Nitrogen and Sulfur Deposition and Forest Nutrient Status in the Valley of Mexico

Mexico City experiences some of the most severe air pollution in the world. Ozone injury has been documented in sensitive tree species in urban and forested areas in the Valley of Mexico. However, little is known of the levels of other atmospheric pollutants and their ecological effects on forests in the Valley of Mexico. In this study bulk throughfall deposition of inorganic nitrogen (N) and sulfur (S) was measured for one year at a forested site upwind (east) and downwind (southwest) of Mexico City. Edaphic and plant (Pinus hartwegii Lindl.) indicators of N and S nutrient status were also measured. Streamwater NO₃ ^- and SO₄ ^2- concentrations were also determined as an indicator of watershed-level N and S loss. Annual bulk throughfall deposition of inorganic N and S at the high-pollution forested site 23 km southwest of Mexico City (Desierto de los Leones National Park; DL) was 18.5 and 20.4 kg ha^-1. Values for N and S deposition at Zoquiapan (ZOQ), a relatively low-pollution site 53 km east of Mexico City, were 5.5 and 8.8 kg ha^-1 yr^-1. Foliar concentrations of N, foliar N:P and C:N ratios, extractable soil NO₃ ^-, and streamwater NO₃ ^- concentrations indicate that the forest at DL is N enriched, possibly as a result of chronic N deposition. Sulfur concentrations in current-year foliage were also slightly greater at DL than at ZOQ, but S concentrations in one-year-old foliage were not statistically different between the two sites. Streamwater concentrations of NO₃ ^- ranged from 0.8 to 44.6 μEq L^-1 at DL compared to 0.0 to 11.3 μEq L^-1 at ZOQ. In summary, these findings support the hypothesis that elevated N deposition at DL has increased the level of available N, increased the N status of P. hartwegii, and resulted in export of excess N as NO₃ ^- in streamwater.     

Factors controlling the removal of sulfate and acidity from the waters of an acidified lake

Although Lake Anna, an impoundment in Central Virginia, receives acid mine drainage (AMD) from Contrary Creek, the effects of the AMD pollution on the lake are less severe than expected. Previous work at Lake Anna has shown that bacterial sulfate reduction in the lake sediments plays an important role in the recovery of the lake from the AMD inputs. Sulfate removal rates were measured in sediment microcosms under a variety of experimental conditions to determine the factors controlling the rate of sulfate and acidity removal from the lake water. Sulfate removal rates were not significantly different over the short term (3 weeks) in summer sediment microcosms incubated at 6 vs 26 °C. Winter sediment microcosms showed no significant sulfate removal during the 18 day experiment when incubated at either 6 or 28 °C. Thus there is a strong seasonal temperature effect in Lake Anna sediments but no significant short term effect. Simulated AMD, with and without Fe, was added to sediment microcosms collected from an unpolluted part of the lake. The microcosms with Fe had significantly higher rates of sulfate removal indicating that Fe plays an important role in transporting sulfate to the sediment and/or in preventing oxidation of the reduced sulfide. After 27 days, from 54 to 96% of the added sulfate in the simulated AMD was recovered as FeS or S⁰ in the top 4 cm of sediment. In a separate experiment, ³⁵S-SO _inf4 ^sup2? was found to attach to precipitating Fe oxyhydroxides (1.5 to 4.7 mol SO _inf4 ^sup2? mol^?1 Fe precipitate) upon mixing Contrary Creek (AMD) and Lake Anna waters. Results of this study suggest that sulfate removal may be more rapid in metal rich AMD systems thans in metal poor systems characteristic of those which receive acidic deposition.     

Silicon budget of eutrophic Lake Kasumigaura, Japan

Purpose

Determining the dynamics of silicon in lakes, one of the essential nutrients for diatoms, is valuable for understanding aquatic environmental problems. The dissolved silicon (DSi) and biogenic silicon (BSi) budgets in Lake Kasumigaura, a shallow eutrophic lake in Japan, during the last three decades were assessed based on the analysis of dated sediment cores and a water quality database.

Materials and methods

Sediment cores (100?cm long) were taken at the center of Lake Kasumigaura in 2005, 2007, and 2009 and at two other sites in 2007. BSi contents of the dated sediments were determined by wet alkaline digestion. The net sedimentation rates of BSi were defined as the difference between the DSi load from inflowing rivers and the DSi and BSi loads from the outflow of the lake, calculated using DSi concentrations and diatom abundances in the lake from 1980 to 2007 and DSi concentrations of the inflowing rivers during 1994, 2007, and 2009. The gross sedimentation rates of BSi were estimated by multiplying BSi concentrations in lake water by the diatom sinking rate reported by previous studies.

Results and discussion

Budgetary calculations based on the database showed that 60?C70?% of DSi inputs from the inflowing rivers during the 27?years could ultimately be accumulated as diatom frustules in bottom sediments in the lake. The sediment analysis revealed that the amount of BSi accumulated in the lake from 1980 to 2007 was 2.0?C2.6?×?10¹¹?g, similar to the amount based on the database of 1.3?C2.4?×?10¹¹?g. Although the gross sedimentation rates of BSi likely increased, the net sedimentation rates of BSi decreased significantly from 6?C10?×?10⁹?g?year^?1 in the 1980s to 2?C6?×?10⁹?g?year^?1 in the 2000s, suggesting a fast recycling of BSi in recent years caused by an increase in sediment resuspension and regeneration.

Conclusions

The sediment core information and the water quality database can be used for calculating the long-term silicon budgets in Lake Kasumigaura. An increase in the DSi release rates was identified, which is consistent with recent sediment resuspension. Comparing the sediment core information with the database suggests the long-term dissolution of sediment BSi; however, analysis of the BSi content in sediment cores representing a much longer time period is needed to confirm this.     

Rates of Tidal Sedimentation from Records of Industrial Pollution and Environmental Magnetism: The Tees Estuary,North-East England

The geochemical and magnetic properties of four sediment cores from Greatham Creek in the Tees estuary, north-east England, provide a record of industrial pollution in the intertidal zone. The peak magnetic concentrations, as interpreted from down-core profiles of χ, SIRM, χ_ARM, and Soft magnetisation, provide a rapid and non-destructive proxy for geochemical analyses. In the absence of variation in grain size or post-depositional migration of sediment pollution, differences in the depth of synchronous peak metal and magnetic concentrations between cores can be attributed to the period and frequency of tidal inundation and, hence, accretion rate. Peak Pb and Zn concentrations can be related to the maximum influx from mining activity in the Tees catchment c. AD 1880 or to industrial activity within the Tees estuary during the 20th Century. The former provides rates of tidal sedimentation of approximately 1, 2, 3 and c. 10 mm yr^-1 for the upper saltmarsh, the lower saltmarsh, the mudflats and a tidal sandflat, respectively, whilst the latter gives corresponding accretion rates of 4, 10, 12 and c. 25 mm yr^-1.     

Translocation of urban Gila Monsters: a problematic conservation tool

The Gila Monster (Heloderma suspectum) is a large, venomous lizard protected throughout its distribution in the southwestern United States and northwestern Mexico. Rapid urban growth in key areas of its range and increased encounters with humans prompted us to investigate translocation as a conservation tool with “nuisance” Gila Monsters. Twenty-five Gila Monsters reported as nuisances by residents in the northeastern Phoenix Metropolitan Area were translocated from 0 to 25,000 m from their point of capture. Subjects (N=18) translocated less than 1000 m returned to their original site of capture within 2-30 days; none of those (N=7) translocated more than 1000 m successfully returned, they exhibited high daily rates of speed, and were deprived the use of familiar refuges. We conclude that small distance translocations within suitable habitats are ineffective in removing Gila Monsters from areas deemed unsuitable. Moreover, individuals moved significantly greater distances are unlikely to remain at a translocation site, and may experience a variety of costs (e.g., predation risk) associated with high rates of movement.     

Increase in denitrification capacity of soils due to addition of alkylbenzene sulfonates

 In semi-arid regions wastewater irrigation is a valuable resource for agricultural production. The contamination of irrigated soils with surfactants is one of the ecological risks related to irrigating with untreated wastewater. In this study, the effects of branched alkylbenzene sulfonates (ABS) on microbial biomass, respiratory activity, and denitrification capacity of soil samples (eutric vertisols) taken from an irrigation district in the Mexico City area were investigated in laboratory experiments. Increasing concentrations of ABS lead to a decrease in soil microbial biomass and an increase in soil respiratory activity as well as in the metabolic quotient (qCO₂) of the soils. Denitrification capacity was lowest without the addition of ABS and highest at a medium ABS concentration of 50 μg g^–1. Denitrification capacity seems to be highly sensitive to ABS addition at moderate concentrations. From the laboratory results, high rates of denitrification and N₂O evolution from fields irrigated with wastewater containing ABS are expected. Received: 11 November 1997     

Watershed vs in-lake alkalinity generation: A comparison of rates using input-output studies

As a means of assessing the relative contributions of watershed (terrestrial) and in-lake processes to overall lake/watershed alkalinity budgets, alkalinity production rates for watersheds and low alkalinity lakes were compiled from the literature and compared. Based on net alkalinity production data, derived using wet or bulk deposition data, mean and median alkalinity production for 20 watersheds in North America and Europe were 89 and 69 meq m^?2 yr^?1 (range 20 to 235 meq m^?2 yr^?1). For a subset of 10 watersheds with dry deposition data, terrestrial alkalinity production neutralized an additional 35 meq m^?2 yr^?1 of acidic deposition. For 11 lakes, mean and median in-lake alkalinity generation were 99 and 88 meq m^?2 yr^?1 (range 22 to 240 meq m^?2 yr^?1). Analysis of data indicates that for the low alkalinity systems described here, areal alkalinity production rates for watersheds and lakes are approximately equal. This relationship suggests that watershed area to lake area ratio can be used as a convenient estimator of the relative importance of watershed and in-lake sources of alkalinity for drainage lake systems. For precipitation-dominated seepage lakes and other systems where hydrology limits soil-water contact, hydrologic flow paths and residence times can be of overriding importance in determining alkalinity sources. For regions dominated by drainage lakes with high watershed area to lake area ratios (such as the Northeastern U.S.), however, alkalinity budgets are dominated by watershed processes. Omission of in-lake alkalinity consideration for most lakes in such regions would have little impact on computed alkalinity budgets or on predicted response to changes in acidic deposition loadings.     

The significance of in-lake production of alkalinity

Alkalinity production in terrestrial and aquatic ecosystems of Canada, the U.S.A., Norway and Sweden is calculated from either strong acid titrations or budgets for base cations and strong acid anions, using mass-balance budgets. Where alkalinity budgets for lakes and their catchments are calculated in acid-vulnerable geological settings, in-lake processes often contribute more to lake alkalinity than yield from terrestrial catchments. Nitrate and sulfate removal, and Ca exchange with sediments are the predominant alkalinity generating mechanisms in lakes. Nitrate and sulfte removal rates increase as the concentrations of NO^? ₃ and SO₄ ^2? in lake water increase, so that in-lake acid neutralizing capacity increases as acid deposition increases. Both processes occur in sediments overlain by oxic waters, at rates which seem to be controlled primarily by diffusion.     

Evasion of mercury vapor from the surface of a recently limed acid forest lake in Sweden

Mercury is emitted from soil and water surfaces, but few actual direct flux measurements have been reported. During June, 1994 we performed the first micrometeorological measurements of Hg vapor fluxes over a boreal forest lake. Using highly precise methods with multiple replicate samplers, we measured concentration gradients of Hg vapor, CO₂ and H₂O over the lake surface. Mercury was readily emitted from the lake surface, and we found no evidence of Hg dry deposition to the lake. Emission rates over the lake averaged 8.5 ng m² h^?1, and appeared to be weakly influenced by water temperature and solar radiation. These fluxes were somewhat higher than those previously measured using surface chambers at this site.     

Historical and Geographical Trends in Sediment Chronology from Lakes and Marine Sites Along the Norwegian Coast

Sediment cores collected from 12 lakes and eight marine sites along the Norwegian and Svalbard coast as part of a project investigating polycyclic aromatic hydrocarbons (PAH) in sediments were dated radiometrically using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am fallout radionuclides. In all lake cores, except on Svalbard, the ¹³⁷Cs activity versus depth profile appears to have been significantly modified by post-depositional migration within the sediment column. The relatively low ¹³⁷Cs inventories suggest that these sites were not significantly impacted by fallout from the 1986 Chernobyl accident. All the marine cores have ¹³⁷Cs inventories that are substantially lower than in lake sediments almost certainly due to leaching of ¹³⁷Cs from the marine sediments due to higher solubility in the seawater. In the marine surface sediments, the unsupported ²¹⁰Pb concentrations are up to an order of magnitude lower than in the corresponding lake sediments reflecting the higher (dry mass) sedimentation rate at the marine sites. Five of the cores including marine sites and lakes have unusual high ²¹⁰Pb flux most likely due to sediment focusing. Most of the irregularities in the ²¹⁰Pb records seem to be due to slump events but some patterns are also due to possibly increased accumulation rates. Three of the marine cores show systematic increase in their sedimentation rate from c.1960 towards the present while only one lake shows the same systematic increase.     

A review of the chemical record in lake sediment of energy related air pollution and its effects on lakes

Inter-lake variation in accumulation rates of energy-related elements is a function of gross sedimentation rate (sediment focusing), position on pollution gradients, and water chemistry. Accumulation rates of Pb in lake sediments from profundal area cores in the Adirondack Mountains of New York and northern New England range from 0.1 to 0.2 ug/cm²/y (pre-1800 A.D.) to as much as 2 μg/cm²/y (recent sediment). Rates increase from the late 1800's to nearly the present, in parallel. Accumulation rates for V remain at background values which range up to 0.5 ug/cm²/y and increase 5 to 10 × background in Adirondack Mountain lakes. Chronically acidic lakes have a subsurface maximum. Of these three metals, only Pb has elevated deposition rates in high elevation lakes in the Rocky Mountains of Colorado. Mining activity is believed responsible for the implied air pollution there.     

Predicting vertical accretion rates at an archaeological site on the Mississippi River floodplain: Effigy Mounds National Monument,Iowa

The Sny Magill Unit of Effigy Mounds National Monument, Iowa, contains the largest cluster of prehistoric effigy mounds on public land in North America. The mounds are situated atop a low terrace of the Upper Mississippi River, where they are slowly being buried by overbank deposition during floods. The terrace surface includes forest soils with argillic (Bt) or cambic (Bw) horizons developed in up to 1 m of loamy overbank deposits on top of Pleistocene sand and gravel. Radiocarbon evidence suggests that overbank deposits have accumulated since the end of the mound-building period (about 700 years BP), yielding a vertical accretion rate of about 0.6 mm yr^− 1. On the basis of ¹³⁷Cs analysis, accretion rates over the past 40–50 years average 1.25–2.07 mm yr^− 1, with some evidence for a decreasing rate since 1964. If these accretion rates are projected forward, several of the effigy mounds could be buried by flood deposits within 150–300 years. This ¹³⁷Cs-derived estimate agrees closely with an estimate of burial times based on flood frequency and observed flood deposit thickness during recent floods. However, the floodplain and backwater environments of the Upper Mississippi River are aggrading much more rapidly than the Sny Magill terrace surface, suggesting that burial of the entire terrace could occur within 80–400 years and the entire mound group could be buried within 150–850 years. The projected accretion rates and time to burial are subject to large uncertainties because of environmental change in the watershed, including recent trends toward increasing flood stages and decreasing suspended sediment loads.     

Runoff sediment particle sizes associated with soil erosion in the Lake Tahoe Basin,USA

Runoff sediment from disturbed soils in the Lake Tahoe Basin has resulted in light scattering, accumulation of nutrients, and subsequent loss in lake clarity. Little quantified information about erosion rates and runoff particle‐size distributions (PSDs) exists for determining stream and lake loading associated with land management. Building on previous studies using rainfall simulation (RS) techniques for quantifying infiltration, runoff, and erosion rates, we determine the dependence and significance of runoff sediment PSDs and sediment yield (SY, or erodibility) on slope and compare these relationships between erosion control treatments (e.g., mulch covers, compost, or woodchip incorporation, plantings) with bare and undisturbed, or ‘native’ forest soils. We used simulated rainfall rates of 60–100 mm h⁻¹ applied over replicated 0·64 m² plots. Measured parameters included time to runoff (s), infiltration and runoff rates (mm h⁻¹), SY (g mm⁻¹ runoff), and average sediment concentration (SC, g L⁻¹) as well as PSDs in runoff samples. In terms of significant relationships, granitic soils had larger particle sizes than volcanic soils in bulk soil and runoff samples. Consequently, runoff rates, SCs, and SYs were greater from bare volcanic as compared to that from bare granitic soils at similar slopes. Generally, runoff rates increased with increasing slope on bare soils, while infiltration rates decreased. Similarly, SY increased with slope for both soil types, though SYs from volcanic soils are three to four times larger than that from granitic soils. As SY increased, smaller particle sizes are observed in runoff for all soil conditions and particle sizes decreased with increasing slope. Copyright © 2008 John Wiley & Sons, Ltd.     

Specific rates of net methylmercury production in lake sediments

Specific rates of Hg (²⁰³HgCl₂) methylation and McHg (¹⁴CH₃HgI) demethylation in aerobic and anaerobic conditions were determined in samples of surface sediments (0 to 2 cm) taken from five small headwater lakes in Southern Finland. The highest rates of methylation were measured in anaerobic conditions. However, the importance of aerobic methylation increased with increasing Fe and Mn content in sediment. There was little difference between aerobic and anaerobic demethylation. The results demonstrate that the net McHg production in lake sediments depends on the individual characteristics of the lake, particularly pH and and sediment properties. These characteristics seem to affect demethylation in anaerobic conditions and methylation in aerobic conditions.     

Comparison of wheat yield under uniform and variable rates of fertilizer on spatially‐eroded land

Abstract

Field studies were made to determine the yield and quality of wheat at different landscape positions managed with uniform vs. variable rates of nitrogen (N). A moderately‐eroded wheat farm near Thana (Swat) was divided into four parallel transects which were further divided into two strips each. On one strip, fertilizer was applied at a uniform rate of 120 kg N ha^‐1, and along the other strip, three different rates of N (80, 110, and 125 kg N ha^‐1) were applied to match the crop productivity patterns. A basal dose of 90 kg P₂O₅ and 60 kg K₂O ha^‐1 was applied to the whole field. Soil profiles were described for the three different zones, i.e., low, medium, and high productivity zones. Soil in Zone I was Pirsabak, moderately deep variant, and in Zones II and III, Badwan soil series. Although uniformly fertilized strip (120 kg N ha^‐1) received 40 and 10 kg N ha¹ more than Zone I and Zone II (variable management strategy), there were no significant differences in yield. The differences in three fertilizer management zones were due to differences in moisture content at sowing, infiltration rate, lime content, steepness, and soil depth. Test weight of wheat grains was not significantly affected. Protein content of wheat was significantly higher in variably fertilized strips than in uniformly treated strips. Based on these results, it is suggested that farms with spatially‐variable soils should be fertilized according to the crop productivity and soil fertility patterns.     

Measurement of methylmercury and mercury in run-off,lake and rain waters

During one year, samples from eight drainage lakes, seven run-off stations and three deposition sites from various geographical areas in Sweden were collected and analyzed for methyl Hg (MeHg) and total Hg (Hg-tot). The MeHg concentrations ranged from 0.04 to 0.64 ng L^?1, 0.04 to 0.8 ng L^?1, and <0.05 to 0.6 ng L^?1 in run-off, lake water and rain water, respectively. The corresponding Hg-tot concentrations were found in the range 2 to 12 ng L^?1, 1.35 to 15 ng L^?1, and 7 to 90 ng L^?1, respectively. A Hg-tot level of about 60 ng Hg L^?1 was found in throughfall water. The MeHg and Hg-tot concentrations are positively correlated in both run-off and lake water, but not in rain and throughfall water. A strong positive correlation between the MeHg, as well as the Hg-tot concentration, and the water color is observed in both run-off and lake waters, which suggests that the transport of MeHg and other Hg fractions from soil via run-off water to the lake is closely related to the transport of organic substances; and is a consequence of the biogeochemical processes and the water flow pathway. The ratio between the mean values of MeHg and Hg-tot seems to be an important parameter, with an indicated negative coupling to the mean value of pH for run-off water, but a strong positive correlation to Hg-content in fish, the ratio between the area of the catchment and the lake, as well as to the retention time of lake.     

The influence of trophic level as measured by δ15N on mercury concentrations in freshwater organisms

The relationship between mercury (Hg) concentrations in freshwater biota and trophic position, as defined by stable nitrogen isotope ratios (δ¹⁵N), was examined in 6 lakes in northwestern Ontario. The heavier isotope of nitrogen (¹⁵N) increases an average of 3 parts per thousand (‰) from prey to predator and is used as a measure of an organism's trophic position. Dorsal muscle from lake trout, burbot, walleye, northern pike, white sucker, lake cisco, lake whitefish, and yellow perch was analyzed for Hg and δ¹⁵N using flameless atomic absorption and mass spectrometry respectively. Within each lake, log Hg was significantly related to δ¹⁵N (r ² ranged from 0.47 to 0.91,P<0.01). For four species, yellow perch, northern pike, lake cisco, and lake trout, log Hg was positively related to δ¹⁵N (r ² ranged from 0.37 to 0.47,P≤0.09) across all lakes. We also used δ¹⁵N measurements (assuming a 3‰ shift between an organism and its diet) and the developed within-lake regression equations to calculate a prey Hg for each individual fish. These food Hg values were then used to predict predator Hg using Norstromet al's bioenergetics model. Predicted results were strongly correlated to measured Hg concentrations (r=0.91,P<0.001), indicating that δ¹⁵N has potential to be used in modeling.     

Soil respiration in a chihuahuan desert rangeland

Soil respiration of a desert soil was measured at the New Mexico State University Ranch in Southern New Mexico. Respiration rates were highest during late July and August after summer rains. Soil respiration data were used to estimate soil organic matter turnover which was 54 yr using summer data and 20 yr using both summer and winter data. The long turnover estimate for summer measurements resulted from temperatures above optimum in June and July. Diurnal soil respiration was also measured after a simulated 2.54 cm rain event. For both wetted and dry soils, temperature controlled the patterns of soil respiration with an optimum of near 41°C. Activation energy values decreased from 84.91 to 39.5 kJ mol^?1 when the soil was wetted. A light-dark container method was tested as a possible means of estimating algal uptake of CO₂, however, the method was not feasible for desert soils.     

Polluted precipitation and the geochronology of mercury deposition in lake sediment of northern Minnesota

Elevated Hg levels in game fish from wilderness lakes in northern Minnesota led to the present study of sediment cores from two lakes to ascertain the source and history of Hg deposition. Natural background levels of Hg were found to range from 0.03 to 0.06 μg g^?1, with cultural levels as high as 0.16 μg g^?1. Reconstructed geochronologies reveal a dramatic two-fold increase in Hg flux, from 0.008 to 0.017 μg cm^?2 yr^?1, occuring after the year 1880, suggesting an anthropogenic influence. No industrial or geologic source of Hg is found in the study watersheds. The entire historical increase in Hg flux can be accounted for by atmospheric loading provided that 1/5 of all the Hg presently supplied to the watershed via precipitation is ultimately deposited in lake sediment. Hg levels in fish are not correlated with Hg levels in lake sediment, although there is a link to acid-sensitivity of lake water, amount of acid-neutralizing geologic material exposed in the watershed, and watershed area/lake volume ratio. Thermal stratification of lake water and a complexation-adsorption mechanism are proposed to account for variations in Hg levels observed in sediment collected from different sites.     

Simultaneous Use of Trace Metals, 210Pb and 137Cs in Floodplain Sediments of a Lowland River as Indicators of Anthropogenic Impacts

This study focuses on the distribution of selected trace metals, ¹³⁷Cs and ²¹⁰Pb, in floodplain deposits of the lowland Warta River (southern Poland) downstream of Cz?stochowa, a large city with an iron smelter. The depth profiles of trace metal (Zn, Pb, Cu, Ni, Cd and Mn), ²¹⁰Pb and ¹³⁷Cs contents in floodplain sediments were used to derive deposition rates on the floodplain for the twentieth century. The applicability of particular chronometric tools is considered within the context of their mutual relationships and confirmed by the consistency of the results. Deposition rate estimates for the past 50 years based on the vertical patterns of trace metal concentrations, which were correlated with particular events in the development of the smelter, range from 0.4 cm·year^?1 in profiles situated in backswamps far from the channel to over 1.1 cm·year^?1 in profiles of the natural levee adjacent to the river. Deposition rates based on ²¹⁰Pb inventories in the profiles range from 0.08 to 0.66 g·cm^?2·year^?1, which corresponds to linear sedimentation rates of 0.10 to 0.91 cm·year^?1, respectively. Dating of characteristic levels associated with peak fallout of ¹³⁷Cs gives sediment accretion rates resembling those obtained from trace metals and ²¹⁰Pb. The period of the highest sediment accumulation rate could be related to the highest loads of effluent from the iron smelter and city of Cz?stochowa, which were substantially reduced after the construction of effluent treatment plant.