Effects of nitrogen deposition on the acidification of terrestrial and aquatic ecosystems

The concentration of ammonium and nitrate in precipitation has increased during this century. The deposition of N compounds (wet + dry) is reaching 30 to 40 kg ha^?1yr^?1 in many areas in Central Europe and above 20 kg in the southern parts of Scandinavia. In extreme situations throughfall data indicate depositions above 60 kg ha^?1yr^?1 in Central Europe and above 40 kg ha^?1yr^?1 in south Sweden. Very high depositions are observed on slopes at forest edges and adjacent to areas with animal farms and manure spreading. In areas with low N deposition almost all deposited N (>95%) will be absorbed in the tree canopies or in the soil. In areas with high deposition an increased outflow is observed which in some cases reach 10 to 15 kg ha-lyr-1. The increased output is an indication of N saturation of the ecosystem and it leads to acidification effects in soils, soilwater, groundwater and surface waters.     

Nutrient fluxes from a soil treatment process for pig slurry

Abstract. The effects of pig slurry applications to a hydrologically isolated field treatment plant (at Solepur) were studied over a period of eight years. Thirty repeated doses, averaging 160 m³ ha^?1 were applied from April to October of each year (1991–1995), to reach a total application of 4930 m³ ha^?1. All slurry samples were analysed for their total solids (TS), macronutrient (C, N, P, K, Ca) and micronutrient (Cu, Zn) content. In total, 284 tonnes of total solids (57 t TS ha^?1 yr^?1), 115 tonnes of carbon (23 t C ha^?1yr^?1), 24.5 tonnes of nitrogen (4900 kg N ha^?1 yr^?1), 7964 kg of phosphorus (1593 kg P ha^?1 yr^?1), 16 518 kg of potassium (3304 kg K ha^?1 yr^?1), 183 kg copper (37 kg Cu ha^?1 yr^?1) and 266 kg zinc (53 kg Zn ha^?1 yr^?1) were applied to the soil. Thus, this site provides an opportunity to assess the balance and to examine the long‐term behaviour of nutrients under conditions of intensive land application of pig slurries or similar effluents. The main nutrient fluxes through the soil‐water system were determined for each element. Over 40% of the total carbon applied was retained by the soil. About 25% of the slurry nitrogen applied remained in the soil profile and 12.5% was leached through the drainage water as nitrate. Most of the slurry phosphorus applied was retained in the soil profile either as P‐Dyer extractable (83%), or as total soil phosphorus (112%); <0.01% was found in the drainage water. Forty‐three per cent of the potassium applied in the slurry was recovered from the soil profile and 15% was recovered in the drainage water. Most of the copper (62%) and zinc (74%) applied in the slurry remained in the soil as EDTA extractractable forms; very low percentages (0.05% and 0.6% respectively) were found in the drainage water.     

Long-term nitrogen balance for pearl millet (Pennisetum glaucum L.) in an acid sandy soil of Niger

On acid sandy soils of Niger (West Africa) fertilizer N recovery by pearl millet (Pennisetum glaucum L.) is often more than 100 per cent in years with normal or above average rainfall. Biological nitrogen fixation (BNF) by N₂-fixing bacteria may contribute to the N supply in pearl millet cropping systems. For a long-term field experiment comprising treatments with and without mineral fertilizer (F) and with and without crop residue application (CR) a N balance sheet was calculated over a period of six years (1983-1988). After six years of successive millet cropping total N uptake (36-77 kg N ha^?1 yr^?1) was distinctly higher than the amount of fertilizer N applied (30 kg N ha^?1 yr^?1). The atmospheric input of NH₄-N and NO₃-N in the rainwater was about 2 kg N ha_?1 yr^?1, 70 % in the form of NH₄-N. Gaseous NH₃ losses from urea (broadcast, incorporated) were estimated from other experiments to amount to 36 % of the fertilizer N applied. Nitrogen losses by leaching (15 to > 25 kg N ha^?1 yr^?1) were dependent on the treatment and on the quantity and distribution of single rainfall events (>50 mm). Decline in total soil N content (0-60 cm) ranged from 15 to 48 kg N ha^?1 yr^?1. The long-term N balance (1983-1988) indicated an annual net gain between 6 (+CR-F) and 13 (+CR+F) kg N ha^?1 yr^?1. For the control (-CR-F) the long-term N balance was negative (10 kg N ha^?1 yr^?1). In the treatment with crop residues only, the N balance was mainly determined by leaching losses, whereas in treatments with mineral fertilizer application the N balance depended primarily on N removal by the millet crop. The annual net gain in the N balance increased from 7 kg ha^?1 with mineral fertilizer to 13 kg ha^?1 in the combination mineral fertilizer plus crop residues. In both the rhizosphere and the bulk soil (0-15 cm), between 9 and 45% of the total bacterial population were N₂-fixing (diazotrophic) bacteria. The increased N gain upon crop residue application was positively correlated with an increase in the number of diazotrophic and total bacteria. The data on bacterial numbers suggest that the gain of N in the longterm N balance is most likely due to an N input by biological nitrogen fixation. In addition, evidence exists from related studies that the proliferation of diazotrophs and total bacteria in the rhizosphere due to crop residue application stimulated root growth of pearl millet, and thus improved the phosphorus (P) acquisition in the P deficient soil.     

Long continued applications of N fertilizer to cereals on sandy loam: grain and straw response to residual N

Abstract. The residual value of mineral N fertilizer applied in the spring was investigated in a field experiment where four cereals (winter wheat, winter barley, spring barley and spring oats) had been grown at reduced (0.7N), normal (1N) or high (1.3N) N fertilizer rates for 20 to 28 years. The effect of previous N fertilizer dressing was tested in two succeeding years by replacing the original N rate with five test N rates ranging from 0 to 240 kg N ha^?1 for winter cereals and 0 to 200 kg N ha^?1 for spring cereals. In the first test year, winter wheat grown on plots previously supplied with the high rate of mineral fertilizer (202 kg N ha^?1 yr^?1) yielded more grain and straw and had a higher total N uptake than wheat on plots previously supplied with the normal (174 kg N ha^?1 yr^?1) or reduced (124 kg N ha^?1 yr^?1) rate. The grain yield response and N uptake was not significantly affected by the N supply in the test year. The winter wheat grown in the second test year was unaffected by the previous N supply. Grain and straw yield response and total N uptake for spring barley, winter barley and oats, were almost identical irrespective of the previous N rate. After 20 to 28 years there were no significant differences in soil C and N (0 to 20 cm) between soil receiving three rates of N fertilizer. Soil from differently fertilized oat plots showed no significant differences in N mineralizing capacity. Nitrate leaching losses from the soils at the three N rates were estimated and the N balances for the 20 to 28 years experimental period calculated. The data indicated a reduction in overall loss of 189 to 466 kg N ha^?1 at the normal and high N rates compared with the reduced N rate. We conclude that the N supplying capacity and soil organic matter content of this fertile sandy loam soil under continuous cereal cropping with straw removal was not significantly affected by differences in N fertilizer residues.     

Nitrogen Balance in the Magruder Plots Following 109 Years in Continuous Winter Wheat

Abstract

The Magruder plots are the oldest continuous soil fertility wheat research plots in the Great Plains region, and are one of the oldest continuous soil fertility wheat plots in the world. They were initiated in 1892 by Alexander C. Magruder who was interested in the productivity of native prairie soils when sown continuously to winter wheat. This study reports on a simple estimate of nitrogen (N) balance in the Magruder plots, accounting for N applied, N removed in the grain, plant N loss, denitrification, non‐symbiotic N fixation, nitrate (NO₃ ^?) leaching, N applied in the rainfall, estimated total soil N (0–30 cm) at the beginning of the experiment and that measured in 2001. In the Manure plots, total soil N decreased from 6890 kg N ha^?1 in the surface 0–30 cm in 1892, to 3198 kg N ha^?1 in 2002. In the Check plots (no nutrients applied for 109 years) only 2411 kg N ha^?1 or 35% of the original total soil organic N remains. Nitrogen removed in the grain averaged 38.4 kg N ha^?1 yr^?1 and N additions (manure, N in rainfall, N via symbiotic N fixation) averaged 44.5 kg N ha^?1 yr^?1 in the Manure plots. Following 109 years, unaccounted N ranged from 229 to 1395 kg N ha^?1. On a by year basis, this would translate into 2–13 kg N ha^?1 yr^?1 that were unaccounted for, increasing with increased N application. For the Manure plots, the estimate of nitrogen use efficiency (NUE) (N removed in the grain, minus N removed in the grain of the Check plots, divided by the rate of N applied) was 32.8%, similar to the 33% NUE for world cereal production reported in 1999.     

Simulated nitrogen deposition affects soil fauna from a semiarid Mediterranean ecosystem in central Spain

Nitrogen (N) deposition is a major threat to the semiarid Mediterranean ecosystems. We simulated a gradient of N deposition (0, 10, 20 and 50 kg N ha^?1 year^?1?+?6.4 kg N ha^?1 year^?1 ambient deposition) in a Mediterranean shrubland from central Spain. In autumn 2011 (after 4 years of experimental duration), soil cores were taken to extract the soil fauna. Acari (45.54%) and Collembola (44.00%) were the most represented taxonomical groups, and their abundance was negatively related to soil pH. Simulated N deposition had an impact on the total number of individuals in soil as well as on Collembola and Pauropoda abundance. Collembola abundance increased with N loads up to 20 kg N ha^-1 year^-1 and then decreased. This response was attributed to soil acidification (between 0 and 20 kg N ha^-1 year^-1) and increased soil ammonium (between 20 and 50 kg N ha^-1 year^-1). Pauropoda were favoured by additions of 50 kg N ha^-1 year^-1, and it was the only taxonomical group whose abundance was exclusively related to N deposition, suggesting their potential as bioindicators. Contrary to predictions, there was a negative relationship between soil faunal abundance and plant diversity. In conclusion, soil faunal communities from semiarid Mediterranean ecosystems in central Spain seem to be primarily influenced by soil chemistry (mainly pH) but are also susceptible to increased N deposition. The main drivers of change under increased N deposition scenarios seem to be soil acidification and increased ammonium in soils where nitrate is the dominant mineral N form.     

Assessment of critical loads and their exceedance on Dutch forests using a multi-layer steady-state model

Critical acid loads for Dutch forests were derived using a multi-layer steady-state model that includes canopy interactions, nutrient cycling, mineral weathering and N transformations. Values were calculated for combinations of 12 tree species and 23 soil types for a 10×10 km grid. Critical acid loads thus derived increased with decreasing soil depth. Nearly 90% of the values varied approximately between 1500 and 4000 mol_c ha^?1 yr^?1 at 10 cm soil depth and between 750 and 2000 mol_c ha^?1 yr^?1 at the bottom of the rootzone. Separate critical loads calculated for N and S at the bottom of the rootzone varied between approximately 300 and 1000 mol_c ha^?1 yr^?1 for N and between 150 and 1250 mol_c ha^?1 yr^?1 for S. Using deposition data of 1990, a median reduction of the deposition by approximately 75% was calculated to achieve the critical loads at the bottom of the rootzone. The overall uncertainty in this value was estimated to be about 10%, although it can be much larger for specific soil types such as clay and peat soils. For N a larger reduction deposition percentage was calculated than for S, especially for coniferous forests with a high present N input.     

Acidification of Nova Scotia Lakes

Although water chemistry of precipitation and lakes in Nova Scotia is dominated by C1 from sea salt, correction for marine influence reveals that the dominant anion in acidified lakes is SO₄. Atmospheric deposition of non-marine SO₄ (SO₄) and NO₃- for the period 1977–1980 at 4 stations in southwest Nova Scotia averaged 47 meq SO₄ ^* m^?2 yr^?1 and 21 meq NI₃-m^?2 yr^?1 compared with 38 and 13 meq, respectively, for the average of 3 stations in the northeastern third of the province. Precipitation pH increased from 4.5 to 4.8 along the same axis. Almost 50% of the SO₄ deposition occurred when storms came from the southwest, indicating low pressure tracks which pass south of major Canadian sources of S. SO₄ ^* deposition in metropolitan Halifax (1982 bulk data) was 87 meq m^?2 yr^?1, due to local emissions of ca. 28 300 tonne S in the area, as well as LRTAP. Concurrent deposition of NO₃-N was 15 meq m^?2 yr^?1 (2.1 kg ha^?1 yr ^?1). Loadings from SO₄ deposition in the Halifax area amount to 42 kg ha^?1 yr^?1 and clearly exceed the federal guideline (M.O.I., 1983) of 20 kg ha^?1 yr^?1. Water chemistry of southwest, northeast, and Halifax area lakes show the same general SOI trends as observed for atmospheric deposition. In addition we find a positive relationship between SOI concentrations in the urban lakes and proximity to the center of the urban area.     

Calculating critical loads of acid deposition with PROFILE — A steady-state soil chemistry model

A steady state soil chemistry model was used to calculate the critical load of acidity for forest soils and surface waters at Lake GÄrdsjön in S.W. Sweden. The critical load of all acid precursors (potential acidity) for the forest soil is 1.64 kmol_c ha^?1 yr^?1, and 1.225 kmol_c ha^?1 yr^?1 for surface waters. For the most sensitive receptor, the critical load is exceeded by 1.0 kmol_c ha^?1 yr^?1, and a 80% reduction in S deposition is required, if N deposition remains unchanged. The critical load is largely affected by the present immobilization of N in the terrestrial ecosystem which is higher than the base cation uptake. The model, PROFILE, is based on mass balance calculations for the different soil layers. From measurable soil properties, PROFILE reproduces the present stream water composition as well as present soil solution chemistry. The model calculates the weathering rate from independent geophysical properties such as soil texture and mineral composition.     

Nitrogen deposition impacts on the amount and stability of soil organic matter in an alpine meadow ecosystem depend on the form and rate of applied nitrogen

The effects of atmospheric nitrogen (N) deposition on carbon (C) sequestration in terrestrial ecosystems are controversial. Therefore, it is important to evaluate accurately the effects of applied N levels and forms on the amount and stability of soil organic carbon (SOC) in terrestrial ecosystems. In this study, a multi‐form, small‐input N addition experiment was conducted at the Haibei Alpine Meadow Ecosystem Research Station from 2007 to 2011. Three N fertilizers, NH₄Cl, (NH₄)₂SO₄ and KNO₃, were applied at four rates: 0, 10, 20 and 40 kg N ha^?1 year^?1. One hundred and eight soil samples were collected at 10‐cm intervals to a depth of 30 cm in 2011. Contents and δ¹³C values of bulk SOC were measured, as well as three particle‐size fractions: macroparticulate organic C (MacroPOC, > 250 µm), microparticulate organic C (MicroPOC, 53–250 µm) and mineral‐associated organic C (MAOC, < 53 µm). The results show that 5 years of N addition changed SOC contents, δ¹³C values of the bulk soils and various particle‐size fractions in the surface 10‐cm layer, and that they were dependent on the amounts and forms of N application. Ammonium‐N addition had more significant effects on SOC content than nitrate‐N addition. For the entire soil profile, small additions of N increased SOC stock by 4.5% (0.43 kg C m^?2), while medium and large inputs of N decreased SOC stock by 5.4% (0.52 kg C m^?2) and 8.8% (0.85 kg C m^?2), respectively. The critical load of N deposition appears to be about 20 kg N ha^?1 year^?1. The newly formed C in the small‐input N treatment remained mostly in the > 250 µm soil MacroPOC, and the C lost in the medium or large N treatments was from the > 53 µm POC fraction. Five years of ammonium‐N addition increased significantly the surface soil POC:MAOC ratio and increased the instability of soil organic matter (SOM). These results suggest that exogenous N input within the critical load level will benefit C sequestration in the alpine meadow soils on the Qinghai–Tibetan Plateau over the short term.     

Effect of soybean inoculation with Bradyrhizobium and wheat inoculation with Azotobacter on their productivity and N turnover in a Vertisol

A long-term field experiment was conducted for 8 years on a Vertisol in central India to assess quantitatively the direct and residual N effects of soybean inoculation with Bradyrhizobium and wheat inoculation with Azotobacter in a soybean–wheat rotation. After cultivation of soybean each year, its aerial residues were removed before growing wheat in the same plots using four N levels (120, 90, 60 and 30 kg ha^?1) and Azotobacter inoculation. Inoculation of soybean increased grain yield by 10.1% (180 kg ha^?1), but the increase in wheat yields with inoculation was only marginal (5.6%; 278 kg ha^?1). There was always a positive balance of soil N after soybean harvest; an average of +28 kg N ha^?1 yr^?1 in control (nodulated by native rhizobia) plots compared with +41 kg N ha^?1 yr^?1 in Rhizobium-inoculated plots. Residual and direct effects of Rhizobium and Azotobacter inoculants caused a fertilizer N credit of 30 kg ha^?1 in wheat. Application of fertilizers or microbial inoculation favoured the proliferation of rhizobia in crop rhizosphere due to better plant growth. Additional N uptake by inoculation was 14.9 kg N ha^?1 by soybean and 20.9 kg N ha^?1 by wheat crop, and a gain of +38.0 kg N ha^?1 yr^?1 to the 0–15 cm soil layer was measured after harvest of wheat. So, total N contribution to crops and soil due to the inoculants was 73.8 kg N ha^?1 yr^?1 after one soybean–wheat rotation. There was a total N benefit of 13.8 kg N ha^?1 yr^?1 to the soil due to regular long-term use of microbial inoculants in soybean–wheat rotation.     

Carbon sequestration in Norway spruce in south Sweden as influenced by air pollution,water availability,and fertilization

Carbon sequestration in 30 yr old Norway spruce in south Sweden following manipulation of nutrient and water availability is presented. The site has an annual precipitation of 1100 mm and a deposition of about 20 kg N and 25 kg S per ha^?1 yr^?1. The soil type is a poorly developed podzol. Treatment include irrigation; artificial drought; ammonium sulphate addition; nitrogen-free-fertilization and irrigation with liquid fertilizers including a complete set of nutrients. The experiment has a randomized block design with four replicates per treatment. A comprehensive investigation of the above ground C storage on an areal basis was made at the start of the experiment and after 3 yr of treatment. After 3 yr of treatment with simulated N-S deposition using ammonium sulphate (100 kg N, 114 kg S ha^?1 yr^?1), C accumulation rates in the above ground compartments had increased by 37%. Similarly, irrigation caused increased C accumulation rates by 25%, whereas simulated drought during the vegetation period during 2 yr followed by 1 yr of recovery caused a 15% reduction of the C accumulation rates. Irrigation combined with liquid fertilization (100 kg N ha^?1 yr^?1), including all important nutrient elements, led to 65% increase in C accumulation rates compared to the control. The C sequestration of the latter treatment gradually increased and, during yr 5 of treatment, 8.6 Mg C ha^?1 accumulated in stems and branches, compared to 3.6 Mg ha^?1 for the control. It is concluded that there is a strong interaction between N-deposition and C accumulation rates in Norway spruce in south Sweden. The C accumulation rates are also sensitive to water availability. The study indicates a great potential to cultivate Norway spruce in south Sweden as a renewable energy source. A shift in energy source from fossil fuels to renewable energy sources will directly reduce the net emissions of CO₂ to the atmosphere.     

Cadmium accumulation in soils from long-continued applications of superphosphate

A simple, sensitive method developed for the analysis of geostandards was used to measure the accumulation of Cd in soils from superphosphate applied annually to grass-land and arable soils for many years. Rates of application were equivalent to 33 kg P and 5 g Cd ha^?1 yr^?1 for 95 yr in three experiments in England and to 37 kg P and 20 g Cd ha^?1 yr ^?1 for 30 yr in one experiment in New Zealand. Very little Cd accumulated in the surface horizons (0–22.5cm) of either of the arable soils from England; about one-quarter of the applied Cd was detected in the sub-soil (22.5–45.0 cm) of one experiment (Broadbalk) but none in the second (Barnfield). About one-half of the applied Cd was retained in the 0–22.5 cm horizon of grassland soils from both England and New Zealand. The light (<2.2 gcm^?3) organic-rich fraction of Park Grass soil from Éngland contained about three times as much Cd as the heavier, mineral-rich fraction. This suggests that when Cd is incorporated into organic matter its mobility is decreased and soil pH then has smaller effects on its mobility. Uptake of Cd by grass-clover pasture in New Zealand averaged only 0.4 g Cd ha^?1 yr^?1 or 2% of the amount applied.     

Catch Crop and Animal Slurry in Spring Barley Grown with Straw Incorporation

Abstract

Four rates of straw (0, 4, 8 and 12 t ha^?1 yr^?1) were incorporated in a field experiment with continuous spring barley. The experiment was conducted on a sandy soil (5.5% clay) and a sandy loam soil (11.2% clay). After eight years, the straw incorporation was combined with catch-crop growing with and without winter application of animal slurry and also spring fertilization with mineral fertilizer (0, 50, 100 or 125 kg N ha^?1 yr^?1). The combined experiment was conducted for three lyears on the sandy soil and for four years on the sandy loam soil. The effects on barley dry matter yield and N uptake are presented together with the long-term effects of the straw incorporations on crop growth and soil C and N. Grain yield on the sandy loam was unaffected by straw incorporation. On the sandy soil the highest straw application rates reduced grain yield in the unfertilized barley. When the barley received mineral fertilizer at recommended levels (100 kg N ha^?1 yr^?1), grain yield on this soil was also unaffected by the high straw rates. Including a catch crop had a positive effect on the grain yield of barley on both soils. The total N uptake in grain and straw generally increased with straw application up to 8 t ha^?1 yr^?1. With the highest straw application rate (12 t ha^?1 yr^?1), the total N uptake decreased but still exceeded N uptake in barley grown with straw removal. The barley accumulated higher amounts of N when a catch crop was included. The total N uptake in the barley was significantly higher after animal slurry application. The extra N uptake, however, was much lower than the amounts of N applied with the slurry. Incorporation of straw had only a small influence on N uptake after slurry application. The straw, therefore, was not able to store the applied N during winter. In the two four-year periods before the combined experiment, grain yield on the sandy loam was generally negatively affected by straw incorporations. In the second period, N uptake began to show a positive effect of the straw. On the sandy soil, grain yield and N uptake during the whole period were generally positively affected by the straw incorporations except for the highest straw rate (12 t ha^?1 yr^?1). The sandy loam soil showed higher increases in C and N content after the repeated straw incorporations and catch-crop growing than the sandy soil. When application of animal slurry was combined with the catch crop, no further increases in soil C and N were found relative to soil where a catch crop was grown without slurry application. Large amounts of the N applied with the slurry may therefore have been lost by denitrification or nitrate leaching.     

Nitrogen Fixation,Soil Nitrogen Availability,and Biomass in Pure and Mixed Plantations of Alder and Pine in Central Korea

ABSTRACT

Rates of nitrogen (N) fixation, soil N availability, and aboveground biomass were measured in 27-year-old pure and mixed Alnus hirsuta and Pinus koraiensis plantations in central Korea. Nodule biomass and N fixation were 179.3 kg ha^{? 1} and 46.6 kg ha^{? 1}yr^{? 1} for the pure A. hirsuta plantation (PA) and 95.2 kg ha^{? 1} and 41.1 kg ha^{? 1}yr^{? 1} for the mixed A. hirsuta + P. koraiensis plantation (MAP), respectively. A. hirsuta seemed to provide more than two thirds of annual N requirement for P. koraiensis.Rates of acetylene reduction were significantly related to soil temperature (R² = 0.51, P < 0.001), but not to soil moisture content. Total inorganic N [ammonium (NH₄ ⁺)plus nitrate (NO₃ ^?)] availability measured using ion exchange bags were significantly higher under PA (27.91 μ g-N bag^{? 1}) and MAP (31.34 μ g-N bag^{? 1}) than under the pure P. koraiensis plantation (PP) (14.31 μ g-N bag^{? 1}). Especially soils under the influence of A. hirsuta showed at least 2 fold increase in resin total inorganic N concentrations. Total aboveground biomass (Mg ha^{? 1}) was 147.3 for PA, 145.8 for MAP, and 174.8 for PP, respectively, and was not significantly different among plantations. A. hirsuta significantly increased soil N availability; however, the influence of N fixation on aboveground biomass was not significant for the study plantations.     

Modeling Effects of Soil Fertility of Nutrients and Precipitation of 22 Years on Sustainable Productivity and Profitability of Pearlmillet and Sorghum Rotation in Semi-arid Vertisols

Based on experiments conducted during 1988–2009 on rainfed pearl millet/sorghum with 9 treatments in Vertisols, an efficient treatment for sustainable productivity is identified. Twenty kg of nitrogen (N) from farmyard manure (FYM) + 20 kg N (urea) + 10 kg phosphorus (P) ha^?1 in pearl millet and 40 kg N (urea) + 20 kg P + 25 kg zinc sulfate (ZnSO₄) ha^?1 in sorghum gave maximum yield and rainwater-use efficiency, whereas 20 kg N (FYM) + 20 kg (urea) + 10 kg P ha^?1 in pearl millet and 40 kg (urea) + 20 kg P ha^?1 in sorghum and gave maximum soil N, P, and potassium (K) over years. The regression model of 20 kg N (crop residue) + 20 kg N (urea) + 10 kg P ha^?1 gave maximum R² for predicting sorghum equivalent yield separately through precipitation and soil variables, whereas 20 kg N (FYM) + 20 kg N (urea) + 10 kg P ha^?1 gave maximum R² under combined model of both variables. Treatment of 20 kg N (FYM) + 20 kg N (urea) + 10 kg P ha^?1 was superior for attaining maximum sorghum equivalent yield of 1062 kg ha^?1, net returns of Rs. 4805 ha^?1, benefit/cost (BC) ratio of 1.50, and 127 kg ha^?1 of soil N, 10.3 kg ha^?1 of soil P, and 386 kg ha^?1 of soil K over years.     

Retention and Leaching of Elevated N Deposition in a Forest Ecosystem with Gleysols

The responses of nitrogen transformations and nitrate (NO_{_3} ^-) leaching to experimentally increased N deposition were studied in forested sub-catchments (1500 m²) with Gleysols in Central Switzerland. The aim was toinvestigate whether the increase in NO₃ ^- leaching,due to elevated N deposition, was hydrologically driven orresulted from N saturation of the forest ecosystem.Three years of continuous N addition at a rate of 30 kgNH₄NO₃-N ha^-1 yr^-1 had no effects on bulksoil N, on microbial biomass N, on K₂SO₄-extractableN concentrations in the soil, and on net nitrification rates.In contrast, N losses from the ecosystem through denitrification and NO₃ ^- leaching increased significantly. Nitrate leaching was 4 kg N ha^-1yr^-1at an ambient N deposition of 18 kg N ha^-1 yr^-1.Leaching of NO₃ ^- at elevated N deposition was 8 kg Nha^-1 yr^-1. Highest NO₃ ^- leaching occurredduring snowmelt. Ammonium was effectively retained within theuppermost centimetres of the soil as shown by the absence ofNH₄ ⁺ in the soil solution collected with microsuction cups. Quantifying the N fluxes indicated that 80% ofthe added N were retained in the forest ecosystem.Discharge and NO₃ ^- concentrations of the outflow from the sub-catchments responded to rainfall within 30 min. The water chemistry of the sub-catchment outflow showed thatduring storms, a large part of the runoff from this Gleysol derived from precipitation and from water which had interactedonly with the topsoil. This suggests a dominance of near-surface flow and/or preferential transport through this soil. The contact time of the water with the soil matrix wassufficient to retain NH₄ ⁺, but insufficient for a complete retention of NO₃ ^-. At this site with soilsclose to water saturation, the increase in NO₃ ^- leaching by 4 kg N ha^-1 yr^-1 through elevated N inputsappeared to be due to the bypassing of the soil and the rootsystem rather than to a soil-internal N surplus.     

Modeling of Interactive Effects of Rainfall,Evaporation, Soil Temperature,and Soil Fertility for Sustainable Productivity of Sorghum + Cowpea and Cotton + Black Gram Intercrops under Rotation Trials in a Rain-Fed Semi-arid Vertisol

Long-term effects of the different combinations of nutrient-management treatments were studied on crop yields of sorghum + cowpea in rotation with cotton + black gram. The effects of rainfall, soil temperature, and evaporation on the status of soil fertility and productivity of crops were also modeled and evaluated using a multivariate regression technique. The study was conducted on a permanent experimental site of rain-fed semi-arid Vertisol at the All-India Coordinated Research Project on Dryland Agriculture, Kovilpatti Centre, India, during 1995 to 2007 using 13 combinations of nutrient-management treatments. Application of 20 kg nitrogen (N) (urea) + 20 kg N [farmyard manure (FYM)] + 20 kg phosphorus (P) ha^?1 gave the greatest mean grain yield (2146 kg ha^?1) of sorghum and the fourth greatest mean yield (76 kg ha^?1) of cowpea under sorghum + cowpea system. The same treatment maintained the greatest mean yield of cotton (546 kg ha^?1) and black gram (236 kg ha^?1) under a cotton + cowpea system. When soil fertility was monitored, this treatment maintained the greatest mean soil organic carbon (4.4 g kg^?1), available soil P (10.9 kg ha^?1), and available soil potassium (K) (411 kg ha^?1), and the second greatest level of mean available soil N (135 kg ha^?1) after the 13-year study. The treatments differed significantly from each other in influencing soil organic carbon (C); available soil N, P, and K; and yield of crops attained under sorghum + cowpea and cotton + black gram rotations. Soil temperature at different soil depths at 07:20 h and rainfall had a significant influence on the status of soil organic C. Based on the prediction models developed between long-term yield and soil fertility variables, 20 kg N (urea) + 20 kg N (FYM) + 20 kg P ha^?1 could be prescribed for sorghum + cowpea, and 20 kg N (urea) + 20 kg N (FYM) could be prescribed for cotton + black gram. These combinations of treatments would provide a sustainable yield in the range of 1681 to 2146 kg ha^?1 of sorghum, 74 to 76 kg ha^?1 of cowpea, 486 to 546 kg ha^?1 of cotton, and 180 to 236 kg ha^?1 of black gram over the years. Beside assuring greater yields, these soil and nutrient management options would also help in maintaining maximum soil organic C of 3.8 to 4.4 g kg^?1 soil, available N of 126 to 135 kg ha^?1, available soil P of 8.9 to 10.9 kg ha^?1, and available soil K of 392 to 411 kg ha^?1 over the years. These prediction models for crop yields and fertility status can help us to understand the quantitative relationships between crop yields and nutrients status in soil. Because black gram is unsustainable, as an alternative, sorghum + cowpea could be rotated with cotton for attaining maximum productivity, assuring sustainability, and maintaining soil fertility on rain-fed semi-arid Vertisol soils.     

Effects of genotype on the response of Populus tremuloides michx. To ozone and nitrogen deposition

Elevated O₃ concentrations and N deposition levels co -occur in much of eastern United States. However, very little is known about their combined effects on tree growth. The effects of three O₃ treatments: charcoal-filtered air, non-filtered air and O₃, added at the rate of 80 ppb for 6 hr d^?1 3 d per week), four N deposition levels (0, 10, 20 and 40 kg ha^?1 yr^?1), and their interactions on growth of two Populus tremuloides clones in open-top chambers at two sites 600 km apart in Michigan were examined. Our results revealed a highly significant fertilization effect of the N treatments, even at the 10 kg ha^?1 yr^?1 rate. Ozone alone induced foliar injury, but not significant growth reductions. There was an indication that O₃ decreased growth at the O N level, but this decrease was reversed in all N treatments by the N fertilization effect. Further study is needed to more fully understand the combined effects of N deposition and O₃.     

The flux of Cd,Cu, Pb and Zn in mining polluted soils

The monitoring of heavy metal deposition onto soils surrounding old Pb-Zn mines in two locations in the UK has shown that relatively large amounts of Cd, Pb, Zn and, in one case, Cu are entering the soil annually. Small particles of ore minerals in windblown mine tailings were found to be contributing up to 1.46 g m^?2 yr^?1 of Pb, 1.41 g m^?2 yr^?1 of Zn and 0.027 g m^?2 yr^?1 of Cd. However, when these inputs from bulk deposition are compared with the concentrations of the same metals within the soil profiles it is apparent that relatively little long-term accumulation is occurring. Metals are being lost from the soil profiles, probably through leaching. A calculated relative retention parameter gave values that ranged from 0.01 to 0.17 for Cd, 0.11 to 0.19 for Zn, 0.32 to 0.63 for Cu and over 1 for Pb. These relative retention values were found to follow the order of electronegativity of the elements concerned: Pb>Cu>Zn>Cd. Distribution coefficient (Kd) values quantifying the adsorptive capacity of the mine soils for Cd and Pb showed marked differences for the two metals (12 to 69 cm³ g^?1 for Cd and 14 to 126 cm³ g^?1 for Pb) and may, in part, account for the two to one hundred-fold variation in the relative retention parameter for the different metals within these soils.