay mineral composition and swelling state of 1:2 layer silicates. The different cesium exchange properties of the two soil groups could also be verified by more or less pronounced hysteresis effects of sorption (Q/I relation) and desorption curves.  相似文献   

6.
Development and Classification of Marsh Soils from the Unterweser Region, West Germany. II. Importance of Sulfur Metabolism, Methane Production and Ca/Mg Ratio for Classifying Marsh Soils The importance of sulfur metabolism in each step of marsh soil development (Brümmer, 1968) is also confirmed for the marsh soils of the Unterweser region. Sulfur contents and sulfur fractions indicate that soil development has advanced further in brackish marshes than in marine and river marshes. The results give additional evidence that the various properties of marsh soils are only partly caused by sedimentation conditions. – The sedimentation areas (Müller, 1954) apply only to small regions. Thus, methane production predominates in the freshwater area, while sulfate reduction predominates in the marine area. Both processes occur at high rates in the brackish area. Classifying soils on the basis of the Ca/Mg ratio gives the same soil groups as Brümmers classification. Consequently, classifying the marsh soils of Niedersachsen on the basis of Ca/Mg ratio is a suitable method, if the idea that sedimentation conditions cause soil properties – especially the contents of exchangeable Ca and Mg – and the present designations of the soil groups are rejected.  相似文献   

7.
The surface properties of soil carbonate were related to its distribution in thirteen profiles of a catenary sequence of calcareous soils from Azerbaijan. When carbonate surfaces were contaminated by Mg2+, 45Ca was used as a tracer for Mg2+ as well as Ca2+, thus enabling the carbonate surface areas to be estimated. These were shown to be inversely and curvilinearly related to soil carbonate contents, but with some abnormality for the three extremely saline/alkaline soils. Na+ does not appear to be specifically adsorbed on carbonate surfaces in the latter. The specific and the total surface areas of carbonate in the surface soils are very sensitive indices of profile development, and are combined with the content and particle-size distribution of carbonate in the profiles to show the variation in soil development along the catenary sequence.  相似文献   

8.
Abstract

In a soil system variation in the concentration of any one ion as induced by external addition might bring changes in the ionic‐equilibria, diffusion rate and strength of adsorption of all the ions involved. In four Indiana soils the changes in ionic equilibria, selectivity coefficient and rate of diffusion coefficient for K, Na, Ca and Mg were investigated at 5 levels of added K. The experiments were carried out under controlled laboratory conditions by incubating soils for 3 weeks at 25C. All soils had a greater fraction of Ca and Mg on the exchange phase than in solution, whereas with K and Na the reverse occurred. Potassium adsorption isotherms for all the soils differed indicating the difference in the nature of soil materials involved. Chalmers soil with high clay content with high exchange capacity had high differential buffer value for K. In all the soils, K was adsorbed preferentially to Na at all the levels of K addition, Calcium was adsorbed preferentially to Mg on the Zanesville and Toronto soils. However, in Chalmers and Raub soils, reverse was observed when the level of K addition was exceeded 1.0 and 0.5 me K/100g soil, respectively. This difference in Mg for Ca is attributed to smaller proportion of Mg saturation on the exchange surface. Divalent cations were preferentially adsorbed over monvalent ions. Increasing levels of K addition increased the diffusion rates of all the ions under consideration. The rate of diffusion for K and Ca were governed by concentrations of these ions on the exchange and solution phase.  相似文献   

9.
Reconstruction of the paleo‐environment and geopedogenesis of non‐calcarous marshland soils (Eutric Gleysols) of Lower Saxony The genesis of non‐calcarous marshland soils is still controversially. For clarification, the paleo‐environments of two Eutric Gleysols were reconstructed by using X‐ray fluorescence spectroscopy, light microscopy, and scanning electron microscopy. Profile 1 shows seven facies. The diatom composition reveals paleo‐environments variable in time with lacustrine, brackish, and marine conditions. Pyrite was found at the transition of clastic material and peat and within the peat, indicating together with frequently found small Zr:Al and Si:Al ratios and small Ca:Sr ratios calm, brackish, and lagoonal sedimentation conditions with reed‐peat formation. Profile 2 shows two facies; their transition is very sharp and characterized by a sudden change in diatom composition, geochemical quality, and carbonate contents. The diatom flora and Ca:Sr ratios of the lower facies reveal a tidal creek habitat with a connection to the sea and exceptional small Si:Al and Zr:Al ratios. The results, particularly for many facies of profile 1, suggest a decalcification during geopedogenesis. Two genetic phases of this decalcification are therefore likely for today non‐calcarous marshland soils, either during early geopedogenesis or during later terrestrial development.  相似文献   

10.
Highly organic soils, and in particular ombrotrophic bogs, have been often used to reconstruct climate changes and heavy metal contaminations. Ombrotrophic peat bogs, in fact, are domed peatlands in which the surface layers are hydrologically isolated from the influence of local groundwaters and surface waters, and are supplied only by atmospheric depositions. In the present work, the attention of Authors has been focused on Pb, Cu, and Zn, coming mainly from anthropogenic activities, and 137Cs, released mostly during the Chernobyl disaster. Practically, an undisturbed peat profile was cored in 2005 from a Swiss ombrotrophic bog and analysed using energy-dispersive miniprobe multielement analyzer X-ray fluorescence and Low Background γ-ray spectrometry in order to investigate and quantify the impact of human activities (e.g., industry, traffic, combustion of fossil fuels, “environmental disasters”) in causing Pb, Cu, Zn, and 137Cs contaminations during the centuries. Obtained data show that highly organic soils in general, and ombrotrophic bogs in particular, reflect the anthropogenic inputs in heavy metal and radionuclide contaminations. In fact, these environments allowed to follow the depositional history of Pb, Cu, and Zn, both underlining a general increasing of their production since the Industrial Revolution, and remarking past single impacting events such as the introduction of leaded gasoline and of particular agricultural practices. Further, although 137Cs showed a main peak corresponding to the Chernobyl disaster, confirming the role of bogs as archive of human activity, data revealed a certain mobility of this radionuclide along the profile. Thus, highly organic soils can be considered as both “witness” of the impact of human activity during centuries and indicator of the health of our planet.  相似文献   

11.
盐阳离子类型及浓度对土壤持水及干缩开裂的作用效果   总被引:4,自引:3,他引:1  
为探索阳性盐离子对土壤持水性能的影响,同时定量分析失水过程所致的土体收缩及裂缝特征,选取陕西粉黏壤土作为供试土壤,分别采用含有K+、Na+、Ca2+和Mg2+4种离子的盐溶液(浓度均为5、30和100 g/L)对土样进行饱和处理,采用离心机法测定土-水曲线,进一步对土壤持水能力进行评价;同时测定土体沉降高度,采用数字图像处理技术获取面积密度和长度密度等裂隙度量指标,对土体收缩和开裂水平进行定量分析。结果发现:1)van Genuchten模型适用于盐溶液浸泡土壤的土-水曲线拟合;2)4种盐离子均基本导致土壤持水能力降低(5 g/L Na+除外),且持水性与离子浓度呈负相关关系;同时使得土壤饱和含水率、残余含水率和进气吸力降低,其中土壤饱和含水率与离子浓度呈负相关关系;3)K+和高浓度Na+有利于减轻土壤轴向收缩度,且土体轴向收缩应变与K+(P0.01)和Na+(P0.05)浓度呈负相关关系;在收缩过程中,不同离子对土壤容重的影响程度表现为Mg2+Ca2+Na+K+;4)4种离子均可减轻土壤开裂程度,且裂缝面积密度和长度密度与K+(P0.01)、Na+(P0.01)和Ca2+(P0.05)浓度呈负相关关系,与Mg2+浓度呈正相关关系(P0.01)。研究可为盐碱土壤持水能力评价、制定灌溉制度提供参考。  相似文献   

12.
Initial soil development from marine sediments in a lysimeter Marine sandy and clayey sediments were put into a lysimeter with controlled ground-water level. Under these conditions the soil development was quick within the first four years. Redox potentials of +400 mV were reached in the upper parts of the soils after half a year. The carbonate content decreased by 0,1 - 0,2% per annum. The total sulfur contents decreased by 10% - 30% during the first year. Humus formation started within the second year. Compared to Puccinellia areas a lower salinity and wider Ca/Mg-ratio occurred in the upper parts of the sandy soil after one year, in the clayey soil after two years, respectively. The change in the hydroregime was essential for the soil development. The particle size distribution was of minor importance. The intensity of the processes was not effected by the vegetation.  相似文献   

13.
Small infiltrometers were used to measure infiltration rates into strongly and maderately developed compound prisms, sampled individually from surface layers of two dry clay soils. Initially, both rates were equally high but after three hours a higher rate was measured for the moderately developed compound prisms. These data were used to interpret adsorption and outflow phenomena of water in undisturbed, large and initially dry soil cores (diameter 20 cm) sampled from the upper 20 cm of the two soils, following application rates of about 8 mm/h and 28 mm/h. The two soils adsorbed an average of 6.4 mm water before the start of discharge, independent of the applied intensity. They discharged water at a constant and high rate for several hours, allowing adsorption of about 10% of the applied water. This represents a high degree of “short-circuiting” for all treatments, except one: adsorption was 40% at the 28 mm/h rate for the soil with the moderately developed prisms. The moisture content in the transmission zone was not constant as it would have been in homogeneous soil but increased regularly as a function of time. Slow wetting of both soils through a crust, followed by rain with an intensity of 30 mm/h, resulted in the adsorption of only about 3% of the applied rain in both soils.In general, more effective wetting of a dry clay surface soil at a given rainfall intensity is initially associated with less “short-circuiting” to deeper horizons. However, the resulting higher moisture content allows less adsorption in the surface layer and is therefore associated with increased “short-circuiting” thereafter, as long as large vertical pores have not been closed by swelling.  相似文献   

14.
Formation and classification of humus-rich marshland soils of the Weser marshland, Germany The formation and classification of marshland soils are still controversial. To improve the knowledge on the formation of humus-rich marshland soils 11 soil profiles have been investigated. The soils mostly showed Phragmitis in the subsoil. The Gr-horizons began at low depths (40–60 cm). The clay content was often about 60% and the Corg content up to 480 g kg?1. The amount of total sulfur was up to 29.6 g kg?1, that of exchangeable sulfate up to 4608 mg kg?1 and that of sulfate in the saturation extract 51.2 mg l?1. With pH (H2O) values between 2.0 and 7.4, Carbonate/S ratios < 3 and total sulfur contents > 7.5 g kg?1 some soils showed “Actual Acid Sulfate Soil” (AASS) properties. The pH(per) values varied between 2.4 and 7.1, thus some profiles showed “Potential Acid Sulfate Soils” (PASS) properties. Brakish as well as marine environments with an intensive sulfur dynamics and carbonate leaching are likely within the geogenetic phase of soil development. Via the control of the water regime the pedogenetic phase is mainly of anthropogenic influence. We propose to classify humus-rich marshland soils into “Organomarsch” and “Thiomarsch” on the soil type level of the German systematics.  相似文献   

15.
研究了我国典型3种可变电荷土壤和4种恒电荷土壤在陪伴阳离子分别为K十、Na十、Ca2+时和1mmolL-1KC1、K2SO4支持电解质中NO3-的吸附。结果表明,NO3-吸附量随pH的增加而减小。在添加相同浓度NO3-时,3种可变电荷土壤对NO3-的吸附量顺序为Ca(NO3)2> KNO3>NaNO3>KNO3十KCI>KNO3+K2SO4;在初始NO3-浓度0.5-5mmolL-1的范围内,吸附量随浓度变化的关系符合Langmuir等温吸附式.由此求出与NO3-吸附结合能有关的常数(K)在不同共存离子存在下数值较小且差异不大,因此认为不同陪伴阳离子和不同伴随阴离子对NO3-吸附的电性机理影响不大,只是改变了土壤表面的正电荷数量从而使吸附量发生变化。4种恒电荷土壤对NO3-的吸附量通常很小,其中在Ca(NO3)2介质中较在其他介质中稍大,最大吸附量仅为1.5~mmol kg-1左右,约为可变电荷土壤的1/10,且在浓度较低时常观察到负吸附。  相似文献   

16.
White pan breads were prepared with flour highly fortified with calcium (Ca), using Ca carbonate (Ca, 38.8%) or a high Ca whey powder (Ca, 5.6%) as the Ca source; bread was also prepared using Ca carbonate plus lactose. Ca was added to flour at 924 mg/100 g of flour, a level 4.4 times higher than specified under the U.S. enrichment standards. Breads were dried and finely ground to prepare test diets (Ca, 0.5%) which were then fed to growing rats for four weeks (growth phase) or eight weeks (approaching maturity). At either interval, femur ash content, femur Ca content, femur strength, or Ca absorption values did not differ significantly among groups fed breads fortified either with Ca carbonate, Ca carbonate + lactose, or whey. Thus, breads can be highly fortified with Ca carbonate to be labeled as “high” in Ca, and this Ca may be as well absorbed and utilized as dairy Ca.  相似文献   

17.
Characterization of former sedimentation conditions of freshwater and brackish marshes in Lower Saxony on the basis of ecological diatom groups Eighteen soils ranked as freshwater and brackish marshes in surveys were examined for their diatom flora. In 9 cases it was possible to reconstruct the former sedimentation conditions. According to the findings. 4 of 6 freshwater marshes had sedimented under marine-estuarine and estuarine or marine conditions. For the brackish marshes brackish to marine sedimentation environments were inferred. Brackish to marine sedimentation conditions were, therefore, not restricted to soils now indicated as marine marshes on surveys.  相似文献   

18.
内蒙河套灌区咸淡水交替灌溉模拟及预测   总被引:4,自引:1,他引:3  
为探索一种适合内蒙河套灌区特点、对区域土壤及地下水环境影响最小的咸淡水轮灌模式,预测长期微咸水灌溉条件下区域环境的变化,在田间试验及土壤水盐信息空间结构性分区的基础上,构建了描述非饱和—饱和水盐运动的耦合模型及其算法。通过对耦合模型的率定检验表明,模型计算值与实测值拟合较好,耦合模型能进行较好的循环计算,误差在允许范围以内,表明耦合模型具有较高的可靠性。基于耦合模型的咸淡水灌溉模式的数值模拟研究发现,“淡水-咸水-咸水”的咸淡水交替灌溉模式对区域土壤及地下水环境的影响在所有方案中最小;采用“淡咸咸”灌溉模式进行长期微咸水灌溉,整个研究区在非生育期的脱盐量大于生育期的积盐量,并且盐分主要通过排水沟系统排出区域外,土壤总体呈脱盐趋势;在模拟期内地下水位只有微小幅度的下降,地下水矿化度及含水层中的盐分呈下降趋势。在黄河水量逐年减少的形势下,“淡咸咸”灌溉模式为河套灌区提供了一条使区域环境可持续发展的开源途径,耦合模型的构建将为内蒙古河套灌区节水改造工程实施后及开发利用微咸水后的区域水土环境的预测预报提供参考及简便实用的途径。  相似文献   

19.
Summary

A simple, single‐step extraction with LiEDTA for the estimation of CEC and exchangeable bases in soils has been developed. Multivalent cations are stripped from the soil adsorption sites by the strongly chelating agent EDTA, and are replaced by Li. In soils without CaCO3 or water soluble salts, exchangeable divalent cations (Ca, Mg) are chelated by EDTA and exchangeable monovalent cations (Na, K) are replaced in a single extraction step using 0.25–2.5 g of soil and 10.0 ml of extractant.

In calcareous soils the CEC can be determined in the same way, but for the extraction of exchangeable Ca and Mg, another separate extraction is needed because dissolution of calcite by EDTA is unavoidable. This extraction is done with as much NaEDTA as needed to extract only exchangeable Ca and Mg in a 1:2 (m/V) soil/alkaline‐50% (V/V) aethanolic solution to minimize dissolution of calcite.

In gypsiferous soils gypsum is transformed into insoluble BaSO4 and soluble CaEDTA by LiBaEDTA thus avoiding interference of Ca from dissolution of gypsum, which renders the traditional methods for determining CEC unsuitable for such soils. To determine exchangeable Ca and Mg, Na4EDTA is used as for calcareous soils.

In saline/sodic soils replacement of Na by Li is incomplete but the Na/Li‐ratio at the complex after extraction is proportional to the molar Na/Li‐ratio in the extracts, so that the CEC and original exchangeable sodium (ESP) content can be calculated. Additional analysis of Cl and, if necessary, SO4 in the extracts of saline soils can be used to correct for the effect of dissolution of the salts on the sum of exchangeable cations.

This new method is as convenient as the recently developed AgTU (silverthiourea), but is better suitable for calcareous and gypsiferous soils.  相似文献   

20.
新疆克里雅绿洲土壤盐分、pH和盐基离子空间异质性分析   总被引:1,自引:0,他引:1  
以克里雅绿洲盐渍化土壤为研究对象,以野外调查与实地数据为基础,采用空间自相关分析与径向基函数插值法,定量分析了克里雅绿洲土壤的含盐量、pH及盐基离子的空间异质特征。结果表明:绿洲盐渍土表聚性强、呈碱性,土壤含盐量从南至北呈现逐渐增大趋势。土壤含盐量、Na~+、Ca(2+)、K~+、Mg2~+、Cl–、SO_4~(2-)均属于强空间变异,HCO_3~–属于中等强度的空间变异,而pH属极弱变异。土壤盐分含量、pH和盐基离子的Moran’s I指数均通过了显著性检验,研究区土壤含盐量、p H与盐基离子在空间上呈现低聚集性。Pearson相关性分析结果显示,土壤盐分含量与Na~+、K~+、Cl~–和SO_4~(2-)含量具有强正相关性(P0.01),与Ca~(2+)和Mg~(2+)含量中等程度正相关(P0.05);土壤pH与土壤含盐量及盐基离子含量极弱相关。该研究结果可为绿洲水资源合理开发与农业可持续发展提供科学依据,同时可作为盐渍土改良和沙漠化防治等环保工作的决策支撑。  相似文献   

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