Effect of Stabilized Rice Bran Fractions on the Formation of Rice Flour Pasting Properties

Rice flour composition played a key role in determining the changes in pasting properties of rice flour. The influence of incorporating defatted rice bran (DFRB), rice bran fiber (RBF), rice bran protein (RBP), and stabilized rice bran (SRB) fractions on the mechanism of rice flour pasting viscosities was investigated. Pasting properties of long‐ and medium‐grain rice flour substituted with 5, 10, 15, 20, and 100% bran fractions resulted in a significant decrease (P < 0.05) in rice flour pasting property values. Flour substituted with RBP had the lowest pasting property measurements compared with other fractions, and the greater the percentage substituted, the lower the pasting property values. DFRB and RBF were least affected properties when used as a replacement. Results were attributed to the contribution of rice starch in the mechanism of rice paste formation, in which decreasing starch in a rice flour sample, as a result of substituting with fractions of SRB, may have resulted in faster swelling of starch granules to the maximum extent and increased their susceptibility to be disrupted by shear, resulting in low paste viscosities. Results also suggested that protein structural integrity and the nature of starch–protein bonding affected rice flour pasting mechanism formation.     

Effect of Alkaline‐Soluble Proteins on Pasting Properties of Nonwaxy Rice Flour

The pasting properties of rice flours and reconstituted rice flours from mixing a common starch with proteins extracted from different rice cultivars at different total protein content levels were studied. Results showed that not only the total protein content but also the protein composition had an effect on the pasting properties of the rice flours. Among the different strands of rice proteins, globulin had the strongest influence on the pasting properties, followed by glutelin, whereas prolamin had the least influence. At the subunit level of the proteins, proteins with a molecular weight of 17,000, most likely from globulin, had the strongest effect on the peak viscosity of the rice flour, followed by those of 33,000. In comparison with that of the rice starch, the influence of proteins in rice was limited. The effect of interactions between the rice proteins and the starch, such as the role of starch‐granule‐associated proteins, was not isolated in this study, and further investigation is required to quantify this effect.     

Albumin Significantly Affects Pasting and Textural Characteristics of Rice Flour

The influence of albumin on the pasting and rheological properties of rice flour was investigated. Albumin was removed from the flour of three rice cultivars (Amaroo, Opus, and Langi) by water extraction and the pasting profile of the albumin‐depleted flour was analyzed using the Rapid ViscoAnalyser (RVA). Removal of albumin resulted in a significant (P < 0.5) decline in all the pasting parameters measured. When the extracted albumin was added to pure rice starch, exactly opposite trends occurred. The concentration of albumin in rice starch had a positive linear relationship with all pasting parameters measured. When the gels formed after RVA analyses were analyzed using the TA‐TX2 texture analyzer, the concentration of albumin had a positive linear relationship with hardness, but a near linear negative relationship with adhesiveness. The presence of albumin in rice starch slowed the uptake of water by starch in the initial stages of cooking, but the water uptake accelerated in later stages, and the final water absorption was higher in the samples containing albumin than in pure starch. The water‐soluble nature of albumin suggests that protein‐water‐starch interactions could be responsible for its effect on the physical properties of rice.     

Impact of Rice Flour Cold‐Water‐Soluble Fraction Removal on Gelatinization and Pasting Properties

The influence of the cold‐water‐soluble fraction on gelatinization and pasting properties of rice flour was investigated. The cold‐water‐soluble fraction was removed by water extraction under room temperature. The gelatinization properties of untreated and treated flour were analyzed with a differential scanning calorimeter, and pasting profiles were measured with a rapid viscosity analyzer. The removal of the cold‐water‐soluble fraction resulted in the formation of a loosened starch granule structure, a morphological alteration of protein bodies, a markedly lower gelatinization temperature, and a significantly higher pasting enthalpy. The impact on paste viscosity followed different trends. In some cultivars that had lower endogenous amylase activity, the paste viscosity was greatly reduced by the removal of the cold‐water‐soluble fraction. In others, the higher level of endogenous amylase activity led to more soluble saccharides being released through starch hydrolysis. Removing the soluble fraction caused a remarkable increase in peak viscosity. The overall effect on paste viscosity of removing the cold‐water‐soluble fraction was attributed to multiple factors, involving loosening of the starch granule structure, alteration of morphology of protein bodies, and the release of saccharides by endogenous amylase activity.     

Degree of Milling Effects on Rice Pasting Properties

The effects of degree of milling on pasting properties of medium‐grain (cv. Bengal and Orion) and long‐grain rice (cv. Cypress and Kaybonnet) were quantified using a Brabender ViscoAmylograph and a Rapid Visco Analyser. For all the cultivars tested, surface and total lipid contents decreased as the degree of milling increased. The peak viscosities for all rice increased with the degree of milling and the rates of increase were higher for medium‐grain than long‐grain cultivars. Degree of milling did not have a consistent effect on final viscosity for all the cultivars tested.     

Effect of Surfactant Structure on the Pasting Properties of Wheat Flour and Starch Suspensions

Systematic studies were performed on the effect of the surfactant alkyl chain length (10–16 carbon atoms) and the head group charge/structure (anionic, cationic, nonionic) on the pasting properties of wheat flour and starch aqueous suspensions by means of a Rapid Visco Analyser (RVA). An excellent agreement was observed between the effect of surfactants on the onset temperature of the pasting process (PT) and the time to reach peak viscosity (t_peak) of wheat flour and wheat starch suspensions. Moreover, a correlation was found between the effect of different surfactants on these two parameters. With the exception of the cationic surfactants (alkyl trimethyl ammonium bromides), the effect of surfactants (alkyl sulfates, maltosides, monoglycerides, and sucrose esters) was found to be strongly dependent on the surfactant chain length. Shorter chain surfactants (C10–C12) induced an earlier pasting, while longer chain surfactants (C14–C16) had the opposite effect. The effect of surfactants on PT and t_peak of flour suspensions was enlarged when the surfactant concentration was increased from ≈1% to 15% (w/w) on a dry starch basis.     

Pasting Process in Rice Flour Using Rapid Visco Analyser Curves and First Derivatives

The objective of these studies was to gain a better understanding of the pasting process in rice. We chose six different medium grain rice flour samples with amylose contents of 0.41–24.9% and protein contents of 4.89–10.65%. By using the first derivative of Rapid Visco Analyser (RVA) curves, changes in the pasting rates could be obtained. We found that samples containing low amylose contents (CM101 [CA] 0.41% amylose and 7.04% protein) exhibited a single smooth transition during pasting. Pastes from all other samples, M201 (TX), Nato (LA), Koshihikari (CA), Mercury (LA), and Nanking Sel (LA) with higher amylose contents (10.65–24.9%) underwent multiple phase transitions and rate changes before the peak viscosity. Disruption of disulfide linkages using dithiothreitol (DTT) led to a decrease in the rate of the single pasting step observed for CM101 (CA). Rice containing larger concentrations of amylose showed an increase in the first, but a decrease in subsequent steps. Our data suggests that amylopectin and protein are mutually important in the initialization of pasting in rice. At later stages of pasting, amylose and its complexes seem to become important.     

Prediction of Specific Japanese Sponge Cake Volume Using Pasting Properties of Flour

In Japanese soft wheat (Triticum aestivum L.) breeding programs, protein content (PC), and specific surface area (SSA) of flour have been used as important factors for the baking quality of Japanese sponge cake. We proposed batter pasting viscosity (BPV) as a parameter to predict the baking quality of Japanese sponge cake. BPV was measured using a Rapid Visco‐Analyser (RVA) with a modified heating profile. Twenty soft wheat samples from the 2006‐07 season and 22 from the 2007‐08 season, including Japanese soft wheat cultivars, advanced breeders' lines, and Western White (WW) imported from the United States, were milled and evaluated for solvent retention capacity (SRC) values of four solvents, batter pasting properties, flour pasting properties, PC, SSA, and specific cake volume (SCV) to investigate their relationships. BPV was the most strongly correlated of the parameters to SCV (r = –0.90, P < 0.001). Stepwise multiple regression analysis selected BPV and minimum viscosity (MV) of flour pasting as significant independent variables to predict SCV (corrected R² = 0.848). The variability in BPV related to cake batter expansion was highly explained by PC and sucrose SRC (corrected R² = 0.854, P < 0.001). MV was correlated to SSA (r = 0.56, P < 0.001) and might be related to the prevention of sponge cake shrinkage during baking.     

Rheological Properties of Fermented Rice Flour Gel

To clarify the rheological properties of fermented rice noodle (sour mifen) produced in South China, we studied the mechanical properties of gels made from fermented and nonfermented (control) rice flours using static tensile testing, two-bite testing, and dynamic viscoelastic measurement. Rheological measurement under large deformation showed that retrogradation in fermented rice gel proceeded more slowly than in nonfermented rice gel. Lower hardness and brittleness and higher cohesiveness and resilience (degree of recovery) for gels made from fermented rice flour demonstrated that the gel was less firm but more elastic and flexible. Storage moduli of both types of gel increased with time, but the starch retrogradation was suppressed for fermented rice gel. Fermented rice gel exhibited higher resilience and lower rigidity than nonfermented gel, thus the gel stability improved. The chemical analysis of both starches suggests that the partial hydrolysis of amylopectin occurred during the fermentation process.     

Impact of Proteins on Pasting and Cooking Properties of Nonparboiled and Parboiled Rice

The role of proteins in the pasting and cooking properties of non‐parboiled (npb) and parboiled (pb) rice was tested by means of a reducing agent dithiothreitol (DTT) and a protease (trypsin). DTT increased the swelling power and carbohydrate leaching of flour from npb rice flour but decreased its amylose leaching. Although DTT slightly increased the Rapid Visco Analyser (RVA) viscosity at the initial stages of the pasting process, it decreased RVA viscosity in the further phases of the experiment. Preincubation of flour with a trypsin decreased RVA viscosity along the whole temperature profile. Addition of DTT to the cooking water decreased water absorption and rice hardness and increased leaching of solids during cooking and stickiness of the cooked npb rice. Addition of DTT to the cooking water of flour from pb rice increased swelling power, carbohydrate leaching, and amylose leaching. Addition of DTT also increased RVA viscosity. Preincubation with trypsin had a similar effect but the changes were less pronounced. Addition of DTT increased stickiness of cooked pb rice and increased water absorption and leaching of solids during cooking. Taken together, the results provide evidence for the existence of a protein barrier affecting starch swelling, rheological, and cooking properties of both npb and pb rice.     

Effects of Added Minerals on Pasting of Partial Waxy Wheat Flour and Starch and on Noodle Making Properties

Mineral content, as determined and expressed by ash content, serves as an index of wheat flour quality for flour millers and food manufacturers who prefer flour of low mineral content, even though the significance of mineral content on the functional properties of wheat flour is not well understood. We explored whether minerals have any influence on the functional properties of wheat flour and product quality of white salted noodles. Ash, obtained by incinerating wheat bran, was incorporated into two hard white spring wheat flours and their starches to raise the total ash content to 1, 1.5, or 2%. Pasting properties were determined using a rapid visco analyzer (RVA). Addition of ash increased the peak viscosity of the flours in both water and buffer solution but did not affect the peak viscosity of starch. Wheat flours with added ash showed lower pasting temperature by approximately 10°C in buffer solution. Mineral extracts (15.3% ash) isolated from wheat bran, when added to increase the ash content of wheat flour and starch to 2%, increased the peak viscosity and lowered the pasting temperature of flour by 13.2–16.3% but did not affect the pasting properties of the isolated starch. The mineral premix also increased peak viscosity of wheat flour but not in starch. Added ash increased noodle thickness and lowered water retention of cooked noodles while it exhibited no significant effect on cooked noodle texture as determined using a texture analyzer.     

Key Proteins Causing Changes in Pasting Properties of Rice During Aging

Key components that cause changes in pasting properties of rice during storage aging were investigated in this work. The main nonstarch components in rice were sequentially removed from fresh and aged rice, the aging effect of the component was separated, and thus the aging contribution rate of the component (CACR) on rice aging could be deduced. The results showed that the largest contributor to rice aging was albumin with a CACR of 65%, followed by globulin and prolamin with the CACRs of 38 and 14%, respectively, and the CACR of glutelin was small (1%). In contrast, the CACRs of fat and crude starch were –7 and –11%, respectively. These findings suggest that albumin and globulin are predominantly responsible for changes in pasting properties of rice during storage aging. This conclusion directs future researchers to the changes occurring in albumin and globulin for disclosing the mechanisms of rice aging.     

A Comparative Study on Pasting and Hydration Properties of Native Rice Starches and Their Mixtures

Four rice starches were isolated from waxy and nonwaxy rice cultivars collected from different places in China. Individual rice starches were examined, along with their corresponding mixtures in different ratios, in terms of pasting and hydration properties. Analysis by micro‐viscoamylography (MVAG) showed that waxy rice starch and its blends had higher peak viscosity (PV), breakdown (BD), and setback (SB) than the remaining starches and mixtures. Apparent amylose content (AC) was 16.95–29.85% in nonwaxy individual rice starches and 13.69–25.07% in rice starch blends. Incorporating waxy rice starch (25%) significantly decreased the AC. AC correlated negatively with swelling power (SP) (r = ‐0.925, P < 0.01). SP exhibited nonlinear relationship (r² = 0.8204) with water solubility (WS) and both increased with temperature. The correlation showed that WS is also an index of starch characteristics and the granules rigidity affected the granule swelling potential. The results show that turbidity of gelatinized starch suspensions stored at 4 ± 0.5°C generally increased during storage up to five days.     

Effect of Storage on Fat Acidity and Pasting Characteristics of Wheat Flour

Two cultivars of wheat (Triticum aestivum L.), Sunco and Sunsoft, were used to study the influence of storage time and temperature on the formation of starch-lipid complexes in flour pastes. Untreated and fat-reduced whole meal flours were stored separately for up to 12 months at 4, 20, and 30°C. The stored samples were analyzed for fat acidity, pasting properties, and iodine binding values. Fat acidity increased significantly in the untreated flour samples stored at 30 and 20°C compared with 4°C. Starch pasting properties, as measured using a Rapid Visco Analyser (RVA) indicated that the final viscosity of untreated flour samples of both cultivars increased significantly with storage time and elevated temperature, and correlated positively with increased fat acidity. Iodine binding values of the RVA pastes decreased with storage time and elevated temperature, and correlated negatively with fat acidity and final viscosity. The fat-reduced Sunco and Sunsoft flours showed less pronounced changes compared with untreated flours, whereas small changes in the RVA parameters were noted in grains stored over 12 months. The results indicate that free fatty acids are released during storage and that they increase the potential for starch-lipid complex formation when stored whole meal wheat flours are pasted in the RVA. These changes were evident after two to three months of storage at 20 and 30°C.     

Starch Damage and Pasting Properties of Rice Flours Produced by Dry Jet Grinding

Milling method and particle size affect some properties of rice flour. To prepare ultra‐fine rice flour of <30 μm, hammer and dry jet grinding methods were examined and the effect of particle size on starch damage and pasting properties of the flour were elucidated. A jet mill could make finer flour (<10 μm mean size) with a narrower particle size distribution than a hammer mill could. Starch damage increased dramatically at a mean size of <10 μm. Particles of a similar size (<60 μm) had different levels of starch damage between mills. Not only the particle size, but also the milling method affected the level of damaged starch. Flour samples of ≥45 μm mean size had similar viscosity curves, but samples of <20 μm had different curves. Peak viscosity and final viscosity decreased sharply at <10 μm. Setback viscosity for particles of 3 μm from both brown rice and white rice were higher than the peak viscosity. Stability to heat and shearing stress were decreased for <20 μm flours as the breakdown viscosities decreased. Starch damage and pasting properties of flour ground from the nonwaxy japonica cultivar Koshihikari changed dramatically at a mean size of <10 μm.     

Environmental Influences on Flour Composition,Dough Rheology,and Baking Quality of Spring Wheat

The highly variable environmental conditions across the Pacific Northwest (PNW) influence the milling and baking quality of wheat grain produced in this region. This study was conducted to compare the flour composition, dough rheology, and baking quality of soft and hard spring wheat grain produced in diverse environments. Thirteen soft and five hard spring wheat cultivars were grown at Lind, WA (semiarid) and Fairfield, WA (high precipitation) for three years. Grain was evaluated for flour composition, rheology, and experimental baked product quality. Flour composition, rheological properties, and baking qualities were primarily influenced by the environment. Protein contents, microSDS values, and water absorption levels were significantly (P < 0.0001) higher for all cultivars grown at Lind compared with those from Fairfield. Cookie diameters were larger (P < 0.0001) for soft flours from Fairfield, whereas loaf volumes were higher (P < 0.0001) for hard wheat flours from Lind. Results indicate that producing soft or hard wheat outside of its optimal climatic zone reduces experimental baked product quality.     

Modeling Selected Properties of Extruded Rice Flour and Rice Starch by Neural Networks and Statistics

Rice flour and rice starch were single‐screw extruded and selected product properties were determined. Neural network (NN) models were developed for prediction of individual product properties, which performed better than the regression models. Multiple input and multiple output (MIMO) models were developed to simultaneously predict five product properties or three product properties from three input parameters; they were extremely efficient in predictions with values of R² > 0.95. All models were feedforward backpropagation NN with three‐layered networks with logistic activation function for the hidden layer and the output layers. Also, model parameters were very similar except for the number of neurons in the hidden layer. MIMO models for predicting product properties from three input parameters had the same architecture and parameters for both rice starch and rice flour.     

Effects of Inorganic Phosphates on the Thermodynamic,Pasting, and Asian Noodle‐Making Properties of Whole Wheat Flour

The effects of four inorganic phosphates on the thermodynamic and pasting properties of whole wheat flour as well as color, cooking quality, textural properties, and structural characteristics of whole wheat noodles were studied. The addition of phosphates increased the gelatinization temperature and enthalpy of melting of starch in whole wheat flour. Rapid visco analysis showed that all phosphates significantly increased whole wheat flour peak viscosity and final viscosity. Moreover, the whole wheat noodles prepared with disodium phosphate, trisodium phosphate, and sodium tripolyphosphate (STPP) exhibited brighter appearance, and the use of STPP and sodium hexametaphosphate reduced the cooking loss of whole wheat noodles. Texture profile analysis of cooked noodles revealed that the addition of phosphates significantly decreased the hardness and slightly increased the springiness, cohesiveness, and resilience. The microstructure of whole wheat noodles showed a larger degree of connectivity of the protein network and coverage of starch granules in the presence of inorganic phosphates. The results suggested that inorganic phosphates exhibited substantial effects on improving the quality of whole wheat noodles. Of the four phosphates studied, STPP appeared to be the most effective one in improving the overall properties of whole wheat noodles when they were normalized to constant phosphate content.     

Environmental Influences on Flour Quality for Sheeted Noodles in Idaho 377s Hard White Wheat

Production of common wheat (Triticum aestivum L.) in the Pacific Northwest of the United States specifically for Asian noodle products is a relatively new goal for grain producers. We surveyed commercial fields of the hard white spring wheat cultivar Idaho 377s in two years to determine the variables contributing to Asian noodle quality and to validate previous observations made with small‐plot research. Fields were surveyed in 1998 and 1999 in two areas of the Snake River Plain of southeastern Idaho separated by ≈100 km, with both irrigated fields and rain‐fed fields sampled in both zones. Samples were evaluated for grain characteristics then milled and evaluated for flour quality, alkaline noodle color, and color and texture of nonalkaline Chinese (salted, neutral pH) noodles. Grain from rain‐fed fields produced brighter and more yellow alkaline noodles than grain from irrigated fields. Grain produced in rain‐fed fields also had lower peak flour pasting viscosity than grain produced in irrigated fields. Flour ash was lowest in grain from rain‐fed fields located in a higher elevation district (Upper Valley) and greatest in grain from irrigated fields located in a lower elevation district (Lower Valley). Noodle hardness and chewiness were greater in Chinese noodles made from grain produced in the Upper Valley than grain from the Lower Valley. Chinese noodle color had significant interaction with the location and irrigation management used for producing the grain. However, Chinese noodle brightness was consistently negatively correlated with flour protein concentration. The color and texture of noodles produced from flours milled from on‐farm commercial production was consistent with previous experiment station small‐plot research.