Risk analysis of pesticides applied to rice paddies using RICEWQ 1.6.2v and RIVWQ 2.02

Rice is commonly cultivated in Southern Europe in large river basins where the extensive use of herbicides may impact water quality at basin scale level. Consequently, pesticide risk assessment would be more relevant when considering a rice cultivation area as a whole. Accordingly, two watershed-scale scenarios were developed to represent the specific agronomic, water and pesticide management practices of rice cultivation in Greece. These scenarios were utilized for the parameterization of the rice water quality model (RICEWQ) 1.6.2v and the surface water model river water quality (RIVWQ) 2.02. in order to predict the environmental concentrations of pesticides in groundwater (GW) and surface water (SW) systems within a rice area. The annual average pesticide concentrations at 1 m depth, predicted by RICEWQ were used to assess the risk for GW contamination. The predicted exposure concentrations derived through modelling and eco-toxicological endpoints obtained from the literature, were used to calculate acute and long-term toxicity exposure ratios (TERs) for aquatic organisms. Application of these scenarios with RICEWQ and RIVWQ models enabled us to perform a risk assessment exercise for several herbicides registered in Greece for use in rice. Such a risk assessment approach could be further scaled up to represent a whole rice cultivated basin in order to be used for regulatory purposes.     

Risk assessment of pesticides in paddy fields and the Safīdrūd River in Gīlān,Iran

Safīdrūd River is the longest river in northern Iran and serves 2.5 million people as a water resource for drinking, irrigation, pisciculture, and recreation. To evaluate the fate of pesticides in paddy fields on the Safīdrūd river bank and the Safīdrūd basin, a comprehensive model is developed in this paper to predict pesticide concentration. The model includes degradation and sorption to soil in paddy field and two-dimensional turbulent with degradation in river. To investigate the effects of pesticides on health, an inclusive risk assessment is defined by parameters such as the maximum annual prediction environmental concentration and mean prediction environmental concentration of pesticides in the intake zone of the Safīdrūd river for the Rasht water treatment plant. The risk quotient of all pesticides were higher than 1 (i.e., for Diazinon it was calculated to be 670) which indicate high risk in the Rasht potable water and can potentially cause various digestive cancers and other refractory and mutagenic diseases. As a result, it is necessary to codify the global planning of pesticide application in the paddy fields by the local government.     

The development of a coupled model (PCPF-SWMS) to simulate water flow and pollutant transport in Japanese paddy fields

A new coupled model (PCPF–SWMS) was developed for simulating fate and behavior of pollutant in paddy water and paddy soil. The model coupled the PCPF-1, a lumped model simulating pesticide concentrations in paddy water and 1 cm-surface sediment compartment, and the SWMS-2D, a finite element numerical model solving Richard's and advection-dispersion equations for solute transport in soil compartment. The coupling involved improvements on interactions of the water flow and the concentration the pollutant of at the soil interface between both compartments. The monitoring data collected from experimental plots in Tsukuba, Japan in 1998 and 1999 were used to parameterise and calibrate hydraulic functioning, hydrodynamic and hydrodispersive parameters of the paddy soil. The analysis on the hydraulic functioning of paddy soil revealed that the hard pan layer was the key factor controlling percolation rate and tracer transport. Matric potential and tracer monitoring highlighted the evolution of saturated hydraulic conductivity (K _S) of hard pan layer during the crop season. K _S slightly decreased after puddling by clay clogging and strongly increased after mid term drainage by drying cracks. The model was able to calculate residential time in every soil layers. Residential time of tracer in top saturated layers was evaluated to be less than 40 days. It took 60 days to reach the unsaturated layers below hardpan layer.     

Pesticide discharge and water management in a paddy catchment in Japan

Concentrations of several pesticides were monitored in a paddy block and in the Kose river, which drains a paddy catchment in Fukuoka prefecture, Japan. Detailed water management in the block was also monitored to evaluate its effect on the pesticide contamination. The concentrations of applied pesticides in both block irrigation channel and drainage canal increased to tens of μg/L shortly after their applications. The increase in pesticide concentrations was well correlated with the open of irrigation and drainage gates in the pesticide-applied paddy plots only 1–3 days after pesticide application. High concentration of other pesticides, mainly herbicides, was also observed in the inflow irrigation and drainage waters, confirming the popularity of early irrigation and drainage after pesticide application in the area. The requirement of holding water after pesticide application (as a best management practice) issued by the authority was thus not properly followed. In a larger scale of the paddy catchment, the concentration of pesticides also increased significantly to several μg/L in the water of the Kose river shortly after the start of the pesticide application period either in downstream or mid–upstream areas, confirming the effect of current water management to the water quality. More extension and enforcement on water management should be done in order to control pesticide pollution from rice cultivation in Japan.     

Model development for surface drainage loading estimates from paddy rice fields

A field experiment was performed at two Korean research sites to evaluate water and nutrient behavior in paddy rice culture operations for 2 years. One site was irrigated with groundwater, whereas the other site was irrigated with surface water. Both sites received average annual rainfall of about 1,300 mm, and about 70–80% of it was concentrated during July–September coinciding with rice growing season. Although most of the nutrient outflow was attributed to plant uptake, nutrient loss by surface drainage was substantial. The simplified computer model, PADDIMOD, was developed to simulate water and nutrient behaviors in the paddy rice field. The model predicts daily ponded water depth, surface drainage, and nutrient concentrations. It was formulated with a few equations and simplified assumptions, but its application and a model fitness test indicated that the simulation results reasonably matched the observed data. It is a simple and practical planning model that could be used to evaluate nutrient loading from paddy rice fields alone or in combination with other complex watershed models. Further validation might be required for general application of the PADDIMOD to the simulation of paddy rice fields with various agricultural environments.     

Future potential impacts of climate change on agricultural watershed hydrology and the adaptation strategy of paddy rice irrigation reservoir by release control

This study is to assess the climate change impact on the temporal variation of paddy rice irrigation reservoir water level from the future evaluated watershed inflow, and to suggest an adaptation method of the future reservoir water level management for stable water supply of paddy irrigation demands. A 366.5 km² watershed including two irrigation reservoirs located in the upper middle part of South Korea was adopted. For the future evaluation, the SLURP model was set up using 9 years daily reservoir water level and streamflow records at the watershed outlet. The average Nash-Sutcliffe model efficiencies for calibration and validation were 0.69 and 0.65, respectively. For the future climate condition, the NIES MIROC3.2 hires data by SRES A1B and B1 scenarios of the IPCC was adopted. The future data were downscaled by applying Change Factor statistical method through bias-correction using 30 years past weather data. The results of future impact showed that the future reservoir storages of autumn and winter season after completion of irrigation period decreased for 2080s A1B scenario. Considering the future decrease of summer and autumn reservoir inflows, the reservoir operation has to be more conservative for preparing the water supply of paddy irrigation, and there should be a more prudent decision making for the reservoir release by storm events. Therefore, as the future adaptation strategy, the control of reservoir release by decreasing in August and September could secure the reservoir water level in autumn and winter season by reaching the water level to almost 100% like the present reservoir water level management.     

Dissolved nitrogen model for paddy field ponded water during irrigation period

Based on an experimental field study in Japan, a model was developed to simulate dissolved nitrogen in water ponded in a paddy field. As input data, the model uses meteorological data, water balance in the field, nitrogen concentration in inlet water, and the nitrogen contribution of applied fertilizer. Five model parameters need calibration. A practical application of the model is the simulation of NH₄-N and NO₂₊₃-N concentrations in water ponded in a paddy field. The model improves our understanding of the interactions between forms of dissolved nitrogen in ponded water and can explain the complex changes in dissolved nitrogen concentrations in water ponded on a paddy field.     

Effect of N-fertilizer application on return flow water quality from a terraced paddy field in Northern Taiwan

Intensive use of chemical fertilizer for crops may be responsible for nitrogen and phosphate accumulation in both groundwater and surface waters. The return flow polluted by nutrients not only results in the limitation of water reuse goals but also creates many environmental problems, including algal blooms and eutrophication in neighboring water bodies, posing potential hazards to human health. This study is to evaluate the N-fertilizer application of terraced paddy fields impacting return flow water quality. Water quality monitoring continued for two crop-periods around subject to different water bodies, including the irrigation water, drainage water at the outlet of experimental terraced paddy field, and shallow groundwater were conducted in an experimental paddy field located at Hsin-chu County, Northern Taiwan. The analyzed results indicate that obviously increasing of ammonium-N (NH₄ ⁺-N) and nitrate-N (NO₃ ^?-N) concentrations in the surface drainage water and ground water just occurred during the stage of basal fertilizer application, and then reduced to relatively low concentrations (<0.1 mg/l and <3 mg/l, respectively) in the remaining period of cultivation. The experimental results demonstrate the potential pollution load of nitrogen can be reduced by proper drainage water control and fertilizer application practices.     

Fuzzy optimization model for integrated management of total nitrogen loads from distributed point and nonpoint sources in watershed

A fuzzy optimization model is developed to allocate allowable total nitrogen (T-N) loads to distributed nonpoint sources (NPSs) and point sources (PSs) in a watershed for river water quality management using the linear programing technique. The watershed is divided into uniform grid cells on which T-N loads issuing from NPSs such as paddy fields, upland crop fields and cities are controlled. A geographic information system integrated with the digital elevation model facilitates computation of route lengths of surface and subsurface flows from cells to a river running through the watershed. The T-N loads discharged from their sources are assumed to decay, subject to distance-related first-order kinetics. As management goals, maximizations of total allowable NPS loads, total allowable PS loads and total yield of rice are considered from environmental and economic viewpoints. A prime constraint is an effluent limitation standard for the aggregate amount of loads that arrive at the downstream end of the river. The fuzzy sets theory helps appropriately describe vague attitudes of decision-makers (i.e., stakeholders and management authorities) in terms of constraints and conflicting goals. An application of the fuzzy optimization model, developed as an improvement over our last nonfuzzy model, to a real watershed in Shiga prefecture, Japan, demonstrates that the fuzzy model embodies our last model, and is capable of creating management alternatives for T-N load allocation in a more practical and flexible manner.     

The role of synthetic pesticides in the intensification of highland agriculture in Thailand

The objective of this study is to quantify the relationship between synthetic pesticide use and agricultural intensification in the northern highlands of Thailand. We surveyed the crop management decisions of 295 farmers across 12 villages, and assessed the level of pesticide use in terms of monetary value, the active ingredients used, and using the Environmental Impact Quotient method. The results show that 77% of the farmers relied solely on synthetic pesticides for their pest management activities. The average farmer used 13.3 kg of active ingredients per hectare of agricultural land, but the variation was large. The highest levels of pesticide use were observed with the cultivation of cut flowers and greenhouse vegetables, while greater land use intensity was associated with increased usage of synthetic pesticides and a greater potential environmental impact. We found that those farmers following public certification of Good Agricultural Practices (Q-GAP), were neither able to reduce pesticide use nor its environmental impact. The findings suggest that to limit the environmental impact caused by the use of synthetic pesticides, greater priority must be given to developing and promoting non-synthetic methods of pest control together with gradually restricting the supply of highly hazardous pesticides.     

Effects of Applying Potassium,Zeolite and Vermiculite on the Radiocesium Uptake by Rice Plants Grown in Paddy FieldSoils Collected from Fukushima Prefecture

Abstract

Radionuclides were released into the environment as a consequence of the Fukushima Daiichi Nuclear Power Plant accident that occurred on 11 March 2011. Radiocesium at an abnormal concentration was detected in brown rice produced in paddy fields located in northern part of Fukushima Prefecture. We examined several hypotheses that could potentially explain the excessive radiocesium level in brown rice in some of the paddy fields, including (i) low exchangeable potassium content of the soil, (ii) low sorption sites for cesium (Cs) in the soil, and (iii) radiocesium enrichment of water that is flowing into the paddy fields from surrounding forests. The results of experiments using pots with contaminated soil indicated that the concentration of radiocesium in rice plants was decreased by applying potassium or clay minerals such as zeolite and vermiculite. The obtained results indicated that high concentrations of radiocesium in rice are potentially a result of the low exchangeable potassium and sorption sites for Cs in the soils. Application of potassium fertilizer and clay minerals should provide an effective countermeasure for reducing radiocesium uptake by plants. Radiocesium-enriched water produced by leaching contaminated leaf litter was used to irrigate rice plants in the cultivation experiments. The results indicated that the radiocesium concentrations in rice plants increased when the radiocesium-enriched water was applied to the potted rice plants. This indicated the possibility that the radiocesium levels in brown rice will increase if the nuclide is transported with water into the rice paddy fields from surrounding forests.     

水稻田表水磷素的动态特征及其潜在环境效应的研究

通过独立排灌式磷肥大田试验探讨了水稻田表水磷素的动态特征及其潜在的环境效应。研究发现, 施入磷肥增加了田表水磷素水平, 首次水样总磷水平为0.201～ 1.301 mg/kg, 溶解磷水平为0.058～ 0.926 mg/kg; 在等量施磷的条件下, 与单施无机磷肥比较, 有机无机磷配施能显著地提高田表水磷素水平; 在首次采样的一周之内, 两者总磷水平相差达3.85～1.89 倍, 但随着时间的推移, 因施磷结构的不同导致田表水磷素水平的差异逐渐缩小并趋于一致。任一次田间排水都存在诱发附近水域水体富营养化的可能。从减少磷素流失的角度出发, 在施磷灌水后约一周之内或田间耘田时, 田间排水磷素流失潜能增大, 另外, 还要避免在雨水集中的季节施用磷肥。     

Seasonal characteristics of surface water quality in the wastewater catchment system of an urbanizing basin

Vientiane, Lao PDR, has been subject to extensive and ongoing urbanization plans, including development of natural marshes and residentialization of paddy fields into suburban areas, despite natural marshes playing a vital role in treating wastewater from urban areas. Therefore, it is important to understand the current situation regarding the nutrient balance in these natural wastewater treatment systems to predict future conditions and design appropriate measures against water quality deterioration. However, limited data are available in Vientiane on the hydrological characteristics of water and nutrient runoff that flow into marshes through drainage canals. In this study, we conducted a periodic survey of drainage canals and Mak Hiao River in the wastewater catchment system surrounding Vientiane during the rainy and dry seasons. We monitored the discharge of surface water at 21 observation sites and analyzed water quality of nitrogen, phosphorus, and total organic carbon. These observations revealed that the concentrations of dissolved nitrogen and phosphorus were significantly higher at sites in urban areas, followed by sites in the main river basin and those in agricultural areas. Dissolved nitrogen and phosphorus concentrations varied with runoff discharge, especially in urban and river basin sites, with lower concentrations in the rainy season and higher concentrations in the dry season. On the other hand, we found no significant differences between the rainy and dry seasons in nutrient concentrations in the agricultural basin. Finally, we proposed measures to counteract the deterioration of water quality during dry seasons and simulated the impact of these measures.     

Factors driving growers’ selection and implementation of an apple crop protection strategy at the farm level

While protecting their crops, apple growers must also satisfy the requirements of their buyers regarding pesticide residues and fruit characteristics. Based on an analysis of farm pesticide application schedules and semi-structured interviews of 35 apple growers in two areas of France, this study described how growers designed and implemented their apple protection strategies, and identified the factors which helped and/or prevented them from using less pesticide. Different combinations of economic and environmental concerns led to three main protection strategies. Growers implementing the bio-ecological strategy (S1) had high environmental concerns, used no synthetic pesticides, and compensated their lower yields with high selling prices. Growers implementing the combined strategy (S2) had moderate environmental concerns. They planted scab-resistant varieties and sprayed natural products, while diversifying their outlets and cultivars to compensate for low selling prices. The low risk strategy (S3) was implemented by growers from cooperatives with low environmental concerns who aimed for high yields and visual quality by using mainly synthetic pesticides. S2 and S3 growers were constrained by low selling prices and by the increased workload and economic risks represented by alternative methods. Extending the range of alternatives to pesticides and implementing innovative advice methodologies could be levers to reduce pesticide use.     

Terraced paddy field rainfall-runoff mechanism and simulation using a revised tank model

Terraced paddy fields play important roles in water and soil conservation because their water storage effect reduces and delays flood peaks. This study applies the terraced paddy field rainfall-runoff mechanism to the tank model. Though the traditional four-section tank model can easily simulate rainfall-runoff in a terraced paddy field, it has many parameters that are difficult to calibrate. To address the shortcomings of the traditional four-section tank model, this study develops a revised tank model to simulate rainfall-runoff. This study selects a terraced paddy field located in Hsuing-Pu village in Hsiuing-Chu County as the experimental field. The field under investigation was equipped with automatic monitoring stations, water-stage, and rain gauges. These stations collected data on rainfall and water flow to simulate the rainfall-runoff model in that region. To simulate the runoff behavior of the experimental terraced paddy field, two rainfall events were selected from the gathered data and five normal evaluation indexes based on static and hydrological theory were applied to calculate the results of simulation simultaneously. The revised tank model performed better than expected, and precisely predicted the variations and trends in flow charge. Comparison with representation indexes proved that the revised tank model is an appropriate and valuable tool for rainfall-runoff simulation.     

Combining multi-source data to explore a mechanism for the effects of micrometeorological elements on nutrient variations in paddy land water

Paddy land plays a key role in global crop production. Thus, paddy land water is a potential source of nitrogen and phosphorus; both nutrients largely contribute to non-point source pollution because they usually vary closely with micrometeorological elements (MEs) during the growth period. However, few studies have focused on the mechanism of co-variation between nutrients and MEs at the field scale. The relationships between nutrients in the paddy land water and MEs as well as soil water content, soil temperature, and the normalized difference vegetation index (NDVI) are still unclear. In this paper, an in situ experiment was designed to obtain 5 years of meteorological data and nutrient data (nitrogen and phosphorus); the size of the experiment plot is in accordance with the spatial resolution of NDVI data. Multi-source meteorological and satellite data were integrated to explore the mechanism of co-variation. The results show that precipitation, air temperature, and solar radiation are the three MEs significantly affecting the nitrogen concentration in the paddy land water during the growth period. The air temperature is the most important ME influencing the phosphorus concentration. At the same time, the NDVI, as an effective indicator of the photosynthetic potential of rice used to explore the relationship between nutrients, has a prominent influence on soluble nutrients, especially on dissolved phosphorus. These findings could significantly improve our understanding about the responses of paddy land nutrients during the growth period to the surrounding drivers, inclusive of MEs, soil water, soil temperature, and NDVI. Undoubtedly, it is a potentially helpful means to monitor the sources of non-point pollution.     

A distributed hydro-environmental watershed model with three-zoned cell profiling

A cell-based distributed watershed model is developed which enables us to simulate the hydrological and hydraulic aspects of the watershed in a refined fashion. With three-zoned cell profiling, the model is composed of three sub-models; tank model for a surface water zone, soil moisture model for a surface soil zone, and unconfined shallow groundwater flow model for a subsurface zone. Inclusion of the soil moisture sub-model modified to reroute the infiltration, routed from the tank sub-model, into the return flow and the groundwater recharge features the model. The groundwater flow sub-model, numerically approximated by use of the finite volume method and the implicit time-marching scheme, considers a network of on-farm drainage canals as internal boundaries, which is an essential need for modeling the watershed including farmlands. Cascade-linking of the three sub-models in a cell and assembling of all the cells over the entire watershed domain provides the global equations system to be solved. Applicability of the model is demonstrated with its practical application to a real watershed in that paddy and upland crop fields take great part of the land-use practice. It is then indicated in a quantified manner that rice farming significantly contribute as a major groundwater recharger in an irrigation period to fostering and conservation of regional water resources. Along with appropriately profiling a cell, the model is so versatile and tough that it can be applied without difficulty to a watershed of diverse terrains and land-uses and the computations can stably be carried out. It is thus concluded that the model presently developed could be a powerful “watershed simulator” to investigate and assess the time-varying hydro-environmental properties of a watershed while separating and integrating the hydrological and hydraulic components of particular importance.     

A model driven by crop water use and nitrogen supply for simulating changes in the regional yield of rain-fed lowland rice in Northeast Thailand

Climate change will have significant impacts on the rain-fed rice production ecosystem, and particularly on the ecosystem’s hydrology and water resources. Under rain-fed lowland conditions, substantial variations among fields in grain yield are commonly observed, but a method that can account for field-scale yield variability to produce regional-scale yield estimates is lacking, thereby limiting our ability to predict future rice production under changing climate and variable water resources. In this study, we developed a model for estimating regional yields of rain-fed lowland rice in Northeast Thailand, by combining a simple crop model with a crop calendar model. The crop model incorporates the effects of two important resources (water and nitrogen) on crop growth. The biomass accumulation is driven by water use, whereas the nitrogen supply determines canopy development and thereby constrains crop water use. Accounting for the wide range of planting dates and the strong photoperiod-sensitive characteristics of rice varieties through the calendar model is an essential component in determining regional yield estimates. The present model does not account for the effects of mid-season drought or flooding, but was nonetheless able to explain the spatial and temporal yield variations at the province level for the past 25 years. Thus, it can be used as a prototype for simulating regional yields of rain-fed lowland rice.     

新疆玉米有害生物发生、施药现状及减药对策分析

通过问卷调查、走访种植大户及田间实地调查等方式,对新疆玉米主产区玉米有害生物发生与用药情况进行系统调查,明确新疆玉米有害生物发生种类、农药使用水平,分析存在问题并提出相应减药对策,从而为新疆玉米有害生物的科学防控及化学农药增效提供指导。结果表明,新疆玉米主要病害6种、害虫36种、杂草38种,主要以"6虫6草"为主。玉米有害生物防治常用农药共26类,其中杀虫剂14类,主要为拟除虫菊酯类、新烟碱类及生物源类;除草剂12类,主要为三氮苯类、磺酰脲类及酰胺。农药使用频次为2～6次/年,制剂施用量为1.938～6.193 kg/hm~2,其中,昌吉州农药使用频次和制剂施用量最高,分别为5～6次/年、4.033～6.193 kg/hm~2;喀什地区农药使用频次和制剂施用量最低,分别为2～3次/年、1.938～3.356 kg/hm~2。     

排草丹除草剂在水稻上残留动态研究

 报道了48％排草丹水剂在水稻上的残留分析方法及稻田生态环境中残留消解动态试验研究，计算出排草丹在稻株、土壤和水中降解半衰期。每亩施用3.0 m1，兑水50 kg,在杂草2～3叶期喷施一次，距收期60天,稻谷中排草丹及其代谢产物的最终残留量低于最低检出浓度0．02 mg／kg。