The composition of humus in permafrost-affected soils of the Bol’shezemel’skaya and Kolyma tundra areas

Tundra soils (except for the soils of barren circles) in the moderately and extremely continental tundra areas are characterized by the pronounced surface accumulation of humic substances. The humate-fulvate nature of humus is typical of the upper horizons of surface eluvial-gley soils, gley soils, and raw-humus mountainous brown soils; the C ha/C fa ratio in them varies from 0.5 to 0.91. The fulvate-humate nature of humus (C ha/C fa = 1.27–1.50) is typical of cryozems and sandy podburs. The first and the third fractions of humic substances (hs 1 and hs 3) predominate in the composition of humus. The coefficients of correlation (R) between the major parameters of soil humus and the physicochemical characteristics of tundra soils have been calculated. These coefficients between the contents of C org, C ha, C fa, C ha1, and C ha3 and the total acidity are equal to 0.73, 0.76, 0.72, 0.85, and 0.67, respectively; for the exchangeable Mg²⁺, their values are equal to 0.66, 0.88, 0.85, 0.74, and 0.90, respectively; and for the exchangeable Ca²⁺, 0.55, 0.47, 0.39, 0.41, and 0.61, respectively (p < 0.05). The composition of exchangeable cations and the total acidity specify the conditions of fractionation of humic substances in the studied soils. The differentiation of the qualitative composition of humus in the profiles of tundra soils is well pronounced and is mainly controlled by the distribution of clay and fine silt particles.     

Relationships between parameters of the humus status of forest and meadow soils and their altitudinal position on the main Crimean range

The influence of bioclimatic conditions related to the elevation above sea level on the quantitative and qualitative parameters of humus in mountain soils has been studied. It is shown that changes in the water and temperature conditions with the altitude do not exert significant effect on the humus content in mountain- forest soils, because the total amount of soil organic matter mainly depends on the composition and state of the vegetation cover. The humus content is the highest in meadow soils formed on mountain plateau with excessive moistening, which determines the formation of dense grass cover and the temperature regime favorable for humification. The percentage of Cha in the composition of Corg and the optical density of humic acids (HAs) are the qualitative parameters of the soil humus status changing with the altitude. The intensity of humus coloring of the soil depends on the content and optical density of HAs. A comparison of color intensity in the mountainous meadow chernozemlike soils and plain chernozems has shown its significant dependence on the hydrothermic conditions.     

阿尔泰山区土壤有机碳氧化稳定性的初步比较分析

以阿尔泰山区土壤为研究基础,初步比较分析了山地土壤有机碳的氧化稳定性,及垂直变化规律,认为土壤的Kos值具有一定的垂直地带性;并认为在今后的土地开发利用中,应遵从其规律,做到合理地利用土地资源。     

Humus in paleosols of archaeological monuments in the dry steppes of the Volga-Don interfluve

Traditional chemical methods and ¹³C-NMR spectroscopy were used to study the humus in chestnut paleosols buried under kurgans of different ages (the 16th–15th centuries BC; the 1st, 2nd–3rd, and 13th–14th centuries AD) and under the Anna Ioanovna Rampart (1718–1720) and in their recent analogues on virgin plots. It was found that the decrease in the humus content of the paleosols as a result of the diagenetic processes is exponentially related to the age of the soil burial. The loss of humus from the upper 30 cm of the paleosol buried 3500 yrs ago amounted to 76 ± 14%, and this system did not reach a stationary state. The constants of the humus mineralization in the paleosols were determined. A tendency for an increase in the degree of the organic matter humification in the chestnut soils during the past 3500 yrs was found. With an increase in the age of the burial, the portion of aromatic structures in the structure of the humic acids increased and the portion of aliphatic fragments decreased. The cyclic changes in the composition of the humus related to the secular variations in the climatic humidity were identified.     

Soil organic matter accumulation, litter decomposition and humus forms under mediterranean-type forests in southern Tuscany, Italy

The amount of organic matter and rate of litter decomposition in relation to vegetation type under mediterranean-type forests in southern Tuscany was studied. Since existing concepts are largely based on studies of soils on calcareous substrates in this region, particular attention was paid to soils on non-calcareous materials. The humus type and distribution at five sites on acid metamorphic rocks and at one site on dolomitic limestone with different vegetation types was investigated. The input of above-ground litter was also determined. On the metamorphic rocks, clear trends in humus profile development could be observed from deciduous through sclerophyllous to coniferous vegetation: there was a decrease in litter nitrogen content (9.3 to 5.8 g N kg^?1 DM), an increase in the amount of organic matter in ectorganic layers (2.53 to 4.66 kg m^?2), a decrease in the decay constant k (0.26 ± 0.02 to 0.17 ± 0.03 a^?1), and a decrease in soil faunal activity. The results indicate that, under eu-mediterranean to sub-mediterranean forests, decomposition rates are comparable to those under temperate deciduous forests, and that the dominant humus form is a leptomoder. The spatial variation in the amount of organic matter within the plots was considerable, and was related to vegetation type.     

Assessment of degradation and generation of humus in a coffee soil affected by weed cover by means of a stable carbon isotopic ratio

We evaluated the effect of soil conservation by weeds on the degradation and generation of humic acids, fulvic acids, and water‐soluble non‐humic substances (WS‐NHS) in a red‐acid soil (Vertic Dystrudept) (Indonesia) from the changes in humus composition and stable carbon isotopic ratio (δ¹³C). Three plots, a weeded plot (T‐1; the common practice), a plot covered with Paspalum conjugatum Berg., a C₄ plant (T‐2), and a plot in which native weeds were allowed to grow (T‐3), were prepared. An incubation experiment determined the δ¹³C values of the humus fractions generated from Paspalum in soil. Based on the increase in δ¹³C value, the proportion of total C that originated from Paspalum C after 4 years under coffee was 16 ± 4% in the T‐2 topsoil (0–10 cm). Humic and fulvic acids in the T‐1 topsoil decreased to 46 and 84%, respectively, whilst both increased or remained constant in the T‐2 and T‐3 soils. The WS‐NHS content varied little and was independent of land management. The preferential loss of the humic acids with a smaller degree of humification as assessed by their darkness in colour was shown in T‐1. The decrease in the degree of humification suggested the accumulation of the weed‐derived humic acids in T‐2 and T‐3. In the T‐2 topsoil, 36 ± 2%, 13 ± 3% and 15 ± 2% of C in the humic acids, fulvic acids and WS‐NHS, respectively, were estimated to be Paspalum‐derived after 4 years. The estimated initial C loss during the same period was 17 ± 3%, 14 ± 2% and 7 ± 2%, respectively, for those fractions, which suggests the fastest turnover rate for the humic acids and significant retardation of their degradation in soil colonized by weeds.     

Bodenatmung,Stickstoffmineralisation und Humusabbau ostafrikanischer Böden nach Trocknung und Wiederbefeuchtung

Soil respiration, nitrogen mineralization and humus decomposition of East African soils after drying and remoistening Soil respiration and nitrogen mineralization of 51 East African cultivated, savanna and forest soils were compared after 3 and 21 weeks of air drying. The average soil respiration after 21 weeks of drying was 1.221 ± 0.106 times higher than that after 3 weeks of drying whereas the average nitrogen mineralization was not increased significantly (factor 1.132 ± 0.256). The increase in soil respiration was correlated positively with the water soluble organic matter. During air dryings of 3 days and moist incubations of 4 days at 30°C, which were repeated 20 times in 10 soils, 3–10% of the organic carbon and 8–19% of the organic nitrogen (low humus vertisol 69%) were mineralized. Changes in the amount and the extinction of humic and fulvic acids were considered to be indicative for an increased humification during the drying and remoistening of soils.     

Assessment of phosphate solubility in forest and highly fertilized Andisols and Andic soils

Abstract

Phosphate solubility in Andisols and Andic soils (forest and fertilized) has been studied in soil solutions at two soil:solution ratios (1:2.5 and 1:25). Forest soils approached the variscite solubility (pIAP=30.4±0.3) while fertilized soils were closer to the amosphous analog of variscite (pIAP= 29.8±0.2). In some samples, phosphorus (P) activities were consistent with simultaneous equilibrium between aluminum (Al) and iron (Fe) phosphates. The dilution ratio, DR=10(P)_1:25/(P)_l:25, was 10.0±0.4 for all samples. This suggests a dissolution of phosphate minerals attaining apparent saturation in 24 h. However, the high content of dissolved organic carbon and Al in aqueous extracts also pointed to the existence of soluble ternary complexes of P with Al(Fe)‐humus complexes. These results could be consistent with simultaneous control between the dissolution of variscite‐like minerals and humus‐Al(Fe)‐P associations. Nevertheless, DR seems a valuable criterion to assess soil P status, especially in fertilized soils with high active Al and Fe contents.     

太白山山地土壤的腐殖质研究

土壤腐殖质的含量和组成是区分土壤肥沃程度的一项重要指标,也是划分土类的一个主要依据。在水平方向上,由于气候、植被、母质等诸成土因子的变化,形成了各个不同的土壤带。已经表明,表征土壤发生发育的腐殖质组成特性也呈现出明显的地带性差别。在高差较大的山区,随着海拔高度的增加,气温逐渐下降,湿度不断增加,植被由一个群落被另一个群落所取代,土壤呈垂直带分布。Ассинг(1960)曾指出,山地土壤腐殖质的含量和组成具有与平地土壤不同的特点。我们对太白山北坡山地土壤的腐殖质研究也证实了这一现象。本文即报道这方面工作的结果。     

The microbial biomass and its activity and structure in the soils of old forests in the European Russia

The humus-accumulative layer of soils (podzolic, gray, rzhavozem, burozem, and karbolitozem) of old-age forests (>60–450 years old) localized in various vegetation subzones (middle-taiga, southern taiga, subtaiga, dark coniferous forests outside the boreal region, and mountain forests) of the European part of Russia (22 sites of soil sampling of them, 13 in nature reserves and specially protected territories) was studied. The carbon content of the microbial biomass (C_mic) in the soil was determined by the substrate-induced respiration method. The fungal to bacterial ratio was determined by the selective inhibition technique with antibiotics. The basal respiration (BR) was also measured. The BR/C_mic = qCO₂ ratio and the portion of C_mic in the total organic soil carbon was determined. It was shown that the C_mic and BR in the soils of a separate vegetation subzone varied significantly; however, their values increased from the middle-taiga to dark coniferous subzone and decreased in the mountain-forest zone (348 ± 44, 670 ± 66, 1000 ± 86, 1142 ± 49, 789 ± 79 μkg C/g soil and from 0.68 ± 0.23, 1.85 ± 0.10, 2.13 ± 0.15, 1.56 ± 0.14, 0.92 ± 0.07 μkg CO₂-C/soil h, respectively). The fungal component in the humus-accumulative layer of soils is 53–99% of the total Cmic; however, its absolute values increase from the middle subzone to the southern one. The Cmic pool and the total BR in the profile of some soils (mineral horizons and forest litter) were calculated.     

Specificity of soil hydrolytically microbial complex under different moisture conditions

It has been established that soil moisture has a significant impact on the activity of chitinolytic microbial processes, rather than pectinolytic processes. The degradation of polysaccharides with an increase in soil moisture in microbial complex markedly increases the role of prokaryotic microorganisms, especially actinomycetes. For the first time, using the FISH method, the amount of detected phylogenetic composition of a metabolically active hydrolytic complex of humus horizons of grey forest and gley and weakly podzolic soil and humus has been estimated depending on the humidity. At optimum moisture, phylogenetic groups Actinobacteria and Firmicutes dominated in the chitinolytic process. An increase in the proportion of proteobacteria is observed with an increase in humidity. The role of gamma- and alphaproteobacteria and actino-bacteria is heightened with the drying of soil in the hydrolytic complex. A quantitative estimate of the rate of degradation of polysaccharides (pectin and chitin) in different types of soils at different levels of moisture is given. The dependence of the phylogenetic composition of an active microbial hydrolytic complex of humus horizons of grey forest and gley, weakly podzolic soils and humus on humidity is revealed.     

Impact of ski pistes on soil properties: a case study from a mountainous area in the Mediterranean region

In this study, soils on 17 ski pistes in the Sierra Nevada, Spain, were investigated to identify changes induced by ski management practices and also to determine the effectiveness of grass seeding in restoring soil quality. When compared with unaffected reference soils, those of ski runs had substantial loss of organic carbon (?34%, ?11.9 ± 3.6 t ha^?1) and micropore volume and size (?33%, ?0.07 ± 0.01 cm³ cm^?3 and ?48%, ?1.62 ± 0.28 μm). Microstructure showed a dramatic reduction in organic cements and fungal hyphae. The organic content of soil seeded with grass significantly improved compared with soil not seeded or seeded unsuccessfully (P < 0.05), especially where the topsoil was reinstated. Organic C content, microporosity and soil respiration increased by 200% (+21 ± 5 t ha^?1), 70% (+0.07 ± 0.03 cm³ cm^?3) and 140% (+0.10 ± 0.04 mg CO₂ g^?1 day^?1), respectively. Average micropore size in aggregates which in undisturbed soils was 3.40 ± 0.28 μm reverted to 3.52 ± 0.36 μm. However, the microstructure of the revegetated soils did not attain the levels of organic cements and fungal hyphae in the natural soils. Dolomite and salts were added to the soil to aid slope stabilization, fertility and de‐icing of access tracks. As a consequence, there were increases in pH, exchangeable sodium percentage (ESP), electrical conductivity, calcium carbonate equivalent and base saturation. The influence of management on soil properties was found to be greater than that of environmental factors.     

Reconstruction of the paleotemperature and precipitation in the Pleistocene according to the isotope composition of humus and carbonates in loess on the Russian Plain

The isotope composition of carbon and oxygen in humus and carbonates has been studied in the Pleistocene loess and soil of the Russian Plain in order to reconstruct the paleoclimatic parameters during the time of their formation. It is established that most of the buried soils were formed upon the mean annual temperature exceeding the modern temperature by 1–2°C. The climate aridity (the portion of C4 plants in the ecosystem) varied from 0 to 25%. It is shown that the isotope composition of carbon and oxygen in the humus and carbonates may be a reliable indicator of the paleoclimate (i.e., the paleotemperature, paleoprecipitation, and aridity dynamics). An isotope procedure of culling soil samples unsuitable for paleoclimatic reconstruction is proposed.     

Soils of the subtaiga landscapes on the northern spurs of the Tsagan-Daban Ridge in the Selenga Mountains

The soil cover patterns in the subtaiga landscapes on the northern spurs of the Tsagan-Daban Ridge in the Selenga Mountains have been studied. Gray-humus lithozems and bedrock outcrops are typical of the steep south-facing slopes under herbaceous pine forests. Soddy iron-illuvial podburs are formed under forest vegetation on gentle slopes of northern and western aspects with a thick mantle of loose colluvial deposits. Dark-humus metamorphic soils occur on the slopes of western and northwestern aspects below 700 m a.s.l. under secondary forb-grassy communities that replaced the initial herbaceous pine forests. Windblown hollows (yardangs) are occupied by humus psammozems under steppe pine forests. The morphological and physicochemical characteristics of these soils are discussed in the paper.     

云南省森林土壤腐殖质组分特征及影响因素

云南省森林生态系统在全球碳循环及平衡中具有不可替代的作用,但其森林土壤腐殖质组分特征及其影响因素尚不十分清楚。基于云南省不同林区采集的88个表层土样,通过描述性统计和回归分析量化了海拔、土壤类型、坡向和坡度、年均温和年降水量对土壤腐殖质组分分布影响的相对重要性,探讨云南省森林土壤腐殖质组分分布特征。结果表明:云南省森林土壤表层有机碳含量为8.40～199.73 g·kg^–1,平均含量为51.37 g·kg^–1,土壤可提取腐殖质碳含量为2.54～84.02 g·kg^–1,平均含量为24.52 g·kg^–1;胡富比均值小于1,土壤腐殖质聚合度较低;土壤腐殖质组分分布特征总体表现为滇西北、滇东北部较高,滇中、滇南部较低;土壤类型、海拔、年均温是影响云南省森林土壤腐殖质组分含量的主导因子,各因素的贡献程度总体呈现为土壤类型最高,其次是年均温、海拔,这说明土壤类型对森林表层土壤腐殖质的积累起重要作用。     

Soil organic carbon in density fractions of tropical soils under forest – pasture – secondary forest land use changes

Our knowledge of effects of land use changes and soil types on the storage and stability of different soil organic carbon (SOC) fractions in the tropics is limited. We analysed the effect of land use (natural forest, pasture, secondary forest) on SOC storage (depth 0–0.1 m) in density fractions of soils developed on marine Tertiary sediments and on volcanic ashes in the humid tropics of northwest Ecuador. The origin of organic carbon stored in free light (< 1.6 g cm^?3) fractions, and in two light fractions (LF) occluded within aggregates of different stability, was determined by means of δ¹³C natural abundance. Light occluded organic matter was isolated in a first step after aggregate disruption by shaking aggregates with glass pearls (occluded I LF) and in a subsequent step by manual destruction of the most stable microaggregates that survived the first step (occluded II LF). SOC storage in LFs was greater in volcanic ash soils (7.6 ± 0.6 Mg C ha^?1) than in sedimentary soils (4.3 ± 0.3 Mg C ha^?1). The contribution of the LFs to SOC storage was greater in natural forest (19.2 ± 1.2%) and secondary forest (16.6 ± 1.0%) than in pasture soils (12.8 ± 1.0%), independent of soil parent material. The amount of SOC stored in the occluded I LF material increased with increasing silt + clay content (sedimentary soils, r = 0.73; volcanic ash soils, r = 0.58) and aggregation (sedimentary soils, r = 0.52; volcanic ash soils, r = 0.45). SOC associated with occluded I LF, had the smallest proportion of new, pasture‐derived carbon, indicating the stabilizing effect of aggregation. Fast turnover of the occluded II LF material, which was separated from highly stable microaggregates, strongly suggested that this fraction is important in the initial process of aggregate formation. No pasture‐derived carbon could be detected in any density fractions of volcanic ash soils under secondary forest, indicating fast turnover of these fractions in tropical volcanic ash soils.     

Characteristics of dissolved organic matter and phenolic compounds in forest soils under silver birch (Betula pendula), Norway spruce (Picea abies) and Scots pine (Pinus sylvestris)

The aim was to characterize dissolved organic matter in soils under different tree species. Molecular size distribution and chemical composition of dissolved organic carbon and nitrogen were determined in water extracts from humus layers and mineral soils taken from silver birch ( Betula pendula Roth.), Norway spruce ( Picea abies (L.) Karst.) and Scots pine ( Pinus sylvestris L.) stands. Concentrations of tannins and 15 phenolic acids in the humus layers were measured. Per unit of organic matter, the concentrations of dissolved organic C and N were larger in birch and spruce humus layers than in the pine humus layer. In the underlying mineral soil, the concentrations of dissolved organic C were similar at all sites, but the concentration of dissolved organic N was greater in spruce and pine soils than in birch soil. In all soils, the 10–100 kDa fraction was the most abundant molecular size group and hydrophobic acids the most abundant chemical group of dissolved organic C. In all humus layers, hydrophobic acids and hydrophilic bases were the major components of dissolved organic N. There were only minor differences in the concentrations of total tannins in the humus layers under different tree species. Small-molecule tannins (about < 0.5 kDa) were most abundant in the birch humus, and large-molecule tannins in the pine humus. Coniferous humus contained more ferulic and p -coumaric acids than did the birch humus. The concentrations of 3,4 and 3,5-dihydroxybenzoic acid, vanillic acid and 4-hydroxybenzoic acid were similar in all soils.     

Difference in the pH values of hydromorphic soils in field and laboratory analyses

There are marked differences in the pH values determined in water suspension under laboratory conditions and in soil solution under field conditions in hydromorphic soils (gleysols and stagnosols). The value δpH = pH_susp–pH_sol can be either positive or negative. Among the main factors that affect the value of δpH are the laboratory preparation of soil samples and the suspension effect. The sign of the pH effect (value of δpH) depends on the participation of humus, carbonate, and exchange bases in the formation of aggregates destructed in the laboratory. The value of δpH is negative in noncalcareous soils with low content of exchangeable bases and fulvate composition of humus and positive in calcareous soils or soils enriched with exchangeable bases and humate composition of humus. In cases of a significant δpH effect, the value of pH_susp cannot be regarded as an adequate measure of soil acidity.     

Composition and Characteristics of Organo—Mineral Complexes of Red Soils in South China

The objective of the present study is to reveal the composition and characteristics of organo-mineral complexes in red soils (red soil,lateritic red soil and latosol) of south China in terms of chemical dissolution and fractional peptization methos.In the combined humus,most of the extractable humus could dissolve in 0.1 M NaOH extractant and belonged to active humus (H1),and there was only a small amount of humus which could be further dissolved in 0.1 M Na4P2O7 extractant at pH 13 and was stably combined humus (H2).The H1/H2 ratio ranged from 3.3 to 33.8 in red soils,and the proportions of both H1 and total extractable organic carbon (H1 H2) in total soil organic carbon and the ratios of H1 to H2 and H1 to (H1 H2) were all higher in lateritic red soil and latosol than in red soil.The differences of combined humus composition in various red soils were directly related to the content of Fe and Al oxides.In organo-mineral complexes,the ratio of Na-dispersed fraction (G1) to Na-ground-dispersed fraction (G2) was generally smaller than 1 for red soils,but there was a higher G1/G2 ratio in red soil than in lateritic red soil and latosol.G1 fraction had a higher content of fulvic acid (FA),but G2 fraction had a higher content of humic acid (HA).The ratios of H1 to H2 and HA to FA were higher in G2 than in G1.The differences in the composition and activity of humus between G1 and G2 fractions were related to the content of free Fe and Al oxides.The quantities of complex Fe and Al,the Fe/C and Al/C atomic ratios were higher in G2 than in G1,and the ratio of Al/C was much higher than that of Fe/C.It may be deduced that aluminum plays a more important role than iron in the formation process of organo-mineral complexes in red soils.     

Temperature field of complex soilscapes (by the example of the Vladimir opolie region)

Problems of the assessment of soil temperature regime at the polypedon level have yet to be solved. An approach suggested by the authors consists of three stages: (1) the characterization and prediction of the soil water regime as a factor influencing the soil temperature regime, (2) the obtaining of thermophysical functions for the particular elements of complex soilscapes, and (3) the calculation and assessment of the temperature regime of complex soilscapes in the form of the functional fields of soil temperature isopleths. This approach has been applied to predict the soil temperature regime of an arable field in the Vladimir opolie region. The complex soilscape of the field consists of medium loamy agrogray soils, agrogray soils with the second humus horizon, and podzolized agrogray soils. At the beginning of the growing season, minimum temperatures are observed in the areas of agrogray soils with the second humus horizon; the difference in soil temperatures at a depth of 20 cm reaches 1°C, and the difference in the sum of active soil temperatures reaches 20°C. Then, this difference changes considerably, so that the agrogray soils with the second humus horizon become warmer than the agrogray soils. In general, the functional field of soil temperatures within the complex soilscape is highly dynamic and diverse, which is specified by the variability in the water-physical and thermophysical properties of particular soils.