塿土非代换性钾剖面分布模型与系统分类探讨

Ｌｏｕ土非代换性钾在剖面分析特征，拟合是一个非线性方程，ｙ＝αｅ＾ｂ＾ｘ（ｃ＋ｄｃｏｓ２π（ｘ－ｅ）／ｆ），并以此可对Ｌｏｕ土进行初步的系统分类，初拟对５个剖面可分为三个类型。图中Ａ部位反映了Ｌｏｕ土肥熟堆垫表层（或Ｌｏｕ化过程）中土壤非代换性钾的变化状态，表现为耕作层（现代）高，以下土层则逐渐降低，这和肥熟堆垫过程，栽培作物的吸收，迁移和富集等土壤生态环境有关。也表明了在植物参与下Ｌｏｕ土剖面     

长期定位施肥对黑垆土剖面养分分布特征的影响

对黄土高原旱地 15年连续施肥后土壤剖面养分分布的研究发现 ,施化肥对土壤剖面有机质、全N、全P含量的影响深达 100cm以下 ,所有施肥处理有机质、全N、全P、NO3--N、有效P含量在耕层 (0～20cm)都有不同程度增加 ;40～60、60～80cm土层有机质、全N、全P都低于长年不施肥处理 ,造成土壤下层养分的亏缺。长期大量施用氮肥造成N素养分下淋累积 ;长期大量施用磷肥土壤耕层有效P显著提高 ,而 20cm以下土层变化不大。     

土壤非交换性钾释放动力学特征及其生物

采用生物耗竭法和0.2mol L-1的NaTPB化学浸提法,利用不同动力学方程对我国8种主要土壤非交换性钾的释钾特性及其生物有效性进行定量评估。结果表明,供试土壤非交换性钾释放分为快速释放和稳定释放两个阶段,一级动力学方程、Elovich 方程、双常数曲线方程和抛物线扩散方程均能描述土壤非交换性钾的释放过程。根据双常数方程中的参数（a）所表征的土壤非交换性钾释放速率常数,供试8种土壤的释钾能力按取土地区存在着自西向东、自北向南渐减的趋势。盆栽试验中,在累积释钾量高且释放速率快的土壤上,黑麦草累积生物量、累积吸钾量和相对含钾量较高,表现出强的供钾能力;与此相反,累积释放量低且释放速率慢的土壤上,黑麦草各项指标偏低,供钾能力较弱。以黑麦草钾素丰缺临界值34.00 mg kg-1 DW-1和土壤非交换性钾释放速率396.32 mg kg-1 h-1作为评价指标,供试8种土壤中,仅取自新疆石河子、陕西常武和黑龙江哈尔滨地区的土壤在短期不施用钾肥的情况下能保证黑麦草丰产且不出现缺钾症状。因此,为了维持土壤钾素平衡和保证作物高产稳产,在我国西北、东北地区耕地土壤中应加强秸秆的循环利用,而在华中和华东地区则需增施钾肥和有机肥。     

定位施肥对黑垆土剖面养分的影响

根据９年的田间定位试验资料，我们分析了９种不同施肥处理黑垆土耕层（０－２０ｃｍ）、古耕层（２０－５０ｃｍ）和垆土层（５０－８０ｃｍ）三层土壤养分的变化。结果表明：施肥对黑土剖面养分的影响随深度的增加而减弱，一般为，耕层＞古耕层＞垆土层。不同处理耕层土壤养分差异比较明显，耕层以下土尽管异减小，但其归变化与耕层趋势一致。各层土壤速效养分对照比裸地均有下降。综合评价施肥对黑垆土剖面的培肥效果，ＮＰＭ＞Ｍ     

山东主要土壤供钾能力和非交换性钾释放的研究

用生物耗竭方法,研究和比较了山东省主要农业土壤:棕壤、褐土和潮土的供钾能力。结果表明,以土壤交换性钾、缓效钾含量和耗竭过程中作物吸钾总量和吸收来自土壤非交换性钾的数量、比率及土壤非交换性钾释放速度和数量为依据,评价土壤供钾能力有褐土＞潮土＞棕壤的总趋势。     

耕作土壤非交换性钾有效性的研究

采用两种化学连续提取法及连续耗钾实验,研究了几种耕作土壤非有效性钾释放特性及有效性。结果表明,供试土壤非交换性释放特性和有效性与粘土矿的密切相关,富含伊利石的土壤非交换性钾的释放量大,速率快,有效性高,黑麦草吸收该土壤的非交换性钾量及总吸钾量高,生物量大。而富含高岭石或蒙脱石的土壤非有效性钾有效性明显较低,非交换性钾的释放量和速率,黑麦草吸收该土壤的非交换性钾量,总吸钾量及生物量的均值分别仅为富含     

我国北方主要土壤非交换性钾释放速率的研究

采用连续流动交换技术研究了我国北方２５个供试土壤非交换性钾的释放速率。结果表明,土壤晨交换性钾释放缓慢,而持续时间长;最大释放速率变幅为０．１９５￣２．３０ｍｇ／（ｋｇ·ｍｉｎ）,６００分钟平均释放速率变幅为０．０６６￣１．１２１ｍｇ（ｋｇ·ｍｉｎ）,释放持续时间一般在６００分种以上。在６００分种释放时间内非交换性钾释放百分率变幅在５．４％￣３９．６％之间。土壤非交换性钾释放速率与盆栽耗钾试验中玉     

不同提取方法土壤非交换性钾释放动力学及其速率的研究

采用Ca2+饱和土壤的 0.50molL-1硝酸、0.0 1molL-1草酸和氢质阳离子交换树脂恒温连续提取法 ,利用Elovich和二级动力学模型 ,结合生物吸钾试验 ,研究探讨了描述土壤非交换性钾释放及其速率较为理想的连续提取法及其动力学模型。研究结果表明 ,氢质树脂提取法的Elovich模型描述非交换性钾释放及其速率的效果较为理想 ,拟合方程的相关系数达极显著水平(r =0.982～ 0.996 ) ;不同时间非交换性钾累积释放量的计算值与实测值的标准差最小 (S =1.335～2.480 ) ;通过速率方程计算的不同时间非交换性钾释放速率与黑麦草吸收的非交换性钾数量的相关性也最为密切 (r =0.944～ 0.963) ,故氢质阳离子交换树脂连续提取法结合Elovich模型是描述土壤非交换性钾释放及其速率较为理想的组合方法。以伊利石为主的 2、3和 8号土壤非交换性钾释放速率明显高于其它以高岭石或蒙脱石为主的供试土壤     

旱地黑垆土剖面酶活性分布特征与生育期变化

本文对旱地苜蓿地与小麦连作土壤剖面酶活性的分布特征进行研究,同时分析了不同施肥条件下冬小麦生育期酶活性的变化。苜蓿连作系统CK、P、NPM处理土壤剖面(0～200cm)酶活性分析表明:不同施肥处理土壤酶活性的剖面分布状况为:耕层到底层急剧降低,不同施肥对其深层分布影响不明显,施NPM在一定程度上增加了底层土壤酶活性,但数学统计CK、P、NPM三处理之间差异未达显著水平。过氧化氢酶活性在整个剖面较高,随着剖面深入降低的不多,而蛋白酶、脲酶、碱性磷酸酶、蔗糖酶活性随剖面深入急剧降低;冬小麦连作土壤酶活性剖面分布特征与苜蓿连作一致,但施肥对20～40cm土层酶活性有一定的影响。过氧化氢酶活性随冬小麦的生长而增大,碱性磷酸酶活性生育期变化与土壤有效磷生育期变化有密切关系,而其余两种酶生育期变化规律不明显。     

Response of soil exchangeable and crop potassium concentrations to variable fertilizer and cropping regimes in long-term field experiments on different soil types

Annual potassium (K) balances have been calculated over a 40‐year period for five field experiments located on varying parent materials (from loamy sand to clay) in south and central Sweden. Each experiment consisted of a number of K fertilizer regimes and was divided into two crop rotations, mixed arable/livestock (I) and arable only (II). Annual calculations were based on data for K inputs through manure and fertilizer, and outputs in crop removal. Plots receiving no K fertilizer showed negative K balances which ranged from 30 to 65 kg ha^?1 year^?1 in rotation I, compared with 10–26 kg ha^?1 year^?1 for rotation II. On sandy loam and clay soils, the K yield of nil K plots (rotation I) increased significantly with time during the experimental period indicating increasing release of K from soil minerals, uptake from deeper soil horizons and/or depletion of exchangeable soil K (K_ex). Significant depletion of K_ex in the topsoil was only found in the loamy sand indicating a K supply from internal sources in the sandy loam and clay soils. On silty clay and clay soils, a grass/clover ley K concentration of ～2% (dry weight) was maintained during the 40‐year study period on the nil K plots, but on the sandy loam, loam and loamy sand, herbage concentrations were generally less than 2% K.     

Influence of exchangeable potassium on soil erodibility

Abstract. Regular application of slurry manure in large quantities is thought to degrade soil structure and increase erodibility. One hypothesis links this to the large input of potassium which increases the exchangeable potassium percentage (EPP) and, thereby, dispersion. The effect of EPP on erodibility was quantified in three experiments. In the laboratory, eleven rainfall experiments were conducted using a silty topsoil from a typic Hapludalf which was fertilized to EPPs of 4 to 18%. Field rainfall experiments on 22 Inceptisols and Alfisols were used to examine whether the long-term application of monovalent cations (Na⁺, K⁺ and NH₄⁺) with slurry manure had changed soil properties, especially erodibility. In addition, erodibilities of 32 soils determined with natural and simulated rains were taken from literature. The experiments on these 65 soils together covered a wide range of soils, slopes and rainfalls. Dispersion by a large percentage of highly hydrated ions (K⁺, Na⁺) reduced the infiltration rate faster, caused runoff up to 5 min earlier, and increased sediment concentrations by 15g/l compared to low EPP soils. These changes increased soil erodibility of the Universal Soil Loss Equation (USLE) by 0.021 t × h/N × ha (where N = Newtons) for each 1% increase in EPP + ESP (exchangeable sodium percentage). The ESP contributed little to this increase as ESP was less than 1/10 of EPP in the experiments.
Fields with long-term manure application had similar chemical, physical and microbiological soil properties as fields without slurry manure except for slightly greater pH (+ 0.6) and P (+ 17 mg/kg) values. We conclude that, as long as the potassium input and output are balanced, the long-term use of slurry manure does not increase erodibility.     

Potassium fertilization and soil diagnostic criteria for forage corn (Zea mays L.) production contributing to lower potassium input in regional fertilizer recommendation

Abstract

Effective soil diagnostic criteria for exchangeable potassium (Ex-K) combined with inorganic potassium (K) application rates were developed to lower K input in forage corn (Zea mays L.) production using experimental fields with different application rates and histories of cattle manure compost. Two corn varieties, ‘Cecilia’ as a low K uptake variety and ‘Yumechikara’ as a high K uptake variety, were selected from among 20 varieties and tested to make diagnostic criteria for K fertilization applicable to varieties with different K uptakes. The K uptakes increased from 96 to 303 kg K ha^?1 for ‘Cecilia’ and from 123 to 411 kg K ha^?1 for ‘Yumechikara’ with increasing Ex-K content on a dry soil basis from 0.11 to 0.92 g kg^?1 with no inorganic K fertilizer application. The K uptake by corn for achieving the target dry matter yield of 18 Mg ha^?1 was estimated to be approximately 200 kg K ha^?1 in common between the two varieties. Yields of both varieties achieved the target yield at an Ex-K content of approximately 0.30 g kg^?1 with no K fertilization, although ‘Yumechikara’ reached the target yield at a lower Ex-K content. At the low Ex-K content of 0.1 g kg^?1, inorganic K fertilizer application at 83 kg K ha^?1 was needed to gain the target yield, and apparent K recovery rate for K fertilizer was calculated to be 70% for both varieties. The K uptakes for gaining the target yield by the K fertilization were lower than that by soil K supply. Based on these results, diagnostic criteria of Ex-K and inorganic K application rates were set up as follows: at an Ex-K content of < 0.15 g kg^?1, inorganic K fertilizer is applied at 83 kg K ha^?1 (100 kg ha^?1 as potassium oxide (K₂O) equivalent); at an Ex-K content of 0.15–0.30 g kg^?1, the application rate is reduced to 33 kg K ha^?1 (40 kg K₂O ha^?1); at an Ex-K content of ≥ 0.30 g kg^?1, inorganic K fertilizer is not applied because of sufficient K in the soil. Additionally, we propose that cattle manure compost be used to supplement soil K fertility.     

山西褐土长期施钾和秸秆还田对冬小麦产量和钾素平衡的影响

在山西石灰性褐土一年一作条件下,通过16年的田间定位试验,研究了长期施钾和秸秆还田对小麦产量和土壤钾素平衡的影响。结果表明,只施用氮、磷肥,冬小麦年平均产量5.5 t/hm2,土壤钾素养分严重亏缺,年平均亏缺104.3 kg/hm2,与试验前的初始值比较,土壤速效钾和缓效钾含量分别下降23.6%和14.3%。在施用氮、磷肥的基础上每年施用钾肥(K2O 150 kg/hm2),平均增产10.2%以上;小麦秸秆还田平均增产6.6%以上,二者配合平均增产17.6%,年平均吸钾量提高32.0 kg/hm2。与试验初始值比较,土壤速效钾、缓效钾分别提高38.6%和11.0%。在施用氮、磷肥的基础上,长期施用钾肥和秸秆还田在显著增加冬小麦的经济产量、生物产量和吸钾量的同时,也减少年度间因气候因素等影响引起的产量变异,提高年度间产量和植物吸钾量的稳定性。     

Potassium behavior and clay mineral composition in the soil with low effectiveness of potassium application

ABSTRACT

Increasing exchangeable potassium (ExK) content in soil to an appropriate level is important to mitigate the transfer of radioactive cesium to crops. We focused on a buckwheat (Fagopyrum esculentum Moench) field with a low ExK content, despite the application of K, in Fukushima Prefecture, Japan (Field A), following the Tokyo Electric Power Company Fukushima Dai-ichi (No. 1) Nuclear Power Plant accident in March 2011. We examined the relationship between K concentration and clay mineral composition in the soil of Field A and compared the findings with another field in Fukushima Prefecture (Field B) to clarify whether K applied to the soil was leached or remaining fixed. Pot experiments showed that K concentration in water seepage from pots following irrigation was significantly lower in pots from Field A than in those from Field B. Soil ExK content after soybean cultivation was lower in soils of Field A than those of Field B. These results indicate that K applied to Field A was fixed in the soil. Analysis of clay mineral composition confirmed the distinctive vermiculitic nature of Field A soils. This clay mineralogy would be associated with the higher K fixation ability of Field A than Field B soils. This study demonstrated that K fixation in vermiculite was a factor preventing the increase in ExK content from K application to Field A.     

Potassium isotherm partitioning based on modified quantity‐intensity relation and potassium buffering characterization of soils of North India

Background : Potassium (K) availability in soil and plant uptake is restrained by the dynamic interactions among the different pools of K. Aims : To understand these interactions, a study was undertaken to assess the quantity–intensity (Q/I) and buffering characteristics of rainfed maize (Zea mays L.) growing soils. Ten contrasting soils were evaluated for K partitioning changes in exchangeable K (ΔEK) and non‐exchangeable K (ΔNEK) pools in the soil‐solution phase and buffering characteristics using a modified version of Q/I approach. Results : The partitioned Q/I isotherms showed strong adsorption with the increase in K concentration ratio (CR^K) and the changes due to ΔEK were higher than changes due to ΔNEK. Total buffering capacity (PBC^K) significantly correlated (r = 0.92, p <0.01) with clay content with a major share contributed by buffering capacity owing to non‐exchangeable K ( ${\mathrm{PBC}}_{\Delta \mathrm{NEK}}^K$) rather than exchangeable K ( ${\mathrm{PBC}}_{\Delta \mathrm{EK}}^K$). The fixation capacity (β) factor, the magnitude of added K converted into a non‐exchangeable pool, ranged from 41 to 63%, whereas release (α) factor, the magnitude of added K converted to the exchangeable pool, ranged from 19 to 36%. Both threshold solution K (CK_r) and threshold exchangeable K (EK_r) values were found to be high in Satran clay loam (S2) and lower in Doon silty clay loam (S3) soils. The equilibrium exchangeable K (EK_o) was found close to minimum exchangeable K (E_min) in Doon silty clay loam (S3) and Babaweyl sandy clay loam (S1) soils and overall E_min constituted about 8.94 to 0.57% of the EK_o. Conclusion : It may be concluded that K Q/I isotherm partitioning provides a valuable insight to assess the dynamic relations. The ratio of α/β (K recharge index) could be used to evaluate the K enrichment capacity of soil to K additions while EK_r and E_min can be potentially useful in the elucidation of exchangeable K as K fertility index especially in soils with poor K fertilizer management.     

秸秆还田与施钾对华北低产潮土区作物产量及土壤钾素的影响

在华北平原的低产田上,研究了3年秸秆还田和施钾肥对小麦-玉米作物产量和耕层土壤钾素状况的影响。结果表明,相对于NP处理,NPK和NPK+秸秆还田(St)处理对小麦和玉米均有显著的增产效果;NPK+St处理增产最为明显,而且降低了年度间的产量变异系数。秸秆还田可以显著增加土壤速效形态钾含量。同季作物种植下,NPK+St处理的钾肥利用率、钾肥农学效率和钾肥偏生产力都高于NPK处理。NPK+St能提高0～20 cm耕层土壤速效钾、非交换性钾、矿物态钾和全钾含量。因此,秸秆还田有利于土壤不同形态钾素的稳定和增加,而NPK+St处理不仅能保证作物高产稳产,还能提高土壤各形态钾素含量。     

生物炭对土壤钾素生物有效性影响的研究进展

土壤缺钾已成为影响作物产量和品质,限制我国农业可持续发展的重要因素之一,亟待深入开展如何提高土壤钾素生物有效性的相关研究。本文收集整理了近年来研究者比较感兴趣的生物炭对土壤肥力,特别是对土壤钾素生物有效性影响的相关资料,从生物炭影响土壤温度、水分、p H值、阳离子交换量、微生物生物量与活性、作物根系生长与活动等方面论述了生物炭影响土壤钾素生物有效性的可能机理,并提出了今后需要深入研究的方面。     

Ability of different soil extraction methods to predict potassium release from soil in ley over three consecutive years

To avoid over‐fertilization of potassium (K) and thereby a mineral composition in the grass crop not optimal for animal health, estimation of K release from soil is important. The analytical methods should therefore predict the total K release. Furthermore, to minimize costs for the farmers they should provide information which remains valid over a period of several years. The relationship between different soil extraction procedures for K and K uptake in ley for three subsequent years after soil sampling was studied in 19 field experiments on a range of mineral soil types in Norway. Potassium determined with solutions that extracted exchangeable K or parts of exchangeable K (0.01 M CaCl₂, 0.5 M NaHCO₃, 1 M NH₄oAc, or ammonium acetate lactate) was significantly (p < 0.05) related to the K yield only in the 1st yr after soil sampling. Potassium extracted with boiling in 1 M or 2 M HNO₃ was significantly related to the K yield only in the 2nd and 3rd yr. Potassium extracted with cold 2 M HCl, boiling 0.1 M HNO₃ or 0.5 M HNO₃ was significantly related to the K yield in all 3 yr after soil sampling. Among these extractants, 0.1 M and 0.5 M HNO₃‐extractable K were better predictors of K uptake than 2 M HCl‐extractable K. These three extractants release some non‐exchangeable K in addition to exchangeable K. The fraction of 1 M HNO₃‐K extractable with 0.1 M HNO₃ varied from 4% to 45%, whereas from 15% to 78% of 1 M HNO₃‐K was extractable with 0.5 M HNO₃. Consequently, the more easily releasable fraction of K extracted by boiling with 1 M HNO₃ varied considerably between different sites.     

红壤酸化及石灰改良影响冬小麦根际土壤钾的有效性

【目的】了解初始酸度对石灰改良红壤钾素有效性的效应,为酸化红壤改良提供依据和支撑。【方法】本试验以湖南祁阳典型的第四纪红土为基础,人为调节出土壤pH分别为4.0、4.5、4.8、5.2的土壤。每个酸度土壤的一半加石灰改良至pH 6.0 (石灰改良处理),另一半不变(酸化处理)。以该土壤进行了小麦盆栽试验。每个盆内放入一个尼龙网根袋,并添加供试红壤1.65 kg (根袋中加150 g)。小麦生长80天后收获,调查了小麦生物量和钾吸收量,测定比较了小麦根际和非根际土壤不同形态的钾含量变化。【结果】1)不同酸化土壤冬小麦生物量(地上部和根部)与初始pH显著正相关(P＜0.05),也与钾吸收量显著正相关(P＜0.05)。石灰改良处理冬小麦生物量均显著高于相应的酸化处理,也随初始pH升高而显著升高。2)不同酸化土壤冬小麦根际土壤速效钾随pH升高显著降低,非根际土壤的速效钾含量均显著高于相应的根际土壤(除pH 4.0外)。石灰改良处理根际土壤速效钾含量均显著低于相应的酸化处理,且非根际土壤显著高于对应根际土,非根际土壤速效钾含量随初始pH升高而显著下降。3)不同酸化土壤冬小麦根际土壤钾离子饱和度随pH升高而显著下降,非根际土壤钾离子饱和度则随pH升高呈增加趋势。石灰改良处理土壤各处理根际土钾离子饱和度均显著低于对应的非根际土,同时非根际土钾离子饱和度与酸化处理的变化趋势一致。4)不同酸化处理红壤冬小麦生物量与根际速效钾亏缺量呈极显著正相关(P＜0.01),冬小麦根际土壤速效钾亏缺率和冬小麦吸钾量及根际钾离子饱和度亏缺率均呈极显著正相关(P＜0.01);而石灰改良处理根际土壤速效钾亏缺率则与初始pH呈显著负相关(P＜0.05)。【结论】在本试验的pH范围内,酸化条件下,根际土壤速效钾含量随pH降低而升高,而冬小麦吸钾量及生物量均随pH升高而升高。表明酸化红壤影响冬小麦钾养分吸收的主导因素是土壤的酸度。施石灰降低了土壤的酸度,提高酸化红壤作物产量和吸钾量。红壤施用石灰校正酸化应在pH降到5.0之前进行。酸化红壤石灰改良后,还应注意适量补充钾肥。