Effect of liming on extractable Zn, Cu, Fe and Mn in selected Scottish soils

Ten naturally acidic Scottish soils have been limed with CaCO₃ at 0,0.25, 0.50, 0.75, 1.00 and 1.25 times the recommended lime requirement, and then subjected to three cycles of alternate wetting to field capacity at 20°C for 1 month and drying for 1 month. The Zn, Cu, Fe and Mn extracted by DTPA solution, both at pH 7.3 and also after adjustment to match the final soil pH, were measured by flame AAS. The same elements were determined in ammonium acetate extracts, for extractants buffered at pH 4.8, pH 7.0 or at the final soil pH. The effect of extractant pH upon the amounts of trace elements removed is discussed for the two extractants, with particular reference to Zn. The influence of soil pH upon the amounts of trace elements extracted is also considered. There appears to be a distinct relationship between rate of decrease of DTPA-extractable Fe with increasing soil pH and the effect of pH upon DTPA-extractable Zn, high rates of decrease of extractable Fe being associated with a more continuous decline in extractable Zn with increasing soil pH. Possible reasons for this relationship are discussed, in the light of an experiment conducted to examine the effect of Fe and A1 on loss of Zn from solution at high pH. DTPA-extractable Cu varied little with increasing soil pH.     

Zn、B、Mn微肥提高玉米产量与品质的研究

研究结果表明,不同浓度Zn、B、Mn微肥处理对促进玉米生长、提高玉米产量与秸杆品质,增加生物学产量及经济产量均有效果。     

长期不同施肥对南方黄泥田水稻子粒与土壤锌、 硼、 铜、 铁、 锰含量的影响

在福建黄泥田长期定位施肥试验的第26年,研究了不同施肥模式对水稻子粒与土壤微量元素含量的影响。结果表明,与不施肥（CK）相比,化肥+牛粪（NPKM）、 化肥+秸秆还田（NPKS）及单施化肥（NPK）处理的水稻子粒Zn、 B、 Cu含量均有不同程度的提高,并尤以NPKM处理最为明显,三种微量元素含量分别提高14.3%、 25.1%、 465.2%,均达差异显著水平。NPKM与NPKS处理还不同程度地提高了子粒Mn含量,但各施肥处理的子粒Fe含量均显著降低。各施肥处理尤其是NPKM与NPKS均显著提高了子粒微量元素吸收量。NPK处理的土壤有效B、 Fe、 Zn、 Cu含量与CK相比均呈下降趋势,且有效Zn、 Mn含量较试验前土壤分别降低了36.4%与24.6%,而NPKM与NPKS处理缓解了下降趋势,且NPKM处理的土壤有效Zn、 B、 Mn含量分别较CK提高46.6%、 52.0%、 43.0%,均达差异显著水平。土壤有机质与子粒B、 Cu、 Zn含量呈显著正相关,子粒必需氨基酸、 粗蛋白与子粒Zn含量呈显著正相关。以上结果说明,长期化肥配施牛粪或秸秆还田有利于提高水稻子粒Zn、 B、 Cu等微量元素含量和产量,改善子粒营养品质,一定程度上又可缓解土壤有效微量元素含量的下降,是适合南方黄泥田的施肥模式。     

小黑麦子粒中铁、锰、铜、锌含量对氮素反应的品种差异及其类型

采用盆栽试验,以31份具有不同遗传背景的小黑麦品种为材料,设低氮和正常供氮2个氮素水平,探讨小黑麦子粒中铁、锰、铜、锌含量对氮素反应的品种差异及其类型。结果表明: 1）不同供氮条件下,小黑麦子粒中铁、锌含量以正常供氮显著高于低氮条件,锰、铜含量在两个供氮条件下差异不显著;相同供氮条件下,小黑麦子粒中铁、锰、铜、锌含量存在显著的品种差异,变异系数为15.07 %～38.69 %。2） 铁、锰、铜、锌含量对氮素供应的敏感性存在差异,以各小黑麦品种子粒微量元素含量对氮素响应的敏感程度,可将其分为钝感型、中间型和敏感型3种类型。3）相关分析表明,铁、锰含量与粒重相关性不显著,铜、锌含量与粒重呈极显著正相关（相关系数分别为0.45、0.44）;铁、锰、铜、锌含量与子粒中含氮量呈极显著正相关（相关系数分别为0.34、0.55、0.47、0.71）。这些结果可为小黑麦营养品质有利基因的发掘和运用提供参考依据。     

Influence of organic amendments on Fe,Cu, Mn,and Zn availability and clay minerals of different soils

The effects of application of composted olive mill wastewater sludge (A) and depotassified sugarbeet vinasse (V) on total diethylenetriaminepentaacetic acid (DTPA) and sequential extracted micronutrients were investigated. The mineralogy of the fine fraction of soils was also studied. The soils used were a Typic Rhodoxeralf (soil R), a Typic Xeropsamment (soil S), and a Typic Xerorthent (soil C). Fertilization with A and V during 3 years, in general did not significantly affect the total concentration of Fe, Cu, Mn, and Zn versus the control. However, the elements extracted with DTPA generally increased with the organic amendments, more with A than with V. The BCR (European Community Bureau of Reference) sequential extraction indicated that the addition of organic matter generally increased Zn and Mn in the two more available fractions. A great amount of Fe was found in the second and third fractions from the unamended and amended soils. Nevertheless, the sum of the three fractions was enhanced for the organic amendment, except for calcareous soil. The distribution of these elements in the different fractions was significantly affected by the type of soil. The addition of both fertilizers caused modifications in particle size and consequence redistribution of the calcite content between the different fractions.     

中国典型设施栽培土壤Cu、Zn累积特征及风险预测

为了探明铜(Cu)和锌(Zn)在设施栽培土壤中的累积现状及潜在风险,该研究基于中国8个省16个州市典型区域的设施栽培土壤全量和有效态含量,系统分析了Cu、Zn的累积现状及风险特征,并采用分段线性模型(Split-line Model)拟合了土壤Cu、Zn有效态累积量与种植年限的关系,预测了土壤Cu、Zn累积量超风险限量...     

旱地石灰性土壤上长期施磷对小麦籽粒铁锰铜锌含量的影响

  【目的】  研究石灰性土壤上施用磷肥引起的小麦铁、锰、铜、锌含量的变化及其与作物养分吸收和土壤养分有效性的关系,为旱地小麦磷肥合理施用和丰产优质生产提供科学依据。  【方法】  于2004年在陕西杨凌设置不同磷肥用量的长期定位田间试验,土壤为石灰性土壤,pH 8.3。试验在每个小区施氮(N) 160 kg/hm2的基础上,设置施用P₂O₅ 0、50、100、150、200 kg/hm2 5个水平。于2013—2016年3个收获期取样,测定了小麦地上部各器官生物量和铁、锰、铜、锌含量,及0—20和20—40 cm土层土壤有效铁锰铜锌含量。  【结果】  与不施磷相比,施用磷肥提高了小麦产量和籽粒铁、锰含量,但降低了籽粒铜、锌含量,同时提高了土壤有效铁、锰、锌含量,对有效铜含量影响不显著。进一步回归分析得出,施P₂O₅ 165 kg/hm2时产量最高,为6492 kg/hm2;施P₂O₅ 100 kg/hm2时籽粒铁含量最高,为41.7 mg/kg;施P₂O₅ 94 kg/hm2时籽粒锰含量最高,为37.5 mg/kg;施P₂O₅ 136 kg/hm2时籽粒锌含量最低,为25.4 mg/kg;籽粒铜含量在每增施P₂O₅ 100 kg/hm2时会降低0.4 mg/kg。土壤有效锰、锌在施P₂O₅ 100 kg/hm2时达到最大值,比对照分别提高24%和35%;土壤有效铁在施P₂O₅ 200 kg/hm2时增幅最大,为8%;土壤有效铜在各施磷量下无显著变化。产量为最高产量的95% 时施磷量为 108 kg/hm2,当超过这一施磷量时,产量增幅减小,籽粒铁锰含量不再增加,铜锌含量持续降低。  【结论】  黄土高原石灰性旱地土壤上,长期施磷提高了小麦籽粒铁、锰含量,降低了籽粒铜、锌含量。籽粒铁、锰含量增加与土壤有效铁、锰增加促进了小麦的吸收及向籽粒的转移有关,而籽粒铜、锌含量降低与施磷后土壤有效铜没有显著提高,且高磷抑制铜转运和锌吸收有关。为了兼顾小麦高产与营养平衡,这一地区的施磷量应不超过P₂O₅ 108 kg/hm2,以防止小麦籽粒铜、锌含量进一步降低,并维持合适的籽粒铁、锰含量。     

河北省土壤硫含量、形态与分布

对河北省主要土壤类型耕层硫含量进行了分析测定。结果表明 ,河北省土壤全硫平均含量为 250.1mg/kg(50～940mg/kg)。土壤全硫平均含量以沼泽土最高 ,灰色森林土最低 ;土壤有效硫平均含量为 46.1mg/kg ,以沼泽土最高 ,红粘土和栗褐土最低。土壤硫主要以有机态存在 ,占全硫含量的 81.6% ;无机态硫占 18.4%。按土类划分土壤无机硫含量最高的是沼泽土 ,灰色森林土最低 ;土壤有机硫含量也以沼泽土最高 ,灰色森林土最低。土壤全硫含量主要受土壤有机质含量、阳离子代换量和土壤碳酸钙含量的影响。根据土壤硫供应水平计算 ,全省约有20.4%的土壤缺硫 ,北部缺硫面积较大 ,南部缺硫面积较小。根据土壤有效硫含量多寡 ,可把全省土壤硫含量划分为极缺乏区、缺乏区、中等区、丰富区及极丰富区 5类     

小麦籽粒Zn、Fe、Mn、Cu含量的基因型和环境差异及与产量关系的研究

小麦籽粒中微量营养元素含量的高低直接关系到植株的生长发育和人们的饮食健康。本研究以来自河南省5个地区的17个小麦品种(系)为材料,采用酸消解-原子吸收分光光度法测定了籽粒中Zn、Fe、Mn、Cu含量,分析了籽粒微量元素含量的基因型和环境差异及其与产量性状的相关关系。结果表明,小麦籽粒Zn、Fe、Mn、Cu含量分别为38.39±12.57μg·g-1、79.13±49.45μg·g-1、35.24±11.72μg·g-1和4.84±0.78μg·g-1,籽粒Fe含量的变异系数最大,Cu含量的变异系数最小。方差分析表明,基因型、环境以及基因型与环境的互作对籽粒微量元素含量的影响均达极显著水平。对于籽粒Zn、Mn、Cu含量,环境因素的影响起主要作用;对于籽粒Fe含量,基因型与环境互作的影响是主要的。依照Eberhart-Russell模型分析了籽粒微量元素含量的品种稳定性,结果表明籽粒微量元素含量相对稳定的品种,其含量通常较低;在参试17个品种中,"濮99084"籽粒微量元素含量的环境稳定性较高。相关分析表明,籽粒微量元素含量与蛋白质含量呈遗传正相关,与千粒重呈遗传负相关,与产量呈表型正相关,表明同步提高籽粒微量元素含量、蛋白质含量及籽粒产量是可行的。     

Mehlich‐I soil‐test calibration for watermelon: Cu,Zn, and Mn

Abstract

Predictive soil tests were used to detect possible need for Cu, Zn, and Mn fertilizers for the optimum production of watermelons (Citrullus lanatus (Thumb.) Masf.) in north and central Florida. Predictive Mehlich‐I soil testing indicated a possible response to additions of Mn and Cu but not to additions of Zn at three locations: Gainesville, Dunnellon, and Live Oak. Results showed no total marketable yield response to selected Cu, Zn, and Mn treatments at any of the three sites. Yields for the Gainesville, Dunnellon, and Live Oak sites were 41.5, 29.0, and 38.0 Mg/ha, respectively, well above the state average watermelon yield of 19.0 Mg/ha. Tissue analyses at the Gainesville and Live Oak sites showed Cu, Zn, and Mn levels within or above suggested sufficiency ranges. This study indicates that current University of Florida interpretations for the Mehlich‐I extractant can identify sites with adequate extractable Cu, Zn, and Mn levels, thus avoiding unnecessary fertilization. At no time were University of Florida Cu, Zn, or Mn interpretations and recommendations found to be limiting for watermelon production.     

The flux of Cd,Cu, Pb and Zn in mining polluted soils

The monitoring of heavy metal deposition onto soils surrounding old Pb-Zn mines in two locations in the UK has shown that relatively large amounts of Cd, Pb, Zn and, in one case, Cu are entering the soil annually. Small particles of ore minerals in windblown mine tailings were found to be contributing up to 1.46 g m^?2 yr^?1 of Pb, 1.41 g m^?2 yr^?1 of Zn and 0.027 g m^?2 yr^?1 of Cd. However, when these inputs from bulk deposition are compared with the concentrations of the same metals within the soil profiles it is apparent that relatively little long-term accumulation is occurring. Metals are being lost from the soil profiles, probably through leaching. A calculated relative retention parameter gave values that ranged from 0.01 to 0.17 for Cd, 0.11 to 0.19 for Zn, 0.32 to 0.63 for Cu and over 1 for Pb. These relative retention values were found to follow the order of electronegativity of the elements concerned: Pb>Cu>Zn>Cd. Distribution coefficient (Kd) values quantifying the adsorptive capacity of the mine soils for Cd and Pb showed marked differences for the two metals (12 to 69 cm³ g^?1 for Cd and 14 to 126 cm³ g^?1 for Pb) and may, in part, account for the two to one hundred-fold variation in the relative retention parameter for the different metals within these soils.     

鸡粪等有机肥料的养分释放及对土壤有效铜、锌、铁、锰含量的影响

采用室内培养法研究鸡粪、牛粪和猪粪等畜禽有机肥料的矿化率和速效氮、磷、钾养分释放特性,并探讨施用有机肥料对土壤有效铜、锌、铁、锰含量的影响。结果表明,鸡粪、牛粪和猪粪等畜禽有机肥料当季(120d)有机碳矿化率分别为87．5％、71．9％和55．4％,碱解氮释放量分别为39．9％、20．6％和35．3％,速效磷释放量分别为24．6％、61．3％和34．8％,速效钾释放量分别为78．8％、36．8％和41．5％。供试条件下土壤有效铜、锰含量增加,但有效锌含量降低,施用鸡粪可使土壤有效铁含量增加,而施用牛粪和猪粪则使土壤有效铁含量降低。     

鸡粪等有机肥料的养分释放及土壤有效铜、锌、铁、锰含量的影响

采用室内培养法研究鸡粪、牛粪和猪粪等畜禽有机肥料的矿化率和速效氮、磷、钾养分释放特性,并探讨施用有机肥料对土壤有效铜、锌、铁、锰含量的影响.结果表明,鸡粪、牛粪和猪粪等畜禽有机肥料当季(120d)有机碳矿化率分别为87.5%、71.9%和55.4%,碱解氮释放量分别为39.9%、20.6%和35.3%,速效磷释放量分别为24.6%、61.3%和34.8%,速效钾释放量分别为78.8%、36.8%和41.5%.供试条件下土壤有效铜、锰含量增加,但有效锌含量降低,施用鸡粪可使土壤有效铁含量增加,而施用牛粪和猪粪则使土壤有效铁含量降低.     

黄土高原地区长期施用微肥土壤Cu、Zn、Mn、Fe含量的时空变化

以19年微肥定位试验为基础,研究了长期施用微肥条件下冬小麦土壤Cu、Zn、Mn、Fe含量的时空变化。结果表明,长期施用微肥能增加土壤耕层相应微量元素含量,施铜肥的土壤耕层有效Cu含量增加5倍以上;施锌肥的土壤耕层有效Zn含量增加3.58倍。从剖面变化看,不同处理土壤有效Cu的变化趋势一致,且耕层以下各土层有效Cu含量低于耕层,土壤有效Zn的变化趋势与之相似;土壤有效Mn在80cm土层含量较高,80cm以上以及下面的土层中Mn含量明显低于80cm土层,在土壤剖面上有效Mn存在淋溶和累积现象。施用不同微肥对土壤有效Fe含量的影响各不相同。     

Human health risk assessment associated with Co,Cr, Mn,Ni and V contents in agricultural soils from a Mediterranean site

Potentially toxic element contents in agricultural soils were assessed by comparison with levels recorded in the literature and evaluated using Index of Geoaccumulation (I_geo). The model recommended by United States Environment Protection Agency is applied for the health risk assessment from different exposure pathways. The median values of cobalt (Co), chromium (Cr) and nickel (Ni) exceeds about 2, 3 and 14 times, respectively, the corresponding values given by the Geochemical Atlas of Europe project, however, they present low potential ecological risk. The median values of manganese (Mn) and vanadium (V) are slightly lower than the corresponding values given by the Geochemical Atlas of Europe project. Risk assessment results present negligible health risk to children and adults due to manganese (Mn), nickel (Ni) and vanadium (V) exposure through ingestion of contaminated soil. Only the cobalt (Co) hazard quotient (HQ) and hazard index (HI) for children around two sampling sites exceed the acceptable safe risk level.     

氮肥对啤酒大麦Zn、Mn、Fe、Mo营养效应的研究

以黄褐土为基质进行盆栽试验。结果表明,啤酒大麦植株体内Ｚｎ、Ｍｎ、Ｆｅ、Ｍｏ含量、积累量及其吸收速率等,因施Ｎ水平及生育期的不同而差异很大,从而影响其产量和品质。经统计分析,以施Ｎ０．０８～０．１２ｇ／ｋｇ土为最佳。     

Comparison of mehlich 1 and mehlich 3 extractants for P,K, Ca,Mg, Mn,Cu and Zn in atlantic coastal plain soils

Abstract

The Mehlich 3 (M3) extractant was introduced in 1981 to improve the efficiency of soil testing laboratories by eliminating the need for multiple extractants for P, K, Ca, Mg, Mn, Cu and Zn. The M3 was also intended to be suitable for a wide range of soils, perhaps to serve as a “universal”; soil test extractant. At present, regional soil testing committees throughout the U.S. are investigating the M3 in this regard.

Development of a field calibration data base for a new soil testing extractant is an essential, but expensive and time‐consuming process. An interim measure is the use of conversion equations between new and current extractant(s). These equations allow for use of the new extractant with existing field calibration data. The objectives of this study were (i) to develop conversion equations for the Mehlich 1 (M1) and M3 extractants for Atlantic Coastal Plain soils, and (ii) to determine the influence of soil pH and organic matter content on the relative extractability of P, K, Ca, Mg, Mn and Zn by Ml and M3.

Four hundred soil samples, obtained from field plots and commercial crop samples submitted to the University of Delaware Soil Testing Laboratory were analyzed for P, K, Ca, Mg, Mn, Cu and Zn by M1 and M3. Highly significant correlations between M3 and M1 were found for all nutrients (r=0.92*** to 0.97***) and, except for Cu and Mn, soil pH and OM did not markedly improve the linear regression equations developed for conversion between M3 and M1. Inclusion of OM in a multiple regression equation between M3 and M1 extractable Cu increased R² from 0.46** to 0.71***; R² for Mn+(pH+OM) was 0.48***, relative to 0.35*** for extractable Mn alone. Critical values for M3 P, K, Ca, and Mg, based on conversion equations restricted to soils testing less than high with the M1 extractant, were 41, 49, 295 and 45 mg.dm^‐3, respectively. For Mn and Zn, at a pH of 6.2, M3 critical values were 9.5 and 0.6 mg.dm^‐3, while for Cu, the M3 critical value ranged from 0.5 to 1.1 mgdm^‐3 for soil OM of 2 to 8%.     

The efect of Zinc (Zn) application on the available Iron (Fe) contents of calcareous soils in thrace region

This research was carried out in order to determine the effect of zinc (Zn) application on the available iron (Fe) contents of calcareous soils in Thrace Region. For this purpose, an experiment was carried out in greenhouse conditions by maize growing. The effect of increasing rates of Zn application on the biological indices of maize plant was determined. Fe concentration of maize plant decreased with Zn application and dry matter yield and Fe uptake of maize plant increased with Zn application. These decreases and increases were determined to be statistically significant (P<0.01).