吉林省主要耕作土壤中含钾矿物组成及其与不同形态钾的关系

通过化学分析 ,X-射线衍射及镜检法研究了黑土、白浆土、黑钙土等吉林省主要耕作土壤的含钾矿物组成及不同形态钾的含量。结果表明 ,土壤中的含钾矿物以含钾长石和伊利石为主 ,钾长石主要集中在土壤砂粒部分 ,伊利石主要存在于土壤的粘粒部分。土壤的含钾矿物总量约占土壤矿物总量的 1/ 3多些 ,比南方土壤高 ;缓效钾含量丰富 ,供钾潜力大 ;速效钾含量在黑土、黑钙土中较高 ,而在白浆土中稍低。 3种土壤的全钾量与含钾矿物总量、粘粒中伊利石含量与粘粒含钾量、伊利石含量与缓效钾量、细砂中含钾长石含量与细砂中全钾量、缓效性钾与速效性钾之间呈极显著或显著相关。     

生物耗竭土壤的层间钾自然释放及固钾特性

对经生物耗竭后的８种土壤的研究表明，它们经过自然风干后，土壤的层间钾能自然释放而交换性钾得到部分恢复，但耗竭程度愈烈，恢复能力则随之下降，经淹水或湿润处理后，土壤的交换性钾反有较大程度的再固定；而干湿交换处理后，能促进低施钾水平土壤中新固定态层间钾的释放，高施钾水平土壤中交换性钾的进一步固定。生物耗竭使土壤的固钾能力增强，但白土及黄泥土土壤的固钾率仅１９－４６％，新固定态钾易被作用再利用，而黄潮土     

耕作土壤非交换性钾有效性的研究

采用两种化学连续提取法及连续耗钾实验,研究了几种耕作土壤非有效性钾释放特性及有效性。结果表明,供试土壤非交换性释放特性和有效性与粘土矿的密切相关,富含伊利石的土壤非交换性钾的释放量大,速率快,有效性高,黑麦草吸收该土壤的非交换性钾量及总吸钾量高,生物量大。而富含高岭石或蒙脱石的土壤非有效性钾有效性明显较低,非交换性钾的释放量和速率,黑麦草吸收该土壤的非交换性钾量,总吸钾量及生物量的均值分别仅为富含     

耕作土壤释钾速率及其与钾有效性的关系研究

对 1 0个不同母质土壤进行生物吸钾试验和化学测定 .结果表明 ,二级动力学方程dkt/dt=k(k0 -kt) 2 可以很好地描述连续提取条件下土壤释钾特性。初始释钾速率与有效钾含量呈极显著正相关 ,与黑麦草生物总量及吸钾总量均呈极显著正相关 .2mol/LHNO3提取的释钾速率相关显著性明显高于氢质树脂法 ,其中 0～ 2h的土壤释钾速率能较好地描述土壤钾的有效性     

广东不同母质发育水稻土钾素的固定与释放

本文通过室内模拟和化学方法研究了广东几种不同母质发育的水稻土的钾素的固定与释放特性。结果表明,砂页岩、珠江三角洲沉积物、石灰岩和玄武岩发育的水稻土的固钾量均随钾加入量的增加而增大,但花岗岩发育的水稻土却相反;砂页岩、花岗岩和玄武岩发育的水稻土的固钾量在淹水时最高,而沉积物和石灰岩发育的水稻土则在恒湿时最高;沉积物发育的水稻土的非交换性钾累计释放量和平均释放速率显著高于其它母质发育的水稻土;施钾肥对非交换性钾释放的影响因土壤所含粘土矿物类型而异。     

土壤钾释放速率参数的理论计算及其实践应用

选用二种电场强度研究２０个低丘红壤玉米田试验的钾释放速率特性,用二级动力学方程来表征,并求得土壤释放的速率方程和钾释放的初始速率等参数。     

我国北方主要土壤非交换性钾释放速率的研究

采用连续流动交换技术研究了我国北方２５个供试土壤非交换性钾的释放速率。结果表明,土壤晨交换性钾释放缓慢,而持续时间长;最大释放速率变幅为０．１９５￣２．３０ｍｇ／（ｋｇ·ｍｉｎ）,６００分钟平均释放速率变幅为０．０６６￣１．１２１ｍｇ（ｋｇ·ｍｉｎ）,释放持续时间一般在６００分种以上。在６００分种释放时间内非交换性钾释放百分率变幅在５．４％￣３９．６％之间。土壤非交换性钾释放速率与盆栽耗钾试验中玉     

在不同水土保持耕作中磷和钾的分层研究

通过对25cm以上土层精确的定量样品分析以及在实验室对有效磷和有效钾进行必要的测定,研究了在长期水土保持耕作措施下土壤中磷和钾的分布状况。结果表明在垄作、沟种及平耕地的磷和钾均具有明显的垂直分层性。一般地,最上层5cm土层中的有效磷、钾含量是5~15cm土层中的3.5倍多。     

湖南旱地土壤对铵离子的矿物固定与固定态铵释放的动力学研究

采用振荡平衡法和好气培养-间歇淋洗法研究了湖南省主要旱地土壤对添加铵离子的矿物学固定和土壤固定态铵释放的动力学特性。结果表明,供试土壤对添加铵离子的矿物固定速度很快,反应12小时后基本上达到了最大固定量;而土壤固定态铵的释放则非常缓慢,反应42天后仍未达到最大释放量。这一动力学特征有利于土壤对溶液中NH4+的保持,防止NH4+的环境污染,有效地为作物供氮和提高氮肥利用率。一级动力学方程能较好地拟合供试土壤对铵离子的矿物学固定的动力学资料,一级动力学方程和抛物扩散率方程均能较好地拟合供试土壤固定态铵释放的动力学资料,表现为相关系数r值较高,标准误SE值较低。     

华北与西北地区典型土壤固钾能力差异研究

试验在我国华北和西北小麦玉米种植地区进行,研究了几种典型土壤在连续13年的K肥施用及小麦秸秆还田条件下耕层土对外源K素的固定能力差异.结果表明:相比常年只施NP肥处理,连续施用K肥或秸秆还田可显著降低土壤对外源K素的固定量,土壤固K量随环境溶液中K素浓度的增加而增加,但固定率下降.随土层变深,各定位点土壤固K量和固K率均随之增加,华北两定位点相对明显.轮作地区各处理0 ～ 20 cm土层土壤对外源K素的固定量(率)均远高于原始土壤,而单作区土壤的固K量(率)稍高或低于原始土.土壤固K能力表现出地带性规律,整体看取自华北两个定位点的土壤对外源K的固定能力强于取自西北两个定位点的土壤.     

Plant Availability of Cadmium in Soils: I. Extractable Cadmium in Newly and Long-Term Cultivated Soils

Abstract

Effects of long-term use of phosphate fertilizers on extractable soil Cd in relation to its concentrations in plants were investigated. “Paired” soil samples were collected from newly and long-term cultivated fields and analyzed for Cd by extraction with NH₄OAc, DTPA, NH₄OAc-EDTA, NH₄NO₃, HCl and CaCl₂. Plant samples were also collected and analyzed for Cd. Significant differences in extractable Cd by all the extractants except NH₄NO₃ were observed between the newly and long-term cultivated soils. The Cd concentrations in plants were not increased by the elevated extractable Cd. Although significant relationships were observed between plant Cd and extractable soil Cd, none of the extractants used alone gave a good assessment of plant-available Cd for all the samples used in this study.     

Potassium Release Kinetics in Potato Growing Alluvial Soils of North Western India

Potassium (K) release and kinetics were studied in soils of north western India varying in soil properties. Mathematical equations were tested for their applicability to describe K release in the alluvial soils. The major portion of total K was released within 1 h of the reaction. The initial rapid K release was followed by a slower rate of K release. The linear equation adequately described the K release kinetics. The next best fit to satisfactorily describe the reaction rates of K release was the first order equation. There existed two separate first order equations indicating different rates of K release. Soils having higher native potassium and clay released higher amounts of K and at a faster rate. However, the first order equation showed that the faster rate of reaction might be inhibited by higher amounts of clay, probably because of the restrictive properties of illites.     

Influence of Aluminum Hydroxide on Potassium Release from Two Colombian Soils

Abstract

The effect of sesquioxides on the mechanisms of chemical reactions that govern the transformation between exchangeable potassium (Kex) and non‐exchangeable K (Knex) was studied on acid tropical soils from Colombia: Caribia with predominantly 2∶1 clay minerals and High Terrace with predominantly 1∶1 clay minerals and sesquioxides. Illite and vermiculite are the main clay minerals in Caribia followed by kaolinite, gibbsite, and plagioclase, and kaolinite is the major clay mineral in High Terrace followed by hydroxyl‐Al interlayered vermiculite, quartz, and pyrophyllite. The soils have 1.8 and 0.5% of K₂O, respectively. They were used either untreated or prepared by adding AlCl₃ and NaOH, which produced aluminum hydroxide. The soils were percolated continuously with 10 mM NH₄OAc at pH 7.0 and 10 mM CaCl₂ at pH 5.8 for 120 h at 6 mL h^?1 to examine the release of Kex and Knex. In the untreated soils, NH₄ ⁺ and Ca²⁺ released the same amounts of Kex from Caribia, whereas NH₄ ⁺ released about twice as much Kex as Ca²⁺ from High Terrace. This study proposes that the small ionic size of NH₄ ⁺ (0.54 nm) enables it to enter more easily into the K sites at the broken edges of the kaolinite where Ca²⁺ (0.96 nm) cannot have access. As expected for a soil dominated by 2∶1 clay minerals, Ca²⁺ caused Knex to be released from Caribia with no release by NH₄ ⁺. No Knex was released by either ion from High Terrace. After treatment with aluminum hydroxide, K release from the exchangeable fraction was reduced in Caribia due to the blocking of the exchange sites but release of Knex was not affected. The treatment increased the amount of Kex released from the High Terrace soil and the release of Knex remained negligible although with Ca²⁺ the distinction between Kex and Knex was unclear. The increase in Kex was attributed to the initially acidic conditions produced by adding AlCl₃ which may have dissolved interlayered aluminum hydroxide from the vermiculite present, thus exposing trapped K as exchangeable K. The subsequent precipitation of aluminum hydroxide when NaOH was added did not interfere with the release of this K, and so was probably formed mostly on the surface of the dominant kaolinite. Measurement of availability of K by standard methods using NH₄ salts could result in overestimates in High Terrace and this may be a more general shortcoming of the methods in kaolinitic soils.     

Plant Availability of Cadmium in Soils: II. Factors Related to the Extractability and Plant Uptake of Cadmium in Cultivated Soils

Abstract

Eighty four soil samples collected from southeastern Norway were analyzed for Cd by extraction with NH₄OAc, DTPA, NH₄OAc-EDTA, NH₄NO₃, HCl and CaCl₂. The total Cd, pH, exchangeable K and Ca, dithionite-extractable Mn, available P and fine sand (0.2–0.02 mm) contents were the principal factors related to the extractable Cd, with some inter-extractant variations. Cadmium extracted by NH₄NO₃, NH₄OAc, HCl and CaCl₂ decreased with increasing soil pH, but the Cd extracted by all the extractants increased with increasing total Cd, exchangeable K and Ca, available P, and Mn-oxide contents in the soils. The Cd concentrations in plants were significantly related to the extractable Cd, exchangeable Ca and Mg, pH, Mn-oxides and organic matter content.     

吉林省大豆种植区土壤主要营养元素与大豆产量的相互关系研究

土壤中的营养元素是评价土壤自然肥力的主要因素之一。本文对吉林省大豆种植区土壤中的主要营养元素N、P、K的供应水平进行了分析 ,并探讨了它们与大豆产量之间关系。研究表明 :吉林省大豆种植区土壤供氮水平属于中级 ,供磷和供钾水平属于高级 ,并当土壤碱解氮 :有效磷 :有效钾接近 1∶0 .3～ 0 .4∶1.7～ 1.8时 ,大豆单产水平较高 ,为提高大豆单产、指导科学施肥提供了科学依据     

Potassium Fixation and Release Characteristics of Several Normal and K-Exhausted Soils in the Middle and Lower Reaches of the Yangtse River,China

Potassium (K) fixation and release in soil are important factors affecting K availability to plants and the utilization efficiency of K fertilizer. Three typical soils (red soil, yellow cinnamon soil, and alluvial soil) were collected from the middle and lower reaches of Yangtse River, China, to study the K-fixation and K-release characteristics of the normal and K-exhausted soil. Results showed that K fixation of added K in K-exhausted soils were significantly (P < 0.05) greater than that of the normal soils. There were significantly (P < 0.05) negative correlations among K-fixation capacity, concentration of soil-available K, and K⁺ saturation. Irrespective of soil K exhaustion, K fixation of added K was in the order of red soil > yellow cinnamon soil > alluvial soil, but the cumulative amount of K released from the three soils during successive extractions with 1.0 mol L^?1 nitric acid (HNO₃) was in the opposite order. The cumulative amounts of K released with 1.0 mol L^?1 ammonium acetate (NH₄OAc) and 1.0 mol L^?1 HNO₃ extraction increased with the increasing numbers of extractions. The K-releasing power of soil by successive extraction decreased gradually and finally became almost constant. The release of K was lower in K-exhausted soil than in normal soil. Overall, the information obtained in this study will be helpful in formulating more precise K fertilizer recommendations for certain soils.     

淹水土壤磷释放机理研究进展

磷是水体富营养化的主要控制因素,以农业磷为主的非点源污染通常是水体富营养化的主要来源。在许多农业地区,尤其在季节性洪水淹没的条件下,变化的环境因素导致农业土壤释放到水中的磷加剧。本文主要以影响磷释放吸附的因素为角度,综述了国内外淹水条件下土壤磷释放机理的研究进展,并指出了目前研究存在的问题,提出了建议。