工艺参数对木材化学镀镍金属沉积速率的影响

用点滴加入镀液的方法进行了木材化学镀镍试验,分析施镀温度、镀液pH值和施镀时间等对镍金属沉积速率的影响,得出比较理想的镀镍工艺条件.     

化学镀镍层的发黑处理

由于不同的化学镀镍液具有不同的耐氧化性，所得银白色化学镀镍层的耐氧化性也不同，致使发黑处理时难以获得均匀的黑色膜，而且镀层易剥落，光亮性差，因此实际应用较少。 本发明提供了一种化学镀镍层的发黑处理方法，使化学镀镍层变成均匀、光亮的耐磨、耐蚀的化学镀镍黑色膜，发掘黑色镍层的应用潜能。 化学镀镍层的发黑处理方法是将化学镀镍层浸入下述溶液１０秒～１２０秒： 强氧化剂溶液４份～８份体积，成膜剂１份～２份体积， 水１份～１０份体积，溶液温度为２０℃～５０℃。 为了获得光亮、致密的黑色膜，而且又保持化学镀镍层中…     

化学镀镍桦木单板的镀层成分分析及性能研究

通过对桦木单板表面化学镀镍,可以得到连续、均匀的镀层,从而制得具有良好导电性和电磁屏蔽功能的木材-金属复合材料。扫描电子显微镜(SEM)观察表明:看似光滑的桦木单板表面是很粗糙的,经化学镀后桦木表面金属感极强,但基本构造没有明显改变。利用能谱(EDS)和X射线光电子能谱(XPS)分析表明:镀层中主要成分为镍,磷含量很低。X射线衍射仪分析表明镀层为多晶结构。此木材-金属复合材料的电磁屏蔽效能在9kHz~1.5GHz的频率范围内可达到60dB,导电性和导热性能较素材有显著提高。     

木材表面化学镀处理技术

现实生活中电子产品在室内环境中的运用日益增多,为解决木质产品的电磁屏蔽性,将电子产业成熟的化学沉积金属镀工艺技术引入到木材处理中,阐述了化学镀的机理及其在木材加工中的利用,以木材化学镀铜、镀金工艺为例,从其研究进展、处理工艺、质量评价等方面分析了木材化学镀铜、镀金处理后材料的性能以及生产应用的可行性.     

化学镀镍单板的导电性和电磁屏蔽效能

为了实现单板的导电性和电磁屏蔽效能,对单板进行了化学镀镍研究,通过表面电阻率和电磁波网络分析仪测量方法对化学镀镍单板的导电性和电磁屏蔽效能进行了分析。结果表明：化学镀镍单板的导电性随着金属镍沉积量的增加而增加,但单板的导电性具有各向异性,平行于纤维方向的导电性要好于垂直于纤维方向的导电性。此外,这种各向异性在金属镍沉积量较少的情况下表现得更加明显,化学镀镍单板的电磁波屏蔽效能随着由于金属镍沉积量的增加而引起导电性的增加而增大,在本研究中化学镀镍单板的电磁波屏蔽效能可以达到30～60dB。     

60mm厚枫香木材快速干燥工艺

针对60 mm厚枫香木材,在常规干燥工艺的基础上,通过试验探索出先高温喷蒸预热、后降温,再恒温干燥的改进工艺.试验结果表明:采用改进干燥工艺,不仅干燥周期比常规干燥缩短约12 d,而且板材干燥质量显著提升,有助于提升枫香木材的干燥效率,节约企业的干燥成本.     

刷镀规范对快速镍镀层耐磨性的影响

一、前言快速镍是刷镀维修技术中最常用的镀种之一。因其具有耐磨性较高、镀积速度快等优点,所以被广泛地用于修复各种机械零件的磨损表面。可是快速镍刷镀层的耐磨性并不是不变的,它与所修复零件(镀层)的工作条件,即摩擦磨损工况有关。并且,刷镀工艺参数选择得     

桉树木材的浸渍增强热处理技术

木材热处理是当前木材改性的发展方向.木材经热处理后,其平衡含水率下降,耐久性及尺寸稳定性增加,但力学强度有所下降,在很大程度上限制了热处理木材的应用范围.采用先经三聚氰胺改性脲醛树脂(MUF)浸溃,再进行热处理的工艺,不但处理材的尺寸稳定性改善,而且其力学强度与素材相比无降低,甚至略有提高.     

《木材工业》2006年（第20卷）总目次

第一期1我国木材工业发展方向…………………………………………………………………………………陈绪和5现代木材工业在循环经济中的发展优势……………………………………………………熊满珍鲍甫成8定向结构刨花板产品市场现状与展望…………………………………李薇姜征Dominique Janssens12竹/木复合材料的研究现状与发展趋势……………………………………………王小青刘君良张双保15工艺参数对木材化学镀镍金属沉积速率的影响……………………………………………黄金田赵广杰18竹木基材用紫外光固化涂料…………………………………………     

木材科学研究中的化学问题

木材科学作为一门研究木质化天然材料结构、性质和功能改良的科学,在研究中存在很多化学问题。文中从木材化学成分提取、能源化利用、改性、复合材料制备及年轮化学等研究的机理和工艺着手,综述了木材科学研究中涉及的无机化学、有机化学、高分子化学、表面化学、物理化学及分析化学等化学问题,对木材科学研究的现状和发展趋势进行了总结分析,以期有利于对木材科学的认识和掌握木材科学研究的方向。     

Development of Electroless Copper and Gold Plating on Wood

The use of more and more electron products requires interior wood products to have the performance of electromagnetic shielding. One of the ways to realize it is to introduce the chemical plating which has already been developed in electron industry into wood processing. The paper clarifies the mechanism of electroless copper and gold plating and its application to wood. It emphasizes the development and technology of electroless copper and gold plating on wood. Meanwhile, it points out that it is highly feasible to take this technology into effect.     

化学镀Ni-P合金在木工刀具上的应用研究

利用化学镀技术,在木材加工用硬质合金圆锯片上制备了Ni-P合金镀层,通过XRD、中性盐雾实验和显微硬度分析等手段,对镀层的组织特征、热稳定性、耐蚀性及硬度等进行了分析。锯片的切割实验表明,Ni-P合金镀层具有均匀致密、硬度高、耐磨性高、减摩擦、耐蚀性好等特性。     

Regeneration and reuse of exhausted solutions of electroless nickel plating wood veneer

The regeneration of exhausted solutions of electroless nickel plating wood veneer was realized using soluble calcium salt to precipitate and remove phosphite and then using fluoride to remove residual calcium ions from the solution. The effect of the pH value of the solution, treatment temperature and the molar ratio of calcium ions to phosphite ions on the removal efficiency of phosphite was investigated. Wood veneer was electroless plated using regenerated solutions. A coating with better electrical conductivity and electromagnetic shielding was obtained. __________ Translated from Journal of Northeast Forestry University, 2005, 33(3): 47–48 [译自: 东北林业大学学报, 2005, 33(3): 47–48]     

桦木单板化学镀镍过程的FTIR和XPS分析

采用化学镀法在桦木表面获得Ni-P合金镀层.利用傅立叶红外光谱(FTIR)和X射线光电子能谱(XPS)技术,分析桦木单板化学镀前预处理后,桦木表面官能团的变化和化学镀后元素的变化.FTIR分析表明:分别经活化和解胶处理后的桦木单板表面FTIR谱与素材几乎重合,表明活化和解胶处理过程没有使木材表面发生任何化学反应.XPS分析结果表明:活化后桦木单板表面吸附了内部包裹着具有催化作用的Pd0胶粒,此时Pd0起不到催化作用;解胶后,Pd0才显露出来并催化化学镀反应的进行,但化学镀过程之初是Ni先沉积而P的沉积滞后,所得镀层成分为Ni-P合金.     

Electromagnetic interference shielding material from electroless copper plating on birch veneer

Copper coating on birch veneer substrate was conducted by electroless deposition to prepare electromagnetic interference shielding material. In the process, Pd²⁺ ions were chemically adsorbed on the wood surface modified with chitosan. Then, they were reduced and dipped into a plating bath where copper film was successfully initiated. The coatings were characterized by SEM–EDS, XPS, and XRD. The metal deposition, surface resistivity, and electromagnetic shielding effectiveness were measured. The morphology of the coating observed by SEM is uniform, compact, and continuous. EDS, XPS, and XRD results showed that the coating consists of Cu⁰ with crystalline structure. Moreover, the copper films firmly adhere to the wood surface. Birch veneers plated with crystalline copper film exhibit high electro-conductivity with surface resistivity of 119.1?mΩ?cm^?2 and good electromagnetic shielding effectiveness of over 60?dB in frequencies ranging from 10?MHz to 1.5?GHz.     

Preparation and characterization of electroless nickel-coated cellulose fibres

The aim of this project was to fabricate electroless nickel-coated cellulose fibres. Ultimately, these nickel-coated cellulose fibres will be used to develop a cost-effective polymer composite for electromagnetic interference (EMI) shielding and/or electrostatic discharge (ESD) applications. An attempt has been made to impart electrical conductivity onto cellulose fibres via an electroless nickel plating process. The aim was to achieve a homogeneous, continuous layer of Ni on the cellulose fibres, and the plating conditions were optimized to achieve this. The relationship between the coating morphology and the performance of the coated fibre was also of interest. Testing was carried out using cellulose filter paper and then loose cellulose fibres. Scanning electron microscopic (SEM) images of nickel-coated filter paper showed that nickel particles are bonded to the cellulose fibres. The coating appeared more compacted and continuous as plating time increased, corresponding to lower surface resistivity. This observation suggested a correlation between morphology and electrical conductivity of the coating. For nickel-coated cellulose fibres, after optimization of plating conditions, a uniform deposition of nickel particles around the cellulose surfaces was confirmed by SEM images. EDS and XRD results confirmed similar coating could be produced on filter paper and cellulose fibres. SEM images of cross-sectioned nickel-coated cellulose fibres illustrated nickel particles had penetrated into the inner walls of the cellulose fibres. This impregnation of the fibres should act to increase the bonding between nickel coating and cellulose fibres. These nickel-impregnated cellulose fibres could now be incorporated into a polymer matrix to create an electrically conducting composite with the right processing parameters.     

表面涂层木工刀具的研究进展

介绍几种表面涂层木工刀具的加工方法和使用状况,分析表面涂层刀具的切削特点和磨损形态,概述了国内外研究进展.研究成果表明,涂层处理可以延长刀具使用寿命,减少刃磨和换刀时间,提高生产效率和表面加工质量.     

Surface characteristics of electroless nickel plated electromagnetic shielding wood veneer

Wood is a kind of porous natural material with very poor electro-conductivity, and it has almost no function of electromagnetic shielding. The method of electroless nickel plating was used to produce wooden material with electrical and effective electromagnetic shielding properties. Ni-P alloy layer was obtained on wood surface. The surface feature of plated wood veneer was observed by SEM and the surface composition and microstructure of the layer under different conditions were investigated by EDS and XRD respectively. Meanwhile, the relevant surface resistivity and electromagnetic shielding effectiveness were measured. Correlations of the phosphorous content in the layer to the structure of Ni-P alloy, electro-conductivity and electromagnetic shielding of plated veneers were discussed. SEM photos showed that the surface of electroless nickel plated veneers were covered with Ni-P alloy layer entirely, which made wood veneers more like metal. At the same time, the results showed that with the decreasing of the phosphorous content in the layer, the microstructure of Ni-P alloy layer transformed to be microcrystalline and electro-conductivity and electromagnetic shielding effectiveness were improved. When the phosphorous content was less than 2.37wt pct in the layer, the microstructure of Ni-P alloy layer was microcrystalline structure and its sur- face resistivity and electromagnetic shielding effectiveness were nearly 0.5Ω/□ and 55-60dB respectively.     

无电解电镀法制备具有电磁屏蔽功能的木材-金属复合材料

利用无电解电镀的方法制备了导电且具有电磁屏蔽功能的木材-金属复合材料.探讨了镀液用量、施镀时间和施镀温度对复合材料的表面电阻率和电磁屏蔽效能的影响,同时利用能谱分析(EDS)、X射线衍射分析(XRD)和扫描电镜分析(SEM)方法分别测定了不同施镀温度下得到的各镀层的磷含量、微结构和表面形貌.实验结果表明,在镀液使用量为500mL,施镀时间为30min和施镀温度为62℃的最优条件下,所得镀层的导电性和电磁屏蔽效果最佳.而且发现,随着施镀温度的提高,镀层中磷含量缓慢增加.XRD分析表明不同温度所得各镀层的结构均为多晶结构,通过SEM分析,镀层均匀、连续且具有金属光泽,说明在pH值一定的条件下,施镀温度对镀层结构和表面相貌的影响很小.图7表3参11.