共查询到20条相似文献,搜索用时 62 毫秒
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Moghimi SM Hunter AC Murray JC Szewczyk A 《Science (New York, N.Y.)》2004,303(5658):626-8; author reply 626-8
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The sialic acid-containing glycosphingolipids known as gangliosides can reverse the heat stabilization of DNA by histones. The ability of pure mono-and disialogangliosides to dissociate reconstituted nucleohistone is directly dependent on their sialic acid content; they are effective in concenitrations above their critical micelle concentration. 相似文献
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S J O'Brien D Goldman J Knight H D Moore D E Wildt M Bush R J Montali D Kleiman 《Science (New York, N.Y.)》1984,223(4641):1127-1128
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反胶束是表面活性剂是非极性溶剂中形成的与正常胶束结构相反的含水聚合体。反胶束技术可用于非极性体系中极性物质的分离,也可用于酶的固定化,目前主要用于生物大分子物质的分离,是一种新型的生物分离技术。就该技术的原理、方法、应用及最新研究进展进行了介质。 相似文献
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Although solution self-assembly of block copolymers (BCPs) represents one of the most promising approaches to the creation of nanoparticles from soft matter, the formation of non-centrosymmetric nanostructures with shape anisotropy remains a major challenge. Through a combination of crystallization-driven self-assembly of crystalline-coil BCPs in solution and selective micelle corona cross-linking, we have created short (about 130 nanometers), monodisperse cylindrical seed micelles that grow unidirectionally. These nanostructures grow to form long, non-centrosymmetric cylindrical A-B and A-B-C block co-micelles upon the addition of further BCPs. We also illustrate the formation of amphiphilic cylindrical A-B-C block co-micelles, which spontaneously self-assemble into hierarchical star-shaped supermicelle architectures with a diameter of about 3 micrometers. The method described enables the rational creation of non-centrosymmetric, high aspect ratio, colloidally stable core-shell nanoparticles in a manner that until now has been restricted to the biological domain. 相似文献
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The problem of how rubber is synthesized in the plant has been divided into two portions: (i) the nature of the monomer used and how this monomer is synthesized, and (ii) the nature of the polymerization reaction by which the monomer is transformed to rubber. With respect to the first, the monomer appears to be the 5-carbon branched-chain compound beta-methylcrotonic acid or a derivative thereof. This substance is synthesized in the plant from acetyl-coA. With respect to the second, no information is available, since polymerization of the 5-carbon monomer units to polymers has not yet been achieved outside the living plant. 相似文献
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为了建立植物血凝素(PHA)的最佳反胶束萃取工艺;根据单因素考察结果,采用正交试验法对花菜豆中植物血凝素(PHA)的提取工艺进行研究.结果表明,琥珀酸二辛脂磺酸钠(AOT)浓度是主要影响因素,其次为萃取时间和NaCl浓度;最佳前萃取条件AOT浓度为0.05 g·mL-1,NaCl浓度为0.10mol·L-1,搅拌提取5... 相似文献
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Self-organized supramolecular organic nanostructures have potential applications that include molecular electronics, photonics, and precursors for nanoporous catalysts. Accordingly, understanding how self-assembly is controlled by molecular architecture will enable the design of increasingly complex structures. We report a liquid crystal (LC) phase with a tetragonal three-dimensional unit cell containing 30 globular supramolecular dendrimers, each of which is self-assembled from 12 dendron (tree-like) molecules, for the compounds described here. The present structure is one of the most complex LC phases yet discovered. A model explaining how spatial arrangement of self-assembled dendritic aggregates depends on molecular architecture and temperature is proposed. 相似文献
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以正庚烷-正丁醇-大豆卵磷脂配制反胶束,做了增溶不同量Tris—HCl缓冲液的试验.结果表明:增溶不同水量的反胶束体系稳定性不一样,每3mL增溶40-90μL缓冲液的反胶柬体系光密度在0—300s内不断变化,透明澄清的稳定反胶束体系分布在每3mL增溶0~40μL及90~130μL2个区间.增溶水量较少时,反胶束增溶含蛋白质与不含蛋白质水相的体系之间存在差别.在水-正庚烷-正丁醇-大豆卵磷脂反胶束体系中未发现核糖核酸酶A1(RNase A1)的超活性. 相似文献
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By combining three mutually immiscible polymeric components in a mixed-arm star block terpolymer architecture, we have observed the formation of a previously unknown class of multicompartment micelles in dilute aqueous solution. Connection of water-soluble poly(ethylene oxide) and two hydrophobic but immiscible components (a polymeric hydrocarbon and a perfluorinated polyether) at a common junction leads to molecular frustration when dispersed in aqueous solution. The incompatible hydrophobic blocks form cores that are protected from the water by the poly(ethylene oxide) blocks, but both are forced to make contact with the poly(ethylene oxide) by virtue of the chain architecture. The structures that emerge depend on the relative lengths of the blocks and can be tuned from discrete multicompartment micelles to extended wormlike structures with segmented cores. 相似文献
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Parker BC 《Science (New York, N.Y.)》1963,140(3569):891-892
Experiments with C(14)-labeled bicarbonate demonstrate that organic products of photosynthesis are transported through the stipe tissue of Macrocystis. Depending upon conditions, not all of which have been fully ascertained, the direction of transport may be either predominantly apical or toward the base of the plant. 相似文献