The thermodynamics of sorption with reference to klinki pine

Summary An investigation into the bonding energy relationships for water in wood indicates that as the temperature increases at constant total moisture content, water moves from within the chemical structure to the adsorption surface. The analysis is evaluated for the wood Araucaria klinkii Lauterb and it is indicated that at 25 °C, less water is held in the chemical structure during adsorption than during desorption.Symbols A amplitude of liquid surface profile - A₀ amplitude of solid surface profile - a mean radius of curvature of liquid surface (bubble radius), Å - a₀ mean radius of curvature of solid surface, Å - a_c a constant value of a, Å - F a function of temperature - f capisorption energy fraction - G a function of - g specific Gibbs free energy of saturated water vapour relative to unsaturated water vapour at the same temperature, J/kg - g_c specific Gibbs free energy associated with capisorption, J/kg - g_p specific Gibbs free energy associated with physisorption, J/kg - h change in specific enthalpy of liquid water as it is desorbed, J/kg - l latent heat of vaporisation of free water, J/kg - m wave number/m - p_s pressure of water vapour at saturation, Pa - R specific gas constant for water vapour, J/kg K - r relative humidity - s change in specific entropy of liquid water as it is desorbed, J/kg K - T temperature, K - w dry basis moisture content - x ln p_s/p_s25 - y In r - z length coordinate, m - , , constant coefficients - change in mean height of liquid surface, Å - ₀ a constant length, Å - constant - distance from solid to liquid vapour interface measured normal to solid surface, Å - ₀ a constant value of , Å     

Postbuckling of thin wood-based sandwich panels due to hygroexpansion under high humidity

This study was carried out to investigate the postbuckling behavior of thin wood-based sandwich panels under high humidity. Using the Rayleigh-Ritz method based on the von Karman nonlinear theory for the panel, the solutions for both the approximate and the closed form for postbuckling of orthotropic panels were derived to evaluate the deflection for the boundary condition of all clamped edges. The results suggested that the edge movement be considered for evaluation of a critical moisture content and deflection of thin wood-based panels fixed on the core with an adhesive. The numerical solution obtained from the derived model showed some discrepancy with the experimental results. The predicted results overestimated the center deflection of the panels because creep and plastic deformation might be caused by considerable in-plane stress on panels.Appendix: Abbreviations and symbols total potential energy of panel - A _ij ,D _ij extensional and bending stiffness, respectively - _x , _y midplane strains inx andy directions, respectively - _xy midplane shear strain inxy plane - N _x ^M , N _y ^M hygroscopic forces inx andy directions, respectively - h panel thickness - a, b panel length inx andy directions, respectively - x, y, z coordinate system - u, v, w displacement inx, y, andz directions, respectively - MC moisture content change - a _x ,a _y coefficient of linear expansion inx andy directions, respectively - LE linear expansion (MC) - s arc length - R radius of curvature - N _x ,N _y resultant in-plane forces per unit length inx andy directions, respectively - N _n nondimensional loadN _x ^M b ²/E ₂ h ³ - N _cr nondimensional critical load,N _x,cr ^M b ²/E ₂ h ³ - ratio of the core to the total width,a _c /a + a _c - E _c effective core MOE,E +E (i.e., the summation of MOE parallel to the grain and perpendicular to the grain) - h _c core thickness     

Salt distribution in response to optical stratification porosity and relative windspeed in a coastal forest in Niigata, Japan

Wind velocity, vertical stand structure and seasalt distribution were measured at various heights inside a plantation of coastal pine forest, with thinning and unthinning, to assess whether any relationships exist between the wind profile, stand structure and seasalt distribution in the coastal pine forest. The vertical stand structure, i.e., optical stratification porosity (OSP), which is defined as vertical distribution of the proportion of sky hemisphere not obscured by tree elements inside a forest stand, was determined for each height by computer analysis of digital images taken with a hemispherical lens. The distribution of OSP in the coastal forest follows the Lambert-Beer's law with absorbency coefficient (). The relative windspeed within canopy can be described using the exponential form with the attenuation coefficient (). The sea-salt was collected using salt gauze (a surgical dressing of loosely woven cotton) both inside and outside the coastal forest, and the distribution of sea-salt within canopy was also in accordance with an exponential function. The relationships among windspeed, OSP and sea-salt indicate that the distributions of both sea-salt and windspeed within canopy were very closely correlated with the distribution of OSP. A linear relationship between OSP and sea-salt has been found. Additionally, linear regression between coefficients and has been obtained as well. Based on these relationships between OSP, wind and sea-salt in the coastal forest, the sea-salt distribution and wind profile within the canopy of the coastal forest can be predicted according to OSP. These results may therefore be useful in analyzing the effects of sea-salt on vegetation and evaluating the filter functions of coastal forests.This revised version was published online in November 2005 with corrections to the Cover Date.     

Vertikalbewegungen Rickettsiose-kranker Larven vonAmphimallon solstitiale (LINNAEUS),Anomala dubia aenea (DE GEER) undMaladera brunnea (LINNAEUS)(Col., Lamellicornia)

Zusammenfassung DurchRickettsiella melolonthae (Krieg) PHILIP infizierte Maikäfer-Engerlinge wandern während des Spätherbstes und Winters im Freiland absterbend auf die Erdoberfläche. Als Begleitarten inMelolontha Larvenpopulationen kamen im Gebiet vor:Amphimallon solstitiale (L.),Anomala dubia aenea (DeG.) undMaladera brunnea (L.). MitR. melolonthae künstlich infiziert, zeigten sie im Orientierungsversuch die gleiche Aufwanderungstendenz wie kranke Maikäferengerlinge, am deutlichsten die vonM. brunnea. Auf dem Waldboden fanden sich kranke Larven dieser Art in einigen Fällen.

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Summary Larvae ofMelolontha spp. infested withRickettsiella melolonthae (Krieg) PHILIP move during October– January to the top of the soil where they eventually die. Larvae ofAmphimallon solstitiale (L.),Anomala dubia aenea (DeG.) andMaladera brunnea (L.) are susceptible forR. melolonthae, too. In experiments, artificially infested individuals showed a similar tendency to move upward. This was most pronounced inM. brunnea, of which some infested larvae were found on the forest floor.

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Résumé Larves du hanneton, infectées parRickettsiella melolonthae (Krieg) PHILIP, se rendent à la surface de la terre au fin de l'automme et dans l'hivers. Comme espèces accompagnant les populations larvaires deMelolontha nous avons trouvés:Amphimallon solstitiale (L.),Anomala dubia aenea (DeG.) etMaladera brunnea (L.). Ils out démonstré, après une infection artificielle avecR. melolonthae, la mème tendence dans les essais d'orientation comme les vers blancs malades deMelolontha. Le phé nomène etait le plus prononcé parmi les larves deMaladera. De cette espèce nous avons trouvés plusieurs larves malades à la surface de la terre en plein champs.

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Rickettsiella melolonthae (Krieg) Philip Melolontha- . . Melolontha- :Amphimallon solstitiale (L.),Anomala dubia aenea (De G.) Maladera brunnea (L.). R. melolonthae , Melolontha-, M. brunnea. .

     

Dynamic properties of three types of wood-based composites

This study used a vibration test method to show that grain angles of face veneer have substantial effects on sound velocities and dynamic Youngs moduli of three types of wood-based composites. The sound velocity at 0° grain angle of face veneer was the highest, and it decreased with increasing grain angle in the range of 0° to 90°. This tendency was similar to that for dynamic Youngs modulus. The relationship between the grain angle of face veneer and the sound velocity of three types of wood-based composites can be expressed in the form of Hankinsons equation or a second-order parabolic equation. This study also showed that the application of orthotropic elasticity theory was valid for the three types of wood-based composites. The relationship between the grain angle of the face veneer and the Youngs modulus of three types of wood-based composites can be expressed in the form of the Jenkin equation, Hankinsons equation, or a second-order parabolic equation. Rule of mixture can also be used to predict the Youngs modulus of wood-based composite from the Youngs moduli of the two elements.Part of this study was presented at the 53rd Annual Meeting of the Japan Wood Research Society, Fukuoka, Japan, March 2003 and the 15th Annual Meeting of Chugoku Shikoku Branch of the Japan Wood Research Society, Higashi-Hiroshima, Japan, September 2003     

Überblick über die gegenwärtige Erforschung schädlicher und nützlicher Dipteren in der CSSR

Summary Review of the present studies on injurious and useful Diptera in SSRThe problems on Diptera studied in SSR as well as the names of scientists working on these problems are summarized. In SSR more than 100 scientists are working dipterologically at present. They come together biannual in order to discuss results and problems.

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Dipl-Ing. Jan Dirlbek, Prag-Ruzyn, Ústav Orchany Rostlin/SSR.     

Effect of cutting position on rooting and shoot growth of two poplar clones

One-year-old shoots from stooling beds of Populus × deltoides Walker and Populus jackii Northwest were collected in late fall to determine the effect of cutting position on rooting and growth of hardwood poplar cuttings. Cuttings with a minimum diameter of 9.0 mm were obtained from basal, middle and distal locations on the poplar shoot. Rooting and shoot growth were assessed in the greenhouse and under field conditions. Walker poplar cuttings collected from basal portions of the shoot and planted in the field had 87.6% rooting and 103.8 cm growth compared to 78.8% and 103.4 cm and 67.6% and 88.8 cm for middle and distal locations respectively. For Northwest rooting and growth under field conditions was 84.4% and 94.7 cm for basal, 78.4% and 90.5 cm for mid and 64.4% and 84.3 cm for distal locations. Rooting in the greenhouse was superior to the field. Walker cuttings had fewer roots and buds per cutting than Northwest, however, growth of Walker in the field was superior.     

Die neuesten Erkenntnisse der forstlichen Entomologie in der Tschechoslowakei

Summary Present development of forestry entomology in the SSRThis article gives an outline on the occurrence of the more important harmful forest insects in the SSR in the year 1950–1962 and on the results of their study. The Norway spruce suffered from the year 1954 notably byIps typographus L. The control was based on insecticides, studies included optimal density of natural regeneration at the mass propagation etc. It was found, for instance, that typical density borings in bark (151–300 borings per 1 sq.m. of bark) shows variation in the shortest distance between borings from 54–70 mm. Relation between density of borings and their distance indicates function y = a.x^–b, (constant a = 476,9 and constant b= 0,38). It was further found thatIps typographus L. shows even sister generations twice in a year (about 60%, eventually even 30% females of the preceding population). Sister laying is conditioned mainly climatically, i.e. also by the forest stand elevation above sea level. A secure control of further harmful species of Norway spruce,Trypodendron lineatum (Ol.) was carried out by extirpation of wintering beetles in soil, eventually by treating of round wood by emulsions on the HCH + DDT basis.Cephaleia abietis L. shows two diapause periods in a larval stage. For this reason, the development of this species lasts prevailingly two years (90% population). Swarming imagines are controlled by chemical aerosols (10% DDT in the dosis 4–8 kg/ha). On obtained from eggsTrichogramma cephalciae Hochm. et Mart. which cannot be grown on eggs of butterflies. Investigations found that the clean eating ofZeiraphera diniana Guen. begins at the density of 300 caterpillars per one meter of long branch. Chemical control (aerosol 10 l/ha) is recommended when feeding is repeated for three years. The mass propagation ofBupalus piniarinus L. appeared on the Scotch pine. The critical number amounts 400 caterpillars per one kg of needles.Hylobius abletis L. is controlled by insecticides in trap barks and by underground traps for concentration of egg laying. Oak was injuried mostly by the rollerTortrix viridana. The critical number is one caterpillar per one bud. Other, in the SSR new harmful insect of oakArchips crataegana (Hb.) showed the critical number 100 egg heaps on the stem to the height of 2 m. The eggs of the above mentioned species showedTrichogramma embryophagum cacoeciae March., which can easily be grown on butterfly eggs. Oak 60–200 years old was attacked byApethymus biaccatus (Gmel.) andA. abdominalis (Lep.). Silver fir was harmed mainly by the rollerChoristoneura murinana (Hb.). Also the critical number was found. Egg rearing gaveTrichogramma minutum Ril. Ash indicates new type of bark injuries caused probably by a representative of the genusLestes (Fig. 1.). Poplars are damaged by the species of the familyCerambycidae, further byCryptorrhynchus lapathi L. and by the species of the familyAegeridae. Saperda carcharias L. has in the Czechoslovak conditions a generation of three years. Eggs overwinter.Cryptorrhynchus lapathi L. has in the southern Moravia mostly (70% population) one year generation, the rest shows a generation of two years. Beech and hornbeaum were harmfully attacked byErannis aurantiaria Hb.) andColotois pennaria (L.). It is obvious that in the year 1950–1962 several species (Alchips crataegana (Hb.),Apethymus braccatus (Gmel.),A. abdominalis (Lep.) on oak,Erannis aurantiaria (Hb.) andColotois pennaria (L.) on. hornbeam and oak,Pachynematus scutellatus Htg. on Norway spruce etc.) previously not known as important forest injurious insect, appeared as calamity species. Further it is obvious that some harmful insects probably under the influence of changed structure and also forest stand microclimate are retreating whereas other species show mass outbreak. For this reason it is necessary to study the lawfulness of the propagation of the individual species.

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Résumé Les plus récentes expériences de l'entomologie en TchécoslovaquieLe travail contient un aperçu concernant la présence d'insectes nuisibles forestiers de certaine importance en Tchécoslovaquie au cours des années 1950–1962 ainsi que le résultat de leur recherche. Jusqu'à 1954 l'épicéa a été assaili surtout par l'Ips typogiaphus L. On cherche une solution de la défense au moyen des insecticides, la densité optimale d'attaque en cas de la reproduction excessive etc. Par exemple il a été constaté que lors de la densité typique de forage de l'écorce (151–300 forages par mètre carré d'écorce) leur distance ré ciproque varie de 54 à 70 mm. Le rapport entre la densité de forage et de leurs distances présente la forme de fonction y = a.x^–b, où la constante a = 476,9 et la constante b = 0,38. Ensuite il a été constaté qu'en ce qui concerne l'Ips typogiaphus L. existent même deux gé nérations-soeurs au cours de l'année (environ 60 % respectivement encore 30 % des femelles de la population pécédente). La production de pondaisonsoeur est soumis surtout au facteurs climatiques, c'est à dire même á l'altitude des peuplements. Contre un antre parasite de l'épicéa, leTrypodendron lineatum (Ol.), une certaine défense fut élaborée par l'extermination d'imagos hivernant dans le sol ou par le traitement de rondin par des émulsions sur la base HCH + DDT. En ce qui conceme laCephaleia abietis L. on a constaté deux phases de diapause en état de larve. C'est pourquoi le développement duparasite est en majorité biennal (90% de la population). II a été introduit une lutte chimique contre l'essaimage d'imagos par des aerosols (10% de DDT dans une dose de 4 à 8 kg par ha). On a réussi à faire sortir des oeufs de laTrichogramma cephalciae Hochm. et Mart. que l'on ne peut pas cultiver sur les oeufs de papillons. En ce qui concerne laZeiraphera diniana Guen. il fut constaté que la défoliation compléte a lieu par 300 chenilles sur une branche d'un métre de longueur. La lutte chimique est recommandée en cas d'attaque repétée au cours de trois ans. Sur des pins il fut constaté la multiplication de masse duBupalus piniarius L. où le chiffre critique et atteint par 400 chenilles sur un kg d'aiguilles. En ce qui concerne l'Hylobius abietis L. on élabora une manière de défense en utilisant des insecticides dans des pièges d'écorce et des pièges souterrains pour saisir les pondaisons. Sur le chêne c'était laTortrix viridana qui a causé les plus grands dé gâts. Le chiffre critique est exprimé par une chenille pour un bourgeon. En ce qui concerne l'ulté rieur parasite de chêne nouvellement apparu en Tchécoslovaquie, l'Archips crataegana (Hb.), le chiffre critique fut fixé par 100 agglomérations ovulaires sur le tronc jusqu'à 2 mètres de hauteur. On a obtenu laTrichogramma embryophagum cacoeciae March., qui peut être facilement cultivée sur les oeufs de papillons. Sur les chênes d'un âge de 60 à 200 sont apparus ensuite comme parasite desApethymus braccatus (Gmel.) et desApethymus abdominalis (Lep.). Sur le sapin apparaît surtout laChoristoneura murinana (Hb.). Un chiffre critique fut fixé. On a obtenu à partir des oeufs laTrichogramma minutum Ril. On a découvert sur le frêne un nouveau type de lésion de l'é corce provoqué vraisemblablement par la libellule g.Lestes (Fig. 1). Les capricornes, leCryptorrhynchus et lesSesia spp. sont nuisibles aux peupliers. En Tchécoslovaquie laSaperda carcharias L. a une géneration triennale. Les oeufs hivernent. LeCryptorrhynchus lapathi L. a en Moravie du Sud en majorité (70% de la population) une génération annuelle, le restant, biennale. Ensuite sur le hêtre et sur le charme a eu lieu l'apparition désastreuse de la chenille arpenteuseErannis aurantiaria (Hb.) et de laColotois pennaria (L.). Il en ressort donc qu'au cours des années 1950–52 plusieurs espèces ont fait une apparition désastreuse:Archips crataegana (Hb.),Apethymus biaccatus (Gmel.),Apethymus abdominalis (Lep.) sur le chêne,Erannis aurantiaria (Hb.) etColotois pennaria (L.) sur le charme et le hêtre, lePachynematus scutellatus Htg. sur l'épicéa et d'autres qui é taíent auparavent inconnus comme parasites considérables de la forêt.On peut en déduire qu'évidemment sous l'influence de la structure transformée et par consé quent du microclima des peuplements, certains parasites tendent à disparaître, tandis que d'autres insectes deviennent parasites désastreux. C'est pourquoi une recherche approfondie des lois de la reproduction en masse des différentes espèces est nécéssaire.

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- 1950–1962. . 1954. Ips typographus L. , , . . , (151–300 1 ² ) 54 70 . y = a x^–b, a = 476,9 b = 0,38. , Ips typographus L. ( 60%, 30% ). , . . . Trypodendron lineatum (01.) , HCH + DDT. Cephalia abietis (L.) , (90% ). (10% 4–8 (). Trichogramma cephalciae Hochhm. & Mart., . Zeiraphera diniana Guen. 300 1 . . . ( 10 /) . Bupalus piniarius L., 1 400 . Hylobius abietis L. . Tortrix viridana L. 1 1 . , ,Archips crataegana (Hb.) 100 2 . Trichogramma embryophagum cacoeciae March., . 60–200 Apethymus braccatus (Gmel.) Apethymus abdominalis (Lep.). Choristoneura murinana (Hb.). . Trichogramma minutum Ril. - Lestes (. 1). , .Saperda carcharias L. . .Cryptorrhynchus lapathi L. (70% ) , . Erannis aurantiaria (Hb.) Colotois pennaria (L.). , 1950–1962. (Archips crataegana (Hb.),Apethymus braccatus (Gmel.),Apethymus abdominalis (Lep.), Erannis aurantiaria (Hb.) Colotois pennaria (L.), Pachynematus scutellatus Htg. . .), . , , . .

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Herrn Prof. Dipl.-Ing. Dr. A. Pfeffer zum 60. Geburtstag gewidmet.     

Biometric relationships for non-destructive above ground biomass estimations in young plantations of Acacia salicina Lindl. and Eucalyptus occidentalis Endl.

Above ground oven dried biomass (BM) of individual trees in young stands of Acacia salicina Lindl. and Eucalyptus occidentalis Endl. were correlated linearly and logarithmically to the square of the basal diameter at 0.2 m (DB) and to the latter multiplied by the height of the tree. Number of main stems at basal height per tree were included as well. DB measurements in young Eucalypt stands provided better BM estimates than the commonly used diameter at breast height (1.3 m) (DBH).The following biometric relationships, after cross-validation against an independent data set, showed the best fit: BM=0.1282* (DB²) and BM=0.1700* (DB²) for A. salicina and E. occidentalis, respectively, with (DB²) ranging from 0–400 cm² and BM in kg tree^–1. For acceptable relative errors in biomass estimations (DB²) should be larger than 100 cm².Foliage to wood ratios at (DB²)<100 cm² for both tree species generally exceeded 1, but rapidly leveled off at 0.81±0.28 and 0.92±0.19 for the Acacia and Eucalypt spp., respectively, at higher (DB²) values.     

Die Anfälligkeit verschiedener Sommerweizensorten gegenüber Befall durch die beiden Weizengallmü ckenarten (Dipt., Cecidomyidae)

The susceptibility of some spring wheat varieties to the attack by the two wheat blossom midge species (Dipt., Cecidomyidae) The susceptibility of 20 spring wheat varieties to the attack byContarinia tritici (Kirby) andSitodiplosis mosellana (Géhin) was studied from 1971 to 1976 on small plots. Some varieties proved to be very susceptible, others were partly resistant. Meritus showed a high susceptibility to both wheat blossom midge species, while Arm showed a very low one. The resistance observed could not be explained by incoincidence. Of the varieties still being in trade, Opal should not be grown in areas of damage byS. mosellana. Kleiber and Kolibri are apt for this. Arin can be recommended to be grown in areas, where damage by both wheat blossom midges occurs.     

Leaf-water potential and soil-water depletion of walnut mulched with polyethylene and intercropped with alfalfa in Central Italy

In Italy, new agroforestry cultural models could play an important role in the diffusion of plantation forestry timber species. We studied the stem growth rates and leaf water potentials () of common walnut (Juglans regia L.), and gravimetric soil moisture (_DW) depletion during the third and fourth growing seasons in an agroforestry trial in central Italy. Since the establishment of experimental plots in 1992, walnut was intercropped with alfalfa (Medicago sativa L.), with or without polyethylene (PE) mulching along tree rows. By the end of the study period, the unmulched-intercropped walnut was almost 68% smaller in stem diameter and height than the sole-unmulched control, demonstrating walnuts sensitivity to alfalfa competition. The competitive effect of alfalfa on walnut stem growth was effectively controlled/reduced by PE mulching. Stem growth rates of mulched-intercropped walnut were always lower than the control, but much higher (ca. 235% in stem diameter and height) than those of unmulched-intercropped walnut. The higher field performance of mulched-intercropped walnut compared to the un- mulched-intercropped treatment was associated with higher soil moisture and predawn and midday values during the summers driest periods. The presence of PE mulching was also associated with lower levels of soil moisture during the early and late growing season, but this did not negatively affect walnut and growth rates. These results suggest that in the climatic conditions of central Italy, competition for soil moisture between young common walnut trees and alfalfa can be substantially lowered, but not completely eliminated, by PE mulching.This revised version was published online in November 2005 with corrections to the Cover Date.     

Bearing properties of engineered wood products I: effects of dowel diameter and loading direction

The embedment tests of laminated veneer lumber (LVL) with two moduli of elasticity (MOE; 7.8 GPa and 9.8GPa), parallel strand lumber (PSL), and laminated strand lumber (LSL) were conducted in accordance with ASTM-D 5764. The load-embedment relation for each of these engineered wood products (EWPs) was established. The directional characteristics of bearing strength (_e), initial stiffness (k _e), and effective elastic foundation depth were obtained from the tested results. The effective elastic foundation depth (=E/k _e,E = MOE), based on the theory of a beam on elastic foundation, was obtained from thek _e and MOE. An of 90° (perpendicular to the grain) was calculated by dividingE ₉₀ [MOE of 90° from the compression test, but MOE of 0° (E ₀), parallel to the grain, obtained from the bending test] byk _e90, the initial stiffness of 90°. This study aimed to obtain the bearing characteristics of each EWP, taking into consideration their anisotropic structures, for estimating the fastening strength of a dowel-type fastener. The relations between the bearing coefficients ( _e,k _e,) on the loading direction and dowel diameter were established from the load-embedment curves. Based on the results of the embedment test, tested EWPs showed different tendencies in all directions from wood and glued laminated timber.Part of this study was presented at the 49th Annual Meeting of the Japan Wood Research Society, Tokyo, April 1999     

Synthesis of isoacteoside, a dihydroxyphenylethyl glycoside

The total chemical synthesis of isoacteoside (1), 2-(3,4-dihydroxyphenyl)ethyl 6-O-caffeoyl-3-O-(-l-rhamnopyranosyl)--d-glucopyranoside, is described. An acteoside acetate with benzyl groups at the catechols (3: 2-(3,4-dibenzyloxyphenyl)ethyl 2,6-di-O-acetyl-4-O-[3,4-bis(O-benzyl)caffeoyl]-3-O-(-l-rhamnopyranosyl)--d-glucopyranoside) was treated with a solution of methy-lamine in methanol (MeNH₂ in MeOH) to perform both deacetylation and caffeoyl migration, affording an isoacteoside derivative with benzyl groups at the catechols4b: 2-(3,4-dibenzyloxyphenyl)ethyl 6-O-[3,4-bis(O-benzyl) caffeoyl] -3-O-(-l-rhamnopyranosyl)--d-glucopyranoside —in 34% yield. Debenzylation of4b was successfully accomplished by catalytic transfer hydrogenation using 1,4-cyclohexadiene to give the target compound isoacteoside (1) in 54% yield.¹H and¹³C nuclear magnetic resonance spectral data of the synthesized isoacteoside (1) were identical with those of the natural isoacteoside isolated fromPaulownia tomentosa (Thumb.) Steud.Part of this research was presented at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 2001     

Chemical and physical changes required for producing dimensionally stable wood-based composites

Summary The springback of compressed wood caused by built-up internal stresses results in excessive thickness swelling of wood-based composites when exposed to moisture. Steam pretreatment can cause partial hydrolysis of hemicellulose for both hardwoods and softwoods which markedly increases the compressibility of wood and in turn significantly reduces the build-up of internal stresses in composites during hot pressing. This steam pretreatment process is a very effective method for producing dimensionally stable wood-based composites. Mild steam pretreatments (e.g. 3 to 4 min at 1.55 MPa) cause a significant reduction of the water insoluble xylan content in hardwoods and the amount of xylan, mannan and galactan in softwoods without any apparent changes in the cellulose or lignin content.The authors wish to thank G. Bastien and B. S. Lethbridge for technical assistance. W. Schwald is grateful to the Fonds zur Förderung der wissenschaftlichen Forschung, Vienna, Austria for granting an Erwin-Schrödinger scholarship (Proj. No. J0128C)     

Tropical red gums — a source of 1,8-cineole-rich Eucalyptus oil

Tropical provenances of Eucalyptus camaldulensis Dehnh. and E. tereticornis Smith were studied, in their natural habitat in Australia and in a 3.75-year-old progeny trial in Zimbabwe, for their potential to produce medicinal-grade essential oils. Substantial interand intra-specific variation in the contents of five prominent monoterpenes, 1,8-cineole, -pinene, -pinene, limonene and p-cymene was found. Plantations of E. camaldulensis established in the wet/dry tropics using seed from Petford in northern Queensland offer immediate potential for oil production. Other widely-planted Queensland provenances with oil potential are Gilbert River Bridge E. camaldulensis and, after some genetic improvement, E. tereticonis from Morehead and Kennedy Rivers. Select individual trees at Petford provide oil of enhanced quality, at about double the yield of average trees.     

Mapping the territory: agroforestry awareness among Washington State land managers

There is growing interest in research to develop potential agroforestry models for temperate climates. In Washington State, recent studies and anecdotal information suggest that agroforestry is already employed by land managers, and if so, this experience should inform future research efforts. Because this population is not well defined, a mail survey was designed to: 1) Assess Washington land manager awareness of agroforestry, 2) assess perceptions of agroforestry as a land management tool, 3) assess the perceived potential opportunities or obstacles for land managers to practice agroforestry, and 4) identify landowner groups believed to be practicing agroforestry in Washington State.Three groups of land managers were surveyed: employees of the Soil Conservation Service (SCS), Washington State University Cooperative Extension Service (WSUCE) and OTHER, consisting of university faculty, private land managers, State and Federal land managers and owners of small natural resource businesses.Agroforestry was not a new concept for most (94%) respondents, further 55% of those familiar with agroforestry were practicing agroforestry or providing advice to landowners who were practicing agroforestry. Use in (government mandated) soil conservation plans on farmland (100% of all respondents) was the most frequently cited potential application for agroforestry in the state followed by range and pasture land and managing non-commercial forest land (both 84%), use on commercial forest plantation (83%) and fruit and nut orchards (61%).Diversifies land use (25%), enhanced productivity (18%), aesthetics (13%) and income diversity (13%) were the four most frequently cited potential advantages to practicing agroforestry. Lack of information (28%), lack of technical assistance (18%), establishment costs (14%) and not an established practice (14%) were the most frequently identified potential obstacles to practicing agroforestry. Respondents suggested there is great potential for application of agroforestry throughout the state, and non-industrial private forest land owners were selected for future study of this potential.     

Influence of moisture content on the vibrational properties of hematoxylin-impregnated wood

The vibrational property of hematoxylinimpregnated wood was investigated from the aspect of moisture content dependence. The specific dynamic Young's modulus (E/) and loss tangent (tan) of hematoxylin-impregnated wood were determined in the relative humidity (RH) range of 0%–97%, and were compared with those of the untreated and some conventional chemically treated woods. The changes in theE/ and tan of wood with increasing RH were suppressed by acetylation and formaldehyde treatment because of a marked reduction in the hygroscopicity of the wood. Although the hematoxylin impregnation did not significantly affect the hygroscopicity of the wood, its influence onE/ and tan were similar to that of formaldehyde treatment at low RH and of acetylation at medium RH. It was supposed that at low to medium RH hematoxylin restrains the molecular motion of amorphous substances in the cell wall because of its bulkiness and rigidity. On the other hand, at high RH it seems to work as a plasticizer with adsorbed water molecules.     

Structure of xylan from culms of bamboo grass (Sasa senanensis Rehd.)

Xylan prepared from culms of kumaizasa (Sasa senanensis Rehd.), a representative species of bamboo grass, was hydrolyzed with-xylanase ofStreptomyces olivaceoviridis E-86. Four arabinoxylo-oligosaccharides and two glucuronoxylo-oligosaccharides were isolated from the enzymatic hydrolysate of the xylan by chromatography on a charcoal column, a Dowex 1-x8 column, a Toyo-pearl HW-40S column, and a LiChrospher 100 NH₂ column and on preparative paper chromatography. The results of the structural analyses of the saccharides showed that the isolated oligosaccharides had the structures of 3²--l-arabinofuranosyl-xylobiose, 3²--l-arabinofuranosyl-xylotriose, 3²--[-d-xylopyranosyl-(1 2)-l-arabinofuranosyl]-xylobiose, 3³--[-d-xylopyranosyl-(1 2)-l-arabinofuranosyl]-xylotriose, 2³--4-O-methyl-d-glucuronosyl-xylotriose, and 2³--d-glucuronosyl-xylotriose. From the structural analysis of the oligosaccharides derived from the xylan, kumaizasa xylan was concluded to be a kind of arabinoglucuronoxylan having not only stubs of singlel-arabinose and singled-glucuronic acid but also stubs of disaccharide units such as-d-xylopyranosyl-(1 2)-l-arabinofuranose.     

Paraiso (Melia azedarach var. “Gigante”) woodlots: an agroforestry alternative for the small farmer in Paraguay

This paper describes the salient aspects and analyses the potential of the Paraiso Woodlot System, which is becoming popular as an agroforestry alternative to land use in the degraded acid sandy soils of the humid sub-tropical Guayaybi area of Paraguay. The system consists of a combination of paraiso (Melia azedarach var gigante) with other trees, especially Leucaena leucocephala, and annual crops.The fast growth habit, deep root system, addition of large quantities of organic matter through leaf and litter fall, compatibility with agricultural crops, high value of the sawlogs and production of substantial quantities of poles and firewood make paraiso an excellent species for agroforestry combination. Preliminary results of the trials indicate that the woodlots are successful and with increasing efforts of the extension agencies, they are being accepted as a viable alternative to traditional agricultural systems.Besides discussing the potential of these woodlots based on initial results, the paper identifies the constraints of the system and highlights the priority research areas.     

Reducing end groups in brich xylan and their alkaline degradation

Summary The structure of the reducing end group in xylan can be written: --D-Xylp-(14)--D-Xylp-(13)--L-Rhap-(12)---D-GalpA-(14)-D-XylIn alkaline media the reducing xylose group is easily isomerized and removed by a -elimination which leads to a reducing galacturonic acid end group. The 1, 2-linkage between rhamnose and the galacturonic acid explains the retarding effect on the alkaline peeling. Even under fairly mild conditions the galacturonic acid group is converted to other groups which are very stable in alkaline media. Model experiments permit the conclusion that OH-3 in the reducing group is subjected to -hydroxyelimination. The 3-deoxy-2-O--L-rhamnopyranosyl-D-threo-hex-2-enuronic acid group formed is unstable in acid medium and escapes observation by the techniques employed for determination of the end groups.Upon prolonged alkaline treatment and increased proportion of these groups is lost and a rapid peeling proceeds until a xylose group with a 4-O-methylglucuronic acid substituent is liberated. The consecutive reactions of this group are similar to those of the galacturonic acid groups.The formation of 3-deoxyaldonic acid end groups, an important stopping reaction in cellulose, is of minor importance in xylan.The financial support from the 1959 Års Fond för Teknisk och Skoglig Forskning samt Utbildning is gratefully acknowledged.